Dye adsorption performance of nanocellulose beads with different carboxyl group content
Abstract The problems caused by water pollution are increasingly serious, wastewater contains a lot of heavy metal ions, textile dyes, medicines, etc. However, most adsorption materials usually face problems such as inefficient recycling, high cost, and secondary pollution. As a natural polymer, cel...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Xue, Jianghua [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Cellulose - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994, 30(2022), 3 vom: 02. Dez., Seite 1623-1636 |
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| Übergeordnetes Werk: |
volume:30 ; year:2022 ; number:3 ; day:02 ; month:12 ; pages:1623-1636 |
| Links: |
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| DOI / URN: |
10.1007/s10570-022-04964-1 |
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SPR049295330 |
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10.1007/s10570-022-04964-1 doi (DE-627)SPR049295330 (SPR)s10570-022-04964-1-e DE-627 ger DE-627 rakwb eng Xue, Jianghua verfasserin aut Dye adsorption performance of nanocellulose beads with different carboxyl group content 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The problems caused by water pollution are increasingly serious, wastewater contains a lot of heavy metal ions, textile dyes, medicines, etc. However, most adsorption materials usually face problems such as inefficient recycling, high cost, and secondary pollution. As a natural polymer, cellulose has low cost, degradability and good biocompatibility. In this work, by changing the addition amount of sodium hypochlorite during 2,2,6,6-Tetramethylpiperidine-1-oxyl radical (TEMPO) oxidation, nanocellulose with different carboxyl content could be prepared, which is expected to be a good high-efficiency cationic adsorbent due to its rich in hydroxyl groups on the surface and negatively charged. Then the calcium chloride solution was used as the cross-linking agent to prepare TEMPO-oxidized cellulose nanofibril beads (TOCNB) by the dropping solidification method. As the content of carboxyl groups increases, the Zeta potential value of the nanocellulose dispersion became increasingly negative. The nanocellulose beads all presented a good three-dimensional network porous structure. With the increase of carboxyl group content, the specific surface area increases from 173 to 367 $ m^{2} $ $ g^{−1} $, and the adsorption capacity for methylene blue (MB) also gradually strengthened. The saturated adsorption capacity of TOCNB on MB was calculated as high as 925.93 mg $ g^{−1} $. The nanocellulose bead was a cationic adsorbent with highly efficient adsorption and adjustable specific surface area, and the preparation method was simple, fast, efficient and green. Nanocellulose beads (dpeaa)DE-He213 Dye adsorption (dpeaa)DE-He213 Methylene blue (dpeaa)DE-He213 Carboxyl content (dpeaa)DE-He213 Zhu, Enwen aut Zhu, Hengfeng aut Liu, Dongning aut Cai, Haopeng aut Xiong, Chuanxi aut Yang, Quanling aut Shi, Zhuqun aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 30(2022), 3 vom: 02. Dez., Seite 1623-1636 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:30 year:2022 number:3 day:02 month:12 pages:1623-1636 https://dx.doi.org/10.1007/s10570-022-04964-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2022 3 02 12 1623-1636 |
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10.1007/s10570-022-04964-1 doi (DE-627)SPR049295330 (SPR)s10570-022-04964-1-e DE-627 ger DE-627 rakwb eng Xue, Jianghua verfasserin aut Dye adsorption performance of nanocellulose beads with different carboxyl group content 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The problems caused by water pollution are increasingly serious, wastewater contains a lot of heavy metal ions, textile dyes, medicines, etc. However, most adsorption materials usually face problems such as inefficient recycling, high cost, and secondary pollution. As a natural polymer, cellulose has low cost, degradability and good biocompatibility. In this work, by changing the addition amount of sodium hypochlorite during 2,2,6,6-Tetramethylpiperidine-1-oxyl radical (TEMPO) oxidation, nanocellulose with different carboxyl content could be prepared, which is expected to be a good high-efficiency cationic adsorbent due to its rich in hydroxyl groups on the