Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates
Abstract Lead-free bismuth-based halide perovskites and their analogues have attracted research interest for their high stability and optoelectronic properties. However, the morphology-controlled synthesis of bismuth-based perovskite nanocrystals has been rarely demonstrated. Herein, we report the c...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Wang, Chao [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
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| Anmerkung: |
© Tsinghua University Press 2022 |
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| Übergeordnetes Werk: |
Enthalten in: Nano research - [S.l.] : Tsinghua Press, 2008, 16(2022), 1 vom: 27. Juni, Seite 1703-1711 |
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| Übergeordnetes Werk: |
volume:16 ; year:2022 ; number:1 ; day:27 ; month:06 ; pages:1703-1711 |
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| DOI / URN: |
10.1007/s12274-022-4656-0 |
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| Katalog-ID: |
SPR051348187 |
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| 245 | 1 | 0 | |a Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates |
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| 520 | |a Abstract Lead-free bismuth-based halide perovskites and their analogues have attracted research interest for their high stability and optoelectronic properties. However, the morphology-controlled synthesis of bismuth-based perovskite nanocrystals has been rarely demonstrated. Herein, we report the colloidal synthesis of zero-dimensional (0D) $ Cs_{3} %$ BiCl_{6} $ nanosheets (NSs), $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs/nanoplates (NPs) and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs through a hot-injection method. We demonstrate that the $ Cs_{3} %$ BiCl_{6} $ NSs, as an initial product of $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs, can transform into $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs or $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs via Cl-induced metal ion insertion reactions under the templating effect of $ Cs_{3} %$ BiCl_{6} $. This growth mechanism is also applicable for the synthesis of $ Cs_{4} %$ CdBi_{2} %$ Cl_{12} $ nanoplates. Furthermore, the alloying of $ Cd^{2+} $ into $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ lattice could weaken the strong coupling effect between Mn and Mn, which leads to a prolonged photoluminescence lifetime and an enhanced photoluminescence quantum yield (PLQY). As a proof of concept, the alloyed $ Cs_{4} %$ Mn_{x} %$ Cd_{1−x} %$ Bi_{2} %$ Cl_{12} $ NPs are used as a scintillator, which show a lowest detection limit of 134.5 nGy/s. The X-ray imaging results display a high spatial resolution of over 20 line pairs per millimeter (lp/mm). These results provide new insights in the synthesis of anisotropic bismuth-based perovskite nanocrystals and their applications in radiation detection. | ||
| 650 | 4 | |a bismuth-based perovskites |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a layered double perovskite |7 (dpeaa)DE-He213 | |
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| 650 | 4 | |a morphology control |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a scintillators |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Xiao, Jiawen |4 aut | |
| 700 | 1 | |a Yan, Zhengguang |4 aut | |
| 700 | 1 | |a Niu, Xiaowei |4 aut | |
| 700 | 1 | |a Lin, Taifeng |4 aut | |
| 700 | 1 | |a Zhou, Yingchun |4 aut | |
| 700 | 1 | |a Li, Jingyu |4 aut | |
| 700 | 1 | |a Han, Xiaodong |4 aut | |
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10.1007/s12274-022-4656-0 doi (DE-627)SPR051348187 (SPR)s12274-022-4656-0-e DE-627 ger DE-627 rakwb eng Wang, Chao verfasserin aut Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2022 Abstract Lead-free bismuth-based halide perovskites and their analogues have attracted research interest for their high stability and optoelectronic properties. However, the morphology-controlled synthesis of bismuth-based perovskite nanocrystals has been rarely demonstrated. Herein, we report the colloidal synthesis of zero-dimensional (0D) $ Cs_{3} %$ BiCl_{6} $ nanosheets (NSs), $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs/nanoplates (NPs) and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs through a hot-injection method. We demonstrate that the $ Cs_{3} %$ BiCl_{6} $ NSs, as an initial product of $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs, can transform into $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs or $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs via Cl-induced metal ion insertion reactions under the templating effect of $ Cs_{3} %$ BiCl_{6} $. This growth mechanism is also applicable for the synthesis of $ Cs_{4} %$ CdBi_{2} %$ Cl_{12} $ nanoplates. Furthermore, the alloying of $ Cd^{2+} $ into $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ lattice could weaken the strong coupling effect between Mn and Mn, which leads to a prolonged photoluminescence lifetime and an enhanced photoluminescence quantum yield (PLQY). As a proof of concept, the alloyed $ Cs_{4} %$ Mn_{x} %$ Cd_{1−x} %$ Bi_{2} %$ Cl_{12} $ NPs are used as a scintillator, which show a lowest detection limit of 134.5 nGy/s. The X-ray imaging results display a high spatial resolution of over 20 line pairs per millimeter (lp/mm). These results provide new insights in the synthesis of anisotropic bismuth-based perovskite nanocrystals and their applications in radiation detection. bismuth-based perovskites (dpeaa)DE-He213 layered double perovskite (dpeaa)DE-He213 nanoplates (dpeaa)DE-He213 morphology control (dpeaa)DE-He213 scintillators (dpeaa)DE-He213 Xiao, Jiawen aut Yan, Zhengguang aut Niu, Xiaowei aut Lin, Taifeng aut Zhou, Yingchun aut Li, Jingyu aut Han, Xiaodong aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 16(2022), 1 vom: 27. Juni, Seite 1703-1711 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:16 year:2022 number:1 day:27 month:06 pages:1703-1711 https://dx.doi.org/10.1007/s12274-022-4656-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2022 1 27 06 1703-1711 |
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10.1007/s12274-022-4656-0 doi (DE-627)SPR051348187 (SPR)s12274-022-4656-0-e DE-627 ger DE-627 rakwb eng Wang, Chao verfasserin aut Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2022 Abstract Lead-free bismuth-based halide perovskites and their analogues have attracted research interest for their high stability and optoelectronic properties. However, the morphology-controlled synthesis of bismuth-based perovskite nanocrystals has been rarely demonstrated. Herein, we report the colloidal synthesis of zero-dimensional (0D) $ Cs_{3} %$ BiCl_{6} $ nanosheets (NSs), $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs/nanoplates (NPs) and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs through a hot-injection method. We demonstrate that the $ Cs_{3} %$ BiCl_{6} $ NSs, as an initial product of $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs, can transform into $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs or $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs via Cl-induced metal ion insertion reactions under the templating effect of $ Cs_{3} %$ BiCl_{6} $. This growth mechanism is also applicable for the synthesis of $ Cs_{4} %$ CdBi_{2} %$ Cl_{12} $ nanoplates. Furthermore, the alloying of $ Cd^{2+} $ into $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ lattice could weaken the strong coupling effect between Mn and Mn, which leads to a prolonged photoluminescence lifetime and an enhanced photoluminescence quantum yield (PLQY). As a proof of concept, the alloyed $ Cs_{4} %$ Mn_{x} %$ Cd_{1−x} %$ Bi_{2} %$ Cl_{12} $ NPs are used as a scintillator, which show a lowest detection limit of 134.5 nGy/s. The X-ray imaging results display a high spatial resolution of over 20 line pairs per millimeter (lp/mm). These results provide new insights in the synthesis of anisotropic bismuth-based perovskite nanocrystals and their applications in radiation detection. bismuth-based perovskites (dpeaa)DE-He213 layered double perovskite (dpeaa)DE-He213 nanoplates (dpeaa)DE-He213 morphology control (dpeaa)DE-He213 scintillators (dpeaa)DE-He213 Xiao, Jiawen aut Yan, Zhengguang aut Niu, Xiaowei aut Lin, Taifeng aut Zhou, Yingchun aut Li, Jingyu aut Han, Xiaodong aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 16(2022), 1 vom: 27. Juni, Seite 1703-1711 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:16 year:2022 number:1 day:27 month:06 pages:1703-1711 https://dx.doi.org/10.1007/s12274-022-4656-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2022 1 27 06 1703-1711 |
