High ceramic content composite solid-state electrolyte films prepared via a scalable solvent-free process
Abstract The development of high-performance solid-state electrolyte (SSE) films is critical to the practical application of all-solid-state Li metal batteries (ASSLMBs). However, developing high-performance free-standing electrolyte films remains a challenging task. In this work, we demonstrate a n...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Chen, Daiqian [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
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| Anmerkung: |
© Tsinghua University Press 2022 |
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| Übergeordnetes Werk: |
Enthalten in: Nano research - [S.l.] : Tsinghua Press, 2008, 16(2022), 3 vom: 12. Sept., Seite 3847-3854 |
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| Übergeordnetes Werk: |
volume:16 ; year:2022 ; number:3 ; day:12 ; month:09 ; pages:3847-3854 |
| Links: |
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| DOI / URN: |
10.1007/s12274-022-4845-x |
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| Katalog-ID: |
SPR049855301 |
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| 520 | |a Abstract The development of high-performance solid-state electrolyte (SSE) films is critical to the practical application of all-solid-state Li metal batteries (ASSLMBs). However, developing high-performance free-standing electrolyte films remains a challenging task. In this work, we demonstrate a novel scalable solvent-free process for fabricating high ceramic content composite solid-state electrolyte (HCCSE) films. Specifically speaking, a mixture of ceramic and polymer is dry mixed, fibered, and calendered into a free-standing porous ceramic film, on which polymer precursor is coated and polymerized to bridge the inorganic ceramic particles, resulting in a flexible HCCSE film with a ceramic content of up to 80 wt.%. High ceramic content not only leads to high ionic conductivity but also brings good mechanical properties; while the organic phase enables electrode electrolyte interfacial stability. When $ Li_{10} %$ GeP_{2} %$ S_{12} $ (LGPS) and polymeric ionic liquid-based solid polymer electrolytes (PIL-SPEs) were used as the inorganic and organic phases, respectively, the room temperature ionic conductivity of the resulted HCCSE reaches 0.91 mS·$ cm^{−1} $. Based on this HCCSE, Li∥Li symmetric battery cycled stably for more than 2,400 h with ultra-low overpotential, and ASSLMBs with different cathodes ($ LiFePO_{4} $ and sulfurized polyacrylonitrile (PAN-S)) present small polarization and decent cyclability at room temperature. This work provides a novel scalable solvent-free strategy for preparing high-performance freestanding composite solid-state electrolyte (CSE) film for room temperature ASSLMBs. | ||
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| 700 | 1 | |a Hu, Chenji |4 aut | |
| 700 | 1 | |a Chen, Qi |4 aut | |
| 700 | 1 | |a Xue, Guoyong |4 aut | |
| 700 | 1 | |a Tang, Lingfei |4 aut | |
| 700 | 1 | |a Dong, Qingyu |4 aut | |
| 700 | 1 | |a Chen, Bowen |4 aut | |
| 700 | 1 | |a Zhang, Fengrui |4 aut | |
| 700 | 1 | |a Gao, Mingwen |4 aut | |
| 700 | 1 | |a Xu, Jingjing |4 aut | |
| 700 | 1 | |a Shen, Yanbin |4 aut | |
| 700 | 1 | |a Chen, Liwei |4 aut | |
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10.1007/s12274-022-4845-x doi (DE-627)SPR049855301 (SPR)s12274-022-4845-x-e DE-627 ger DE-627 rakwb eng Chen, Daiqian verfasserin aut High ceramic content composite solid-state electrolyte films prepared via a scalable solvent-free process 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2022 Abstract The development of high-performance solid-state electrolyte (SSE) films is critical to the practical application of all-solid-state Li metal batteries (ASSLMBs). However, developing high-performance free-standing electrolyte films remains a challenging task. In this work, we demonstrate a novel scalable solvent-free process for fabricating high ceramic content composite solid-state electrolyte (HCCSE) films. Specifically speaking, a mixture of ceramic and polymer is dry mixed, fibered, and calendered into a free-standing porous ceramic film, on which polymer precursor is coated and polymerized to bridge the inorganic ceramic particles, resulting in a flexible HCCSE film with a ceramic content of up to 80 wt.