Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets
Nanoporous layered titanate (HTO) nanosheet membranes were fabricated via restacking nanoporous HTO nanosheets on a hydrophilic polytetrafluoroethylene (PTFE) filter substrate. Nanoporous HTO nanosheets were prepared by exfoliating a nanoporous HTO that was obtained by selectively dissolving $ BaTiO...
Ausführliche Beschreibung
Autor*in: |
Yao, Fangyi [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2022 |
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Schlagwörter: |
Hydrophilic separation membrane |
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Anmerkung: |
© The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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Übergeordnetes Werk: |
Enthalten in: Advanced composites and hybrid materials - [Cham] : Springer International Publishing, 2017, 6(2022), 1 vom: 30. Nov. |
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Übergeordnetes Werk: |
volume:6 ; year:2022 ; number:1 ; day:30 ; month:11 |
Links: |
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DOI / URN: |
10.1007/s42114-022-00579-z |
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Katalog-ID: |
SPR049511971 |
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520 | |a Nanoporous layered titanate (HTO) nanosheet membranes were fabricated via restacking nanoporous HTO nanosheets on a hydrophilic polytetrafluoroethylene (PTFE) filter substrate. Nanoporous HTO nanosheets were prepared by exfoliating a nanoporous HTO that was obtained by selectively dissolving $ BaTiO_{3} $ (BT) nanoparticles in a mesocrystalline BT/HTO nanocomposite in an HCl solution. The BT/HTO nanocomposites were synthesized by the solvothermal treatment of HTO platelike particles in a Ba(OH)2 solution. The pore size of the nanoporous HTO nanosheet membrane was controlled by the BT nanoparticle size in the BT/HTO nanocomposite. Meanwhile, the size of the BT nanoparticle was controllable by the solvothermal synthesis conditions of the BT/HTO nanocomposite, including the reaction temperature, Ba/Ti mole ratio, and solvent in the reaction system. Furthermore, we designed a self-adjusting membrane thickness process (SAMTP) to efficiently fabricate nanoporous HTO nanosheet membranes on the PTFE substrate. The rejection of solutes with different sizes and water permeance capacities demonstrated that the nanoporous HTO nanosheet membranes fabricated by the SAMTP possessed size-controlled nanopores with uniform size in the range of 1.5–100 nm, uniform nanometer-scale thicknesses, excellent hydrophilicity, high water permeance, and good durability. Thus, the fabricated nanoporous HTO nanosheet membranes would be excellent candidates for water treatment and molecule separation. Graphical Abstract In a solvothermal soft chemical process to drill uniform nanopores in a layered titanate nanosheet ($ H_{1.07} %$ Ti_{1.73} %$ O_{4} $, HTO), a technique (SAMTP) was developed for fabricating nanoporous titanate nanosheet membranes for low energy consumption nanofiltration processes. | ||
650 | 4 | |a Inorganic nanoporous membrane |7 (dpeaa)DE-He213 | |
650 | 4 | |a Hydrophilic separation membrane |7 (dpeaa)DE-He213 | |
650 | 4 | |a Nanoporous layered titanate nanosheet |7 (dpeaa)DE-He213 | |
650 | 4 | |a Water treatment |7 (dpeaa)DE-He213 | |
700 | 1 | |a Zhang, Wenxiong |4 aut | |
700 | 1 | |a Hu, Dengwei |4 aut | |
700 | 1 | |a Li, Sen |4 aut | |
700 | 1 | |a Kong, Xingang |4 aut | |
700 | 1 | |a Uemura, Shinobu |4 aut | |
700 | 1 | |a Kusunose, Takafumi |4 aut | |
700 | 1 | |a Feng, Qi |4 aut | |
