Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid

In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_...
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Autor*in:	Asif, Hafiz Muhammad [verfasserIn] Khan, Muhammad Ali Zhou, Yunshan Zhang, Lijuan Iqbal, Arshad Hussain, Saghir Khalid, Muhammad Rani, Sonia Sun, Ran

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2022

Schlagwörter:	Polyoxometalate Porphyrin Hybrid Optical nonlinearity

Anmerkung:	© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Übergeordnetes Werk:	Enthalten in: Journal of cluster science - New York, NY : Springer Science + Business Media B.V., 1990, 34(2022), 3 vom: 08. Aug., Seite 1615-1624
Übergeordnetes Werk:	volume:34 ; year:2022 ; number:3 ; day:08 ; month:08 ; pages:1615-1624

Links:	Volltext

DOI / URN:	10.1007/s10876-022-02315-5

Katalog-ID:	SPR050064894

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100	1		\|a Asif, Hafiz Muhammad \|e verfasserin \|4 aut
245	1	0	\|a Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid
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520			\|a In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(S) states and triplet excited(T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract
650		4	\|a Polyoxometalate \|7 (dpeaa)DE-He213
650		4	\|a Porphyrin \|7 (dpeaa)DE-He213
650		4	\|a Hybrid \|7 (dpeaa)DE-He213
650		4	\|a Optical nonlinearity \|7 (dpeaa)DE-He213
700	1		\|a Khan, Muhammad Ali \|4 aut
700	1		\|a Zhou, Yunshan \|4 aut
700	1		\|a Zhang, Lijuan \|4 aut
700	1		\|a Iqbal, Arshad \|4 aut
700	1		\|a Hussain, Saghir \|4 aut
700	1		\|a Khalid, Muhammad \|4 aut
700	1		\|a Rani, Sonia \|4 aut
700	1		\|a Sun, Ran \|4 aut
773	0	8	\|i Enthalten in \|t Journal of cluster science \|d New York, NY : Springer Science + Business Media B.V., 1990 \|g 34(2022), 3 vom: 08. Aug., Seite 1615-1624 \|w (DE-627)320573427 \|w (DE-600)2016762-3 \|x 1572-8862 \|7 nnns
773	1	8	\|g volume:34 \|g year:2022 \|g number:3 \|g day:08 \|g month:08 \|g pages:1615-1624
856	4	0	\|u https://dx.doi.org/10.1007/s10876-022-02315-5 \|z lizenzpflichtig \|3 Volltext
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912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_39
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2144
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2188
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2232
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2446
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2472
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_2548
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4246
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4328
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4336
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
912			\|a GBV_ILN_4700
951			\|a AR
952			\|d 34 \|j 2022 \|e 3 \|b 08 \|c 08 \|h 1615-1624