%. High ceramic content not only leads to high ionic conductivity but also brings good mechanical properties; while the organic phase enables electrode electrolyte interfacial stability. When $ Li_{10} %$ GeP_{2} %$ S_{12} $ (LGPS) and polymeric ionic liquid-based solid polymer electrolytes (PIL-SPEs) were used as the inorganic and organic phases, respectively, the room temperature ionic conductivity of the resulted HCCSE reaches 0.91 mS·$ cm^{−1} $. Based on this HCCSE, Li∥Li symmetric battery cycled stably for more than 2,400 h with ultra-low overpotential, and ASSLMBs with different cathodes ($ LiFePO_{4} $ and sulfurized polyacrylonitrile (PAN-S)) present small polarization and decent cyclability at room temperature. This work provides a novel scalable solvent-free strategy for preparing high-performance freestanding composite solid-state electrolyte (CSE) film for room temperature ASSLMBs. free-standing (dpeaa)DE-He213 solid-state electrolyte film (dpeaa)DE-He213 composite solid-state electrolyte (dpeaa)DE-He213 solid-state battery (dpeaa)DE-He213 Hu, Chenji aut Chen, Qi aut Xue, Guoyong aut Tang, Lingfei aut Dong, Qingyu aut Chen, Bowen aut Zhang, Fengrui aut Gao, Mingwen aut Xu, Jingjing aut Shen, Yanbin aut Chen, Liwei aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 16(2022), 3 vom: 12. Sept., Seite 3847-3854 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:16 year:2022 number:3 day:12 month:09 pages:3847-3854 https://dx.doi.org/10.1007/s12274-022-4845-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2022 3 12 09 3847-3854 |
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10.1007/s12274-022-4845-x doi (DE-627)SPR049855301 (SPR)s12274-022-4845-x-e DE-627 ger DE-627 rakwb eng Chen, Daiqian verfasserin aut High ceramic content composite solid-state electrolyte films prepared via a scalable solvent-free process 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2022 Abstract The development of high-performance solid-state electrolyte (SSE) films is critical to the practical application of all-solid-state Li metal batteries (ASSLMBs). However, developing high-performance free-standing electrolyte films remains a challenging task. In this work, we demonstrate a novel scalable solvent-free process for fabricating high ceramic content composite solid-state electrolyte (HCCSE) films. Specifically speaking, a mixture of ceramic and polymer is dry mixed, fibered, and calendered into a free-standing porous ceramic film, on which polymer precursor is coated and polymerized to bridge the inorganic ceramic particles, resulting in a flexible HCCSE film with a ceramic content of up to 80 wt.%. High ceramic content not only leads to high ionic conductivity but also brings good mechanical properties; while the organic phase enables electrode electrolyte interfacial stability. When $ Li_{10} %$ GeP_{2} %$ S_{12} $ (LGPS) and polymeric ionic liquid-based solid polymer electrolytes (PIL-SPEs) were used as the inorganic and organic phases, respectively, the room temperature ionic conductivity of the resulted HCCSE reaches 0.91 mS·$ cm^{−1} $. Based on this HCCSE, Li∥Li symmetric battery cycled stably for more than 2,400 h with ultra-low overpotential, and ASSLMBs with different cathodes ($ LiFePO_{4} $ and sulfurized polyacrylonitrile (PAN-S)) present small polarization and decent cyclability at room temperature. This work provides a novel scalable solvent-free strategy for preparing high-performance freestanding composite solid-state electrolyte (CSE) film for room temperature ASSLMBs. free-standing (dpeaa)DE-He213 solid-state electrolyte film (dpeaa)DE-He213 composite solid-state electrolyte (dpeaa)DE-He213 solid-state battery (dpeaa)DE-He213 Hu, Chenji aut Chen, Qi aut Xue, Guoyong aut Tang, Lingfei aut Dong, Qingyu aut Chen, Bowen aut Zhang, Fengrui aut Gao, Mingwen aut Xu, Jingjing aut Shen, Yanbin aut Chen, Liwei aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 16(2022), 3 vom: 12. Sept., Seite 3847-3854 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:16 year:2022 number:3 day:12 month:09 pages:3847-3854 https://dx.doi.org/10.1007/s12274-022-4845-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2022 3 12 09 3847-3854 |