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10.1007/s42114-022-00579-z doi (DE-627)SPR049511971 (SPR)s42114-022-00579-z-e DE-627 ger DE-627 rakwb eng Yao, Fangyi verfasserin aut Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Nanoporous layered titanate (HTO) nanosheet membranes were fabricated via restacking nanoporous HTO nanosheets on a hydrophilic polytetrafluoroethylene (PTFE) filter substrate. Nanoporous HTO nanosheets were prepared by exfoliating a nanoporous HTO that was obtained by selectively dissolving $ BaTiO_{3} $ (BT) nanoparticles in a mesocrystalline BT/HTO nanocomposite in an HCl solution. The BT/HTO nanocomposites were synthesized by the solvothermal treatment of HTO platelike particles in a Ba(OH)2 solution. The pore size of the nanoporous HTO nanosheet membrane was controlled by the BT nanoparticle size in the BT/HTO nanocomposite. Meanwhile, the size of the BT nanoparticle was controllable by the solvothermal synthesis conditions of the BT/HTO nanocomposite, including the reaction temperature, Ba/Ti mole ratio, and solvent in the reaction system. Furthermore, we designed a self-adjusting membrane thickness process (SAMTP) to efficiently fabricate nanoporous HTO nanosheet membranes on the PTFE substrate. The rejection of solutes with different sizes and water permeance capacities demonstrated that the nanoporous HTO nanosheet membranes fabricated by the SAMTP possessed size-controlled nanopores with uniform size in the range of 1.5–100 nm, uniform nanometer-scale thicknesses, excellent hydrophilicity, high water permeance, and good durability. Thus, the fabricated nanoporous HTO nanosheet membranes would be excellent candidates for water treatment and molecule separation. Graphical Abstract In a solvothermal soft chemical process to drill uniform nanopores in a layered titanate nanosheet ($ H_{1.07} %$ Ti_{1.73} %$ O_{4} $, HTO), a technique (SAMTP) was developed for fabricating nanoporous titanate nanosheet membranes for low energy consumption nanofiltration processes. Inorganic nanoporous membrane (dpeaa)DE-He213 Hydrophilic separation membrane (dpeaa)DE-He213 Nanoporous layered titanate nanosheet (dpeaa)DE-He213 Water treatment (dpeaa)DE-He213 Zhang, Wenxiong aut Hu, Dengwei aut Li, Sen aut Kong, Xingang aut Uemura, Shinobu aut Kusunose, Takafumi aut Feng, Qi aut Enthalten in Advanced composites and hybrid materials [Cham] : Springer International Publishing, 2017 6(2022), 1 vom: 30. Nov. (DE-627)1004720920 (DE-600)2911408-1 2522-0136 nnns volume:6 year:2022 number:1 day:30 month:11 https://dx.doi.org/10.1007/s42114-022-00579-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 6 2022 1 30 11 |
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10.1007/s42114-022-00579-z doi (DE-627)SPR049511971 (SPR)s42114-022-00579-z-e DE-627 ger DE-627 rakwb eng Yao, Fangyi verfasserin aut Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Nanoporous layered titanate (HTO) nanosheet membranes were fabricated via restacking nanoporous HTO nanosheets on a hydrophilic polytetrafluoroethylene (PTFE) filter substrate. Nanoporous HTO nanosheets were prepared by exfoliating a nanoporous HTO that was obtained by selectively dissolving $ BaTiO_{3} $ (BT) nanoparticles in a mesocrystalline BT/HTO nanocomposite in an HCl solution. The BT/HTO nanocomposites were synthesized by the solvothermal treatment of HTO platelike particles in a Ba(OH)2 solution. The pore size of the nanoporous HTO nanosheet membrane was controlled by the BT nanoparticle size in the BT/HTO nanocomposite. Meanwhile, the size of the BT nanoparticle was controllable by the solvothermal synthesis conditions of the BT/HTO nanocomposite, including the reaction temperature, Ba/Ti mole ratio, and solvent in the reaction system. Furthermore, we designed a self-adjusting membrane thickness process (SAMTP) to efficiently fabricate nanoporous HTO nanosheet membranes on the PTFE substrate. The rejection of solutes with different sizes and water permeance capacities demonstrated that the nanoporous HTO nanosheet membranes fabricated by the SAMTP possessed size-controlled nanopores with uniform size in the range of 1.5–100 nm, uniform nanometer-scale thicknesses, excellent hydrophilicity, high water permeance, and good durability. Thus, the fabricated nanoporous HTO nanosheet membranes would be excellent candidates for water treatment and molecule separation. Graphical Abstract In a solvothermal soft chemical process to drill uniform nanopores in a layered titanate nanosheet ($ H_{1.07} %$ Ti_{1.73} %$ O_{4} $, HTO), a technique (SAMTP) was developed for fabricating nanoporous titanate nanosheet membranes for low energy consumption nanofiltration processes. Inorganic nanoporous membrane (dpeaa)DE-He213 Hydrophilic separation membrane (dpeaa)DE-He213 Nanoporous layered titanate nanosheet (dpeaa)DE-He213 Water treatment (dpeaa)DE-He213 Zhang, Wenxiong aut Hu, Dengwei aut Li, Sen aut Kong, Xingang aut Uemura, Shinobu aut Kusunose, Takafumi aut Feng, Qi aut Enthalten in Advanced composites and hybrid materials [Cham] : Springer International Publishing, 2017 6(2022), 1 vom: 30. Nov. (DE-627)1004720920 (DE-600)2911408-1 2522-0136 nnns volume:6 year:2022 number:1 day:30 month:11 https://dx.doi.org/10.1007/s42114-022-00579-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 6 2022 1 30 11 |
