Structural and physico-chemical properties of clathrate hydrates of tetraisoamylammonium polyacrylates
Abstract Physico-chemical and structural characteristics have been studied of ionic clathrate hydrates of cross-linked (n = 1%) tetraisoamylammonium (TiAA) polyacrylates with different extent of substitution of proton-ions of the carboxylic groups for TiAA cations (x = 77%, 60%, 40%) in the polyacry...
Ausführliche Beschreibung
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| Autor*in: |
Terekhova, Irina S. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Journal of inclusion phenomena and macrocyclic chemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983, 102(2022), 11-12 vom: 02. Nov., Seite 905-915 |
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| Übergeordnetes Werk: |
volume:102 ; year:2022 ; number:11-12 ; day:02 ; month:11 ; pages:905-915 |
| Links: |
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| DOI / URN: |
10.1007/s10847-022-01171-0 |
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SPR048630853 |
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| 520 | |a Abstract Physico-chemical and structural characteristics have been studied of ionic clathrate hydrates of cross-linked (n = 1%) tetraisoamylammonium (TiAA) polyacrylates with different extent of substitution of proton-ions of the carboxylic groups for TiAA cations (x = 77%, 60%, 40%) in the polyacrylate. Powder X-ray diffraction studies have been carried out. All hydrates are isostructural to the earlier studied clathrate hydrate of cross-linked TiAA polyacrylate with x = 100%. The hexagonal structure with the space group P6/mmm and slightly different unit cell parameters (a ~ 12.24 Å, c ~ 12.70 Å) is related to the idealized Hexagonal Structure I of clathrate hydrates. Compositions, phase transition temperatures and decomposition enthalpies of the hydrates have been determined using differential thermal analysis and differential scanning calorimetry. The stability of the hydrates structure decreases with lessening of the content of TiAA cations in the polymeric molecule. The hydrates decomposition temperatures go down from + 14.6 to + 9.8 °C (for x = 100–40%) and the decomposition enthalpies—from 189.1 kJ/mol of hydrate to 84.0 kJ/mol of hydrate (for the same interval of x). The comparison has been made of physico-chemical characteristics of the ionic clathrate hydrates of cross-linked TiAA polyacrylates with those of the hydrates of tetrabutylammonium (TBA) polyacrylates and also of the ionic clathrate hydrates of TBA salts with monomeric anions. | ||
| 650 | 4 | |a Tetraalkylammonium polyacrylates |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Ionic clathrate hydrates |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Polymer hydration |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Powder X-ray diffraction |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Phase diagrams |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Decomposition enthalpies |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Decomposition temperatures |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Manakov, Andrey Yu. |4 aut | |
| 700 | 1 | |a Villevald, Galina V. |4 aut | |
| 700 | 1 | |a Karpova, Tamara D. |4 aut | |
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10.1007/s10847-022-01171-0 doi (DE-627)SPR048630853 (SPR)s10847-022-01171-0-e DE-627 ger DE-627 rakwb eng Terekhova, Irina S. verfasserin (orcid)0000-0002-4134-311X aut Structural and physico-chemical properties of clathrate hydrates of tetraisoamylammonium polyacrylates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Physico-chemical and structural characteristics have been studied of ionic clathrate hydrates of cross-linked (n = 1%) tetraisoamylammonium (TiAA) polyacrylates with different extent of substitution of proton-ions of the carboxylic groups for TiAA cations (x = 77%, 60%, 40%) in the polyacrylate. Powder X-ray diffraction studies have been carried out. All hydrates are isostructural to the earlier studied clathrate hydrate of cross-linked TiAA polyacrylate with x = 100%. The hexagonal