$ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group
Abstract A new deep-ultraviolet (DUV) birefringent crystal, $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4 (LBOFH), was designed and synthesized by a high-temperature solution method. Its structure features a [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group that is constructed by four π-conjugated units, i.e.,...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Chen, Zilong [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
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| Anmerkung: |
© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2022 |
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| Übergeordnetes Werk: |
Enthalten in: Science China materials - Beijing : Science China Press, 2014, 65(2022), 9 vom: 23. März, Seite 2585-2590 |
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| Übergeordnetes Werk: |
volume:65 ; year:2022 ; number:9 ; day:23 ; month:03 ; pages:2585-2590 |
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| DOI / URN: |
10.1007/s40843-021-1998-4 |
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| Katalog-ID: |
SPR050863096 |
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| 100 | 1 | |a Chen, Zilong |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group |
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| 500 | |a © Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2022 | ||
| 520 | |a Abstract A new deep-ultraviolet (DUV) birefringent crystal, $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4 (LBOFH), was designed and synthesized by a high-temperature solution method. Its structure features a [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group that is constructed by four π-conjugated units, i.e., two [$ BO_{3} $] units and two [BO(OH)2] units connected by the [$ BO_{2} %$ F_{2} $] unit, which forms a near-coplanar configuration. The group exhibits large anisotropic polarizability and highest unoccupied molecular orbital-lowest unoccupied molecular orbital (HUMO-LUMO) gap, thus providing a good balance between the large birefringence (0.124 at 546 nm) and band gap (7.99 eV) in LBOFH. This work suggests new possibilities for the design and fabrication of advanced DUV birefringent crystals using the novel anionic group and the expansion of their alternative system with new hydroxyfluorooxoborates. | ||
| 650 | 4 | |a hydroxyfluorooxoborate |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a anionic group |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a birefringence |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a deep-ultraviolet |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Zeng, Hao |4 aut | |
| 700 | 1 | |a Chu, Dongdong |4 aut | |
| 700 | 1 | |a Zhang, Fangfang |4 aut | |
| 700 | 1 | |a Cheng, Meng |4 aut | |
| 700 | 1 | |a Yang, Zhihua |4 aut | |
| 700 | 1 | |a Pan, Shilie |4 aut | |
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10.1007/s40843-021-1998-4 doi (DE-627)SPR050863096 (SPR)s40843-021-1998-4-e DE-627 ger DE-627 rakwb eng Chen, Zilong verfasserin aut $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2022 Abstract A new deep-ultraviolet (DUV) birefringent crystal, $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4 (LBOFH), was designed and synthesized by a high-temperature solution method. Its structure features a [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group that is constructed by four π-conjugated units, i.e., two [$ BO_{3} $] units and two [BO(OH)2] units connected by the [$ BO_{2} %$ F_{2} $] unit, which forms a near-coplanar configuration. The group exhibits large anisotropic polarizability and highest unoccupied molecular orbital-lowest unoccupied molecular orbital (HUMO-LUMO) gap, thus providing a good balance between the large birefringence (0.124 at 546 nm) and band gap (7.99 eV) in LBOFH. This work suggests new possibilities for the design and fabrication of advanced DUV birefringent crystals using the novel anionic group and the expansion of their alternative system with new hydroxyfluorooxoborates. hydroxyfluorooxoborate (dpeaa)DE-He213 anionic group (dpeaa)DE-He213 birefringence (dpeaa)DE-He213 deep-ultraviolet (dpeaa)DE-He213 Zeng, Hao aut Chu, Dongdong aut Zhang, Fangfang aut Cheng, Meng aut Yang, Zhihua aut Pan, Shilie aut Enthalten in Science China materials Beijing : Science China Press, 2014 65(2022), 9 vom: 23. März, Seite 2585-2590 (DE-627)815914733 (DE-600)2806677-7 2199-4501 nnns volume:65 year:2022 number:9 day:23 month:03 pages:2585-2590 https://dx.doi.org/10.1007/s40843-021-1998-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 65 2022 9 23 03 2585-2590 |
| spelling |