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10.1007/s42114-022-00579-z doi (DE-627)SPR049511971 (SPR)s42114-022-00579-z-e DE-627 ger DE-627 rakwb eng Yao, Fangyi verfasserin aut Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Nanoporous layered titanate (HTO) nanosheet membranes were fabricated via restacking nanoporous HTO nanosheets on a hydrophilic polytetrafluoroethylene (PTFE) filter substrate. Nanoporous HTO nanosheets were prepared by exfoliating a nanoporous HTO that was obtained by selectively dissolving $ BaTiO_{3} $ (BT) nanoparticles in a mesocrystalline BT/HTO nanocomposite in an HCl solution. The BT/HTO nanocomposites were synthesized by the solvothermal treatment of HTO platelike particles in a Ba(OH)2 solution. The pore size of the nanoporous HTO nanosheet membrane was controlled by the BT nanoparticle size in the BT/HTO nanocomposite. Meanwhile, the size of the BT nanoparticle was controllable by the solvothermal synthesis conditions of the BT/HTO nanocomposite, including the reaction temperature, Ba/Ti mole ratio, and solvent in the reaction system. Furthermore, we designed a self-adjusting membrane thickness process (SAMTP) to efficiently fabricate nanoporous HTO nanosheet membranes on the PTFE substrate. The rejection of solutes with different sizes and water permeance capacities demonstrated that the nanoporous HTO nanosheet membranes fabricated by the SAMTP possessed size-controlled nanopores with uniform size in the range of 1.5–100 nm, uniform nanometer-scale thicknesses, excellent hydrophilicity, high water permeance, and good durability. Thus, the fabricated nanoporous HTO nanosheet membranes would be excellent candidates for water treatment and molecule separation. Graphical Abstract In a solvothermal soft chemical process to drill uniform nanopores in a layered titanate nanosheet ($ H_{1.07} %$ Ti_{1.73} %$ O_{4} $, HTO), a technique (SAMTP) was developed for fabricating nanoporous titanate nanosheet membranes for low energy consumption nanofiltration processes. Inorganic nanoporous membrane (dpeaa)DE-He213 Hydrophilic separation membrane (dpeaa)DE-He213 Nanoporous layered titanate nanosheet (dpeaa)DE-He213 Water treatment (dpeaa)DE-He213 Zhang, Wenxiong aut Hu, Dengwei aut Li, Sen aut Kong, Xingang aut Uemura, Shinobu aut Kusunose, Takafumi aut Feng, Qi aut Enthalten in Advanced composites and hybrid materials [Cham] : Springer International Publishing, 2017 6(2022), 1 vom: 30. Nov. (DE-627)1004720920 (DE-600)2911408-1 2522-0136 nnns volume:6 year:2022 number:1 day:30 month:11 https://dx.doi.org/10.1007/s42114-022-00579-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 6 2022 1 30 11 |
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10.1007/s42114-022-00579-z doi (DE-627)SPR049511971 (SPR)s42114-022-00579-z-e DE-627 ger DE-627 rakwb eng Yao, Fangyi verfasserin aut Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Nanoporous layered titanate (HTO) nanosheet membranes were fabricated via restacking nanoporous HTO nanosheets on a hydrophilic polytetrafluoroethylene (PTFE) filter substrate. Nanoporous HTO nanosheets were prepared by exfoliating a nanoporous HTO that was obtained by selectively dissolving $ BaTiO_{3} $ (BT) nanoparticles in a mesocrystalline BT/HTO nanocomposite in an HCl solution. The BT/HTO nanocomposites were synthesized by the solvothermal treatment of HTO platelike particles in a Ba(OH)2 solution. The pore size of the nanoporous HTO nanosheet membrane was controlled by the BT nanoparticle size in the BT/HTO