Deoxylapachol in Tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood
Abstract Kraft cooking is the predominant technology in the pulp and paper industry. However, it is necessary to improve its efficiency and yield. The use of catalysts in kraft cooking increases pulp yield, reduces lignin content in pulp fibers, and energy consumption. In this study, natural 2-methy...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Anita, Yulia [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer Nature B.V. 2023. corrected publication 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Cellulose - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994, 30(2023), 5 vom: 27. Jan., Seite 3363-3375 |
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| Übergeordnetes Werk: |
volume:30 ; year:2023 ; number:5 ; day:27 ; month:01 ; pages:3363-3375 |
| Links: |
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| DOI / URN: |
10.1007/s10570-023-05063-5 |
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SPR04961584X |
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| 520 | |a Abstract Kraft cooking is the predominant technology in the pulp and paper industry. However, it is necessary to improve its efficiency and yield. The use of catalysts in kraft cooking increases pulp yield, reduces lignin content in pulp fibers, and energy consumption. In this study, natural 2-methylanthraquinone (2-MAQ) and deoxylapachol were isolated from the acetone extracts of Indonesian Jepara Tectona grandis (teak) wood using column chromatography and used as catalysts in alkaline cooking. Gas chromatography–mass spectrometry revealed that the extract contained deoxylapachol, iso-deoxylapachol, and 2-MAQ. The Indonesian Gunung Kidul teak wood extract also contained lapachol. The kraft cooking time profile of Eucalyptus globulus wood at 145 ºC and charged with 17% active alkali demonstrated the ability of deoxylapachol to enhance the delignification rate and retain carbohydrates. The lignin content in the kraft-deoxylapachol cooking pulp was determined to be lower than that of the control pulp prepared without catalyst. The molecular weights determined for dissolved lignin in black liquor revealed that the addition of deoxylapachol accelerated lignin decomposition; meanwhile, 86% of the carbohydrates were retained at the end of the kraft-deoxylapachol cooking process. An approximately 0.8–1.2% higher pulp yield was obtained when deoxylapachol was added compared to that obtained in the absence of the catalyst. This study showed that natural deoxylapachol from teak wood can be a promising cooking catalyst for the pulp and paper industry and potentially offers a beneficial impact on society and the environment. | ||
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10.1007/s10570-023-05063-5 doi (DE-627)SPR04961584X (SPR)s10570-023-05063-5-e DE-627 ger DE-627 rakwb eng Anita, Yulia verfasserin (orcid)0000-0003-0217-2079 aut Deoxylapachol in Tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2023. corrected publication 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Kraft cooking is the predominant technology in the pulp and paper industry. However, it is necessary to improve its efficiency and yield. The use of catalysts in kraft cooking increases pulp yield, reduces lignin content in pulp fibers, and energy consumption. In this study, natural 2-methylanthraquinone (2-MAQ) and deoxylapachol were isolated from the acetone extracts of Indonesian Jepara Tectona grandis (teak) wood using column chromatography and used as catalysts in alkaline cooking. Gas chromatography–mass spectrometry revealed that the extract contained deoxylapachol, iso-deoxylapachol, and 2-MAQ. The Indonesian Gunung Kidul teak wood extract also contained lapachol. The kraft cooking time profile of Eucalyptus globulus wood at 145 ºC and charged with 17% active alkali demonstrated the ability of deoxylapachol to enhance the delignification rate and retain carbohydrates. The lignin content in the kraft-deoxylapachol cooking pulp was determined to be lower than that of the control pulp prepared without catalyst. The molecular weights determined for dissolved lignin in black liquor revealed that the addition of deoxylapachol accelerated lignin decomposition; meanwhile, 86% of the carbohydrates were retained at the end of the kraft-deoxylapachol cooking process. An approximately 0.8–1.2% higher pulp yield was obtained when deoxylapachol was added compared to that obtained in the absence of the catalyst. This study showed that natural deoxylapachol from teak wood can be a promising cooking catalyst for the pulp and paper industry and potentially offers a beneficial impact on society and the environment. Cooking catalyst (dpeaa)DE-He213 Deoxylapachol (dpeaa)DE-He213 Delignification (dpeaa)DE-He213 Kraft cooking (dpeaa)DE-He213 Anthraquinone (dpeaa)DE-He213 Sari, Esty Octiana (orcid)0000-0003-4903-6429 aut Nakagawa-izumi, Akiko (orcid)0000-0002-0984-6227 aut Ohi, Hiroshi (orcid)0000-0001-8114-1275 aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 30(2023), 5 vom: 27. Jan., Seite 3363-3375 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:30 year:2023 number:5 day:27 month:01 pages:3363-3375 https://dx.doi.org/10.1007/s10570-023-05063-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2023 5 27 01 3363-3375 |