structure with the space group P6/mmm and slightly different unit cell parameters (a ~ 12.24 Å, c ~ 12.70 Å) is related to the idealized Hexagonal Structure I of clathrate hydrates. Compositions, phase transition temperatures and decomposition enthalpies of the hydrates have been determined using differential thermal analysis and differential scanning calorimetry. The stability of the hydrates structure decreases with lessening of the content of TiAA cations in the polymeric molecule. The hydrates decomposition temperatures go down from + 14.6 to + 9.8 °C (for x = 100–40%) and the decomposition enthalpies—from 189.1 kJ/mol of hydrate to 84.0 kJ/mol of hydrate (for the same interval of x). The comparison has been made of physico-chemical characteristics of the ionic clathrate hydrates of cross-linked TiAA polyacrylates with those of the hydrates of tetrabutylammonium (TBA) polyacrylates and also of the ionic clathrate hydrates of TBA salts with monomeric anions. Tetraalkylammonium polyacrylates (dpeaa)DE-He213 Ionic clathrate hydrates (dpeaa)DE-He213 Polymer hydration (dpeaa)DE-He213 Powder X-ray diffraction (dpeaa)DE-He213 Phase diagrams (dpeaa)DE-He213 Decomposition enthalpies (dpeaa)DE-He213 Decomposition temperatures (dpeaa)DE-He213 Manakov, Andrey Yu. aut Villevald, Galina V. aut Karpova, Tamara D. aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 102(2022), 11-12 vom: 02. Nov., Seite 905-915 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:102 year:2022 number:11-12 day:02 month:11 pages:905-915 https://dx.doi.org/10.1007/s10847-022-01171-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 102 2022 11-12 02 11 905-915 |
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10.1007/s10847-022-01171-0 doi (DE-627)SPR048630853 (SPR)s10847-022-01171-0-e DE-627 ger DE-627 rakwb eng Terekhova, Irina S. verfasserin (orcid)0000-0002-4134-311X aut Structural and physico-chemical properties of clathrate hydrates of tetraisoamylammonium polyacrylates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Physico-chemical and structural characteristics have been studied of ionic clathrate hydrates of cross-linked (n = 1%) tetraisoamylammonium (TiAA) polyacrylates with different extent of substitution of proton-ions of the carboxylic groups for TiAA cations (x = 77%, 60%, 40%) in the polyacrylate. Powder X-ray diffraction studies have been carried out. All hydrates are isostructural to the earlier studied clathrate hydrate of cross-linked TiAA polyacrylate with x = 100%. The hexagonal structure with the space group P6/mmm and slightly different unit cell parameters (a ~ 12.24 Å, c ~ 12.70 Å) is related to the idealized Hexagonal Structure I of clathrate hydrates. Compositions, phase transition temperatures and decomposition enthalpies of the hydrates have been determined using differential thermal analysis and differential scanning calorimetry. The stability of the hydrates structure decreases with lessening of the content of TiAA cations in the polymeric molecule. The hydrates decomposition temperatures go down from + 14.6 to + 9.8 °C (for x = 100–40%) and the decomposition enthalpies—from 189.1 kJ/mol of hydrate to 84.0 kJ/mol of hydrate (for the same interval of x). The comparison has been made of physico-chemical characteristics of the ionic clathrate hydrates of cross-linked TiAA polyacrylates with those of the hydrates of tetrabutylammonium (TBA) polyacrylates and also of the ionic clathrate hydrates of TBA salts with monomeric anions. Tetraalkylammonium polyacrylates (dpeaa)DE-He213 Ionic clathrate hydrates (dpeaa)DE-He213 Polymer hydration (dpeaa)DE-He213 Powder X-ray diffraction (dpeaa)DE-He213 Phase diagrams (dpeaa)DE-He213 Decomposition enthalpies (dpeaa)DE-He213 Decomposition temperatures (dpeaa)DE-He213 Manakov, Andrey Yu. aut Villevald, Galina V. aut Karpova, Tamara D. aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 102(2022), 11-12 vom: 02. Nov., Seite 905-915 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:102 year:2022 number:11-12 day:02 month:11 pages:905-915 https://dx.doi.org/10.1007/s10847-022-01171-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 102 2022 11-12 02 11 905-915 |
