Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance
Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three accep...
Ausführliche Beschreibung
Autor*in: |
Dong, Chang-Shuai [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2022 |
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Schlagwörter: |
Acceptor-acceptor type conjugated polymers |
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Anmerkung: |
© Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 |
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Übergeordnetes Werk: |
Enthalten in: Chinese Journal of Polymer Science - Chinese Chemical Society and Institute of Chemistry, CAS, 2009, 41(2022), 1 vom: 05. Sept., Seite 108-116 |
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Übergeordnetes Werk: |
volume:41 ; year:2022 ; number:1 ; day:05 ; month:09 ; pages:108-116 |
Links: |
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DOI / URN: |
10.1007/s10118-022-2815-0 |
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Katalog-ID: |
SPR048932981 |
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520 | |a Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. | ||
650 | 4 | |a Organoboron polymers |7 (dpeaa)DE-He213 | |
650 | 4 | |a Acceptor-acceptor type conjugated polymers |7 (dpeaa)DE-He213 | |
650 | 4 | |a n-Type polymer thermoelectrics |7 (dpeaa)DE-He213 | |
650 | 4 | |a n-Doping |7 (dpeaa)DE-He213 | |
700 | 1 | |a Meng, Bin |4 aut | |
700 | 1 | |a Liu, Jun |4 aut | |
700 | 1 | |a Wang, Li-Xiang |4 aut | |
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10.1007/s10118-022-2815-0 doi (DE-627)SPR048932981 (SPR)s10118-022-2815-0-e DE-627 ger DE-627 rakwb eng Dong, Chang-Shuai verfasserin aut Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. Organoboron polymers (dpeaa)DE-He213 Acceptor-acceptor type conjugated polymers (dpeaa)DE-He213 n-Type polymer thermoelectrics (dpeaa)DE-He213 n-Doping (dpeaa)DE-He213 Meng, Bin aut Liu, Jun aut Wang, Li-Xiang aut Enthalten in Chinese Journal of Polymer Science Chinese Chemical Society and Institute of Chemistry, CAS, 2009 41(2022), 1 vom: 05. Sept., Seite 108-116 (DE-627)356885143 (DE-600)2093161-X 1439-6203 nnns volume:41 year:2022 number:1 day:05 month:09 pages:108-116 https://dx.doi.org/10.1007/s10118-022-2815-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 41 2022 1 05 09 108-116 |
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10.1007/s10118-022-2815-0 doi (DE-627)SPR048932981 (SPR)s10118-022-2815-0-e DE-627 ger DE-627 rakwb eng Dong, Chang-Shuai verfasserin aut Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. Organoboron polymers (dpeaa)DE-He213 Acceptor-acceptor type conjugated polymers (dpeaa)DE-He213 n-Type polymer thermoelectrics (dpeaa)DE-He213 n-Doping (dpeaa)DE-He213 Meng, Bin aut Liu, Jun aut Wang, Li-Xiang aut Enthalten in Chinese Journal of Polymer Science Chinese Chemical Society and Institute of Chemistry, CAS, 2009 41(2022), 1 vom: 05. Sept., Seite 108-116 (DE-627)356885143 (DE-600)2093161-X 1439-6203 nnns volume:41 year:2022 number:1 day:05 month:09 pages:108-116 https://dx.doi.org/10.1007/s10118-022-2815-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 41 2022 1 05 09 108-116 |
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10.1007/s10118-022-2815-0 doi (DE-627)SPR048932981 (SPR)s10118-022-2815-0-e DE-627 ger DE-627 rakwb eng Dong, Chang-Shuai verfasserin aut Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. Organoboron polymers (dpeaa)DE-He213 Acceptor-acceptor type conjugated polymers (dpeaa)DE-He213 n-Type polymer thermoelectrics (dpeaa)DE-He213 n-Doping (dpeaa)DE-He213 Meng, Bin aut Liu, Jun aut Wang, Li-Xiang aut Enthalten in Chinese Journal of Polymer Science Chinese Chemical Society and Institute of Chemistry, CAS, 2009 41(2022), 1 vom: 05. Sept., Seite 108-116 (DE-627)356885143 (DE-600)2093161-X 1439-6203 nnns volume:41 year:2022 number:1 day:05 month:09 pages:108-116 https://dx.doi.org/10.1007/s10118-022-2815-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 41 2022 1 05 09 108-116 |
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10.1007/s10118-022-2815-0 doi (DE-627)SPR048932981 (SPR)s10118-022-2815-0-e DE-627 ger DE-627 rakwb eng Dong, Chang-Shuai verfasserin aut Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. Organoboron polymers (dpeaa)DE-He213 Acceptor-acceptor type conjugated polymers (dpeaa)DE-He213 n-Type polymer thermoelectrics (dpeaa)DE-He213 n-Doping (dpeaa)DE-He213 Meng, Bin aut Liu, Jun aut Wang, Li-Xiang aut Enthalten in Chinese Journal of Polymer Science Chinese Chemical Society and Institute of Chemistry, CAS, 2009 41(2022), 1 vom: 05. Sept., Seite 108-116 (DE-627)356885143 (DE-600)2093161-X 1439-6203 nnns volume:41 year:2022 number:1 day:05 month:09 pages:108-116 https://dx.doi.org/10.1007/s10118-022-2815-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 41 2022 1 05 09 108-116 |