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10.1007/s12274-022-4845-x doi (DE-627)SPR049855301 (SPR)s12274-022-4845-x-e DE-627 ger DE-627 rakwb eng Chen, Daiqian verfasserin aut High ceramic content composite solid-state electrolyte films prepared via a scalable solvent-free process 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2022 Abstract The development of high-performance solid-state electrolyte (SSE) films is critical to the practical application of all-solid-state Li metal batteries (ASSLMBs). However, developing high-performance free-standing electrolyte films remains a challenging task. In this work, we demonstrate a novel scalable solvent-free process for fabricating high ceramic content composite solid-state electrolyte (HCCSE) films. Specifically speaking, a mixture of ceramic and polymer is dry mixed, fibered, and calendered into a free-standing porous ceramic film, on which polymer precursor is coated and polymerized to bridge the inorganic ceramic particles, resulting in a flexible HCCSE film with a ceramic content of up to 80 wt.%. High ceramic content not only leads to high ionic conductivity but also brings good mechanical properties; while the organic phase enables electrode electrolyte interfacial stability. When $ Li_{10} %$ GeP_{2} %$ S_{12} $ (LGPS) and polymeric ionic liquid-based solid polymer electrolytes (PIL-SPEs) were used as the inorganic and organic phases, respectively, the room temperature ionic conductivity of the resulted HCCSE reaches 0.91 mS·$ cm^{−1} $. Based on this HCCSE, Li∥Li symmetric battery cycled stably for more than 2,400 h with ultra-low overpotential, and ASSLMBs with different cathodes ($ LiFePO_{4} $ and sulfurized polyacrylonitrile (PAN-S)) present small polarization and decent cyclability at room temperature. This work provides a novel scalable solvent-free strategy for preparing high-performance freestanding composite solid-state electrolyte (CSE) film for room temperature ASSLMBs. free-standing (dpeaa)DE-He213 solid-state electrolyte film (dpeaa)DE-He213 composite solid-state electrolyte (dpeaa)DE-He213 solid-state battery (dpeaa)DE-He213 Hu, Chenji aut Chen, Qi aut Xue, Guoyong aut Tang, Lingfei aut Dong, Qingyu aut Chen, Bowen aut Zhang, Fengrui aut Gao, Mingwen aut Xu, Jingjing aut Shen, Yanbin aut Chen, Liwei aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 16(2022), 3 vom: 12. Sept., Seite 3847-3854 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:16 year:2022 number:3 day:12 month:09 pages:3847-3854 https://dx.doi.org/10.1007/s12274-022-4845-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2022 3 12 09 3847-3854 |
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10.1007/s12274-022-4845-x doi (DE-627)SPR049855301 (SPR)s12274-022-4845-x-e DE-627 ger DE-627 rakwb eng Chen, Daiqian verfasserin aut High ceramic content composite solid-state electrolyte films prepared via a scalable solvent-free process 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2022 Abstract The development of high-performance solid-state electrolyte (SSE) films is critical to the practical application of all-solid-state Li metal batteries (ASSLMBs). However, developing high-performance free-standing electrolyte films remains a challenging task. In this work, we demonstrate a novel scalable solvent-free process for fabricating high ceramic content composite solid-state electrolyte (HCCSE) films. Specifically speaking, a mixture of ceramic and polymer is dry mixed, fibered, and calendered into a free-standing porous ceramic film, on which polymer precursor is coated and polymerized to bridge the inorganic ceramic particles, resulting in a flexible HCCSE film with a ceramic content of up to 80 wt.