surface and negatively charged. Then the calcium chloride solution was used as the cross-linking agent to prepare TEMPO-oxidized cellulose nanofibril beads (TOCNB) by the dropping solidification method. As the content of carboxyl groups increases, the Zeta potential value of the nanocellulose dispersion became increasingly negative. The nanocellulose beads all presented a good three-dimensional network porous structure. With the increase of carboxyl group content, the specific surface area increases from 173 to 367 $ m^{2} $ $ g^{−1} $, and the adsorption capacity for methylene blue (MB) also gradually strengthened. The saturated adsorption capacity of TOCNB on MB was calculated as high as 925.93 mg $ g^{−1} $. The nanocellulose bead was a cationic adsorbent with highly efficient adsorption and adjustable specific surface area, and the preparation method was simple, fast, efficient and green. Nanocellulose beads (dpeaa)DE-He213 Dye adsorption (dpeaa)DE-He213 Methylene blue (dpeaa)DE-He213 Carboxyl content (dpeaa)DE-He213 Zhu, Enwen aut Zhu, Hengfeng aut Liu, Dongning aut Cai, Haopeng aut Xiong, Chuanxi aut Yang, Quanling aut Shi, Zhuqun aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 30(2022), 3 vom: 02. Dez., Seite 1623-1636 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:30 year:2022 number:3 day:02 month:12 pages:1623-1636 https://dx.doi.org/10.1007/s10570-022-04964-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2022 3 02 12 1623-1636 |
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10.1007/s10570-022-04964-1 doi (DE-627)SPR049295330 (SPR)s10570-022-04964-1-e DE-627 ger DE-627 rakwb eng Xue, Jianghua verfasserin aut Dye adsorption performance of nanocellulose beads with different carboxyl group content 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The problems caused by water pollution are increasingly serious, wastewater contains a lot of heavy metal ions, textile dyes, medicines, etc. However, most adsorption materials usually face problems such as inefficient recycling, high cost, and secondary pollution. As a natural polymer, cellulose has low cost, degradability and good biocompatibility. In this work, by changing the addition amount of sodium hypochlorite during 2,2,6,6-Tetramethylpiperidine-1-oxyl radical (TEMPO) oxidation, nanocellulose with different carboxyl content could be prepared, which is expected to be a good high-efficiency cationic adsorbent due to its rich in hydroxyl groups on the surface and negatively charged. Then the calcium chloride solution was used as the cross-linking agent to prepare TEMPO-oxidized cellulose nanofibril beads (TOCNB) by the dropping solidification method. As the content of carboxyl groups increases, the Zeta potential value of the nanocellulose dispersion became increasingly negative. The nanocellulose beads all presented a good three-dimensional network porous structure. With the increase of carboxyl group content, the specific surface area increases from 173 to 367 $ m^{2} $ $ g^{−1} $, and the adsorption capacity for methylene blue (MB) also gradually strengthened. The saturated adsorption capacity of TOCNB on MB was calculated as high as 925.93 mg $ g^{−1} $. The nanocellulose bead was a cationic adsorbent with highly efficient adsorption and adjustable specific surface area, and the preparation method was simple, fast, efficient and green. Nanocellulose beads (dpeaa)DE-He213 Dye adsorption (dpeaa)DE-He213 Methylene blue (dpeaa)DE-He213 Carboxyl content (dpeaa)DE-He213 Zhu, Enwen aut Zhu, Hengfeng aut Liu, Dongning aut Cai, Haopeng aut Xiong, Chuanxi aut Yang, Quanling aut Shi, Zhuqun aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 30(2022), 3 vom: 02. Dez., Seite 1623-1636 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:30 year:2022 number:3 day:02 month:12 pages:1623-1636 https://dx.doi.org/10.1007/s10570-022-04964-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2022 3 02 12 1623-1636 |