10.1007/s40843-021-1998-4 doi (DE-627)SPR050863096 (SPR)s40843-021-1998-4-e DE-627 ger DE-627 rakwb eng Chen, Zilong verfasserin aut $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2022 Abstract A new deep-ultraviolet (DUV) birefringent crystal, $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4 (LBOFH), was designed and synthesized by a high-temperature solution method. Its structure features a [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group that is constructed by four π-conjugated units, i.e., two [$ BO_{3} $] units and two [BO(OH)2] units connected by the [$ BO_{2} %$ F_{2} $] unit, which forms a near-coplanar configuration. The group exhibits large anisotropic polarizability and highest unoccupied molecular orbital-lowest unoccupied molecular orbital (HUMO-LUMO) gap, thus providing a good balance between the large birefringence (0.124 at 546 nm) and band gap (7.99 eV) in LBOFH. This work suggests new possibilities for the design and fabrication of advanced DUV birefringent crystals using the novel anionic group and the expansion of their alternative system with new hydroxyfluorooxoborates. hydroxyfluorooxoborate (dpeaa)DE-He213 anionic group (dpeaa)DE-He213 birefringence (dpeaa)DE-He213 deep-ultraviolet (dpeaa)DE-He213 Zeng, Hao aut Chu, Dongdong aut Zhang, Fangfang aut Cheng, Meng aut Yang, Zhihua aut Pan, Shilie aut Enthalten in Science China materials Beijing : Science China Press, 2014 65(2022), 9 vom: 23. März, Seite 2585-2590 (DE-627)815914733 (DE-600)2806677-7 2199-4501 nnns volume:65 year:2022 number:9 day:23 month:03 pages:2585-2590 https://dx.doi.org/10.1007/s40843-021-1998-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 65 2022 9 23 03 2585-2590 |
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10.1007/s40843-021-1998-4 doi (DE-627)SPR050863096 (SPR)s40843-021-1998-4-e DE-627 ger DE-627 rakwb eng Chen, Zilong verfasserin aut $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2022 Abstract A new deep-ultraviolet (DUV) birefringent crystal, $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4 (LBOFH), was designed and synthesized by a high-temperature solution method. Its structure features a [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group that is constructed by four π-conjugated units, i.e., two [$ BO_{3} $] units and two [BO(OH)2] units connected by the [$ BO_{2} %$ F_{2} $] unit, which forms a near-coplanar configuration. The group exhibits large anisotropic polarizability and highest unoccupied molecular orbital-lowest unoccupied molecular orbital (HUMO-LUMO) gap, thus providing a good balance between the large birefringence (0.124 at 546 nm) and band gap (7.99 eV) in LBOFH. This work suggests new possibilities for the design and fabrication of advanced DUV birefringent crystals using the novel anionic group and the expansion of their alternative system with new hydroxyfluorooxoborates. hydroxyfluorooxoborate (dpeaa)DE-He213 anionic group (dpeaa)DE-He213 birefringence (dpeaa)DE-He213 deep-ultraviolet (dpeaa)DE-He213 Zeng, Hao aut Chu, Dongdong aut Zhang, Fangfang aut Cheng, Meng aut Yang, Zhihua aut Pan, Shilie aut Enthalten in Science China materials Beijing : Science China Press, 2014 65(2022), 9 vom: 23. März, Seite 2585-2590 (DE-627)815914733 (DE-600)2806677-7 2199-4501 nnns volume:65 year:2022 number:9 day:23 month:03 pages:2585-2590 https://dx.doi.org/10.1007/s40843-021-1998-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 65 2022 9 23 03 2585-2590 |
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10.1007/s40843-021-1998-4 doi (DE-627)SPR050863096 (SPR)s40843-021-1998-4-e DE-627 ger DE-627 rakwb eng Chen, Zilong verfasserin aut $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2022 Abstract A new deep-ultraviolet (DUV) birefringent crystal, $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4 (LBOFH), was designed and synthesized by a high-temperature solution method. Its structure features a [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group that is constructed by four π-conjugated units, i.e., two [$ BO_{3} $] units and two [BO(OH)2] units connected by the [$ BO_{2} %$ F_{2} $] unit, which forms a near-coplanar configuration. The group exhibits large anisotropic polarizability and highest unoccupied molecular orbital-lowest unoccupied molecular orbital (HUMO-LUMO) gap, thus providing a good balance between the large birefringence (0.124 at 546 nm) and band gap (7.99 eV) in LBOFH. This work suggests new possibilities for the design and fabrication of advanced DUV birefringent crystals using the novel anionic group and the expansion of their alternative system with new hydroxyfluorooxoborates. hydroxyfluorooxoborate (dpeaa)DE-He213 anionic group (dpeaa)DE-He213 birefringence (dpeaa)DE-He213 deep-ultraviolet (dpeaa)DE-He213 Zeng, Hao aut Chu, Dongdong aut Zhang, Fangfang aut Cheng, Meng aut Yang, Zhihua aut Pan, Shilie aut Enthalten in Science China materials Beijing : Science China Press, 2014 65(2022), 9 vom: 23. März, Seite 2585-2590 (DE-627)815914733 (DE-600)2806677-7 2199-4501 nnns volume:65 year:2022 number:9 day:23 month:03 pages:2585-2590 https://dx.doi.org/10.1007/s40843-021-1998-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 65 2022 9 23 03 2585-2590 |