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10.1007/s10570-023-05063-5 doi (DE-627)SPR04961584X (SPR)s10570-023-05063-5-e DE-627 ger DE-627 rakwb eng Anita, Yulia verfasserin (orcid)0000-0003-0217-2079 aut Deoxylapachol in Tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2023. corrected publication 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Kraft cooking is the predominant technology in the pulp and paper industry. However, it is necessary to improve its efficiency and yield. The use of catalysts in kraft cooking increases pulp yield, reduces lignin content in pulp fibers, and energy consumption. In this study, natural 2-methylanthraquinone (2-MAQ) and deoxylapachol were isolated from the acetone extracts of Indonesian Jepara Tectona grandis (teak) wood using column chromatography and used as catalysts in alkaline cooking. Gas chromatography–mass spectrometry revealed that the extract contained deoxylapachol, iso-deoxylapachol, and 2-MAQ. The Indonesian Gunung Kidul teak wood extract also contained lapachol. The kraft cooking time profile of Eucalyptus globulus wood at 145 ºC and charged with 17% active alkali demonstrated the ability of deoxylapachol to enhance the delignification rate and retain carbohydrates. The lignin content in the kraft-deoxylapachol cooking pulp was determined to be lower than that of the control pulp prepared without catalyst. The molecular weights determined for dissolved lignin in black liquor revealed that the addition of deoxylapachol accelerated lignin decomposition; meanwhile, 86% of the carbohydrates were retained at the end of the kraft-deoxylapachol cooking process. An approximately 0.8–1.2% higher pulp yield was obtained when deoxylapachol was added compared to that obtained in the absence of the catalyst. This study showed that natural deoxylapachol from teak wood can be a promising cooking catalyst for the pulp and paper industry and potentially offers a beneficial impact on society and the environment. Cooking catalyst (dpeaa)DE-He213 Deoxylapachol (dpeaa)DE-He213 Delignification (dpeaa)DE-He213 Kraft cooking (dpeaa)DE-He213 Anthraquinone (dpeaa)DE-He213 Sari, Esty Octiana (orcid)0000-0003-4903-6429 aut Nakagawa-izumi, Akiko (orcid)0000-0002-0984-6227 aut Ohi, Hiroshi (orcid)0000-0001-8114-1275 aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 30(2023), 5 vom: 27. Jan., Seite 3363-3375 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:30 year:2023 number:5 day:27 month:01 pages:3363-3375 https://dx.doi.org/10.1007/s10570-023-05063-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2023 5 27 01 3363-3375 |
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10.1007/s10570-023-05063-5 doi (DE-627)SPR04961584X (SPR)s10570-023-05063-5-e DE-627 ger DE-627 rakwb eng Anita, Yulia verfasserin (orcid)0000-0003-0217-2079 aut Deoxylapachol in Tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2023. corrected publication 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Kraft cooking is the predominant technology in the pulp and paper industry. However, it is necessary to improve its efficiency and yield. The use of catalysts in kraft cooking increases pulp yield, reduces lignin content in pulp fibers, and energy consumption. In this study, natural 2-methylanthraquinone (2-MAQ) and deoxylapachol were isolated from the acetone extracts of Indonesian Jepara Tectona grandis (teak) wood using column chromatography and used as catalysts in alkaline cooking. Gas chromatography–mass spectrometry revealed that the extract contained deoxylapachol, iso-deoxylapachol, and 2-MAQ. The Indonesian Gunung Kidul teak wood extract also contained lapachol. The kraft cooking time profile of Eucalyptus globulus wood at 145 ºC and charged with 17% active alkali demonstrated the ability of deoxylapachol to enhance the delignification rate and retain carbohydrates. The lignin content in the kraft-deoxylapachol cooking pulp was determined to be lower than that of the control pulp prepared without catalyst. The