Indexfelder

author_variant	h m a hm hma m a k ma mak y z yz l z lz a i ai s h sh m k mk s r sr r s rs
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allfields	10.1007/s10876-022-02315-5 doi (DE-627)SPR050064894 (SPR)s10876-022-02315-5-e DE-627 ger DE-627 rakwb eng Asif, Hafiz Muhammad verfasserin aut Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(S) states and triplet excited(T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract Polyoxometalate (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Hybrid (dpeaa)DE-He213 Optical nonlinearity (dpeaa)DE-He213 Khan, Muhammad Ali aut Zhou, Yunshan aut Zhang, Lijuan aut Iqbal, Arshad aut Hussain, Saghir aut Khalid, Muhammad aut Rani, Sonia aut Sun, Ran aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 34(2022), 3 vom: 08. Aug., Seite 1615-1624 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624 https://dx.doi.org/10.1007/s10876-022-02315-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2022 3 08 08 1615-1624
spelling	10.1007/s10876-022-02315-5 doi (DE-627)SPR050064894 (SPR)s10876-022-02315-5-e DE-627 ger DE-627 rakwb eng Asif, Hafiz Muhammad verfasserin aut Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(S) states and triplet excited(T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract Polyoxometalate (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Hybrid (dpeaa)DE-He213 Optical nonlinearity (dpeaa)DE-He213 Khan, Muhammad Ali aut Zhou, Yunshan aut Zhang, Lijuan aut Iqbal, Arshad aut Hussain, Saghir aut Khalid, Muhammad aut Rani, Sonia aut Sun, Ran aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 34(2022), 3 vom: 08. Aug., Seite 1615-1624 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624 https://dx.doi.org/10.1007/s10876-022-02315-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2022 3 08 08 1615-1624
allfields_unstemmed	10.1007/s10876-022-02315-5 doi (DE-627)SPR050064894 (SPR)s10876-022-02315-5-e DE-627 ger DE-627 rakwb eng Asif, Hafiz Muhammad verfasserin aut Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(S) states and triplet excited(T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract Polyoxometalate (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Hybrid (dpeaa)DE-He213 Optical nonlinearity (dpeaa)DE-He213 Khan, Muhammad Ali aut Zhou, Yunshan aut Zhang, Lijuan aut Iqbal, Arshad aut Hussain, Saghir aut Khalid, Muhammad aut Rani, Sonia aut Sun, Ran aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 34(2022), 3 vom: 08. Aug., Seite 1615-1624 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624 https://dx.doi.org/10.1007/s10876-022-02315-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2022 3 08 08 1615-1624
allfieldsGer	10.1007/s10876-022-02315-5 doi (DE-627)SPR050064894 (SPR)s10876-022-02315-5-e DE-627 ger DE-627 rakwb eng Asif, Hafiz Muhammad verfasserin aut Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(S) states and triplet excited(T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract Polyoxometalate (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Hybrid (dpeaa)DE-He213 Optical nonlinearity (dpeaa)DE-He213 Khan, Muhammad Ali aut Zhou, Yunshan aut Zhang, Lijuan aut Iqbal, Arshad aut Hussain, Saghir aut Khalid, Muhammad aut Rani, Sonia aut Sun, Ran aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 34(2022), 3 vom: 08. Aug., Seite 1615-1624 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624 https://dx.doi.org/10.1007/s10876-022-02315-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2022 3 08 08 1615-1624
allfieldsSound	10.1007/s10876-022-02315-5 doi (DE-627)SPR050064894 (SPR)s10876-022-02315-5-e DE-627 ger DE-627 rakwb eng Asif, Hafiz Muhammad verfasserin aut Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(S) states and triplet excited(T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract Polyoxometalate (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Hybrid (dpeaa)DE-He213 Optical nonlinearity (dpeaa)DE-He213 Khan, Muhammad Ali aut Zhou, Yunshan aut Zhang, Lijuan aut Iqbal, Arshad aut Hussain, Saghir aut Khalid, Muhammad aut Rani, Sonia aut Sun, Ran aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 34(2022), 3 vom: 08. Aug., Seite 1615-1624 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624 https://dx.doi.org/10.1007/s10876-022-02315-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2022 3 08 08 1615-1624
language	English
source	Enthalten in Journal of cluster science 34(2022), 3 vom: 08. Aug., Seite 1615-1624 volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624