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10.1007/s40843-021-1998-4 doi (DE-627)SPR050863096 (SPR)s40843-021-1998-4-e DE-627 ger DE-627 rakwb eng Chen, Zilong verfasserin aut $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2022 Abstract A new deep-ultraviolet (DUV) birefringent crystal, $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4 (LBOFH), was designed and synthesized by a high-temperature solution method. Its structure features a [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group that is constructed by four π-conjugated units, i.e., two [$ BO_{3} $] units and two [BO(OH)2] units connected by the [$ BO_{2} %$ F_{2} $] unit, which forms a near-coplanar configuration. The group exhibits large anisotropic polarizability and highest unoccupied molecular orbital-lowest unoccupied molecular orbital (HUMO-LUMO) gap, thus providing a good balance between the large birefringence (0.124 at 546 nm) and band gap (7.99 eV) in LBOFH. This work suggests new possibilities for the design and fabrication of advanced DUV birefringent crystals using the novel anionic group and the expansion of their alternative system with new hydroxyfluorooxoborates. hydroxyfluorooxoborate (dpeaa)DE-He213 anionic group (dpeaa)DE-He213 birefringence (dpeaa)DE-He213 deep-ultraviolet (dpeaa)DE-He213 Zeng, Hao aut Chu, Dongdong aut Zhang, Fangfang aut Cheng, Meng aut Yang, Zhihua aut Pan, Shilie aut Enthalten in Science China materials Beijing : Science China Press, 2014 65(2022), 9 vom: 23. März, Seite 2585-2590 (DE-627)815914733 (DE-600)2806677-7 2199-4501 nnns volume:65 year:2022 number:9 day:23 month:03 pages:2585-2590 https://dx.doi.org/10.1007/s40843-021-1998-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 65 2022 9 23 03 2585-2590 |
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Enthalten in Science China materials 65(2022), 9 vom: 23. März, Seite 2585-2590 volume:65 year:2022 number:9 day:23 month:03 pages:2585-2590 |
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Enthalten in Science China materials 65(2022), 9 vom: 23. März, Seite 2585-2590 volume:65 year:2022 number:9 day:23 month:03 pages:2585-2590 |
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Chen, Zilong @@aut@@ Zeng, Hao @@aut@@ Chu, Dongdong @@aut@@ Zhang, Fangfang @@aut@@ Cheng, Meng @@aut@@ Yang, Zhihua @@aut@@ Pan, Shilie @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR050863096</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230507234416.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230507s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s40843-021-1998-4</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR050863096</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s40843-021-1998-4-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Chen, Zilong</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">$ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2022</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract A new deep-ultraviolet (DUV) birefringent crystal, $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4 (LBOFH), was designed and synthesized by a high-temperature solution method. Its structure features a [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group that is constructed by four π-conjugated units, i.e., two [$ BO_{3} $] units and two [BO(OH)2] units connected by the [$ BO_{2} %$ F_{2} $] unit, which forms a near-coplanar configuration. The group exhibits large anisotropic polarizability and highest unoccupied molecular orbital-lowest unoccupied molecular orbital (HUMO-LUMO) gap, thus providing a good balance between the large birefringence (0.124 at 546 nm) and band gap (7.99 eV) in LBOFH. This work suggests new possibilities for the design and fabrication of advanced DUV birefringent crystals using the novel anionic group and the expansion of their alternative system with new hydroxyfluorooxoborates.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">hydroxyfluorooxoborate</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">anionic group</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">birefringence</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">deep-ultraviolet</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zeng, Hao</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chu, Dongdong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Fangfang</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Cheng, Meng</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yang, Zhihua</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Pan, Shilie</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Science China materials</subfield><subfield code="d">Beijing : Science China Press, 2014</subfield><subfield code="g">65(2022), 9 vom: 23. 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|
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Chen, Zilong |