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10.1007/s10570-022-04964-1 doi (DE-627)SPR049295330 (SPR)s10570-022-04964-1-e DE-627 ger DE-627 rakwb eng Xue, Jianghua verfasserin aut Dye adsorption performance of nanocellulose beads with different carboxyl group content 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The problems caused by water pollution are increasingly serious, wastewater contains a lot of heavy metal ions, textile dyes, medicines, etc. However, most adsorption materials usually face problems such as inefficient recycling, high cost, and secondary pollution. As a natural polymer, cellulose has low cost, degradability and good biocompatibility. In this work, by changing the addition amount of sodium hypochlorite during 2,2,6,6-Tetramethylpiperidine-1-oxyl radical (TEMPO) oxidation, nanocellulose with different carboxyl content could be prepared, which is expected to be a good high-efficiency cationic adsorbent due to its rich in hydroxyl groups on the surface and negatively charged. Then the calcium chloride solution was used as the cross-linking agent to prepare TEMPO-oxidized cellulose nanofibril beads (TOCNB) by the dropping solidification method. As the content of carboxyl groups increases, the Zeta potential value of the nanocellulose dispersion became increasingly negative. The nanocellulose beads all presented a good three-dimensional network porous structure. With the increase of carboxyl group content, the specific surface area increases from 173 to 367 $ m^{2} $ $ g^{−1} $, and the adsorption capacity for methylene blue (MB) also gradually strengthened. The saturated adsorption capacity of TOCNB on MB was calculated as high as 925.93 mg $ g^{−1} $. The nanocellulose bead was a cationic adsorbent with highly efficient adsorption and adjustable specific surface area, and the preparation method was simple, fast, efficient and green. Nanocellulose beads (dpeaa)DE-He213 Dye adsorption (dpeaa)DE-He213 Methylene blue (dpeaa)DE-He213 Carboxyl content (dpeaa)DE-He213 Zhu, Enwen aut Zhu, Hengfeng aut Liu, Dongning aut Cai, Haopeng aut Xiong, Chuanxi aut Yang, Quanling aut Shi, Zhuqun aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 30(2022), 3 vom: 02. Dez., Seite 1623-1636 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:30 year:2022 number:3 day:02 month:12 pages:1623-1636 https://dx.doi.org/10.1007/s10570-022-04964-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2022 3 02 12 1623-1636 |
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10.1007/s10570-022-04964-1 doi (DE-627)SPR049295330 (SPR)s10570-022-04964-1-e DE-627 ger DE-627 rakwb eng Xue, Jianghua verfasserin aut Dye adsorption performance of nanocellulose beads with different carboxyl group content 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The problems caused by water pollution are increasingly serious, wastewater contains a lot of heavy metal ions, textile dyes, medicines, etc. However, most adsorption materials usually face problems such as inefficient recycling, high cost, and secondary pollution. As a natural polymer, cellulose has low cost, degradability and good biocompatibility. In this work, by changing the addition amount of sodium hypochlorite during 2,2,6,6-Tetramethylpiperidine-1-oxyl radical (TEMPO) oxidation, nanocellulose with different carboxyl content could be prepared, which is expected to be a good high-efficiency cationic adsorbent due to its rich in hydroxyl groups on the surface and negatively charged. Then the calcium chloride solution was used as the cross-linking agent to prepare TEMPO-oxidized cellulose nanofibril beads (TOCNB) by the dropping solidification method. As the content of carboxyl groups increases, the Zeta potential value of the nanocellulose dispersion became increasingly negative. The nanocellulose beads all presented a good three-dimensional network porous structure. With the increase of carboxyl group content, the specific surface area increases from 173 to 367 $ m^{2} $ $ g^{−1} $, and the adsorption capacity for methylene blue (MB) also gradually strengthened. The saturated adsorption capacity of TOCNB on MB was calculated as high as 925.93 mg $ g^{−1} $. The nanocellulose bead was a cationic adsorbent with highly efficient adsorption and adjustable specific surface area, and the preparation method was simple, fast, efficient and green. Nanocellulose beads (dpeaa)DE-He213 Dye adsorption (dpeaa)DE-He213 Methylene blue (dpeaa)DE-He213 Carboxyl content (dpeaa)DE-He213 Zhu, Enwen aut Zhu, Hengfeng aut Liu, Dongning aut Cai, Haopeng aut Xiong, Chuanxi aut Yang, Quanling aut Shi, Zhuqun aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 30(2022), 3 vom: 02. Dez., Seite 1623-1636 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:30 year:2022 number:3 day:02 month:12 pages:1623-1636 https://dx.doi.org/10.1007/s10570-022-04964-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2022 