sourceStr	Enthalten in Journal of cluster science 34(2022), 3 vom: 08. Aug., Seite 1615-1624 volume:34 year:2022 number:3 day:08 month:08 pages:1615-1624
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Polyoxometalate Porphyrin Hybrid Optical nonlinearity
isfreeaccess_bool	false
container_title	Journal of cluster science
authorswithroles_txt_mv	Asif, Hafiz Muhammad @@aut@@ Khan, Muhammad Ali @@aut@@ Zhou, Yunshan @@aut@@ Zhang, Lijuan @@aut@@ Iqbal, Arshad @@aut@@ Hussain, Saghir @@aut@@ Khalid, Muhammad @@aut@@ Rani, Sonia @@aut@@ Sun, Ran @@aut@@
publishDateDaySort_date	2022-08-08T00:00:00Z
hierarchy_top_id	320573427
id	SPR050064894
language_de	englisch
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author	Asif, Hafiz Muhammad
spellingShingle	Asif, Hafiz Muhammad misc Polyoxometalate misc Porphyrin misc Hybrid misc Optical nonlinearity Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid
authorStr	Asif, Hafiz Muhammad
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topic_title	Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid Polyoxometalate (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Hybrid (dpeaa)DE-He213 Optical nonlinearity (dpeaa)DE-He213
topic	misc Polyoxometalate misc Porphyrin misc Hybrid misc Optical nonlinearity
topic_unstemmed	misc Polyoxometalate misc Porphyrin misc Hybrid misc Optical nonlinearity
topic_browse	misc Polyoxometalate misc Porphyrin misc Hybrid misc Optical nonlinearity
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
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title	Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid
ctrlnum	(DE-627)SPR050064894 (SPR)s10876-022-02315-5-e
title_full	Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid
author_sort	Asif, Hafiz Muhammad
journal	Journal of cluster science
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author_browse	Asif, Hafiz Muhammad Khan, Muhammad Ali Zhou, Yunshan Zhang, Lijuan Iqbal, Arshad Hussain, Saghir Khalid, Muhammad Rani, Sonia Sun, Ran
container_volume	34
format_se	Elektronische Aufsätze
author-letter	Asif, Hafiz Muhammad
doi_str_mv	10.1007/s10876-022-02315-5
title_sort	synthesis, characterization and remarkable nonlinear absorption of a pyridyl containing symmetrical porphyrin-polyoxometalate hybrid
title_auth	Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid
abstract	In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(S) states and triplet excited(T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
abstractGer	In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(S) states and triplet excited(T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
abstract_unstemmed	In this manuscript, a pyridyl containing porphyrin, $ C_{46} %$ H_{36} %$ N_{8} %$ O_{4} $ (denoted as TrisNTPP) and its derived polyoxometalate-porphyrin hybrid, [$ C_{4} %$ H_{9} $)4N]3[$ C_{41} %$ H_{26} %$ N_{7} $NHCO(NH)C($ OCH_{2} $)3$ MnMo_{6} $ $ O_{18} $($ OCH_{2} $)3C(NH)$ CONHN_{7} $ $ H_{26} %$ C_{41} $] (denoted as NTPP@POM) in which two pyridyl containing porphyrin moieties hanged onto one Anderson polyoxometalate, have been successfully synthesized and thoroughly characterized. Fluorescence quenching was observed in NTPP@POM as compared with its precursor Tris@NTPP inferring the transfer of electron/energy from porphyrin moiety to POM moiety. NTPP@POM showed notably enhanced nonlinear absorption (β = 2.32 × $ 10^{–5} $ esu) than Tris@NTPP (β = 0.73 × $ 10^{–5} $ esu). These NLO responses were associated with fluorescence decay mechanism which oriented the singlet excited(S) states and triplet excited(T) states of Tris@NTPP and NTPP@POM. Life time decay studies revealed that NTPP@POM (τ2 = 5.32 ns) were stayed for shorter time in excited triplet state than Tris@NTPP (τ2 = 10 ns), implying shorter life time led towards higher NLO responses. Graphical Abstract © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
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container_issue	3
title_short	Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid
url	https://dx.doi.org/10.1007/s10876-022-02315-5
remote_bool	true
author2	Khan, Muhammad Ali Zhou, Yunshan Zhang, Lijuan Iqbal, Arshad Hussain, Saghir Khalid, Muhammad Rani, Sonia Sun, Ran
author2Str	Khan, Muhammad Ali Zhou, Yunshan Zhang, Lijuan Iqbal, Arshad Hussain, Saghir Khalid, Muhammad Rani, Sonia Sun, Ran
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doi_str	10.1007/s10876-022-02315-5
up_date	2024-07-04T03:18:49.244Z
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Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid

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