nanocomposite. Meanwhile, the size of the BT nanoparticle was controllable by the solvothermal synthesis conditions of the BT/HTO nanocomposite, including the reaction temperature, Ba/Ti mole ratio, and solvent in the reaction system. Furthermore, we designed a self-adjusting membrane thickness process (SAMTP) to efficiently fabricate nanoporous HTO nanosheet membranes on the PTFE substrate. The rejection of solutes with different sizes and water permeance capacities demonstrated that the nanoporous HTO nanosheet membranes fabricated by the SAMTP possessed size-controlled nanopores with uniform size in the range of 1.5–100 nm, uniform nanometer-scale thicknesses, excellent hydrophilicity, high water permeance, and good durability. Thus, the fabricated nanoporous HTO nanosheet membranes would be excellent candidates for water treatment and molecule separation. Graphical Abstract In a solvothermal soft chemical process to drill uniform nanopores in a layered titanate nanosheet ($ H_{1.07} %$ Ti_{1.73} %$ O_{4} $, HTO), a technique (SAMTP) was developed for fabricating nanoporous titanate nanosheet membranes for low energy consumption nanofiltration processes. Inorganic nanoporous membrane (dpeaa)DE-He213 Hydrophilic separation membrane (dpeaa)DE-He213 Nanoporous layered titanate nanosheet (dpeaa)DE-He213 Water treatment (dpeaa)DE-He213 Zhang, Wenxiong aut Hu, Dengwei aut Li, Sen aut Kong, Xingang aut Uemura, Shinobu aut Kusunose, Takafumi aut Feng, Qi aut Enthalten in Advanced composites and hybrid materials [Cham] : Springer International Publishing, 2017 6(2022), 1 vom: 30. Nov. (DE-627)1004720920 (DE-600)2911408-1 2522-0136 nnns volume:6 year:2022 number:1 day:30 month:11 https://dx.doi.org/10.1007/s42114-022-00579-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 6 2022 1 30 11 |
allfieldsSound |
10.1007/s42114-022-00579-z doi (DE-627)SPR049511971 (SPR)s42114-022-00579-z-e DE-627 ger DE-627 rakwb eng Yao, Fangyi verfasserin aut Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Nanoporous layered titanate (HTO) nanosheet membranes were fabricated via restacking nanoporous HTO nanosheets on a hydrophilic polytetrafluoroethylene (PTFE) filter substrate. Nanoporous HTO nanosheets were prepared by exfoliating a nanoporous HTO that was obtained by selectively dissolving $ BaTiO_{3} $ (BT) nanoparticles in a mesocrystalline BT/HTO nanocomposite in an HCl solution. The BT/HTO nanocomposites were synthesized by the solvothermal treatment of HTO platelike particles in a Ba(OH)2 solution. The pore size of the nanoporous HTO nanosheet membrane was controlled by the BT nanoparticle size in the BT/HTO nanocomposite. Meanwhile, the size of the BT nanoparticle was controllable by the solvothermal synthesis conditions of the BT/HTO nanocomposite, including the reaction temperature, Ba/Ti mole ratio, and solvent in the reaction system. Furthermore, we designed a self-adjusting membrane thickness process (SAMTP) to efficiently fabricate nanoporous HTO nanosheet membranes on the PTFE substrate. The rejection of solutes with different sizes and water permeance capacities demonstrated that the nanoporous HTO nanosheet membranes fabricated by the SAMTP possessed size-controlled nanopores with uniform size in the range of 1.5–100 nm, uniform nanometer-scale thicknesses, excellent hydrophilicity, high water permeance, and good durability. Thus, the fabricated nanoporous HTO nanosheet membranes would be excellent candidates for water treatment and molecule separation. Graphical Abstract In a solvothermal soft chemical process to drill uniform nanopores in a layered titanate nanosheet ($ H_{1.07} %$ Ti_{1.73} %$ O_{4} $, HTO), a technique (SAMTP) was developed for fabricating nanoporous titanate nanosheet membranes for low energy consumption nanofiltration processes. Inorganic nanoporous membrane (dpeaa)DE-He213 Hydrophilic separation membrane (dpeaa)DE-He213 Nanoporous layered titanate nanosheet (dpeaa)DE-He213 Water treatment (dpeaa)DE-He213 Zhang, Wenxiong aut Hu, Dengwei aut Li, Sen aut Kong, Xingang aut Uemura, Shinobu aut Kusunose, Takafumi aut Feng, Qi aut Enthalten in Advanced composites and hybrid materials [Cham] : Springer International Publishing, 2017 6(2022), 1 vom: 30. Nov. (DE-627)1004720920 (DE-600)2911408-1 2522-0136 nnns volume:6 year:2022 number:1 day:30 month:11 https://dx.doi.org/10.1007/s42114-022-00579-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 6 2022 1 30 11 |