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Chen, Zilong misc hydroxyfluorooxoborate misc anionic group misc birefringence misc deep-ultraviolet $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group |
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$ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group hydroxyfluorooxoborate (dpeaa)DE-He213 anionic group (dpeaa)DE-He213 birefringence (dpeaa)DE-He213 deep-ultraviolet (dpeaa)DE-He213 |
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$ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group |
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$ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group |
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Chen, Zilong Zeng, Hao Chu, Dongdong Zhang, Fangfang Cheng, Meng Yang, Zhihua Pan, Shilie |
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$ lib_{5} %$ o_{5} %$ f_{2} $(oh)4: a new deep-ultraviolet birefringent crystal with [$ b_{5} %$ o_{5} %$ f_{2} $(oh)4] anionic group |
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$ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group |
| abstract |
Abstract A new deep-ultraviolet (DUV) birefringent crystal, $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4 (LBOFH), was designed and synthesized by a high-temperature solution method. Its structure features a [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group that is constructed by four π-conjugated units, i.e., two [$ BO_{3} $] units and two [BO(OH)2] units connected by the [$ BO_{2} %$ F_{2} $] unit, which forms a near-coplanar configuration. The group exhibits large anisotropic polarizability and highest unoccupied molecular orbital-lowest unoccupied molecular orbital (HUMO-LUMO) gap, thus providing a good balance between the large birefringence (0.124 at 546 nm) and band gap (7.99 eV) in LBOFH. This work suggests new possibilities for the design and fabrication of advanced DUV birefringent crystals using the novel anionic group and the expansion of their alternative system with new hydroxyfluorooxoborates. © Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2022 |
| abstractGer |
Abstract A new deep-ultraviolet (DUV) birefringent crystal, $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4 (LBOFH), was designed and synthesized by a high-temperature solution method. Its structure features a [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group that is constructed by four π-conjugated units, i.e., two [$ BO_{3} $] units and two [BO(OH)2] units connected by the [$ BO_{2} %$ F_{2} $] unit, which forms a near-coplanar configuration. The group exhibits large anisotropic polarizability and highest unoccupied molecular orbital-lowest unoccupied molecular orbital (HUMO-LUMO) gap, thus providing a good balance between the large birefringence (0.124 at 546 nm) and band gap (7.99 eV) in LBOFH. This work suggests new possibilities for the design and fabrication of advanced DUV birefringent crystals using the novel anionic group and the expansion of their alternative system with new hydroxyfluorooxoborates. © Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2022 |
| abstract_unstemmed |
Abstract A new deep-ultraviolet (DUV) birefringent crystal, $ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4 (LBOFH), was designed and synthesized by a high-temperature solution method. Its structure features a [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group that is constructed by four π-conjugated units, i.e., two [$ BO_{3} $] units and two [BO(OH)2] units connected by the [$ BO_{2} %$ F_{2} $] unit, which forms a near-coplanar configuration. The group exhibits large anisotropic polarizability and highest unoccupied molecular orbital-lowest unoccupied molecular orbital (HUMO-LUMO) gap, thus providing a good balance between the large birefringence (0.124 at 546 nm) and band gap (7.99 eV) in LBOFH. This work suggests new possibilities for the design and fabrication of advanced DUV birefringent crystals using the novel anionic group and the expansion of their alternative system with new hydroxyfluorooxoborates. © Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2022 |
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$ LiB_{5} %$ O_{5} %$ F_{2} $(OH)4: A new deep-ultraviolet birefringent crystal with [$ B_{5} %$ O_{5} %$ F_{2} $(OH)4] anionic group |
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https://dx.doi.org/10.1007/s40843-021-1998-4 |
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Zeng, Hao Chu, Dongdong Zhang, Fangfang Cheng, Meng Yang, Zhihua Pan, Shilie |
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Zeng, Hao Chu, Dongdong Zhang, Fangfang Cheng, Meng Yang, Zhihua Pan, Shilie |
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10.1007/s40843-021-1998-4 |
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2024-07-03T18:16:09.008Z |
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|
| score |
7.401 |