Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols ($ C_{3} $–$ C_{6} $) at Different Temperatures from Experimental and Theoretical Points of View
Abstract The densities, %$\rho%$ and speeds of sound, u were measured for pure and the binary mixtures of monoethanolamine (MEA) + 1-alcohols (1-propanol, 1-butanol, 1-pentanol and 1-hexanol) at (298.15–318.15) K and the whole composition range. From the experimental data excess molar volumes, %${V}...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Forghani, Fahime [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Schlagwörter: |
Excess thermal expansion coefficients Isothermal coefficients of excess molar enthalpies |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Journal of solution chemistry - New York, NY [u.a.] : Springer Science + Business Media B.V., 1972, 52(2023), 4 vom: 18. Feb., Seite 385-412 |
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| Übergeordnetes Werk: |
volume:52 ; year:2023 ; number:4 ; day:18 ; month:02 ; pages:385-412 |
| Links: |
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| DOI / URN: |
10.1007/s10953-022-01236-1 |
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| Katalog-ID: |
SPR049656449 |
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| 520 | |a Abstract The densities, %$\rho%$ and speeds of sound, u were measured for pure and the binary mixtures of monoethanolamine (MEA) + 1-alcohols (1-propanol, 1-butanol, 1-pentanol and 1-hexanol) at (298.15–318.15) K and the whole composition range. From the experimental data excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, excess partial molar volumes, %${\overline{V}}_{i}^{\text{E}},%$ excess thermal expansion coefficients, %${\alpha }^{\text{E}}%$, isothermal coefficients of excess molar enthalpies, %$(\partial {H}_{\text{m}}^{\text{E}}/\partial P)_{T,x}%$, isentropic compressibility, %${k}_{\text{s}}^{ }%$ and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$ have been calculated for the binary systems. The excess molar volume and excess isentropic compressibility were correlated with the Redlich–Kister polynomial equation. The excess molar volumes and excess isentropic compressibilities were negative for all binary systems, except, for the system of MEA + 1-hexanol in which excess molar volume showed a sigmoid shape. The effect of temperature and chain length of alcohol on the excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$, are discussed in terms of molecular interactions between unlike molecules. The Extended Real Associated Solution model was applied to correlate the excess molar volumes. | ||
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| 650 | 4 | |a 1-Alcohols |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Speed of sound |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Excess molar volumes |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Excess partial molar volumes |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Excess thermal expansion coefficients |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Isothermal coefficients of excess molar enthalpies |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Excess isentropic compressibility |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a ERAS model |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Iloukhani, Hossein |4 aut | |
| 700 | 1 | |a Khanlarzadeh, Khatereh |4 aut | |
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10.1007/s10953-022-01236-1 doi (DE-627)SPR049656449 (SPR)s10953-022-01236-1-e DE-627 ger DE-627 rakwb eng Forghani, Fahime verfasserin aut Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols ($ C_{3} $–$ C_{6} $) at Different Temperatures from Experimental and Theoretical Points of View 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The densities, %$\rho%$ and speeds of sound, u were measured for pure and the binary mixtures of monoethanolamine (MEA) + 1-alcohols (1-propanol, 1-butanol, 1-pentanol and 1-hexanol) at (298.15–318.15) K and the whole composition range. From the experimental data excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, excess partial molar volumes, %${\overline{V}}_{i}^{\text{E}},%$ excess thermal expansion coefficients, %${\alpha }^{\text{E}}%$, isothermal coefficients of excess molar enthalpies, %$(\partial {H}_{\text{m}}^{\text{E}}/\partial P)_{T,x}%$, isentropic compressibility, %${k}_{\text{s}}^{ }%$ and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$ have been calculated for the binary systems. The excess molar volume and excess isentropic compressibility were correlated with the Redlich–Kister polynomial equation. The excess molar volumes and excess isentropic compressibilities were negative for all binary systems, except, for the system of MEA + 1-hexanol in which excess molar volume showed a sigmoid shape. The effect of temperature and chain