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Enthalten in Advanced composites and hybrid materials 6(2022), 1 vom: 30. Nov. volume:6 year:2022 number:1 day:30 month:11 |
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Enthalten in Advanced composites and hybrid materials 6(2022), 1 vom: 30. Nov. volume:6 year:2022 number:1 day:30 month:11 |
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Inorganic nanoporous membrane Hydrophilic separation membrane Nanoporous layered titanate nanosheet Water treatment |
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Yao, Fangyi @@aut@@ Zhang, Wenxiong @@aut@@ Hu, Dengwei @@aut@@ Li, Sen @@aut@@ Kong, Xingang @@aut@@ Uemura, Shinobu @@aut@@ Kusunose, Takafumi @@aut@@ Feng, Qi @@aut@@ |
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2022-11-30T00:00:00Z |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR049511971</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230301064804.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230301s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s42114-022-00579-z</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR049511971</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s42114-022-00579-z-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Yao, Fangyi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Nanoporous layered titanate (HTO) nanosheet membranes were fabricated via restacking nanoporous HTO nanosheets on a hydrophilic polytetrafluoroethylene (PTFE) filter substrate. Nanoporous HTO nanosheets were prepared by exfoliating a nanoporous HTO that was obtained by selectively dissolving $ BaTiO_{3} $ (BT) nanoparticles in a mesocrystalline BT/HTO nanocomposite in an HCl solution. The BT/HTO nanocomposites were synthesized by the solvothermal treatment of HTO platelike particles in a Ba(OH)2 solution. The pore size of the nanoporous HTO nanosheet membrane was controlled by the BT nanoparticle size in the BT/HTO nanocomposite. Meanwhile, the size of the BT nanoparticle was controllable by the solvothermal synthesis conditions of the BT/HTO nanocomposite, including the reaction temperature, Ba/Ti mole ratio, and solvent in the reaction system. Furthermore, we designed a self-adjusting membrane thickness process (SAMTP) to efficiently fabricate nanoporous HTO nanosheet membranes on the PTFE substrate. The rejection of solutes with different sizes and water permeance capacities demonstrated that the nanoporous HTO nanosheet membranes fabricated by the SAMTP possessed size-controlled nanopores with uniform size in the range of 1.5–100 nm, uniform nanometer-scale thicknesses, excellent hydrophilicity, high water permeance, and good durability. Thus, the fabricated nanoporous HTO nanosheet membranes would be excellent candidates for water treatment and molecule separation. Graphical Abstract In a solvothermal soft chemical process to drill uniform nanopores in a layered titanate nanosheet ($ H_{1.07} %$ Ti_{1.73} %$ O_{4} $, HTO), a technique (SAMTP) was developed for fabricating nanoporous titanate nanosheet membranes for low energy consumption nanofiltration processes.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Inorganic nanoporous membrane</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hydrophilic separation membrane</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nanoporous layered titanate nanosheet</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Water treatment</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Wenxiong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Hu, Dengwei</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Sen</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kong, Xingang</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Uemura, Shinobu</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kusunose, Takafumi</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Feng, Qi</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Advanced composites and hybrid materials</subfield><subfield code="d">[Cham] : Springer International Publishing, 2017</subfield><subfield code="g">6(2022), 1 vom: 30. 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|