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10.1007/s10847-022-01171-0 doi (DE-627)SPR048630853 (SPR)s10847-022-01171-0-e DE-627 ger DE-627 rakwb eng Terekhova, Irina S. verfasserin (orcid)0000-0002-4134-311X aut Structural and physico-chemical properties of clathrate hydrates of tetraisoamylammonium polyacrylates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Physico-chemical and structural characteristics have been studied of ionic clathrate hydrates of cross-linked (n = 1%) tetraisoamylammonium (TiAA) polyacrylates with different extent of substitution of proton-ions of the carboxylic groups for TiAA cations (x = 77%, 60%, 40%) in the polyacrylate. Powder X-ray diffraction studies have been carried out. All hydrates are isostructural to the earlier studied clathrate hydrate of cross-linked TiAA polyacrylate with x = 100%. The hexagonal structure with the space group P6/mmm and slightly different unit cell parameters (a ~ 12.24 Å, c ~ 12.70 Å) is related to the idealized Hexagonal Structure I of clathrate hydrates. Compositions, phase transition temperatures and decomposition enthalpies of the hydrates have been determined using differential thermal analysis and differential scanning calorimetry. The stability of the hydrates structure decreases with lessening of the content of TiAA cations in the polymeric molecule. The hydrates decomposition temperatures go down from + 14.6 to + 9.8 °C (for x = 100–40%) and the decomposition enthalpies—from 189.1 kJ/mol of hydrate to 84.0 kJ/mol of hydrate (for the same interval of x). The comparison has been made of physico-chemical characteristics of the ionic clathrate hydrates of cross-linked TiAA polyacrylates with those of the hydrates of tetrabutylammonium (TBA) polyacrylates and also of the ionic clathrate hydrates of TBA salts with monomeric anions. Tetraalkylammonium polyacrylates (dpeaa)DE-He213 Ionic clathrate hydrates (dpeaa)DE-He213 Polymer hydration (dpeaa)DE-He213 Powder X-ray diffraction (dpeaa)DE-He213 Phase diagrams (dpeaa)DE-He213 Decomposition enthalpies (dpeaa)DE-He213 Decomposition temperatures (dpeaa)DE-He213 Manakov, Andrey Yu. aut Villevald, Galina V. aut Karpova, Tamara D. aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 102(2022), 11-12 vom: 02. Nov., Seite 905-915 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:102 year:2022 number:11-12 day:02 month:11 pages:905-915 https://dx.doi.org/10.1007/s10847-022-01171-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 102 2022 11-12 02 11 905-915 |
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10.1007/s10847-022-01171-0 doi (DE-627)SPR048630853 (SPR)s10847-022-01171-0-e DE-627 ger DE-627 rakwb eng Terekhova, Irina S. verfasserin (orcid)0000-0002-4134-311X aut Structural and physico-chemical properties of clathrate hydrates of tetraisoamylammonium polyacrylates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Physico-chemical and structural characteristics have been studied of ionic clathrate hydrates of cross-linked (n = 1%) tetraisoamylammonium (TiAA) polyacrylates with different extent of substitution of proton-ions of the carboxylic groups for TiAA cations (x = 77%, 60%, 40%) in the polyacrylate. Powder X-ray diffraction studies have been carried out. All hydrates are isostructural to the earlier studied clathrate hydrate of cross-linked TiAA polyacrylate with x = 100%. The hexagonal structure with the space group P6/mmm and slightly different unit cell parameters (a ~ 12.24 Å, c ~ 12.70 Å) is related to the idealized Hexagonal Structure I of clathrate hydrates. Compositions, phase transition temperatures and decomposition enthalpies of the hydrates have been determined using differential thermal analysis and differential scanning calorimetry. The stability of the hydrates structure decreases with lessening of the content of TiAA cations in the polymeric molecule. The hydrates decomposition temperatures go down from + 14.6 to + 9.8 °C (for x = 100–40%) and the decomposition enthalpies—from 189.1 kJ/mol of hydrate to 84.0 kJ/mol of hydrate (for the same interval of x). The