length of alcohol on the excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$, are discussed in terms of molecular interactions between unlike molecules. The Extended Real Associated Solution model was applied to correlate the excess molar volumes. Monoethanolamine (dpeaa)DE-He213 1-Alcohols (dpeaa)DE-He213 Speed of sound (dpeaa)DE-He213 Excess molar volumes (dpeaa)DE-He213 Excess partial molar volumes (dpeaa)DE-He213 Excess thermal expansion coefficients (dpeaa)DE-He213 Isothermal coefficients of excess molar enthalpies (dpeaa)DE-He213 Excess isentropic compressibility (dpeaa)DE-He213 ERAS model (dpeaa)DE-He213 Iloukhani, Hossein aut Khanlarzadeh, Khatereh aut Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 52(2023), 4 vom: 18. Feb., Seite 385-412 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:52 year:2023 number:4 day:18 month:02 pages:385-412 https://dx.doi.org/10.1007/s10953-022-01236-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2023 4 18 02 385-412 |
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10.1007/s10953-022-01236-1 doi (DE-627)SPR049656449 (SPR)s10953-022-01236-1-e DE-627 ger DE-627 rakwb eng Forghani, Fahime verfasserin aut Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols ($ C_{3} $–$ C_{6} $) at Different Temperatures from Experimental and Theoretical Points of View 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The densities, %$\rho%$ and speeds of sound, u were measured for pure and the binary mixtures of monoethanolamine (MEA) + 1-alcohols (1-propanol, 1-butanol, 1-pentanol and 1-hexanol) at (298.15–318.15) K and the whole composition range. From the experimental data excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, excess partial molar volumes, %${\overline{V}}_{i}^{\text{E}},%$ excess thermal expansion coefficients, %${\alpha }^{\text{E}}%$, isothermal coefficients of excess molar enthalpies, %$(\partial {H}_{\text{m}}^{\text{E}}/\partial P)_{T,x}%$, isentropic compressibility, %${k}_{\text{s}}^{ }%$ and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$ have been calculated for the binary systems. The excess molar volume and excess isentropic compressibility were correlated with the Redlich–Kister polynomial equation. The excess molar volumes and excess isentropic compressibilities were negative for all binary systems, except, for the system of MEA + 1-hexanol in which excess molar volume showed a sigmoid shape. The effect of temperature and chain length of alcohol on the excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$, are discussed in terms of molecular interactions between unlike molecules. The Extended Real Associated Solution model was applied to correlate the excess molar volumes. Monoethanolamine (dpeaa)DE-He213 1-Alcohols (dpeaa)DE-He213 Speed of sound (dpeaa)DE-He213 Excess molar volumes (dpeaa)DE-He213 Excess partial molar volumes (dpeaa)DE-He213 Excess thermal expansion coefficients (dpeaa)DE-He213 Isothermal coefficients of excess molar enthalpies (dpeaa)DE-He213 Excess isentropic compressibility (dpeaa)DE-He213 ERAS model (dpeaa)DE-He213 Iloukhani, Hossein aut Khanlarzadeh, Khatereh aut Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 52(2023), 4 vom: 18. Feb., Seite 385-412 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:52 year:2023 number:4 day:18 month:02 pages:385-412 https://dx.doi.org/10.1007/s10953-022-01236-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2023 4 18 02 385-412 |
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10.1007/s10953-022-01236-1 doi (DE-627)SPR049656449 (SPR)s10953-022-01236-1-e DE-627 ger DE-627 rakwb eng Forghani, Fahime verfasserin aut Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols ($ C_{3} $–$ C_{6} $) at Different Temperatures from Experimental and Theoretical Points of View 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The densities, %$\rho%$ and speeds of sound, u were measured for pure and the binary mixtures of monoethanolamine (MEA) + 1-alcohols (1-propanol, 1-butanol, 1-pentanol and 1-hexanol) at (298.15–318.15) K and the whole composition range. From the experimental data excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, excess partial molar volumes, %${\overline{V}}_{i}^{\text{E}},%$ excess thermal expansion coefficients, %${\alpha }^{\text{E}}%$, isothermal coefficients of excess molar enthalpies, %$(\partial {H}_{\text{m}}^{\text{E}}/\partial P)_{T,x}%$, isentropic compressibility, %${k}_{\text{s}}^{ }%$ and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$ have been calculated for the binary systems. The excess molar volume and excess isentropic compressibility were correlated with the Redlich–Kister polynomial equation. The excess molar volumes and excess isentropic compressibilities were negative for all binary systems, except, for the system of MEA + 1-hexanol in which excess molar volume showed a sigmoid