molecular weights determined for dissolved lignin in black liquor revealed that the addition of deoxylapachol accelerated lignin decomposition; meanwhile, 86% of the carbohydrates were retained at the end of the kraft-deoxylapachol cooking process. An approximately 0.8–1.2% higher pulp yield was obtained when deoxylapachol was added compared to that obtained in the absence of the catalyst. This study showed that natural deoxylapachol from teak wood can be a promising cooking catalyst for the pulp and paper industry and potentially offers a beneficial impact on society and the environment. Cooking catalyst (dpeaa)DE-He213 Deoxylapachol (dpeaa)DE-He213 Delignification (dpeaa)DE-He213 Kraft cooking (dpeaa)DE-He213 Anthraquinone (dpeaa)DE-He213 Sari, Esty Octiana (orcid)0000-0003-4903-6429 aut Nakagawa-izumi, Akiko (orcid)0000-0002-0984-6227 aut Ohi, Hiroshi (orcid)0000-0001-8114-1275 aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 30(2023), 5 vom: 27. Jan., Seite 3363-3375 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:30 year:2023 number:5 day:27 month:01 pages:3363-3375 https://dx.doi.org/10.1007/s10570-023-05063-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2023 5 27 01 3363-3375 |
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10.1007/s10570-023-05063-5 doi (DE-627)SPR04961584X (SPR)s10570-023-05063-5-e DE-627 ger DE-627 rakwb eng Anita, Yulia verfasserin (orcid)0000-0003-0217-2079 aut Deoxylapachol in Tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2023. corrected publication 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Kraft cooking is the predominant technology in the pulp and paper industry. However, it is necessary to improve its efficiency and yield. The use of catalysts in kraft cooking increases pulp yield, reduces lignin content in pulp fibers, and energy consumption. In this study, natural 2-methylanthraquinone (2-MAQ) and deoxylapachol were isolated from the acetone extracts of Indonesian Jepara Tectona grandis (teak) wood using column chromatography and used as catalysts in alkaline cooking. Gas chromatography–mass spectrometry revealed that the extract contained deoxylapachol, iso-deoxylapachol, and 2-MAQ. The Indonesian Gunung Kidul teak wood extract also contained lapachol. The kraft cooking time profile of Eucalyptus globulus wood at 145 ºC and charged with 17% active alkali demonstrated the ability of deoxylapachol to enhance the delignification rate and retain carbohydrates. The lignin content in the kraft-deoxylapachol cooking pulp was determined to be lower than that of the control pulp prepared without catalyst. The molecular weights determined for dissolved lignin in black liquor revealed that the addition of deoxylapachol accelerated lignin decomposition; meanwhile, 86% of the carbohydrates were retained at the end of the kraft-deoxylapachol cooking process. An approximately 0.8–1.2% higher pulp yield was obtained when deoxylapachol was added compared to that obtained in the absence of the catalyst. This study showed that natural deoxylapachol from teak wood can be a promising cooking catalyst for the pulp and paper industry and potentially offers a beneficial impact on society and the environment. Cooking catalyst (dpeaa)DE-He213 Deoxylapachol (dpeaa)DE-He213 Delignification (dpeaa)DE-He213 Kraft cooking (dpeaa)DE-He213 Anthraquinone (dpeaa)DE-He213 Sari, Esty Octiana (orcid)0000-0003-4903-6429 aut Nakagawa-izumi, Akiko (orcid)0000-0002-0984-6227 aut Ohi, Hiroshi (orcid)0000-0001-8114-1275 aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 30(2023), 5 vom: 27. Jan., Seite 3363-3375 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:30 year:2023 number:5 day:27 month:01 pages:3363-3375 https://dx.doi.org/10.1007/s10570-023-05063-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2023 5 27 01 3363-3375 |
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10.1007/s10570-023-05063-5 doi (DE-627)SPR04961584X (SPR)s10570-023-05063-5-e DE-627 ger DE-627 rakwb eng Anita, Yulia verfasserin (orcid)0000-0003-0217-2079 aut Deoxylapachol in Tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2023. corrected publication 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Kraft cooking is the predominant technology in the pulp and paper industry. However, it is necessary to improve its efficiency and yield. The use of catalysts in kraft cooking increases pulp yield, reduces lignin content in pulp fibers, and energy consumption. In this study, natural 2-methylanthraquinone (2-MAQ) and deoxylapachol were isolated from the acetone extracts of Indonesian Jepara Tectona grandis (teak) wood using column chromatography and used as catalysts in alkaline cooking. Gas