Heterostructural $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ cathode materials of high performance for aqueous lithium-ion batteries
Abstract Manganese-based active materials, represented by $ LiMn_{2} %$ O_{4} $, are becoming the preferred sustainable cathode material for aqueous lithium-ion batteries. Here we designed and prepared the homologous heterogeneous $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ materials by adjusting the lithium...
Ausführliche Beschreibung
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| Autor*in: |
Meng, Jia-qi [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Ionics - Berlin : Springer, 1995, 28(2022), 12 vom: 07. Okt., Seite 5405-5413 |
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| Übergeordnetes Werk: |
volume:28 ; year:2022 ; number:12 ; day:07 ; month:10 ; pages:5405-5413 |
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| DOI / URN: |
10.1007/s11581-022-04773-3 |
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SPR048540145 |
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| 520 | |a Abstract Manganese-based active materials, represented by $ LiMn_{2} %$ O_{4} $, are becoming the preferred sustainable cathode material for aqueous lithium-ion batteries. Here we designed and prepared the homologous heterogeneous $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ materials by adjusting the lithium contents. Through the combined hydrothermal and sintering methods and using the polyvalent manganese compounds γ-MnOOH/$ Mn_{3} %$ O_{4} $ as self-template, the morphologic transformation and the evolution of microstructure heterostructure of $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ was confirmed. The homologous microstructure heterostructures can significantly affect the electrochemical properties through electrochemical measurement and physical characterization. The optimized sample inherited the hierarchical nano-micro morphology of the template exhibits high capacity, long cycle life, and superior rate capability, with initial discharge specific capacity of 109.9 mAh·$ g^{−1} $ at 1 C and capacity retention of 95.3% after 100 cycles, and which can work reliably at 10 C. Such superior electrochemical performance is attributed to $ Mn_{2} %$ O_{3} $/spinel multiphase composition, suitable crystal parameters, and high valence of Mn, which combines with the advantages of shrinking of the lattice structure to provide structural integrity and the heterostructure to facilitate the fast electrochemical kinetics. This study provides a simple method for the regulation of morphologies, polyvalent, and multiphase for lithium manganate cathodes, and enhances the understanding of their structure–activity relationship. | ||
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10.1007/s11581-022-04773-3 doi (DE-627)SPR048540145 (SPR)s11581-022-04773-3-e DE-627 ger DE-627 rakwb eng Meng, Jia-qi verfasserin aut Heterostructural $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ cathode materials of high performance for aqueous lithium-ion batteries 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Manganese-based active materials, represented by $ LiMn_{2} %$ O_{4} $, are becoming the preferred sustainable cathode material for aqueous lithium-ion batteries. Here we designed and prepared the homologous heterogeneous $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ materials by adjusting the lithium contents. Through the combined hydrothermal and sintering methods and using the polyvalent manganese compounds γ-MnOOH/$ Mn_{3} %$ O_{4} $ as self-template, the morphologic transformation and the evolution of microstructure heterostructure of $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ was confirmed. The homologous microstructure heterostructures can significantly affect the electrochemical properties through electrochemical measurement and physical characterization. The optimized sample inherited the hierarchical nano-micro morphology of the template exhibits high capacity, long cycle life, and superior rate capability, with initial discharge specific capacity of 109.9 mAh·$ g^{−1} $ at 1 C and capacity retention of 95.3% after 100 cycles, and which can work reliably at 10 C. Such superior electrochemical performance is attributed to $ Mn_{2} %$ O_{3} $/spinel multiphase composition, suitable crystal parameters, and high valence of Mn, which combines with the advantages of shrinking of the lattice structure to provide structural integrity and the heterostructure to facilitate the fast electrochemical kinetics. This study provides a simple method for the regulation of morphologies, polyvalent, and multiphase for lithium manganate cathodes, and enhances the understanding of their structure–activity relationship. Aqueous lithium-ion batteries (dpeaa)DE-He213 Li (dpeaa)DE-He213 Mn (dpeaa)DE-He213 O (dpeaa)DE-He213 Heterostructural (dpeaa)DE-He213 Multiple crystalline (dpeaa)DE-He213 Zhang, Jing-jia aut Lu, Dian-hong aut Wei, Zheng-baihe aut Yu, Fu-da aut Wang, Zhen-bo aut Enthalten in Ionics Berlin : Springer, 1995 28(2022), 12 vom: 07. Okt., Seite 5405-5413 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:28 year:2022 number:12 day:07 month:10 pages:5405-5413 https://dx.doi.org/10.1007/s11581-022-04773-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 28 2022 12 07 10 5405-5413 |