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10.1007/s10118-022-2815-0 doi (DE-627)SPR048932981 (SPR)s10118-022-2815-0-e DE-627 ger DE-627 rakwb eng Dong, Chang-Shuai verfasserin aut Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. Organoboron polymers (dpeaa)DE-He213 Acceptor-acceptor type conjugated polymers (dpeaa)DE-He213 n-Type polymer thermoelectrics (dpeaa)DE-He213 n-Doping (dpeaa)DE-He213 Meng, Bin aut Liu, Jun aut Wang, Li-Xiang aut Enthalten in Chinese Journal of Polymer Science Chinese Chemical Society and Institute of Chemistry, CAS, 2009 41(2022), 1 vom: 05. Sept., Seite 108-116 (DE-627)356885143 (DE-600)2093161-X 1439-6203 nnns volume:41 year:2022 number:1 day:05 month:09 pages:108-116 https://dx.doi.org/10.1007/s10118-022-2815-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 41 2022 1 05 09 108-116 |
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Enthalten in Chinese Journal of Polymer Science 41(2022), 1 vom: 05. Sept., Seite 108-116 volume:41 year:2022 number:1 day:05 month:09 pages:108-116 |
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Enthalten in Chinese Journal of Polymer Science 41(2022), 1 vom: 05. Sept., Seite 108-116 volume:41 year:2022 number:1 day:05 month:09 pages:108-116 |
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Dong, Chang-Shuai @@aut@@ Meng, Bin @@aut@@ Liu, Jun @@aut@@ Wang, Li-Xiang @@aut@@ |
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New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. 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|
author |
Dong, Chang-Shuai |
spellingShingle |
Dong, Chang-Shuai misc Organoboron polymers misc Acceptor-acceptor type conjugated polymers misc n-Type polymer thermoelectrics misc n-Doping Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance |
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Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance Organoboron polymers (dpeaa)DE-He213 Acceptor-acceptor type conjugated polymers (dpeaa)DE-He213 n-Type polymer thermoelectrics (dpeaa)DE-He213 n-Doping (dpeaa)DE-He213 |
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misc Organoboron polymers misc Acceptor-acceptor type conjugated polymers misc n-Type polymer thermoelectrics misc n-Doping |
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misc Organoboron polymers misc Acceptor-acceptor type conjugated polymers misc n-Type polymer thermoelectrics misc n-Doping |
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Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance |
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Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance |
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Dong, Chang-Shuai Meng, Bin Liu, Jun Wang, Li-Xiang |
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Dong, Chang-Shuai |
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10.1007/s10118-022-2815-0 |
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acceptor-acceptor-type organoboron conjugated polymers: effect of backbone configuration on thermoelectric performance |
title_auth |
Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance |
abstract |
Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 |
abstractGer |
Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 |
abstract_unstemmed |
Abstract The development of n-type polymer thermoelectrics lags far behind that of p-type ones in view of material diversity and performance. New structural insights into the thermoelectric performance are needed for efficient n-type polymer thermoelectric materials. Herein, we developed three acceptor-acceptor type organoboron polymers and investigated the effect of backbone configuration on thermoelectric performance. The three polymers are designed based on double B←N bridged bipyridine (BNBP) unit with monomeric thieno[3,4-c]pyrrole-4,6-dione (TPD), TPD dimer and TPD trimer as the copolymerizing units, respectively. The three polymers show similar low LUMO energy levels but different backbone configuration. Compared with the wavy backbone configuration, the pseudo-straight backbone configuration imparts the polymer with much enhanced crystallinity and electron mobility. As a result, after n-doping, the polymer with pseudo-straight configuration shows much higher electronic conductivity and power factor. We think these findings could serve as important guidelines for molecular design toward efficient n-type polymer thermoelectric materials. © Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022 |
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title_short |
Acceptor-acceptor-type Organoboron Conjugated Polymers: Effect of Backbone Configuration on Thermoelectric Performance |
url |
https://dx.doi.org/10.1007/s10118-022-2815-0 |
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author2 |
Meng, Bin Liu, Jun Wang, Li-Xiang |
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Meng, Bin Liu, Jun Wang, Li-Xiang |
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doi_str |
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up_date |
2024-07-03T22:20:02.955Z |
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