chromatography–mass spectrometry revealed that the extract contained deoxylapachol, iso-deoxylapachol, and 2-MAQ. The Indonesian Gunung Kidul teak wood extract also contained lapachol. The kraft cooking time profile of Eucalyptus globulus wood at 145 ºC and charged with 17% active alkali demonstrated the ability of deoxylapachol to enhance the delignification rate and retain carbohydrates. The lignin content in the kraft-deoxylapachol cooking pulp was determined to be lower than that of the control pulp prepared without catalyst. The molecular weights determined for dissolved lignin in black liquor revealed that the addition of deoxylapachol accelerated lignin decomposition; meanwhile, 86% of the carbohydrates were retained at the end of the kraft-deoxylapachol cooking process. An approximately 0.8–1.2% higher pulp yield was obtained when deoxylapachol was added compared to that obtained in the absence of the catalyst. This study showed that natural deoxylapachol from teak wood can be a promising cooking catalyst for the pulp and paper industry and potentially offers a beneficial impact on society and the environment. Cooking catalyst (dpeaa)DE-He213 Deoxylapachol (dpeaa)DE-He213 Delignification (dpeaa)DE-He213 Kraft cooking (dpeaa)DE-He213 Anthraquinone (dpeaa)DE-He213 Sari, Esty Octiana (orcid)0000-0003-4903-6429 aut Nakagawa-izumi, Akiko (orcid)0000-0002-0984-6227 aut Ohi, Hiroshi (orcid)0000-0001-8114-1275 aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 30(2023), 5 vom: 27. Jan., Seite 3363-3375 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:30 year:2023 number:5 day:27 month:01 pages:3363-3375 https://dx.doi.org/10.1007/s10570-023-05063-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2023 5 27 01 3363-3375 |
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Anita, Yulia @@aut@@ Sari, Esty Octiana @@aut@@ Nakagawa-izumi, Akiko @@aut@@ Ohi, Hiroshi @@aut@@ |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Kraft cooking is the predominant technology in the pulp and paper industry. However, it is necessary to improve its efficiency and yield. The use of catalysts in kraft cooking increases pulp yield, reduces lignin content in pulp fibers, and energy consumption. In this study, natural 2-methylanthraquinone (2-MAQ) and deoxylapachol were isolated from the acetone extracts of Indonesian Jepara Tectona grandis (teak) wood using column chromatography and used as catalysts in alkaline cooking. 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Anita, Yulia |
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Anita, Yulia misc Cooking catalyst misc Deoxylapachol misc Delignification misc Kraft cooking misc Anthraquinone Deoxylapachol in Tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood |
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Deoxylapachol in Tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood Cooking catalyst (dpeaa)DE-He213 Deoxylapachol (dpeaa)DE-He213 Delignification (dpeaa)DE-He213 Kraft cooking (dpeaa)DE-He213 Anthraquinone (dpeaa)DE-He213 |
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Deoxylapachol in Tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood |
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Deoxylapachol in Tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood |
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deoxylapachol in tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood |
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Deoxylapachol in Tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood |
| abstract |
Abstract Kraft cooking is the predominant technology in the pulp and paper industry. However, it is necessary to improve its efficiency and yield. The use of catalysts in kraft cooking increases pulp yield, reduces lignin content in pulp fibers, and energy consumption. In this study, natural 2-methylanthraquinone (2-MAQ) and deoxylapachol were isolated from the acetone extracts of Indonesian Jepara Tectona grandis (teak) wood using column chromatography and used as catalysts in alkaline cooking. Gas chromatography–mass spectrometry revealed that the extract contained deoxylapachol, iso-deoxylapachol, and 2-MAQ. The Indonesian Gunung Kidul teak wood extract also contained lapachol. The kraft cooking time profile of Eucalyptus globulus wood at 145 ºC and charged with 17% active alkali demonstrated the ability of deoxylapachol to enhance the delignification rate and retain carbohydrates. The lignin content in the kraft-deoxylapachol cooking pulp was determined to be lower than that of the control pulp prepared without catalyst. The molecular weights determined for dissolved lignin in black