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10.1007/s11581-022-04773-3 doi (DE-627)SPR048540145 (SPR)s11581-022-04773-3-e DE-627 ger DE-627 rakwb eng Meng, Jia-qi verfasserin aut Heterostructural $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ cathode materials of high performance for aqueous lithium-ion batteries 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Manganese-based active materials, represented by $ LiMn_{2} %$ O_{4} $, are becoming the preferred sustainable cathode material for aqueous lithium-ion batteries. Here we designed and prepared the homologous heterogeneous $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ materials by adjusting the lithium contents. Through the combined hydrothermal and sintering methods and using the polyvalent manganese compounds γ-MnOOH/$ Mn_{3} %$ O_{4} $ as self-template, the morphologic transformation and the evolution of microstructure heterostructure of $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ was confirmed. The homologous microstructure heterostructures can significantly affect the electrochemical properties through electrochemical measurement and physical characterization. The optimized sample inherited the hierarchical nano-micro morphology of the template exhibits high capacity, long cycle life, and superior rate capability, with initial discharge specific capacity of 109.9 mAh·$ g^{−1} $ at 1 C and capacity retention of 95.3% after 100 cycles, and which can work reliably at 10 C. Such superior electrochemical performance is attributed to $ Mn_{2} %$ O_{3} $/spinel multiphase composition, suitable crystal parameters, and high valence of Mn, which combines with the advantages of shrinking of the lattice structure to provide structural integrity and the heterostructure to facilitate the fast electrochemical kinetics. This study provides a simple method for the regulation of morphologies, polyvalent, and multiphase for lithium manganate cathodes, and enhances the understanding of their structure–activity relationship. Aqueous lithium-ion batteries (dpeaa)DE-He213 Li (dpeaa)DE-He213 Mn (dpeaa)DE-He213 O (dpeaa)DE-He213 Heterostructural (dpeaa)DE-He213 Multiple crystalline (dpeaa)DE-He213 Zhang, Jing-jia aut Lu, Dian-hong aut Wei, Zheng-baihe aut Yu, Fu-da aut Wang, Zhen-bo aut Enthalten in Ionics Berlin : Springer, 1995 28(2022), 12 vom: 07. Okt., Seite 5405-5413 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:28 year:2022 number:12 day:07 month:10 pages:5405-5413 https://dx.doi.org/10.1007/s11581-022-04773-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 28 2022 12 07 10 5405-5413 |
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10.1007/s11581-022-04773-3 doi (DE-627)SPR048540145 (SPR)s11581-022-04773-3-e DE-627 ger DE-627 rakwb eng Meng, Jia-qi verfasserin aut Heterostructural $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ cathode materials of high performance for aqueous lithium-ion batteries 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Manganese-based active materials, represented by $ LiMn_{2} %$ O_{4} $, are becoming the preferred sustainable cathode material for aqueous lithium-ion batteries. Here we designed and prepared the homologous heterogeneous $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ materials by adjusting the lithium contents. Through the combined hydrothermal and sintering methods and using the polyvalent manganese compounds γ-MnOOH/$ Mn_{3} %$ O_{4} $ as self-template, the morphologic transformation and the evolution of microstructure heterostructure of $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ was confirmed. The homologous microstructure heterostructures can significantly affect the electrochemical properties through electrochemical measurement and physical characterization. The optimized sample inherited the hierarchical nano-micro morphology of the template exhibits high capacity, long cycle life, and superior rate capability, with initial discharge specific capacity of 109.9 mAh·$ g^{−1} $ at 1 C and capacity retention of 95.3% after 100 cycles, and which can work reliably at 10 C. Such superior electrochemical performance is attributed to $ Mn_{2} %$ O_{3} $/spinel multiphase composition, suitable crystal parameters, and high valence of Mn, which combines with the advantages of shrinking of the lattice structure to provide structural integrity and the heterostructure to facilitate the fast electrochemical kinetics. This study provides a simple method for the regulation of morphologies, polyvalent, and multiphase for lithium manganate cathodes, and enhances the understanding of their structure–activity relationship. Aqueous lithium-ion batteries (dpeaa)DE-He213 Li (dpeaa)DE-He213 Mn (dpeaa)DE-He213 O (dpeaa)DE-He213 Heterostructural (dpeaa)DE-He213 Multiple crystalline (dpeaa)DE-He213 Zhang, Jing-jia aut Lu, Dian-hong aut Wei, Zheng-baihe aut Yu, Fu-da aut Wang, Zhen-bo aut Enthalten in Ionics Berlin : Springer, 1995 28(2022), 12 vom: 07. Okt., Seite 5405-5413 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:28 year:2022 number:12 day:07 month:10 pages:5405-5413 https://dx.doi.org/10.1007/s11581-022-04773-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 28 2022 12 07 10 5405-5413 |