comparison has been made of physico-chemical characteristics of the ionic clathrate hydrates of cross-linked TiAA polyacrylates with those of the hydrates of tetrabutylammonium (TBA) polyacrylates and also of the ionic clathrate hydrates of TBA salts with monomeric anions. Tetraalkylammonium polyacrylates (dpeaa)DE-He213 Ionic clathrate hydrates (dpeaa)DE-He213 Polymer hydration (dpeaa)DE-He213 Powder X-ray diffraction (dpeaa)DE-He213 Phase diagrams (dpeaa)DE-He213 Decomposition enthalpies (dpeaa)DE-He213 Decomposition temperatures (dpeaa)DE-He213 Manakov, Andrey Yu. aut Villevald, Galina V. aut Karpova, Tamara D. aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 102(2022), 11-12 vom: 02. Nov., Seite 905-915 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:102 year:2022 number:11-12 day:02 month:11 pages:905-915 https://dx.doi.org/10.1007/s10847-022-01171-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 102 2022 11-12 02 11 905-915 |
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10.1007/s10847-022-01171-0 doi (DE-627)SPR048630853 (SPR)s10847-022-01171-0-e DE-627 ger DE-627 rakwb eng Terekhova, Irina S. verfasserin (orcid)0000-0002-4134-311X aut Structural and physico-chemical properties of clathrate hydrates of tetraisoamylammonium polyacrylates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Physico-chemical and structural characteristics have been studied of ionic clathrate hydrates of cross-linked (n = 1%) tetraisoamylammonium (TiAA) polyacrylates with different extent of substitution of proton-ions of the carboxylic groups for TiAA cations (x = 77%, 60%, 40%) in the polyacrylate. Powder X-ray diffraction studies have been carried out. All hydrates are isostructural to the earlier studied clathrate hydrate of cross-linked TiAA polyacrylate with x = 100%. The hexagonal structure with the space group P6/mmm and slightly different unit cell parameters (a ~ 12.24 Å, c ~ 12.70 Å) is related to the idealized Hexagonal Structure I of clathrate hydrates. Compositions, phase transition temperatures and decomposition enthalpies of the hydrates have been determined using differential thermal analysis and differential scanning calorimetry. The stability of the hydrates structure decreases with lessening of the content of TiAA cations in the polymeric molecule. The hydrates decomposition temperatures go down from + 14.6 to + 9.8 °C (for x = 100–40%) and the decomposition enthalpies—from 189.1 kJ/mol of hydrate to 84.0 kJ/mol of hydrate (for the same interval of x). The comparison has been made of physico-chemical characteristics of the ionic clathrate hydrates of cross-linked TiAA polyacrylates with those of the hydrates of tetrabutylammonium (TBA) polyacrylates and also of the ionic clathrate hydrates of TBA salts with monomeric anions. Tetraalkylammonium polyacrylates (dpeaa)DE-He213 Ionic clathrate hydrates (dpeaa)DE-He213 Polymer hydration (dpeaa)DE-He213 Powder X-ray diffraction (dpeaa)DE-He213 Phase diagrams (dpeaa)DE-He213 Decomposition enthalpies (dpeaa)DE-He213 Decomposition temperatures (dpeaa)DE-He213 Manakov, Andrey Yu. aut Villevald, Galina V. aut Karpova, Tamara D. aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 102(2022), 11-12 vom: 02. Nov., Seite 905-915 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:102 year:2022 number:11-12 day:02 month:11 pages:905-915 https://dx.doi.org/10.1007/s10847-022-01171-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 102 2022 11-12 02 11 905-915 |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Physico-chemical and structural characteristics have been studied of ionic clathrate hydrates of cross-linked (n = 1%) tetraisoamylammonium (TiAA) polyacrylates with different extent of substitution of proton-ions of the carboxylic groups for TiAA cations (x = 77%, 60%, 40%) in the polyacrylate. Powder X-ray diffraction studies have been carried out. All hydrates are isostructural to the earlier studied clathrate hydrate of cross-linked TiAA polyacrylate with x = 100%. The hexagonal structure with the space group P6/mmm and slightly different unit cell parameters (a ~ 12.24 Å, c ~ 12.70 Å) is related