liquor revealed that the addition of deoxylapachol accelerated lignin decomposition; meanwhile, 86% of the carbohydrates were retained at the end of the kraft-deoxylapachol cooking process. An approximately 0.8–1.2% higher pulp yield was obtained when deoxylapachol was added compared to that obtained in the absence of the catalyst. This study showed that natural deoxylapachol from teak wood can be a promising cooking catalyst for the pulp and paper industry and potentially offers a beneficial impact on society and the environment. © The Author(s), under exclusive licence to Springer Nature B.V. 2023. corrected publication 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Abstract Kraft cooking is the predominant technology in the pulp and paper industry. However, it is necessary to improve its efficiency and yield. The use of catalysts in kraft cooking increases pulp yield, reduces lignin content in pulp fibers, and energy consumption. In this study, natural 2-methylanthraquinone (2-MAQ) and deoxylapachol were isolated from the acetone extracts of Indonesian Jepara Tectona grandis (teak) wood using column chromatography and used as catalysts in alkaline cooking. Gas chromatography–mass spectrometry revealed that the extract contained deoxylapachol, iso-deoxylapachol, and 2-MAQ. The Indonesian Gunung Kidul teak wood extract also contained lapachol. The kraft cooking time profile of Eucalyptus globulus wood at 145 ºC and charged with 17% active alkali demonstrated the ability of deoxylapachol to enhance the delignification rate and retain carbohydrates. The lignin content in the kraft-deoxylapachol cooking pulp was determined to be lower than that of the control pulp prepared without catalyst. The molecular weights determined for dissolved lignin in black liquor revealed that the addition of deoxylapachol accelerated lignin decomposition; meanwhile, 86% of the carbohydrates were retained at the end of the kraft-deoxylapachol cooking process. An approximately 0.8–1.2% higher pulp yield was obtained when deoxylapachol was added compared to that obtained in the absence of the catalyst. This study showed that natural deoxylapachol from teak wood can be a promising cooking catalyst for the pulp and paper industry and potentially offers a beneficial impact on society and the environment. © The Author(s), under exclusive licence to Springer Nature B.V. 2023. corrected publication 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Abstract Kraft cooking is the predominant technology in the pulp and paper industry. However, it is necessary to improve its efficiency and yield. The use of catalysts in kraft cooking increases pulp yield, reduces lignin content in pulp fibers, and energy consumption. In this study, natural 2-methylanthraquinone (2-MAQ) and deoxylapachol were isolated from the acetone extracts of Indonesian Jepara Tectona grandis (teak) wood using column chromatography and used as catalysts in alkaline cooking. Gas chromatography–mass spectrometry revealed that the extract contained deoxylapachol, iso-deoxylapachol, and 2-MAQ. The Indonesian Gunung Kidul teak wood extract also contained lapachol. The kraft cooking time profile of Eucalyptus globulus wood at 145 ºC and charged with 17% active alkali demonstrated the ability of deoxylapachol to enhance the delignification rate and retain carbohydrates. The lignin content in the kraft-deoxylapachol cooking pulp was determined to be lower than that of the control pulp prepared without catalyst. The molecular weights determined for dissolved lignin in black liquor revealed that the addition of deoxylapachol accelerated lignin decomposition; meanwhile, 86% of the carbohydrates were retained at the end of the kraft-deoxylapachol cooking process. An approximately 0.8–1.2% higher pulp yield was obtained when deoxylapachol was added compared to that obtained in the absence of the catalyst. This study showed that natural deoxylapachol from teak wood can be a promising cooking catalyst for the pulp and paper industry and potentially offers a beneficial impact on society and the environment. © The Author(s), under exclusive licence to Springer Nature B.V. 2023. corrected publication 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| title_short |
Deoxylapachol in Tectona grandis wood as a catalyst for delignification and carbohydrate protection during the kraft cooking of eucalyptus wood |
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https://dx.doi.org/10.1007/s10570-023-05063-5 |
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Sari, Esty Octiana Nakagawa-izumi, Akiko Ohi, Hiroshi |
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| score |
7.401613 |