%. High ceramic content not only leads to high ionic conductivity but also brings good mechanical properties; while the organic phase enables electrode electrolyte interfacial stability. When $ Li_{10} %$ GeP_{2} %$ S_{12} $ (LGPS) and polymeric ionic liquid-based solid polymer electrolytes (PIL-SPEs) were used as the inorganic and organic phases, respectively, the room temperature ionic conductivity of the resulted HCCSE reaches 0.91 mS·$ cm^{−1} $. Based on this HCCSE, Li∥Li symmetric battery cycled stably for more than 2,400 h with ultra-low overpotential, and ASSLMBs with different cathodes ($ LiFePO_{4} $ and sulfurized polyacrylonitrile (PAN-S)) present small polarization and decent cyclability at room temperature. This work provides a novel scalable solvent-free strategy for preparing high-performance freestanding composite solid-state electrolyte (CSE) film for room temperature ASSLMBs. free-standing (dpeaa)DE-He213 solid-state electrolyte film (dpeaa)DE-He213 composite solid-state electrolyte (dpeaa)DE-He213 solid-state battery (dpeaa)DE-He213 Hu, Chenji aut Chen, Qi aut Xue, Guoyong aut Tang, Lingfei aut Dong, Qingyu aut Chen, Bowen aut Zhang, Fengrui aut Gao, Mingwen aut Xu, Jingjing aut Shen, Yanbin aut Chen, Liwei aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 16(2022), 3 vom: 12. Sept., Seite 3847-3854 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:16 year:2022 number:3 day:12 month:09 pages:3847-3854 https://dx.doi.org/10.1007/s12274-022-4845-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2022 3 12 09 3847-3854 |
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10.1007/s12274-022-4845-x doi (DE-627)SPR049855301 (SPR)s12274-022-4845-x-e DE-627 ger DE-627 rakwb eng Chen, Daiqian verfasserin aut High ceramic content composite solid-state electrolyte films prepared via a scalable solvent-free process 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2022 Abstract The development of high-performance solid-state electrolyte (SSE) films is critical to the practical application of all-solid-state Li metal batteries (ASSLMBs). However, developing high-performance free-standing electrolyte films remains a challenging task. In this work, we demonstrate a novel scalable solvent-free process for fabricating high ceramic content composite solid-state electrolyte (HCCSE) films. Specifically speaking, a mixture of ceramic and polymer is dry mixed, fibered, and calendered into a free-standing porous ceramic film, on which polymer precursor is coated and polymerized to bridge the inorganic ceramic particles, resulting in a flexible HCCSE film with a ceramic content of up to 80 wt.%. High ceramic content not only leads to high ionic conductivity but also brings good mechanical properties; while the organic phase enables electrode electrolyte interfacial stability. When $ Li_{10} %$ GeP_{2} %$ S_{12} $ (LGPS) and polymeric ionic liquid-based solid polymer electrolytes (PIL-SPEs) were used as the inorganic and organic phases, respectively, the room temperature ionic conductivity of the resulted HCCSE reaches 0.91 mS·$ cm^{−1} $. Based on this HCCSE, Li∥Li symmetric battery cycled stably for more than 2,400 h with ultra-low overpotential, and ASSLMBs with different cathodes ($ LiFePO_{4} $ and sulfurized polyacrylonitrile (PAN-S)) present small polarization and decent cyclability at room temperature. This work provides a novel scalable solvent-free strategy for preparing high-performance freestanding composite solid-state electrolyte (CSE) film for room temperature ASSLMBs. free-standing (dpeaa)DE-He213 solid-state electrolyte film (dpeaa)DE-He213 composite solid-state electrolyte (dpeaa)DE-He213 solid-state battery (dpeaa)DE-He213 Hu, Chenji aut Chen, Qi aut Xue, Guoyong aut Tang, Lingfei aut Dong, Qingyu aut Chen, Bowen aut Zhang, Fengrui aut Gao, Mingwen aut Xu, Jingjing aut Shen, Yanbin aut Chen, Liwei aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 16(2022), 3 vom: 12. Sept., Seite 3847-3854 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:16 year:2022 number:3 day:12 month:09 pages:3847-3854 https://dx.doi.org/10.1007/s12274-022-4845-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2022 3 12 09 3847-3854 |
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Chen, Daiqian @@aut@@ Hu, Chenji @@aut@@ Chen, Qi @@aut@@ Xue, Guoyong @@aut@@ Tang, Lingfei @@aut@@ Dong, Qingyu @@aut@@ Chen, Bowen @@aut@@ Zhang, Fengrui @@aut@@ Gao, Mingwen @@aut@@ Xu, Jingjing @@aut@@ Shen, Yanbin @@aut@@ Chen, Liwei @@aut@@ |