author |
Yao, Fangyi |
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Yao, Fangyi misc Inorganic nanoporous membrane misc Hydrophilic separation membrane misc Nanoporous layered titanate nanosheet misc Water treatment Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets |
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Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets Inorganic nanoporous membrane (dpeaa)DE-He213 Hydrophilic separation membrane (dpeaa)DE-He213 Nanoporous layered titanate nanosheet (dpeaa)DE-He213 Water treatment (dpeaa)DE-He213 |
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misc Inorganic nanoporous membrane misc Hydrophilic separation membrane misc Nanoporous layered titanate nanosheet misc Water treatment |
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misc Inorganic nanoporous membrane misc Hydrophilic separation membrane misc Nanoporous layered titanate nanosheet misc Water treatment |
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Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets |
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Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets |
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Advanced composites and hybrid materials |
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Yao, Fangyi Zhang, Wenxiong Hu, Dengwei Li, Sen Kong, Xingang Uemura, Shinobu Kusunose, Takafumi Feng, Qi |
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ultra-hydrophilic nanofiltration membranes fabricated via punching in the hto nanosheets |
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Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets |
abstract |
Nanoporous layered titanate (HTO) nanosheet membranes were fabricated via restacking nanoporous HTO nanosheets on a hydrophilic polytetrafluoroethylene (PTFE) filter substrate. Nanoporous HTO nanosheets were prepared by exfoliating a nanoporous HTO that was obtained by selectively dissolving $ BaTiO_{3} $ (BT) nanoparticles in a mesocrystalline BT/HTO nanocomposite in an HCl solution. The BT/HTO nanocomposites were synthesized by the solvothermal treatment of HTO platelike particles in a Ba(OH)2 solution. The pore size of the nanoporous HTO nanosheet membrane was controlled by the BT nanoparticle size in the BT/HTO nanocomposite. Meanwhile, the size of the BT nanoparticle was controllable by the solvothermal synthesis conditions of the BT/HTO nanocomposite, including the reaction temperature, Ba/Ti mole ratio, and solvent in the reaction system. Furthermore, we designed a self-adjusting membrane thickness process (SAMTP) to efficiently fabricate nanoporous HTO nanosheet membranes on the PTFE substrate. The rejection of solutes with different sizes and water permeance capacities demonstrated that the nanoporous HTO nanosheet membranes fabricated by the SAMTP possessed size-controlled nanopores with uniform size in the range of 1.5–100 nm, uniform nanometer-scale thicknesses, excellent hydrophilicity, high water permeance, and good durability. Thus, the fabricated nanoporous HTO nanosheet membranes would be excellent candidates for water treatment and molecule separation. Graphical Abstract In a solvothermal soft chemical process to drill uniform nanopores in a layered titanate nanosheet ($ H_{1.07} %$ Ti_{1.73} %$ O_{4} $, HTO), a technique (SAMTP) was developed for fabricating nanoporous titanate nanosheet membranes for low energy consumption nanofiltration processes. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
abstractGer |