shape. The effect of temperature and chain length of alcohol on the excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$, are discussed in terms of molecular interactions between unlike molecules. The Extended Real Associated Solution model was applied to correlate the excess molar volumes. Monoethanolamine (dpeaa)DE-He213 1-Alcohols (dpeaa)DE-He213 Speed of sound (dpeaa)DE-He213 Excess molar volumes (dpeaa)DE-He213 Excess partial molar volumes (dpeaa)DE-He213 Excess thermal expansion coefficients (dpeaa)DE-He213 Isothermal coefficients of excess molar enthalpies (dpeaa)DE-He213 Excess isentropic compressibility (dpeaa)DE-He213 ERAS model (dpeaa)DE-He213 Iloukhani, Hossein aut Khanlarzadeh, Khatereh aut Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 52(2023), 4 vom: 18. Feb., Seite 385-412 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:52 year:2023 number:4 day:18 month:02 pages:385-412 https://dx.doi.org/10.1007/s10953-022-01236-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2023 4 18 02 385-412 |
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10.1007/s10953-022-01236-1 doi (DE-627)SPR049656449 (SPR)s10953-022-01236-1-e DE-627 ger DE-627 rakwb eng Forghani, Fahime verfasserin aut Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols ($ C_{3} $–$ C_{6} $) at Different Temperatures from Experimental and Theoretical Points of View 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The densities, %$\rho%$ and speeds of sound, u were measured for pure and the binary mixtures of monoethanolamine (MEA) + 1-alcohols (1-propanol, 1-butanol, 1-pentanol and 1-hexanol) at (298.15–318.15) K and the whole composition range. From the experimental data excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, excess partial molar volumes, %${\overline{V}}_{i}^{\text{E}},%$ excess thermal expansion coefficients, %${\alpha }^{\text{E}}%$, isothermal coefficients of excess molar enthalpies, %$(\partial {H}_{\text{m}}^{\text{E}}/\partial P)_{T,x}%$, isentropic compressibility, %${k}_{\text{s}}^{ }%$ and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$ have been calculated for the binary systems. The excess molar volume and excess isentropic compressibility were correlated with the Redlich–Kister polynomial equation. The excess molar volumes and excess isentropic compressibilities were negative for all binary systems, except, for the system of MEA + 1-hexanol in which excess molar volume showed a sigmoid shape. The effect of temperature and chain length of alcohol on the excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$, are discussed in terms of molecular interactions between unlike molecules. The Extended Real Associated Solution model was applied to correlate the excess molar volumes. Monoethanolamine (dpeaa)DE-He213 1-Alcohols (dpeaa)DE-He213 Speed of sound (dpeaa)DE-He213 Excess molar volumes (dpeaa)DE-He213 Excess partial molar volumes (dpeaa)DE-He213 Excess thermal expansion coefficients (dpeaa)DE-He213 Isothermal coefficients of excess molar enthalpies (dpeaa)DE-He213 Excess isentropic compressibility (dpeaa)DE-He213 ERAS model (dpeaa)DE-He213 Iloukhani, Hossein aut Khanlarzadeh, Khatereh aut Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 52(2023), 4 vom: 18. Feb., Seite 385-412 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:52 year:2023 number:4 day:18 month:02 pages:385-412 https://dx.doi.org/10.1007/s10953-022-01236-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2023 4 18 02 385-412 |
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10.1007/s10953-022-01236-1 doi (DE-627)SPR049656449 (SPR)s10953-022-01236-1-e DE-627 ger DE-627 rakwb eng Forghani, Fahime verfasserin aut Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols ($ C_{3} $–$ C_{6} $) at Different Temperatures from Experimental and Theoretical Points of View 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The densities, %$\rho%$ and speeds of sound, u were measured for pure and the binary mixtures of monoethanolamine (MEA) + 1-alcohols (1-propanol, 1-butanol, 1-pentanol and 1-hexanol) at (298.15–318.15) K and the whole composition range. From the experimental data excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, excess partial molar volumes, %${\overline{V}}_{i}^{\text{E}},%$ excess thermal expansion coefficients, %${\alpha }^{\text{E}}%$, isothermal coefficients of excess molar enthalpies, %$(\partial {H}_{\text{m}}^{\text{E}}/\partial P)_{T,x}%$, isentropic compressibility, %${k}_{\text{s}}^{ }%$ and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$ have been calculated for the binary systems. The excess molar volume and excess isentropic compressibility were correlated with the Redlich–Kister polynomial equation. The excess molar volumes and excess isentropic compressibilities were negative for all binary systems, except, for the system of MEA + 1-hexanol in which