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However, developing high-performance free-standing electrolyte films remains a challenging task. In this work, we demonstrate a novel scalable solvent-free process for fabricating high ceramic content composite solid-state electrolyte (HCCSE) films. Specifically speaking, a mixture of ceramic and polymer is dry mixed, fibered, and calendered into a free-standing porous ceramic film, on which polymer precursor is coated and polymerized to bridge the inorganic ceramic particles, resulting in a flexible HCCSE film with a ceramic content of up to 80 wt.%. High ceramic content not only leads to high ionic conductivity but also brings good mechanical properties; while the organic phase enables electrode electrolyte interfacial stability. When $ Li_{10} %$ GeP_{2} %$ S_{12} $ (LGPS) and polymeric ionic liquid-based solid polymer electrolytes (PIL-SPEs) were used as the inorganic and organic phases, respectively, the room temperature ionic conductivity of the resulted HCCSE reaches 0.91 mS·$ cm^{−1} $. Based on this HCCSE, Li∥Li symmetric battery cycled stably for more than 2,400 h with ultra-low overpotential, and ASSLMBs with different cathodes ($ LiFePO_{4} $ and sulfurized polyacrylonitrile (PAN-S)) present small polarization and decent cyclability at room temperature. 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Chen, Daiqian |
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Chen, Daiqian misc free-standing misc solid-state electrolyte film misc composite solid-state electrolyte misc solid-state battery High ceramic content composite solid-state electrolyte films prepared via a scalable solvent-free process |
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High ceramic content composite solid-state electrolyte films prepared via a scalable solvent-free process free-standing (dpeaa)DE-He213 solid-state electrolyte film (dpeaa)DE-He213 composite solid-state electrolyte (dpeaa)DE-He213 solid-state battery (dpeaa)DE-He213 |
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High ceramic content composite solid-state electrolyte films prepared via a scalable solvent-free process |
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Chen, Daiqian Hu, Chenji Chen, Qi Xue, Guoyong Tang, Lingfei Dong, Qingyu Chen, Bowen Zhang, Fengrui Gao, Mingwen Xu, Jingjing Shen, Yanbin Chen, Liwei |
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high ceramic content composite solid-state electrolyte films prepared via a scalable solvent-free process |
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High ceramic content composite solid-state electrolyte films prepared via a scalable solvent-free process |
| abstract |
Abstract The development of high-performance solid-state electrolyte (SSE) films is critical to the practical application of all-solid-state Li metal batteries (ASSLMBs). However, developing high-performance free-standing electrolyte films remains a challenging task. In this work, we demonstrate a novel scalable solvent-free process for fabricating high ceramic content composite solid-state electrolyte (HCCSE) films. Specifically speaking, a mixture of ceramic and polymer is dry mixed, fibered, and calendered into a free-standing porous ceramic film, on which polymer precursor is coated and polymerized to bridge the inorganic ceramic particles, resulting in a flexible HCCSE film with a ceramic content of up to 80 wt.%. High ceramic content not only leads to high ionic conductivity but also brings good mechanical properties; while the organic phase enables electrode electrolyte interfacial stability. When $ Li_{10} %$ GeP_{2} %$ S_{12} $ (LGPS) and polymeric ionic liquid-based solid polymer electrolytes (PIL-SPEs) were used as the inorganic and organic phases, respectively, the room temperature ionic conductivity of the resulted HCCSE reaches 0.91 mS·$ cm^{−1} $. Based on this HCCSE, Li∥Li symmetric battery cycled stably for more than 2,400 h with ultra-low overpotential, and ASSLMBs with different cathodes ($ LiFePO_{4} $ and sulfurized polyacrylonitrile (PAN-S)) present small polarization and decent cyclability at room temperature. This work provides a novel scalable solvent-free strategy for preparing high-performance freestanding composite solid-state electrolyte (CSE) film for room temperature ASSLMBs. © Tsinghua University Press 2022 |