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10.1007/s12274-022-4656-0 doi (DE-627)SPR051348187 (SPR)s12274-022-4656-0-e DE-627 ger DE-627 rakwb eng Wang, Chao verfasserin aut Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2022 Abstract Lead-free bismuth-based halide perovskites and their analogues have attracted research interest for their high stability and optoelectronic properties. However, the morphology-controlled synthesis of bismuth-based perovskite nanocrystals has been rarely demonstrated. Herein, we report the colloidal synthesis of zero-dimensional (0D) $ Cs_{3} %$ BiCl_{6} $ nanosheets (NSs), $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs/nanoplates (NPs) and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs through a hot-injection method. We demonstrate that the $ Cs_{3} %$ BiCl_{6} $ NSs, as an initial product of $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs, can transform into $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs or $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs via Cl-induced metal ion insertion reactions under the templating effect of $ Cs_{3} %$ BiCl_{6} $. This growth mechanism is also applicable for the synthesis of $ Cs_{4} %$ CdBi_{2} %$ Cl_{12} $ nanoplates. Furthermore, the alloying of $ Cd^{2+} $ into $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ lattice could weaken the strong coupling effect between Mn and Mn, which leads to a prolonged photoluminescence lifetime and an enhanced photoluminescence quantum yield (PLQY). As a proof of concept, the alloyed $ Cs_{4} %$ Mn_{x} %$ Cd_{1−x} %$ Bi_{2} %$ Cl_{12} $ NPs are used as a scintillator, which show a lowest detection limit of 134.5 nGy/s. The X-ray imaging results display a high spatial resolution of over 20 line pairs per millimeter (lp/mm). These results provide new insights in the synthesis of anisotropic bismuth-based perovskite nanocrystals and their applications in radiation detection. bismuth-based perovskites (dpeaa)DE-He213 layered double perovskite (dpeaa)DE-He213 nanoplates (dpeaa)DE-He213 morphology control (dpeaa)DE-He213 scintillators (dpeaa)DE-He213 Xiao, Jiawen aut Yan, Zhengguang aut Niu, Xiaowei aut Lin, Taifeng aut Zhou, Yingchun aut Li, Jingyu aut Han, Xiaodong aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 16(2022), 1 vom: 27. Juni, Seite 1703-1711 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:16 year:2022 number:1 day:27 month:06 pages:1703-1711 https://dx.doi.org/10.1007/s12274-022-4656-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2022 1 27 06 1703-1711 |
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10.1007/s12274-022-4656-0 doi (DE-627)SPR051348187 (SPR)s12274-022-4656-0-e DE-627 ger DE-627 rakwb eng Wang, Chao verfasserin aut Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2022 Abstract Lead-free bismuth-based halide perovskites and their analogues have attracted research interest for their high stability and optoelectronic properties. However, the morphology-controlled synthesis of bismuth-based perovskite nanocrystals has been rarely demonstrated. Herein, we report the colloidal synthesis of zero-dimensional (0D) $ Cs_{3} %$ BiCl_{6} $ nanosheets (NSs), $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs/nanoplates (NPs) and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs through a hot-injection method. We demonstrate that the $ Cs_{3} %$ BiCl_{6} $ NSs, as an initial product of $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs, can transform into $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs or $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs via Cl-induced metal ion insertion reactions under the templating effect of $ Cs_{3} %$ BiCl_{6} $. This growth mechanism is also applicable for the synthesis of $ Cs_{4} %$ CdBi_{2} %$ Cl_{12} $ nanoplates. Furthermore, the alloying of $ Cd^{2+} $ into $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ lattice could weaken the strong coupling effect between Mn and Mn, which leads to a prolonged photoluminescence lifetime and an enhanced photoluminescence quantum yield (PLQY). As a proof of concept, the alloyed $ Cs_{4} %$ Mn_{x} %$ Cd_{1−x} %$ Bi_{2} %$ Cl_{12} $ NPs are used as a scintillator, which show a lowest detection limit of 134.5 nGy/s. The X-ray imaging results display a high spatial resolution of over 20 line pairs per millimeter (lp/mm). These results provide new insights in the synthesis of anisotropic bismuth-based perovskite nanocrystals and their applications in radiation detection. bismuth-based perovskites (dpeaa)DE-He213 layered double perovskite (dpeaa)DE-He213 nanoplates (dpeaa)DE-He213 morphology control (dpeaa)DE-He213 scintillators (dpeaa)DE-He213 Xiao, Jiawen aut Yan, Zhengguang aut Niu, Xiaowei aut Lin, Taifeng aut Zhou, Yingchun aut Li, Jingyu aut Han, Xiaodong aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 16(2022), 1 vom: 27. Juni, Seite 1703-1711 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:16 year:2022 number:1 day:27 month:06 pages:1703-1711 https://dx.doi.org/10.1007/s12274-022-4656-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2022 1 27 06 1703-1711 |