excess molar volume showed a sigmoid shape. The effect of temperature and chain length of alcohol on the excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$, are discussed in terms of molecular interactions between unlike molecules. The Extended Real Associated Solution model was applied to correlate the excess molar volumes. Monoethanolamine (dpeaa)DE-He213 1-Alcohols (dpeaa)DE-He213 Speed of sound (dpeaa)DE-He213 Excess molar volumes (dpeaa)DE-He213 Excess partial molar volumes (dpeaa)DE-He213 Excess thermal expansion coefficients (dpeaa)DE-He213 Isothermal coefficients of excess molar enthalpies (dpeaa)DE-He213 Excess isentropic compressibility (dpeaa)DE-He213 ERAS model (dpeaa)DE-He213 Iloukhani, Hossein aut Khanlarzadeh, Khatereh aut Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 52(2023), 4 vom: 18. Feb., Seite 385-412 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:52 year:2023 number:4 day:18 month:02 pages:385-412 https://dx.doi.org/10.1007/s10953-022-01236-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2023 4 18 02 385-412 |
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Monoethanolamine 1-Alcohols Speed of sound Excess molar volumes Excess partial molar volumes Excess thermal expansion coefficients Isothermal coefficients of excess molar enthalpies Excess isentropic compressibility ERAS model |
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Forghani, Fahime @@aut@@ Iloukhani, Hossein @@aut@@ Khanlarzadeh, Khatereh @@aut@@ |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The densities, %$\rho%$ and speeds of sound, u were measured for pure and the binary mixtures of monoethanolamine (MEA) + 1-alcohols (1-propanol, 1-butanol, 1-pentanol and 1-hexanol) at (298.15–318.15) K and the whole composition range. From the experimental data excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, excess partial molar volumes, %${\overline{V}}_{i}^{\text{E}},%$ excess thermal expansion coefficients, %${\alpha }^{\text{E}}%$, isothermal coefficients of excess molar enthalpies, %$(\partial {H}_{\text{m}}^{\text{E}}/\partial P)_{T,x}%$, isentropic compressibility, %${k}_{\text{s}}^{ }%$ and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$ have been calculated for the binary systems. The excess molar volume and excess isentropic compressibility were correlated with the Redlich–Kister polynomial equation. The excess molar volumes and excess isentropic compressibilities were negative for all binary systems, except, for the system of MEA + 1-hexanol in which excess molar volume showed a sigmoid shape. The effect of temperature and chain length of alcohol on the excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$, are discussed in terms of molecular interactions between unlike molecules. 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Forghani, Fahime |
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Forghani, Fahime misc Monoethanolamine misc 1-Alcohols misc Speed of sound misc Excess molar volumes misc Excess partial molar volumes misc Excess thermal expansion coefficients misc Isothermal coefficients of excess molar enthalpies misc Excess isentropic compressibility misc ERAS model Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols ($ C_{3} $–$ C_{6} $) at Different Temperatures from Experimental and Theoretical Points of View |
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Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols ($ C_{3} $–$ C_{6} $) at Different Temperatures from Experimental and Theoretical Points of View Monoethanolamine (dpeaa)DE-He213 1-Alcohols (dpeaa)DE-He213 Speed of sound (dpeaa)DE-He213 Excess molar volumes (dpeaa)DE-He213 Excess partial molar volumes (dpeaa)DE-He213 Excess thermal expansion coefficients (dpeaa)DE-He213 Isothermal coefficients of excess molar enthalpies (dpeaa)DE-He213 Excess isentropic compressibility (dpeaa)DE-He213 ERAS model (dpeaa)DE-He213 |
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misc Monoethanolamine misc 1-Alcohols misc Speed of sound misc Excess molar volumes misc Excess partial molar volumes misc Excess thermal expansion coefficients misc Isothermal coefficients of excess molar enthalpies misc Excess isentropic compressibility misc ERAS model |
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Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols ($ C_{3} $–$ C_{6} $) at Different Temperatures from Experimental and Theoretical Points of View |
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Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols ($ C_{3} $–$ C_{6} $) at Different Temperatures from Experimental and Theoretical Points of View |
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Forghani, Fahime |
| doi_str_mv |
10.1007/s10953-022-01236-1 |
| title_sort |