3 02 12 1623-1636 |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The problems caused by water pollution are increasingly serious, wastewater contains a lot of heavy metal ions, textile dyes, medicines, etc. However, most adsorption materials usually face problems such as inefficient recycling, high cost, and secondary pollution. As a natural polymer, cellulose has low cost, degradability and good biocompatibility. In this work, by changing the addition amount of sodium hypochlorite during 2,2,6,6-Tetramethylpiperidine-1-oxyl radical (TEMPO) oxidation, nanocellulose with different carboxyl content could be prepared, which is expected to be a good high-efficiency cationic adsorbent due to its rich in hydroxyl groups on the surface and negatively charged. Then the calcium chloride solution was used as the cross-linking agent to prepare TEMPO-oxidized cellulose nanofibril beads (TOCNB) by the dropping solidification method. As the content of carboxyl groups increases, the Zeta potential value of the nanocellulose dispersion became increasingly negative. The nanocellulose beads all presented a good three-dimensional network porous structure. With the increase of carboxyl group content, the specific surface area increases from 173 to 367 $ m^{2} $ $ g^{−1} $, and the adsorption capacity for methylene blue (MB) also gradually strengthened. The saturated adsorption capacity of TOCNB on MB was calculated as high as 925.93 mg $ g^{−1} $. 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Xue, Jianghua |
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Xue, Jianghua misc Nanocellulose beads misc Dye adsorption misc Methylene blue misc Carboxyl content Dye adsorption performance of nanocellulose beads with different carboxyl group content |
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Dye adsorption performance of nanocellulose beads with different carboxyl group content Nanocellulose beads (dpeaa)DE-He213 Dye adsorption (dpeaa)DE-He213 Methylene blue (dpeaa)DE-He213 Carboxyl content (dpeaa)DE-He213 |
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misc Nanocellulose beads misc Dye adsorption misc Methylene blue misc Carboxyl content |
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misc Nanocellulose beads misc Dye adsorption misc Methylene blue misc Carboxyl content |
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Dye adsorption performance of nanocellulose beads with different carboxyl group content |
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Xue, Jianghua |
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Cellulose |
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Xue, Jianghua Zhu, Enwen Zhu, Hengfeng Liu, Dongning Cai, Haopeng Xiong, Chuanxi Yang, Quanling Shi, Zhuqun |
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dye adsorption performance of nanocellulose beads with different carboxyl group content |
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Dye adsorption performance of nanocellulose beads with different carboxyl group content |
| abstract |
Abstract The problems caused by water pollution are increasingly serious, wastewater contains a lot of heavy metal ions, textile dyes, medicines, etc. However, most adsorption materials usually face problems such as inefficient recycling, high cost, and secondary pollution. As a natural polymer, cellulose has low cost, degradability and good biocompatibility. In this work, by changing the addition amount of sodium hypochlorite during 2,2,6,6-Tetramethylpiperidine-1-oxyl radical (TEMPO) oxidation, nanocellulose with different carboxyl content could be prepared, which is expected to be a good high-efficiency cationic adsorbent due to its rich in hydroxyl groups on the surface and negatively charged. Then the calcium chloride solution was used as the cross-linking agent to prepare TEMPO-oxidized cellulose nanofibril beads (TOCNB) by the dropping solidification method. As the content of carboxyl groups increases, the Zeta potential value of the nanocellulose dispersion became increasingly negative. The nanocellulose beads all presented a good three-dimensional network porous structure. With the increase of carboxyl group content, the specific surface area increases from 173 to 367 $ m^{2} $ $ g^{−1} $, and the adsorption capacity for methylene blue (MB) also gradually strengthened. The saturated