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10.1007/s12274-022-4656-0 doi (DE-627)SPR051348187 (SPR)s12274-022-4656-0-e DE-627 ger DE-627 rakwb eng Wang, Chao verfasserin aut Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2022 Abstract Lead-free bismuth-based halide perovskites and their analogues have attracted research interest for their high stability and optoelectronic properties. However, the morphology-controlled synthesis of bismuth-based perovskite nanocrystals has been rarely demonstrated. Herein, we report the colloidal synthesis of zero-dimensional (0D) $ Cs_{3} %$ BiCl_{6} $ nanosheets (NSs), $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs/nanoplates (NPs) and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs through a hot-injection method. We demonstrate that the $ Cs_{3} %$ BiCl_{6} $ NSs, as an initial product of $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs, can transform into $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs or $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs via Cl-induced metal ion insertion reactions under the templating effect of $ Cs_{3} %$ BiCl_{6} $. This growth mechanism is also applicable for the synthesis of $ Cs_{4} %$ CdBi_{2} %$ Cl_{12} $ nanoplates. Furthermore, the alloying of $ Cd^{2+} $ into $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ lattice could weaken the strong coupling effect between Mn and Mn, which leads to a prolonged photoluminescence lifetime and an enhanced photoluminescence quantum yield (PLQY). As a proof of concept, the alloyed $ Cs_{4} %$ Mn_{x} %$ Cd_{1−x} %$ Bi_{2} %$ Cl_{12} $ NPs are used as a scintillator, which show a lowest detection limit of 134.5 nGy/s. The X-ray imaging results display a high spatial resolution of over 20 line pairs per millimeter (lp/mm). These results provide new insights in the synthesis of anisotropic bismuth-based perovskite nanocrystals and their applications in radiation detection. bismuth-based perovskites (dpeaa)DE-He213 layered double perovskite (dpeaa)DE-He213 nanoplates (dpeaa)DE-He213 morphology control (dpeaa)DE-He213 scintillators (dpeaa)DE-He213 Xiao, Jiawen aut Yan, Zhengguang aut Niu, Xiaowei aut Lin, Taifeng aut Zhou, Yingchun aut Li, Jingyu aut Han, Xiaodong aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 16(2022), 1 vom: 27. Juni, Seite 1703-1711 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:16 year:2022 number:1 day:27 month:06 pages:1703-1711 https://dx.doi.org/10.1007/s12274-022-4656-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2022 1 27 06 1703-1711 |
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Enthalten in Nano research 16(2022), 1 vom: 27. Juni, Seite 1703-1711 volume:16 year:2022 number:1 day:27 month:06 pages:1703-1711 |
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Enthalten in Nano research 16(2022), 1 vom: 27. Juni, Seite 1703-1711 volume:16 year:2022 number:1 day:27 month:06 pages:1703-1711 |
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Wang, Chao @@aut@@ Xiao, Jiawen @@aut@@ Yan, Zhengguang @@aut@@ Niu, Xiaowei @@aut@@ Lin, Taifeng @@aut@@ Zhou, Yingchun @@aut@@ Li, Jingyu @@aut@@ Han, Xiaodong @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR051348187</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230510060715.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230508s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s12274-022-4656-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR051348187</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s12274-022-4656-0-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Wang, Chao</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Tsinghua University Press 2022</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Lead-free bismuth-based halide perovskites and their analogues have attracted research interest for their high stability and optoelectronic properties. However, the morphology-controlled synthesis of bismuth-based perovskite nanocrystals has been rarely