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10.1007/s11581-022-04773-3 doi (DE-627)SPR048540145 (SPR)s11581-022-04773-3-e DE-627 ger DE-627 rakwb eng Meng, Jia-qi verfasserin aut Heterostructural $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ cathode materials of high performance for aqueous lithium-ion batteries 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Manganese-based active materials, represented by $ LiMn_{2} %$ O_{4} $, are becoming the preferred sustainable cathode material for aqueous lithium-ion batteries. Here we designed and prepared the homologous heterogeneous $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ materials by adjusting the lithium contents. Through the combined hydrothermal and sintering methods and using the polyvalent manganese compounds γ-MnOOH/$ Mn_{3} %$ O_{4} $ as self-template, the morphologic transformation and the evolution of microstructure heterostructure of $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ was confirmed. The homologous microstructure heterostructures can significantly affect the electrochemical properties through electrochemical measurement and physical characterization. The optimized sample inherited the hierarchical nano-micro morphology of the template exhibits high capacity, long cycle life, and superior rate capability, with initial discharge specific capacity of 109.9 mAh·$ g^{−1} $ at 1 C and capacity retention of 95.3% after 100 cycles, and which can work reliably at 10 C. Such superior electrochemical performance is attributed to $ Mn_{2} %$ O_{3} $/spinel multiphase composition, suitable crystal parameters, and high valence of Mn, which combines with the advantages of shrinking of the lattice structure to provide structural integrity and the heterostructure to facilitate the fast electrochemical kinetics. This study provides a simple method for the regulation of morphologies, polyvalent, and multiphase for lithium manganate cathodes, and enhances the understanding of their structure–activity relationship. Aqueous lithium-ion batteries (dpeaa)DE-He213 Li (dpeaa)DE-He213 Mn (dpeaa)DE-He213 O (dpeaa)DE-He213 Heterostructural (dpeaa)DE-He213 Multiple crystalline (dpeaa)DE-He213 Zhang, Jing-jia aut Lu, Dian-hong aut Wei, Zheng-baihe aut Yu, Fu-da aut Wang, Zhen-bo aut Enthalten in Ionics Berlin : Springer, 1995 28(2022), 12 vom: 07. Okt., Seite 5405-5413 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:28 year:2022 number:12 day:07 month:10 pages:5405-5413 https://dx.doi.org/10.1007/s11581-022-04773-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 28 2022 12 07 10 5405-5413 |
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10.1007/s11581-022-04773-3 doi (DE-627)SPR048540145 (SPR)s11581-022-04773-3-e DE-627 ger DE-627 rakwb eng Meng, Jia-qi verfasserin aut Heterostructural $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ cathode materials of high performance for aqueous lithium-ion batteries 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Manganese-based active materials, represented by $ LiMn_{2} %$ O_{4} $, are becoming the preferred sustainable cathode material for aqueous lithium-ion batteries. Here we designed and prepared the homologous heterogeneous $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ materials by adjusting the lithium contents. Through the combined hydrothermal and sintering methods and using the polyvalent manganese compounds γ-MnOOH/$ Mn_{3} %$ O_{4} $ as self-template, the morphologic transformation and the evolution of microstructure heterostructure of $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ was confirmed. The homologous microstructure heterostructures can significantly affect the electrochemical properties through electrochemical measurement and physical characterization. The optimized sample inherited the hierarchical nano-micro morphology of the template exhibits high capacity, long cycle life, and superior rate capability, with initial discharge specific capacity of 109.9 mAh·$ g^{−1} $ at 1 C and capacity retention of 95.3% after 100 cycles, and which can work reliably at 10 C. Such superior electrochemical performance is attributed to $ Mn_{2} %$ O_{3} $/spinel multiphase composition, suitable crystal parameters, and high valence of Mn, which combines with the advantages of shrinking of the lattice structure to provide structural integrity and the heterostructure to facilitate the fast electrochemical kinetics. This study provides a simple method for the regulation of morphologies, polyvalent, and multiphase for lithium manganate cathodes, and enhances the understanding of their structure–activity relationship. Aqueous lithium-ion batteries (dpeaa)DE-He213 Li (dpeaa)DE-He213 Mn (dpeaa)DE-He213 O (dpeaa)DE-He213 Heterostructural (dpeaa)DE-He213 Multiple crystalline (dpeaa)DE-He213 Zhang, Jing-jia aut Lu, Dian-hong aut Wei, Zheng-baihe aut Yu, Fu-da aut Wang, Zhen-bo aut Enthalten in Ionics Berlin : Springer, 1995 28(2022), 12 vom: 07. Okt., Seite 5405-5413 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:28 year:2022 number:12 day:07 month:10 pages:5405-5413 https://dx.doi.org/10.1007/s11581-022-04773-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 28 2022 12 07 10 5405-5413 |