adsorption capacity of TOCNB on MB was calculated as high as 925.93 mg $ g^{−1} $. The nanocellulose bead was a cationic adsorbent with highly efficient adsorption and adjustable specific surface area, and the preparation method was simple, fast, efficient and green. © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Abstract The problems caused by water pollution are increasingly serious, wastewater contains a lot of heavy metal ions, textile dyes, medicines, etc. However, most adsorption materials usually face problems such as inefficient recycling, high cost, and secondary pollution. As a natural polymer, cellulose has low cost, degradability and good biocompatibility. In this work, by changing the addition amount of sodium hypochlorite during 2,2,6,6-Tetramethylpiperidine-1-oxyl radical (TEMPO) oxidation, nanocellulose with different carboxyl content could be prepared, which is expected to be a good high-efficiency cationic adsorbent due to its rich in hydroxyl groups on the surface and negatively charged. Then the calcium chloride solution was used as the cross-linking agent to prepare TEMPO-oxidized cellulose nanofibril beads (TOCNB) by the dropping solidification method. As the content of carboxyl groups increases, the Zeta potential value of the nanocellulose dispersion became increasingly negative. The nanocellulose beads all presented a good three-dimensional network porous structure. With the increase of carboxyl group content, the specific surface area increases from 173 to 367 $ m^{2} $ $ g^{−1} $, and the adsorption capacity for methylene blue (MB) also gradually strengthened. The saturated adsorption capacity of TOCNB on MB was calculated as high as 925.93 mg $ g^{−1} $. The nanocellulose bead was a cationic adsorbent with highly efficient adsorption and adjustable specific surface area, and the preparation method was simple, fast, efficient and green. © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Abstract The problems caused by water pollution are increasingly serious, wastewater contains a lot of heavy metal ions, textile dyes, medicines, etc. However, most adsorption materials usually face problems such as inefficient recycling, high cost, and secondary pollution. As a natural polymer, cellulose has low cost, degradability and good biocompatibility. In this work, by changing the addition amount of sodium hypochlorite during 2,2,6,6-Tetramethylpiperidine-1-oxyl radical (TEMPO) oxidation, nanocellulose with different carboxyl content could be prepared, which is expected to be a good high-efficiency cationic adsorbent due to its rich in hydroxyl groups on the surface and negatively charged. Then the calcium chloride solution was used as the cross-linking agent to prepare TEMPO-oxidized cellulose nanofibril beads (TOCNB) by the dropping solidification method. As the content of carboxyl groups increases, the Zeta potential value of the nanocellulose dispersion became increasingly negative. The nanocellulose beads all presented a good three-dimensional network porous structure. With the increase of carboxyl group content, the specific surface area increases from 173 to 367 $ m^{2} $ $ g^{−1} $, and the adsorption capacity for methylene blue (MB) also gradually strengthened. The saturated adsorption capacity of TOCNB on MB was calculated as high as 925.93 mg $ g^{−1} $. The nanocellulose bead was a cationic adsorbent with highly efficient adsorption and adjustable specific surface area, and the preparation method was simple, fast, efficient and green. © The Author(s), under exclusive licence to Springer Nature B.V. 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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Dye adsorption performance of nanocellulose beads with different carboxyl group content |
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https://dx.doi.org/10.1007/s10570-022-04964-1 |
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Zhu, Enwen Zhu, Hengfeng Liu, Dongning Cai, Haopeng Xiong, Chuanxi Yang, Quanling Shi, Zhuqun |
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Zhu, Enwen Zhu, Hengfeng Liu, Dongning Cai, Haopeng Xiong, Chuanxi Yang, Quanling Shi, Zhuqun |
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10.1007/s10570-022-04964-1 |
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2024-07-04T00:13:21.223Z |
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| score |
7.4008236 |