demonstrated. Herein, we report the colloidal synthesis of zero-dimensional (0D) $ Cs_{3} %$ BiCl_{6} $ nanosheets (NSs), $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs/nanoplates (NPs) and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs through a hot-injection method. We demonstrate that the $ Cs_{3} %$ BiCl_{6} $ NSs, as an initial product of $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs, can transform into $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs or $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs via Cl-induced metal ion insertion reactions under the templating effect of $ Cs_{3} %$ BiCl_{6} $. This growth mechanism is also applicable for the synthesis of $ Cs_{4} %$ CdBi_{2} %$ Cl_{12} $ nanoplates. Furthermore, the alloying of $ Cd^{2+} $ into $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ lattice could weaken the strong coupling effect between Mn and Mn, which leads to a prolonged photoluminescence lifetime and an enhanced photoluminescence quantum yield (PLQY). As a proof of concept, the alloyed $ Cs_{4} %$ Mn_{x} %$ Cd_{1−x} %$ Bi_{2} %$ Cl_{12} $ NPs are used as a scintillator, which show a lowest detection limit of 134.5 nGy/s. The X-ray imaging results display a high spatial resolution of over 20 line pairs per millimeter (lp/mm). 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|
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Wang, Chao |
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Wang, Chao misc bismuth-based perovskites misc layered double perovskite misc nanoplates misc morphology control misc scintillators Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates |
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Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates bismuth-based perovskites (dpeaa)DE-He213 layered double perovskite (dpeaa)DE-He213 nanoplates (dpeaa)DE-He213 morphology control (dpeaa)DE-He213 scintillators (dpeaa)DE-He213 |
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misc bismuth-based perovskites misc layered double perovskite misc nanoplates misc morphology control misc scintillators |
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Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates |
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Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates |
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Wang, Chao |
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Wang, Chao Xiao, Jiawen Yan, Zhengguang Niu, Xiaowei Lin, Taifeng Zhou, Yingchun Li, Jingyu Han, Xiaodong |
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Wang, Chao |
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colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates |
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Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates |
| abstract |
Abstract Lead-free bismuth-based halide perovskites and their analogues have attracted research interest for their high stability and optoelectronic properties. However, the morphology-controlled synthesis of bismuth-based perovskite nanocrystals has been rarely demonstrated. Herein, we report the colloidal synthesis of zero-dimensional (0D) $ Cs_{3} %$ BiCl_{6} $ nanosheets (NSs), $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs/nanoplates (NPs) and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs through a hot-injection method. We demonstrate that the $ Cs_{3} %$ BiCl_{6} $ NSs, as an initial product of $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs, can transform into $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs or $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs via Cl-induced metal ion insertion reactions under the templating effect of $ Cs_{3} %$ BiCl_{6} $. This growth mechanism is also applicable for the synthesis of $ Cs_{4} %$ CdBi_{2} %$ Cl_{12} $ nanoplates. Furthermore, the alloying of $ Cd^{2+} $ into $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ lattice could weaken the strong coupling effect between Mn and Mn, which leads to a prolonged photoluminescence lifetime and an enhanced photoluminescence quantum yield (PLQY). As a proof of concept, the alloyed $ Cs_{4} %$ Mn_{x} %$ Cd_{1−x} %$ Bi_{2} %$ Cl_{12} $ NPs are used as a scintillator, which show a lowest detection limit of 134.5 nGy/s. The X-ray imaging results display a high spatial resolution of over 20 line pairs per millimeter (lp/mm). These results provide new insights in the synthesis of anisotropic bismuth-based perovskite nanocrystals and their applications in radiation detection. © Tsinghua University Press 2022 |
