Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid
In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_...
Ausführliche Beschreibung
Autor*in: |
Asif, Hafiz Muhammad [verfasserIn] |
---|
Format: |
E-Artikel |
---|---|
Sprache: |
Englisch |
Erschienen: |
2022 |
---|
Schlagwörter: |
---|
Anmerkung: |
© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
---|
Übergeordnetes Werk: |
Enthalten in: Journal of cluster science - New York, NY : Springer Science + Business Media B.V., 1990, 34(2022), 3 vom: 08. Aug., Seite 1615-1624 |
---|---|
Übergeordnetes Werk: |
volume:34 ; year:2022 ; number:3 ; day:08 ; month:08 ; pages:1615-1624 |
Links: |
---|
DOI / URN: |
10.1007/s10876-022-02315-5 |
---|
Katalog-ID: |
SPR050064894 |
---|
LEADER | 01000naa a22002652 4500 | ||
---|---|---|---|
001 | SPR050064894 | ||
003 | DE-627 | ||
005 | 20230418064726.0 | ||
007 | cr uuu---uuuuu | ||
008 | 230418s2022 xx |||||o 00| ||eng c | ||
024 | 7 | |a 10.1007/s10876-022-02315-5 |2 doi | |
035 | |a (DE-627)SPR050064894 | ||
035 | |a (SPR)s10876-022-02315-5-e | ||
040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
041 | |a eng | ||
100 | 1 | |a Asif, Hafiz Muhammad |e verfasserin |4 aut | |
245 | 1 | 0 | |a Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid |
264 | 1 | |c 2022 | |
336 | |a Text |b txt |2 rdacontent | ||
337 | |a Computermedien |b c |2 rdamedia | ||
338 | |a Online-Ressource |b cr |2 rdacarrier | ||
500 | |a © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. | ||
520 | |a In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(*S) states and triplet excited(*T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract | ||
650 | 4 | |a Polyoxometalate |7 (dpeaa)DE-He213 | |
650 | 4 | |a Porphyrin |7 (dpeaa)DE-He213 | |
650 | 4 | |a Hybrid |7 (dpeaa)DE-He213 | |
650 | 4 | |a Optical nonlinearity |7 (dpeaa)DE-He213 | |
700 | 1 | |a Khan, Muhammad Ali |4 aut | |
700 | 1 | |a Zhou, Yunshan |4 aut | |
700 | 1 | |a Zhang, Lijuan |4 aut | |
700 | 1 | |a Iqbal, Arshad |4 aut | |
700 | 1 | |a Hussain, Saghir |4 aut | |
700 | 1 | |a Khalid, Muhammad |4 aut | |
700 | 1 | |a Rani, Sonia |4 aut | |
700 | 1 | |a Sun, Ran |4 aut | |
773 | 0 | 8 | |i Enthalten in |t Journal of cluster science |d New York, NY : Springer Science + Business Media B.V., 1990 |g 34(2022), 3 vom: 08. Aug., Seite 1615-1624 |w (DE-627)320573427 |w (DE-600)2016762-3 |x 1572-8862 |7 nnns |
773 | 1 | 8 | |g volume:34 |g year:2022 |g number:3 |g day:08 |g month:08 |g pages:1615-1624 |
856 | 4 | 0 | |u https://dx.doi.org/10.1007/s10876-022-02315-5 |z lizenzpflichtig |3 Volltext |
912 | |a GBV_USEFLAG_A | ||
912 | |a SYSFLAG_A | ||
912 | |a GBV_SPRINGER | ||
912 | |a GBV_ILN_11 | ||
912 | |a GBV_ILN_20 | ||
912 | |a GBV_ILN_22 | ||
912 | |a GBV_ILN_23 | ||
912 | |a GBV_ILN_24 | ||
912 | |a GBV_ILN_31 | ||
912 | |a GBV_ILN_32 | ||
912 | |a GBV_ILN_39 | ||
912 | |a GBV_ILN_40 | ||
912 | |a GBV_ILN_60 | ||
912 | |a GBV_ILN_62 | ||
912 | |a GBV_ILN_63 | ||
912 | |a GBV_ILN_69 | ||
912 | |a GBV_ILN_70 | ||
912 | |a GBV_ILN_73 | ||
912 | |a GBV_ILN_74 | ||
912 | |a GBV_ILN_90 | ||
912 | |a GBV_ILN_95 | ||
912 | |a GBV_ILN_100 | ||
912 | |a GBV_ILN_105 | ||
912 | |a GBV_ILN_110 | ||
912 | |a GBV_ILN_120 | ||
912 | |a GBV_ILN_138 | ||
912 | |a GBV_ILN_150 | ||
912 | |a GBV_ILN_151 | ||
912 | |a GBV_ILN_152 | ||
912 | |a GBV_ILN_161 | ||
912 | |a GBV_ILN_170 | ||
912 | |a GBV_ILN_171 | ||
912 | |a GBV_ILN_187 | ||
912 | |a GBV_ILN_213 | ||
912 | |a GBV_ILN_224 | ||
912 | |a GBV_ILN_230 | ||
912 | |a GBV_ILN_250 | ||
912 | |a GBV_ILN_281 | ||
912 | |a GBV_ILN_285 | ||
912 | |a GBV_ILN_293 | ||
912 | |a GBV_ILN_370 | ||
912 | |a GBV_ILN_602 | ||
912 | |a GBV_ILN_636 | ||
912 | |a GBV_ILN_702 | ||
912 | |a GBV_ILN_2001 | ||
912 | |a GBV_ILN_2003 | ||
912 | |a GBV_ILN_2004 | ||
912 | |a GBV_ILN_2005 | ||
912 | |a GBV_ILN_2006 | ||
912 | |a GBV_ILN_2007 | ||
912 | |a GBV_ILN_2009 | ||
912 | |a GBV_ILN_2010 | ||
912 | |a GBV_ILN_2011 | ||
912 | |a GBV_ILN_2014 | ||
912 | |a GBV_ILN_2015 | ||
912 | |a GBV_ILN_2020 | ||
912 | |a GBV_ILN_2021 | ||
912 | |a GBV_ILN_2025 | ||
912 | |a GBV_ILN_2026 | ||
912 | |a GBV_ILN_2027 | ||
912 | |a GBV_ILN_2031 | ||
912 | |a GBV_ILN_2034 | ||