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Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Manganese-based active materials, represented by $ LiMn_{2} %$ O_{4} $, are becoming the preferred sustainable cathode material for aqueous lithium-ion batteries. Here we designed and prepared the homologous heterogeneous $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ materials by adjusting the lithium contents. Through the combined hydrothermal and sintering methods and using the polyvalent manganese compounds γ-MnOOH/$ Mn_{3} %$ O_{4} $ as self-template, the morphologic transformation and the evolution of microstructure heterostructure of $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ was confirmed. The homologous microstructure heterostructures can significantly affect the electrochemical properties through electrochemical measurement and physical characterization. The optimized sample inherited the hierarchical nano-micro morphology of the template exhibits high capacity, long cycle life, and superior rate capability, with initial discharge specific capacity of 109.9 mAh·$ g^{−1} $ at 1 C and capacity retention of 95.3% after 100 cycles, and which can work reliably at 10 C. Such superior electrochemical performance is attributed to $ Mn_{2} %$ O_{3} $/spinel multiphase composition, suitable crystal parameters, and high valence of Mn, which combines with the advantages of shrinking of the lattice structure to provide structural integrity and the heterostructure to facilitate the fast electrochemical kinetics. This study provides a simple method for the regulation of morphologies, polyvalent, and multiphase for lithium manganate cathodes, and enhances the understanding of their structure–activity relationship.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Aqueous lithium-ion batteries</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Li</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mn</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">O</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Heterostructural</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Multiple crystalline</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Jing-jia</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lu, Dian-hong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wei, Zheng-baihe</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yu, Fu-da</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Zhen-bo</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Ionics</subfield><subfield code="d">Berlin : Springer, 1995</subfield><subfield code="g">28(2022), 12 vom: 07. 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|
| author |
Meng, Jia-qi |
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Meng, Jia-qi misc Aqueous lithium-ion batteries misc Li misc Mn misc O misc Heterostructural misc Multiple crystalline Heterostructural $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ cathode materials of high performance for aqueous lithium-ion batteries |
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Heterostructural $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ cathode materials of high performance for aqueous lithium-ion batteries Aqueous lithium-ion batteries (dpeaa)DE-He213 Li (dpeaa)DE-He213 Mn (dpeaa)DE-He213 O (dpeaa)DE-He213 Heterostructural (dpeaa)DE-He213 Multiple crystalline (dpeaa)DE-He213 |
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misc Aqueous lithium-ion batteries misc Li misc Mn misc O misc Heterostructural misc Multiple crystalline |
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misc Aqueous lithium-ion batteries misc Li misc Mn misc O misc Heterostructural misc Multiple crystalline |
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misc Aqueous lithium-ion batteries misc Li misc Mn misc O misc Heterostructural misc Multiple crystalline |
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Heterostructural $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ cathode materials of high performance for aqueous lithium-ion batteries |
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Heterostructural $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ cathode materials of high performance for aqueous lithium-ion batteries |
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Meng, Jia-qi |
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Meng, Jia-qi Zhang, Jing-jia Lu, Dian-hong Wei, Zheng-baihe Yu, Fu-da Wang, Zhen-bo |
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Elektronische Aufsätze |
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Meng, Jia-qi |
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10.1007/s11581-022-04773-3 |
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heterostructural $ li_{1+x} %$ mn_{2−x} %$ o_{4} $ cathode materials of high performance for aqueous lithium-ion batteries |
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Heterostructural $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ cathode materials of high performance for aqueous lithium-ion batteries |
| abstract |