| abstractGer |
Abstract The development of high-performance solid-state electrolyte (SSE) films is critical to the practical application of all-solid-state Li metal batteries (ASSLMBs). However, developing high-performance free-standing electrolyte films remains a challenging task. In this work, we demonstrate a novel scalable solvent-free process for fabricating high ceramic content composite solid-state electrolyte (HCCSE) films. Specifically speaking, a mixture of ceramic and polymer is dry mixed, fibered, and calendered into a free-standing porous ceramic film, on which polymer precursor is coated and polymerized to bridge the inorganic ceramic particles, resulting in a flexible HCCSE film with a ceramic content of up to 80 wt.%. High ceramic content not only leads to high ionic conductivity but also brings good mechanical properties; while the organic phase enables electrode electrolyte interfacial stability. When $ Li_{10} %$ GeP_{2} %$ S_{12} $ (LGPS) and polymeric ionic liquid-based solid polymer electrolytes (PIL-SPEs) were used as the inorganic and organic phases, respectively, the room temperature ionic conductivity of the resulted HCCSE reaches 0.91 mS·$ cm^{−1} $. Based on this HCCSE, Li∥Li symmetric battery cycled stably for more than 2,400 h with ultra-low overpotential, and ASSLMBs with different cathodes ($ LiFePO_{4} $ and sulfurized polyacrylonitrile (PAN-S)) present small polarization and decent cyclability at room temperature. This work provides a novel scalable solvent-free strategy for preparing high-performance freestanding composite solid-state electrolyte (CSE) film for room temperature ASSLMBs. © Tsinghua University Press 2022 |
| abstract_unstemmed |
Abstract The development of high-performance solid-state electrolyte (SSE) films is critical to the practical application of all-solid-state Li metal batteries (ASSLMBs). However, developing high-performance free-standing electrolyte films remains a challenging task. In this work, we demonstrate a novel scalable solvent-free process for fabricating high ceramic content composite solid-state electrolyte (HCCSE) films. Specifically speaking, a mixture of ceramic and polymer is dry mixed, fibered, and calendered into a free-standing porous ceramic film, on which polymer precursor is coated and polymerized to bridge the inorganic ceramic particles, resulting in a flexible HCCSE film with a ceramic content of up to 80 wt.%. High ceramic content not only leads to high ionic conductivity but also brings good mechanical properties; while the organic phase enables electrode electrolyte interfacial stability. When $ Li_{10} %$ GeP_{2} %$ S_{12} $ (LGPS) and polymeric ionic liquid-based solid polymer electrolytes (PIL-SPEs) were used as the inorganic and organic phases, respectively, the room temperature ionic conductivity of the resulted HCCSE reaches 0.91 mS·$ cm^{−1} $. Based on this HCCSE, Li∥Li symmetric battery cycled stably for more than 2,400 h with ultra-low overpotential, and ASSLMBs with different cathodes ($ LiFePO_{4} $ and sulfurized polyacrylonitrile (PAN-S)) present small polarization and decent cyclability at room temperature. This work provides a novel scalable solvent-free strategy for preparing high-performance freestanding composite solid-state electrolyte (CSE) film for room temperature ASSLMBs. © Tsinghua University Press 2022 |
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| title_short |
High ceramic content composite solid-state electrolyte films prepared via a scalable solvent-free process |
| url |
https://dx.doi.org/10.1007/s12274-022-4845-x |
| remote_bool |
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| author2 |
Hu, Chenji Chen, Qi Xue, Guoyong Tang, Lingfei Dong, Qingyu Chen, Bowen Zhang, Fengrui Gao, Mingwen Xu, Jingjing Shen, Yanbin Chen, Liwei |
| author2Str |
Hu, Chenji Chen, Qi Xue, Guoyong Tang, Lingfei Dong, Qingyu Chen, Bowen Zhang, Fengrui Gao, Mingwen Xu, Jingjing Shen, Yanbin Chen, Liwei |
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| doi_str |
10.1007/s12274-022-4845-x |
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2024-07-04T02:33:11.951Z |
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| score |
7.3987494 |