912 | |a GBV_ILN_2037 | ||
912 | |a GBV_ILN_2038 | ||
912 | |a GBV_ILN_2039 | ||
912 | |a GBV_ILN_2044 | ||
912 | |a GBV_ILN_2048 | ||
912 | |a GBV_ILN_2049 | ||
912 | |a GBV_ILN_2050 | ||
912 | |a GBV_ILN_2055 | ||
912 | |a GBV_ILN_2056 | ||
912 | |a GBV_ILN_2057 | ||
912 | |a GBV_ILN_2059 | ||
912 | |a GBV_ILN_2061 | ||
912 | |a GBV_ILN_2064 | ||
912 | |a GBV_ILN_2065 | ||
912 | |a GBV_ILN_2068 | ||
912 | |a GBV_ILN_2088 | ||
912 | |a GBV_ILN_2093 | ||
912 | |a GBV_ILN_2106 | ||
912 | |a GBV_ILN_2107 | ||
912 | |a GBV_ILN_2108 | ||
912 | |a GBV_ILN_2110 | ||
912 | |a GBV_ILN_2111 | ||
912 | |a GBV_ILN_2112 | ||
912 | |a GBV_ILN_2113 | ||
912 | |a GBV_ILN_2118 | ||
912 | |a GBV_ILN_2122 | ||
912 | |a GBV_ILN_2129 | ||
912 | |a GBV_ILN_2143 | ||
912 | |a GBV_ILN_2144 | ||
912 | |a GBV_ILN_2147 | ||
912 | |a GBV_ILN_2148 | ||
912 | |a GBV_ILN_2152 | ||
912 | |a GBV_ILN_2153 | ||
912 | |a GBV_ILN_2188 | ||
912 | |a GBV_ILN_2190 | ||
912 | |a GBV_ILN_2232 | ||
912 | |a GBV_ILN_2336 | ||
912 | |a GBV_ILN_2446 | ||
912 | |a GBV_ILN_2470 | ||
912 | |a GBV_ILN_2472 | ||
912 | |a GBV_ILN_2507 | ||
912 | |a GBV_ILN_2522 | ||
912 | |a GBV_ILN_2548 | ||
912 | |a GBV_ILN_4035 | ||
912 | |a GBV_ILN_4037 | ||
912 | |a GBV_ILN_4046 | ||
912 | |a GBV_ILN_4112 | ||
912 | |a GBV_ILN_4125 | ||
912 | |a GBV_ILN_4126 | ||
912 | |a GBV_ILN_4242 | ||
912 | |a GBV_ILN_4246 | ||
912 | |a GBV_ILN_4249 | ||
912 | |a GBV_ILN_4251 | ||
912 | |a GBV_ILN_4305 | ||
912 | |a GBV_ILN_4306 | ||
912 | |a GBV_ILN_4307 | ||
912 | |a GBV_ILN_4313 | ||
912 | |a GBV_ILN_4322 | ||
912 | |a GBV_ILN_4323 | ||
912 | |a GBV_ILN_4324 | ||
912 | |a GBV_ILN_4325 | ||
912 | |a GBV_ILN_4326 | ||
912 | |a GBV_ILN_4328 | ||
912 | |a GBV_ILN_4333 | ||
912 | |a GBV_ILN_4334 | ||
912 | |a GBV_ILN_4335 | ||
912 | |a GBV_ILN_4336 | ||
912 | |a GBV_ILN_4338 | ||
912 | |a GBV_ILN_4393 | ||
912 | |a GBV_ILN_4700 | ||
951 | |a AR | ||
952 | |d 34 |j 2022 |e 3 |b 08 |c 08 |h 1615-1624 |
author_variant |
h m a hm hma m a k ma mak y z yz l z lz a i ai s h sh m k mk s r sr r s rs |
---|---|
matchkey_str |
article:15728862:2022----::yteicaatrztoadeakbeolnaasrtooayiycnannsmerc |
hierarchy_sort_str |
2022 |
publishDate |
2022 |
allfields |
10.1007/s10876-022-02315-5 doi (DE-627)SPR050064894 (SPR)s10876-022-02315-5-e DE-627 ger DE-627 rakwb eng Asif, Hafiz Muhammad verfasserin aut Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(*S) states and triplet excited(*T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract Polyoxometalate (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Hybrid (dpeaa)DE-He213 Optical nonlinearity (dpeaa)DE-He213 Khan, Muhammad Ali aut Zhou, Yunshan aut Zhang, Lijuan aut Iqbal, Arshad aut Hussain, Saghir aut Khalid, Muhammad aut Rani, Sonia aut Sun, Ran aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 34(2022), 3 vom: 08. Aug., Seite 1615-1624 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624 https://dx.doi.org/10.1007/s10876-022-02315-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2022 3 08 08 1615-1624 |
spelling |
10.1007/s10876-022-02315-5 doi (DE-627)SPR050064894 (SPR)s10876-022-02315-5-e DE-627 ger DE-627 rakwb eng Asif, Hafiz Muhammad verfasserin aut Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(*S) states and triplet excited(*T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract Polyoxometalate (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Hybrid (dpeaa)DE-He213 Optical nonlinearity (dpeaa)DE-He213 Khan, Muhammad Ali aut Zhou, Yunshan aut Zhang, Lijuan aut Iqbal, Arshad aut Hussain, Saghir aut Khalid, Muhammad aut Rani, Sonia aut Sun, Ran aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 34(2022), 3 vom: 08. Aug., Seite 1615-1624 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624 https://dx.doi.org/10.1007/s10876-022-02315-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2022 3 08 08 1615-1624 |
allfields_unstemmed |