volumetric and acoustic investigation on the binary mixtures of monoethanolamine + 1-alcohols ($ c_{3} $–$ c_{6} $) at different temperatures from experimental and theoretical points of view |
| title_auth |
Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols ($ C_{3} $–$ C_{6} $) at Different Temperatures from Experimental and Theoretical Points of View |
| abstract |
Abstract The densities, %$\rho%$ and speeds of sound, u were measured for pure and the binary mixtures of monoethanolamine (MEA) + 1-alcohols (1-propanol, 1-butanol, 1-pentanol and 1-hexanol) at (298.15–318.15) K and the whole composition range. From the experimental data excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, excess partial molar volumes, %${\overline{V}}_{i}^{\text{E}},%$ excess thermal expansion coefficients, %${\alpha }^{\text{E}}%$, isothermal coefficients of excess molar enthalpies, %$(\partial {H}_{\text{m}}^{\text{E}}/\partial P)_{T,x}%$, isentropic compressibility, %${k}_{\text{s}}^{ }%$ and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$ have been calculated for the binary systems. The excess molar volume and excess isentropic compressibility were correlated with the Redlich–Kister polynomial equation. The excess molar volumes and excess isentropic compressibilities were negative for all binary systems, except, for the system of MEA + 1-hexanol in which excess molar volume showed a sigmoid shape. The effect of temperature and chain length of alcohol on the excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$, are discussed in terms of molecular interactions between unlike molecules. The Extended Real Associated Solution model was applied to correlate the excess molar volumes. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Abstract The densities, %$\rho%$ and speeds of sound, u were measured for pure and the binary mixtures of monoethanolamine (MEA) + 1-alcohols (1-propanol, 1-butanol, 1-pentanol and 1-hexanol) at (298.15–318.15) K and the whole composition range. From the experimental data excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, excess partial molar volumes, %${\overline{V}}_{i}^{\text{E}},%$ excess thermal expansion coefficients, %${\alpha }^{\text{E}}%$, isothermal coefficients of excess molar enthalpies, %$(\partial {H}_{\text{m}}^{\text{E}}/\partial P)_{T,x}%$, isentropic compressibility, %${k}_{\text{s}}^{ }%$ and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$ have been calculated for the binary systems. The excess molar volume and excess isentropic compressibility were correlated with the Redlich–Kister polynomial equation. The excess molar volumes and excess isentropic compressibilities were negative for all binary systems, except, for the system of MEA + 1-hexanol in which excess molar volume showed a sigmoid shape. The effect of temperature and chain length of alcohol on the excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$, are discussed in terms of molecular interactions between unlike molecules. The Extended Real Associated Solution model was applied to correlate the excess molar volumes. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Abstract The densities, %$\rho%$ and speeds of sound, u were measured for pure and the binary mixtures of monoethanolamine (MEA) + 1-alcohols (1-propanol, 1-butanol, 1-pentanol and 1-hexanol) at (298.15–318.15) K and the whole composition range. From the experimental data excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, excess partial molar volumes, %${\overline{V}}_{i}^{\text{E}},%$ excess thermal expansion coefficients, %${\alpha }^{\text{E}}%$, isothermal coefficients of excess molar enthalpies, %$(\partial {H}_{\text{m}}^{\text{E}}/\partial P)_{T,x}%$, isentropic compressibility, %${k}_{\text{s}}^{ }%$ and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$ have been calculated for the binary systems. The excess molar volume and excess isentropic compressibility were correlated with the Redlich–Kister polynomial equation. The excess molar volumes and excess isentropic compressibilities were negative for all binary systems, except, for the system of MEA + 1-hexanol in which excess molar volume showed a sigmoid shape. The effect of temperature and chain length of alcohol on the excess molar volumes, %${V}_{\text{m}}^{\text{E}}%$, and excess isentropic compressibilities, %${k}_{\text{s}}^{\text{E}}%$, are discussed in terms of molecular interactions between unlike molecules. The Extended Real Associated Solution model was applied to correlate the excess molar volumes. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols ($ C_{3} $–$ C_{6} $) at Different Temperatures from Experimental and Theoretical Points of View |
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https://dx.doi.org/10.1007/s10953-022-01236-1 |
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Iloukhani, Hossein Khanlarzadeh, Khatereh |
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|
| score |
7.401991 |