to the idealized Hexagonal Structure I of clathrate hydrates. Compositions, phase transition temperatures and decomposition enthalpies of the hydrates have been determined using differential thermal analysis and differential scanning calorimetry. The stability of the hydrates structure decreases with lessening of the content of TiAA cations in the polymeric molecule. The hydrates decomposition temperatures go down from + 14.6 to + 9.8 °C (for x = 100–40%) and the decomposition enthalpies—from 189.1 kJ/mol of hydrate to 84.0 kJ/mol of hydrate (for the same interval of x). The comparison has been made of physico-chemical characteristics of the ionic clathrate hydrates of cross-linked TiAA polyacrylates with those of the hydrates of tetrabutylammonium (TBA) polyacrylates and also of the ionic clathrate hydrates of TBA salts with monomeric anions.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Tetraalkylammonium polyacrylates</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ionic clathrate hydrates</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polymer hydration</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Powder X-ray diffraction</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Phase diagrams</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Decomposition enthalpies</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Decomposition temperatures</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Manakov, Andrey Yu.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Villevald, Galina V.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Karpova, Tamara D.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of inclusion phenomena and macrocyclic chemistry</subfield><subfield code="d">Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983</subfield><subfield code="g">102(2022), 11-12 vom: 02. 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Terekhova, Irina S. |
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Terekhova, Irina S. misc Tetraalkylammonium polyacrylates misc Ionic clathrate hydrates misc Polymer hydration misc Powder X-ray diffraction misc Phase diagrams misc Decomposition enthalpies misc Decomposition temperatures Structural and physico-chemical properties of clathrate hydrates of tetraisoamylammonium polyacrylates |
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Structural and physico-chemical properties of clathrate hydrates of tetraisoamylammonium polyacrylates Tetraalkylammonium polyacrylates (dpeaa)DE-He213 Ionic clathrate hydrates (dpeaa)DE-He213 Polymer hydration (dpeaa)DE-He213 Powder X-ray diffraction (dpeaa)DE-He213 Phase diagrams (dpeaa)DE-He213 Decomposition enthalpies (dpeaa)DE-He213 Decomposition temperatures (dpeaa)DE-He213 |
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misc Tetraalkylammonium polyacrylates misc Ionic clathrate hydrates misc Polymer hydration misc Powder X-ray diffraction misc Phase diagrams misc Decomposition enthalpies misc Decomposition temperatures |
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structural and physico-chemical properties of clathrate hydrates of tetraisoamylammonium polyacrylates |
| title_auth |
Structural and physico-chemical properties of clathrate hydrates of tetraisoamylammonium polyacrylates |
| abstract |
Abstract Physico-chemical and structural characteristics have been studied of ionic clathrate hydrates of cross-linked (n = 1%) tetraisoamylammonium (TiAA) polyacrylates with different extent of substitution of proton-ions of the carboxylic groups for TiAA cations (x = 77%, 60%, 40%) in the polyacrylate. Powder X-ray diffraction studies have been carried out. All hydrates are isostructural to the earlier studied clathrate hydrate of cross-linked TiAA polyacrylate with x = 100%. The hexagonal structure with the space group P6/mmm and slightly different unit cell parameters (a ~ 12.24 Å, c ~ 12.70 Å) is related to the idealized Hexagonal Structure I of clathrate hydrates. Compositions, phase transition temperatures and decomposition enthalpies of the hydrates have been determined using differential thermal analysis and differential