10.1007/s10876-022-02315-5 doi (DE-627)SPR050064894 (SPR)s10876-022-02315-5-e DE-627 ger DE-627 rakwb eng Asif, Hafiz Muhammad verfasserin aut Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(*S) states and triplet excited(*T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract Polyoxometalate (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Hybrid (dpeaa)DE-He213 Optical nonlinearity (dpeaa)DE-He213 Khan, Muhammad Ali aut Zhou, Yunshan aut Zhang, Lijuan aut Iqbal, Arshad aut Hussain, Saghir aut Khalid, Muhammad aut Rani, Sonia aut Sun, Ran aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 34(2022), 3 vom: 08. Aug., Seite 1615-1624 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624 https://dx.doi.org/10.1007/s10876-022-02315-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2022 3 08 08 1615-1624 |
allfieldsGer |
10.1007/s10876-022-02315-5 doi (DE-627)SPR050064894 (SPR)s10876-022-02315-5-e DE-627 ger DE-627 rakwb eng Asif, Hafiz Muhammad verfasserin aut Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(*S) states and triplet excited(*T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract Polyoxometalate (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Hybrid (dpeaa)DE-He213 Optical nonlinearity (dpeaa)DE-He213 Khan, Muhammad Ali aut Zhou, Yunshan aut Zhang, Lijuan aut Iqbal, Arshad aut Hussain, Saghir aut Khalid, Muhammad aut Rani, Sonia aut Sun, Ran aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 34(2022), 3 vom: 08. Aug., Seite 1615-1624 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624 https://dx.doi.org/10.1007/s10876-022-02315-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2022 3 08 08 1615-1624 |
allfieldsSound |
10.1007/s10876-022-02315-5 doi (DE-627)SPR050064894 (SPR)s10876-022-02315-5-e DE-627 ger DE-627 rakwb eng Asif, Hafiz Muhammad verfasserin aut Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(*S) states and triplet excited(*T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract Polyoxometalate (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Hybrid (dpeaa)DE-He213 Optical nonlinearity (dpeaa)DE-He213 Khan, Muhammad Ali aut Zhou, Yunshan aut Zhang, Lijuan aut Iqbal, Arshad aut Hussain, Saghir aut Khalid, Muhammad aut Rani, Sonia aut Sun, Ran aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 34(2022), 3 vom: 08. Aug., Seite 1615-1624 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624 https://dx.doi.org/10.1007/s10876-022-02315-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2022 3 08 08 1615-1624 |
language |
English |
source |
Enthalten in Journal of cluster science 34(2022), 3 vom: 08. Aug., Seite 1615-1624 volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624 |
sourceStr |
Enthalten in Journal of cluster science 34(2022), 3 vom: 08. Aug., Seite 1615-1624 volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624 |
format_phy_str_mv |
Article |
institution |
findex.gbv.de |
topic_facet |
Polyoxometalate Porphyrin Hybrid Optical nonlinearity |
isfreeaccess_bool |
false |
container_title |
Journal of cluster science |
authorswithroles_txt_mv |
Asif, Hafiz Muhammad @@aut@@ Khan, Muhammad Ali @@aut@@ Zhou, Yunshan @@aut@@ Zhang, Lijuan @@aut@@ Iqbal, Arshad @@aut@@ Hussain, Saghir @@aut@@ Khalid, Muhammad @@aut@@ Rani, Sonia @@aut@@ Sun, Ran @@aut@@ |
publishDateDaySort_date |
2022-08-08T00:00:00Z |
hierarchy_top_id |
320573427 |
id |
SPR050064894 |
language_de |
englisch |
fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR050064894</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230418064726.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230418s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10876-022-02315-5</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR050064894</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10876-022-02315-5-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Asif, Hafiz Muhammad</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(*S) states and triplet excited(*T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polyoxometalate</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Porphyrin</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hybrid</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Optical nonlinearity</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Khan, Muhammad