Abstract Manganese-based active materials, represented by $ LiMn_{2} %$ O_{4} $, are becoming the preferred sustainable cathode material for aqueous lithium-ion batteries. Here we designed and prepared the homologous heterogeneous $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ materials by adjusting the lithium contents. Through the combined hydrothermal and sintering methods and using the polyvalent manganese compounds γ-MnOOH/$ Mn_{3} %$ O_{4} $ as self-template, the morphologic transformation and the evolution of microstructure heterostructure of $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ was confirmed. The homologous microstructure heterostructures can significantly affect the electrochemical properties through electrochemical measurement and physical characterization. The optimized sample inherited the hierarchical nano-micro morphology of the template exhibits high capacity, long cycle life, and superior rate capability, with initial discharge specific capacity of 109.9 mAh·$ g^{−1} $ at 1 C and capacity retention of 95.3% after 100 cycles, and which can work reliably at 10 C. Such superior electrochemical performance is attributed to $ Mn_{2} %$ O_{3} $/spinel multiphase composition, suitable crystal parameters, and high valence of Mn, which combines with the advantages of shrinking of the lattice structure to provide structural integrity and the heterostructure to facilitate the fast electrochemical kinetics. This study provides a simple method for the regulation of morphologies, polyvalent, and multiphase for lithium manganate cathodes, and enhances the understanding of their structure–activity relationship. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Abstract Manganese-based active materials, represented by $ LiMn_{2} %$ O_{4} $, are becoming the preferred sustainable cathode material for aqueous lithium-ion batteries. Here we designed and prepared the homologous heterogeneous $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ materials by adjusting the lithium contents. Through the combined hydrothermal and sintering methods and using the polyvalent manganese compounds γ-MnOOH/$ Mn_{3} %$ O_{4} $ as self-template, the morphologic transformation and the evolution of microstructure heterostructure of $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ was confirmed. The homologous microstructure heterostructures can significantly affect the electrochemical properties through electrochemical measurement and physical characterization. The optimized sample inherited the hierarchical nano-micro morphology of the template exhibits high capacity, long cycle life, and superior rate capability, with initial discharge specific capacity of 109.9 mAh·$ g^{−1} $ at 1 C and capacity retention of 95.3% after 100 cycles, and which can work reliably at 10 C. Such superior electrochemical performance is attributed to $ Mn_{2} %$ O_{3} $/spinel multiphase composition, suitable crystal parameters, and high valence of Mn, which combines with the advantages of shrinking of the lattice structure to provide structural integrity and the heterostructure to facilitate the fast electrochemical kinetics. This study provides a simple method for the regulation of morphologies, polyvalent, and multiphase for lithium manganate cathodes, and enhances the understanding of their structure–activity relationship. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Abstract Manganese-based active materials, represented by $ LiMn_{2} %$ O_{4} $, are becoming the preferred sustainable cathode material for aqueous lithium-ion batteries. Here we designed and prepared the homologous heterogeneous $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ materials by adjusting the lithium contents. Through the combined hydrothermal and sintering methods and using the polyvalent manganese compounds γ-MnOOH/$ Mn_{3} %$ O_{4} $ as self-template, the morphologic transformation and the evolution of microstructure heterostructure of $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ was confirmed. The homologous microstructure heterostructures can significantly affect the electrochemical properties through electrochemical measurement and physical characterization. The optimized sample inherited the hierarchical nano-micro morphology of the template exhibits high capacity, long cycle life, and superior rate capability, with initial discharge specific capacity of 109.9 mAh·$ g^{−1} $ at 1 C and capacity retention of 95.3% after 100 cycles, and which can work reliably at 10 C. Such superior electrochemical performance is attributed to $ Mn_{2} %$ O_{3} $/spinel multiphase composition, suitable crystal parameters, and high valence of Mn, which combines with the advantages of shrinking of the lattice structure to provide structural integrity and the heterostructure to facilitate the fast electrochemical kinetics. This study provides a simple method for the regulation of morphologies, polyvalent, and multiphase for lithium manganate cathodes, and enhances the understanding of their structure–activity relationship. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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Heterostructural $ Li_{1+x} %$ Mn_{2−x} %$ O_{4} $ cathode materials of high performance for aqueous lithium-ion batteries |
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https://dx.doi.org/10.1007/s11581-022-04773-3 |
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Zhang, Jing-jia Lu, Dian-hong Wei, Zheng-baihe Yu, Fu-da Wang, Zhen-bo |
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Zhang, Jing-jia Lu, Dian-hong Wei, Zheng-baihe Yu, Fu-da Wang, Zhen-bo |
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10.1007/s11581-022-04773-3 |
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| score |
7.4005623 |