scanning calorimetry. The stability of the hydrates structure decreases with lessening of the content of TiAA cations in the polymeric molecule. The hydrates decomposition temperatures go down from + 14.6 to + 9.8 °C (for x = 100–40%) and the decomposition enthalpies—from 189.1 kJ/mol of hydrate to 84.0 kJ/mol of hydrate (for the same interval of x). The comparison has been made of physico-chemical characteristics of the ionic clathrate hydrates of cross-linked TiAA polyacrylates with those of the hydrates of tetrabutylammonium (TBA) polyacrylates and also of the ionic clathrate hydrates of TBA salts with monomeric anions. © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Abstract Physico-chemical and structural characteristics have been studied of ionic clathrate hydrates of cross-linked (n = 1%) tetraisoamylammonium (TiAA) polyacrylates with different extent of substitution of proton-ions of the carboxylic groups for TiAA cations (x = 77%, 60%, 40%) in the polyacrylate. Powder X-ray diffraction studies have been carried out. All hydrates are isostructural to the earlier studied clathrate hydrate of cross-linked TiAA polyacrylate with x = 100%. The hexagonal structure with the space group P6/mmm and slightly different unit cell parameters (a ~ 12.24 Å, c ~ 12.70 Å) is related to the idealized Hexagonal Structure I of clathrate hydrates. Compositions, phase transition temperatures and decomposition enthalpies of the hydrates have been determined using differential thermal analysis and differential scanning calorimetry. The stability of the hydrates structure decreases with lessening of the content of TiAA cations in the polymeric molecule. The hydrates decomposition temperatures go down from + 14.6 to + 9.8 °C (for x = 100–40%) and the decomposition enthalpies—from 189.1 kJ/mol of hydrate to 84.0 kJ/mol of hydrate (for the same interval of x). The comparison has been made of physico-chemical characteristics of the ionic clathrate hydrates of cross-linked TiAA polyacrylates with those of the hydrates of tetrabutylammonium (TBA) polyacrylates and also of the ionic clathrate hydrates of TBA salts with monomeric anions. © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Abstract Physico-chemical and structural characteristics have been studied of ionic clathrate hydrates of cross-linked (n = 1%) tetraisoamylammonium (TiAA) polyacrylates with different extent of substitution of proton-ions of the carboxylic groups for TiAA cations (x = 77%, 60%, 40%) in the polyacrylate. Powder X-ray diffraction studies have been carried out. All hydrates are isostructural to the earlier studied clathrate hydrate of cross-linked TiAA polyacrylate with x = 100%. The hexagonal structure with the space group P6/mmm and slightly different unit cell parameters (a ~ 12.24 Å, c ~ 12.70 Å) is related to the idealized Hexagonal Structure I of clathrate hydrates. Compositions, phase transition temperatures and decomposition enthalpies of the hydrates have been determined using differential thermal analysis and differential scanning calorimetry. The stability of the hydrates structure decreases with lessening of the content of TiAA cations in the polymeric molecule. The hydrates decomposition temperatures go down from + 14.6 to + 9.8 °C (for x = 100–40%) and the decomposition enthalpies—from 189.1 kJ/mol of hydrate to 84.0 kJ/mol of hydrate (for the same interval of x). The comparison has been made of physico-chemical characteristics of the ionic clathrate hydrates of cross-linked TiAA polyacrylates with those of the hydrates of tetrabutylammonium (TBA) polyacrylates and also of the ionic clathrate hydrates of TBA salts with monomeric anions. © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| title_short |
Structural and physico-chemical properties of clathrate hydrates of tetraisoamylammonium polyacrylates |
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https://dx.doi.org/10.1007/s10847-022-01171-0 |
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Manakov, Andrey Yu Villevald, Galina V. Karpova, Tamara D. |
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| score |
7.4028378 |