Ali</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhou, Yunshan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Lijuan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Iqbal, Arshad</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Hussain, Saghir</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Khalid, Muhammad</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Rani, Sonia</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sun, Ran</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of cluster science</subfield><subfield code="d">New York, NY : Springer Science + Business Media B.V., 1990</subfield><subfield code="g">34(2022), 3 vom: 08. Aug., Seite 1615-1624</subfield><subfield code="w">(DE-627)320573427</subfield><subfield code="w">(DE-600)2016762-3</subfield><subfield code="x">1572-8862</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:34</subfield><subfield code="g">year:2022</subfield><subfield code="g">number:3</subfield><subfield code="g">day:08</subfield><subfield code="g">month:08</subfield><subfield code="g">pages:1615-1624</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s10876-022-02315-5</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_636</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2031</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2039</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2093</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2107</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2144</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2188</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2446</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2472</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2548</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4246</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4328</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">34</subfield><subfield code="j">2022</subfield><subfield code="e">3</subfield><subfield code="b">08</subfield><subfield code="c">08</subfield><subfield code="h">1615-1624</subfield></datafield></record></collection>
|
author |
Asif, Hafiz Muhammad |
spellingShingle |
Asif, Hafiz Muhammad misc Polyoxometalate misc Porphyrin misc Hybrid misc Optical nonlinearity Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid |
authorStr |
Asif, Hafiz Muhammad |
ppnlink_with_tag_str_mv |
@@773@@(DE-627)320573427 |
format |
electronic Article |
delete_txt_mv |
keep |
author_role |
aut aut aut aut aut aut aut aut aut |
collection |
springer |
remote_str |
true |
illustrated |
Not Illustrated |
issn |
1572-8862 |
topic_title |
Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid Polyoxometalate (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Hybrid (dpeaa)DE-He213 Optical nonlinearity (dpeaa)DE-He213 |
topic |
misc Polyoxometalate misc Porphyrin misc Hybrid misc Optical nonlinearity |
topic_unstemmed |
misc Polyoxometalate misc Porphyrin misc Hybrid misc Optical nonlinearity |
topic_browse |
misc Polyoxometalate misc Porphyrin misc Hybrid misc Optical nonlinearity |
format_facet |
Elektronische Aufsätze Aufsätze Elektronische Ressource |
format_main_str_mv |
Text Zeitschrift/Artikel |
carriertype_str_mv |
cr |
hierarchy_parent_title |
Journal of cluster science |
hierarchy_parent_id |
320573427 |
hierarchy_top_title |
Journal of cluster science |
isfreeaccess_txt |
false |
familylinks_str_mv |
(DE-627)320573427 (DE-600)2016762-3 |
title |
Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid |
ctrlnum |
(DE-627)SPR050064894 (SPR)s10876-022-02315-5-e |
title_full |
Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid |
author_sort |
Asif, Hafiz Muhammad |
journal |
Journal of cluster science |
journalStr |
Journal of cluster science |
lang_code |
eng |
isOA_bool |
false |
recordtype |
marc |
publishDateSort |
2022 |
contenttype_str_mv |
txt |
container_start_page |
1615 |
author_browse |
Asif, Hafiz Muhammad Khan, Muhammad Ali Zhou, Yunshan Zhang, Lijuan Iqbal, Arshad Hussain, Saghir Khalid, Muhammad Rani, Sonia Sun, Ran |
container_volume |
34 |
format_se |
Elektronische Aufsätze |
author-letter |
Asif, Hafiz Muhammad |
doi_str_mv |
10.1007/s10876-022-02315-5 |
title_sort |
synthesis, characterization and remarkable nonlinear absorption of a pyridyl containing symmetrical porphyrin-polyoxometalate hybrid |
title_auth |
Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid |
abstract |
In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(*S) states and triplet excited(*T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
abstractGer |
In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(*S) states and triplet excited(*T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
abstract_unstemmed |
In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(*S) states and triplet excited(*T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 |
container_issue |
3 |
title_short |
Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid |
url |
https://dx.doi.org/10.1007/s10876-022-02315-5 |
remote_bool |
true |
author2 |
Khan, Muhammad Ali Zhou, Yunshan Zhang, Lijuan Iqbal, Arshad Hussain, Saghir Khalid, Muhammad Rani, Sonia Sun, Ran |
author2Str |
Khan, Muhammad Ali Zhou, Yunshan Zhang, Lijuan Iqbal, Arshad Hussain, Saghir Khalid, Muhammad Rani, Sonia Sun, Ran |
ppnlink |
320573427 |
mediatype_str_mv |
c |
isOA_txt |
false |
hochschulschrift_bool |
false |
doi_str |
10.1007/s10876-022-02315-5 |
up_date |
2024-07-04T03:18:49.244Z |
_version_ |
1803616915807010816 |
fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR050064894</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230418064726.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230418s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10876-022-02315-5</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR050064894</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10876-022-02315-5-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Asif, Hafiz Muhammad</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(*S) states and triplet excited(*T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polyoxometalate</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Porphyrin</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hybrid</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Optical nonlinearity</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Khan, Muhammad Ali</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhou, Yunshan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Lijuan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Iqbal, Arshad</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Hussain, Saghir</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Khalid, Muhammad</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Rani, Sonia</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sun, Ran</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of cluster science</subfield><subfield code="d">New York, NY : Springer Science + Business Media B.V., 1990</subfield><subfield code="g">34(2022), 3 vom: 08. Aug., Seite 1615-1624</subfield><subfield code="w">(DE-627)320573427</subfield><subfield code="w">(DE-600)2016762-3</subfield><subfield code="x">1572-8862</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:34</subfield><subfield code="g">year:2022</subfield><subfield code="g">number:3</subfield><subfield code="g">day:08</subfield><subfield code="g">month:08</subfield><subfield code="g">pages:1615-1624</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s10876-022-02315-5</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_636</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2031</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2039</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2093</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2107</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2144</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2188</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2446</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2472</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2548</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4246</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4328</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">34</subfield><subfield code="j">2022</subfield><subfield code="e">3</subfield><subfield code="b">08</subfield><subfield code="c">08</subfield><subfield code="h">1615-1624</subfield></datafield></record></collection>
|
score |
7.4007463 |