Nanoporous layered titanate (HTO) nanosheet membranes were fabricated via restacking nanoporous HTO nanosheets on a hydrophilic polytetrafluoroethylene (PTFE) filter substrate. Nanoporous HTO nanosheets were prepared by exfoliating a nanoporous HTO that was obtained by selectively dissolving $ BaTiO_{3} $ (BT) nanoparticles in a mesocrystalline BT/HTO nanocomposite in an HCl solution. The BT/HTO nanocomposites were synthesized by the solvothermal treatment of HTO platelike particles in a Ba(OH)2 solution. The pore size of the nanoporous HTO nanosheet membrane was controlled by the BT nanoparticle size in the BT/HTO nanocomposite. Meanwhile, the size of the BT nanoparticle was controllable by the solvothermal synthesis conditions of the BT/HTO nanocomposite, including the reaction temperature, Ba/Ti mole ratio, and solvent in the reaction system. Furthermore, we designed a self-adjusting membrane thickness process (SAMTP) to efficiently fabricate nanoporous HTO nanosheet membranes on the PTFE substrate. The rejection of solutes with different sizes and water permeance capacities demonstrated that the nanoporous HTO nanosheet membranes fabricated by the SAMTP possessed size-controlled nanopores with uniform size in the range of 1.5–100 nm, uniform nanometer-scale thicknesses, excellent hydrophilicity, high water permeance, and good durability. Thus, the fabricated nanoporous HTO nanosheet membranes would be excellent candidates for water treatment and molecule separation. Graphical Abstract In a solvothermal soft chemical process to drill uniform nanopores in a layered titanate nanosheet ($ H_{1.07} %$ Ti_{1.73} %$ O_{4} $, HTO), a technique (SAMTP) was developed for fabricating nanoporous titanate nanosheet membranes for low energy consumption nanofiltration processes. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
abstract_unstemmed |
Nanoporous layered titanate (HTO) nanosheet membranes were fabricated via restacking nanoporous HTO nanosheets on a hydrophilic polytetrafluoroethylene (PTFE) filter substrate. Nanoporous HTO nanosheets were prepared by exfoliating a nanoporous HTO that was obtained by selectively dissolving $ BaTiO_{3} $ (BT) nanoparticles in a mesocrystalline BT/HTO nanocomposite in an HCl solution. The BT/HTO nanocomposites were synthesized by the solvothermal treatment of HTO platelike particles in a Ba(OH)2 solution. The pore size of the nanoporous HTO nanosheet membrane was controlled by the BT nanoparticle size in the BT/HTO nanocomposite. Meanwhile, the size of the BT nanoparticle was controllable by the solvothermal synthesis conditions of the BT/HTO nanocomposite, including the reaction temperature, Ba/Ti mole ratio, and solvent in the reaction system. Furthermore, we designed a self-adjusting membrane thickness process (SAMTP) to efficiently fabricate nanoporous HTO nanosheet membranes on the PTFE substrate. The rejection of solutes with different sizes and water permeance capacities demonstrated that the nanoporous HTO nanosheet membranes fabricated by the SAMTP possessed size-controlled nanopores with uniform size in the range of 1.5–100 nm, uniform nanometer-scale thicknesses, excellent hydrophilicity, high water permeance, and good durability. Thus, the fabricated nanoporous HTO nanosheet membranes would be excellent candidates for water treatment and molecule separation. Graphical Abstract In a solvothermal soft chemical process to drill uniform nanopores in a layered titanate nanosheet ($ H_{1.07} %$ Ti_{1.73} %$ O_{4} $, HTO), a technique (SAMTP) was developed for fabricating nanoporous titanate nanosheet membranes for low energy consumption nanofiltration processes. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
collection_details |
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container_issue |
1 |
title_short |
Ultra-hydrophilic nanofiltration membranes fabricated via punching in the HTO nanosheets |
url |
https://dx.doi.org/10.1007/s42114-022-00579-z |
remote_bool |
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author2 |
Zhang, Wenxiong Hu, Dengwei Li, Sen Kong, Xingang Uemura, Shinobu Kusunose, Takafumi Feng, Qi |
author2Str |
Zhang, Wenxiong Hu, Dengwei Li, Sen Kong, Xingang Uemura, Shinobu Kusunose, Takafumi Feng, Qi |
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doi_str |
10.1007/s42114-022-00579-z |
up_date |
2024-07-04T01:07:22.131Z |
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|
score |
7.400361 |