| abstractGer |
Abstract Lead-free bismuth-based halide perovskites and their analogues have attracted research interest for their high stability and optoelectronic properties. However, the morphology-controlled synthesis of bismuth-based perovskite nanocrystals has been rarely demonstrated. Herein, we report the colloidal synthesis of zero-dimensional (0D) $ Cs_{3} %$ BiCl_{6} $ nanosheets (NSs), $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs/nanoplates (NPs) and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs through a hot-injection method. We demonstrate that the $ Cs_{3} %$ BiCl_{6} $ NSs, as an initial product of $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs, can transform into $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs or $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs via Cl-induced metal ion insertion reactions under the templating effect of $ Cs_{3} %$ BiCl_{6} $. This growth mechanism is also applicable for the synthesis of $ Cs_{4} %$ CdBi_{2} %$ Cl_{12} $ nanoplates. Furthermore, the alloying of $ Cd^{2+} $ into $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ lattice could weaken the strong coupling effect between Mn and Mn, which leads to a prolonged photoluminescence lifetime and an enhanced photoluminescence quantum yield (PLQY). As a proof of concept, the alloyed $ Cs_{4} %$ Mn_{x} %$ Cd_{1−x} %$ Bi_{2} %$ Cl_{12} $ NPs are used as a scintillator, which show a lowest detection limit of 134.5 nGy/s. The X-ray imaging results display a high spatial resolution of over 20 line pairs per millimeter (lp/mm). These results provide new insights in the synthesis of anisotropic bismuth-based perovskite nanocrystals and their applications in radiation detection. © Tsinghua University Press 2022 |
| abstract_unstemmed |
Abstract Lead-free bismuth-based halide perovskites and their analogues have attracted research interest for their high stability and optoelectronic properties. However, the morphology-controlled synthesis of bismuth-based perovskite nanocrystals has been rarely demonstrated. Herein, we report the colloidal synthesis of zero-dimensional (0D) $ Cs_{3} %$ BiCl_{6} $ nanosheets (NSs), $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs/nanoplates (NPs) and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs through a hot-injection method. We demonstrate that the $ Cs_{3} %$ BiCl_{6} $ NSs, as an initial product of $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ and $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs, can transform into $ Cs_{3} %$ Bi_{2} %$ Cl_{9} $ NSs or $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ NPs via Cl-induced metal ion insertion reactions under the templating effect of $ Cs_{3} %$ BiCl_{6} $. This growth mechanism is also applicable for the synthesis of $ Cs_{4} %$ CdBi_{2} %$ Cl_{12} $ nanoplates. Furthermore, the alloying of $ Cd^{2+} $ into $ Cs_{4} %$ MnBi_{2} %$ Cl_{12} $ lattice could weaken the strong coupling effect between Mn and Mn, which leads to a prolonged photoluminescence lifetime and an enhanced photoluminescence quantum yield (PLQY). As a proof of concept, the alloyed $ Cs_{4} %$ Mn_{x} %$ Cd_{1−x} %$ Bi_{2} %$ Cl_{12} $ NPs are used as a scintillator, which show a lowest detection limit of 134.5 nGy/s. The X-ray imaging results display a high spatial resolution of over 20 line pairs per millimeter (lp/mm). These results provide new insights in the synthesis of anisotropic bismuth-based perovskite nanocrystals and their applications in radiation detection. © Tsinghua University Press 2022 |
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Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates |
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https://dx.doi.org/10.1007/s12274-022-4656-0 |
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Xiao, Jiawen Yan, Zhengguang Niu, Xiaowei Lin, Taifeng Zhou, Yingchun Li, Jingyu Han, Xiaodong |
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Xiao, Jiawen Yan, Zhengguang Niu, Xiaowei Lin, Taifeng Zhou, Yingchun Li, Jingyu Han, Xiaodong |
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| doi_str |
10.1007/s12274-022-4656-0 |
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2024-07-03T21:16:30.643Z |
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| score |
7.3985205 |