Evaluation of N-Methyl-2-pyrrolidone Concentration on Synthesis and Characterization of 1% Toluene-4-Sulfonic Acid Monohydrate Doped Polyaniline Film
Abstract Polyaniline (PANI) is one of the most promising conducting polymers to be used in several applications, owing to its easily synthesized, high surface area, cost-effectiveness, and tremendous electrical conductivity. In this research, 1% toluene-4-sulfonic acid monohydrate (PTSA) doped PANI...
Ausführliche Beschreibung
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| Autor*in: |
Beygisangchin, Mahnoush [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Journal of inorganic and organometallic polymers and materials - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1991, 33(2023), 5 vom: 24. Feb., Seite 1246-1260 |
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| Übergeordnetes Werk: |
volume:33 ; year:2023 ; number:5 ; day:24 ; month:02 ; pages:1246-1260 |
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| DOI / URN: |
10.1007/s10904-023-02574-3 |
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| 520 | |a Abstract Polyaniline (PANI) is one of the most promising conducting polymers to be used in several applications, owing to its easily synthesized, high surface area, cost-effectiveness, and tremendous electrical conductivity. In this research, 1% toluene-4-sulfonic acid monohydrate (PTSA) doped PANI film was fabricated using twelve different concentrations from 0.5 to 6 wt % contents of N-methyl-2-pyrrolidone (NMP) as a solvent since the amount of NMP is still a vital aspect to recognize optimum combination. The chemical, optical, thermal, morphological, and electrical conductivity properties are investigated through Fourier transform infrared (FT-IR) spectroscopy, photoluminescence (PL) spectroscopy, ultraviolet-visible (UV–vis) spectroscopy, thermal gravity analysis (TGA), field emission scanning electron microscopy (FE-SEM) and Breuneur–Emmet–Teller (BET), then the four-point probe method. The existence of a hydrogen (H) bonding association between the C=O functional group within NMP and the N–H functional group throughout the PANI films will be shown using FT-IR analysis. Bandgap and PL intensity decreased with increasing NMP concentrations. FE-SEM displays the high-quality morphology of PANI can be achieved by increasing NMP concentrations. The specific electrical conductivity of prepared samples did not significantly change. The 1% PTSA and 3% NMP doped PANI is introduced as optimized PANI film with a low bandgap value of 2.54 (eV), high PL intensity, high specific surface area value of 121.457 ($ m^{2} $/g), and stable conductivity value of 2.45 (Ω cm)−1 owing to the arranged design of benzenoid and quinoid parts in its structure which seems a proper candidate to improve PANI film properties for use in sensing and supercapacitor applications. | ||
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10.1007/s10904-023-02574-3 doi (DE-627)SPR05170997X (SPR)s10904-023-02574-3-e DE-627 ger DE-627 rakwb eng Beygisangchin, Mahnoush verfasserin aut Evaluation of N-Methyl-2-pyrrolidone Concentration on Synthesis and Characterization of 1% Toluene-4-Sulfonic Acid Monohydrate Doped Polyaniline Film 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Polyaniline (PANI) is one of the most promising conducting polymers to be used in several applications, owing to its easily synthesized, high surface area, cost-effectiveness, and tremendous electrical conductivity. In this research, 1% toluene-4-sulfonic acid monohydrate (PTSA) doped PANI film was fabricated using twelve different concentrations from 0.5 to 6 wt % contents of N-methyl-2-pyrrolidone (NMP) as a solvent since the amount of NMP is still a vital aspect to recognize optimum combination. The chemical, optical, thermal, morphological, and electrical conductivity properties are investigated through Fourier transform infrared (FT-IR) spectroscopy, photoluminescence (PL) spectroscopy, ultraviolet-visible (UV–vis) spectroscopy, thermal gravity analysis (TGA), field emission scanning electron microscopy (FE-SEM) and Breuneur–Emmet–Teller (BET), then the four-point probe method. The existence of a hydrogen (H) bonding association between the C=O functional group within NMP and the N–H functional group throughout the PANI films will be shown using FT-IR analysis. Bandgap and PL intensity decreased with increasing NMP concentrations. FE-SEM displays the high-quality morphology of PANI can be achieved by increasing NMP concentrations. The specific electrical conductivity of prepared samples did not significantly change. The 1% PTSA and 3% NMP doped PANI is introduced as optimized PANI film with a low bandgap value of 2.54 (eV), high PL intensity, high specific surface area value of 121.457 ($ m^{2} $/g), and stable conductivity value of 2.45 (Ω cm)−1 owing to the arranged design of benzenoid and quinoid parts in its structure which seems a proper candidate to improve PANI film properties for use in sensing and supercapacitor applications. Polyaniline (dpeaa)DE-He213 PANI (dpeaa)DE-He213 NMP (dpeaa)DE-He213 Bandgap (dpeaa)DE-He213 Thickness (dpeaa)DE-He213 Conductivity (dpeaa)DE-He213 Abdul Rashid, Suraya aut Shafie, Suhaidi aut Lim, Hong Ngee aut Enthalten in Journal of inorganic and organometallic polymers and materials Dordrecht [u.a.] : Springer Science + Business Media B.V., 1991 33(2023), 5 vom: 24. Feb., Seite 1246-1260 (DE-627)320575101 (DE-600)2016951-6 1574-1451 nnns volume:33 year:2023 number:5 day:24 month:02 pages:1246-1260 https://dx.doi.org/10.1007/s10904-023-02574-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 33 2023 5 24 02 1246-1260 |
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10.1007/s10904-023-02574-3 doi (DE-627)SPR05170997X (SPR)s10904-023-02574-3-e DE-627 ger DE-627 rakwb eng Beygisangchin, Mahnoush verfasserin aut Evaluation of N-Methyl-2-pyrrolidone Concentration on Synthesis and Characterization of 1% Toluene-4-Sulfonic Acid Monohydrate Doped Polyaniline Film 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Polyaniline (PANI) is one of the most promising conducting polymers to be used in several applications, owing to its easily synthesized, high surface area, cost-effectiveness, and tremendous electrical conductivity. In this research, 1% toluene-4-sulfonic acid monohydrate (PTSA) doped PANI film was fabricated using twelve different concentrations from 0.5 to 6 wt % contents of N-methyl-2-pyrrolidone (NMP) as a solvent since the amount of NMP is still a vital aspect to recognize optimum combination. The chemical, optical, thermal, morphological, and electrical conductivity properties are investigated through Fourier transform infrared (FT-IR) spectroscopy, photoluminescence (PL) spectroscopy, ultraviolet-visible (UV–vis) spectroscopy, thermal gravity analysis (TGA), field emission scanning electron microscopy (FE-SEM) and Breuneur–Emmet–Teller (BET), then the four-point probe method. The existence of a hydrogen (H) bonding association between the C=O functional group within NMP and the N–H functional group throughout the PANI films will be shown using FT-IR analysis. Bandgap and PL intensity decreased with increasing NMP concentrations. FE-SEM displays the high-quality morphology of PANI can be achieved by increasing NMP concentrations. The specific electrical conductivity of prepared samples did not significantly change. The 1% PTSA and 3% NMP doped PANI is introduced as optimized PANI film with a low bandgap value of 2.54 (eV), high PL intensity, high specific surface area value of 121.457 ($ m^{2} $/g), and stable conductivity value of 2.45 (Ω cm)−1 owing to the arranged design of benzenoid and quinoid parts in its structure which seems a proper candidate to improve PANI film properties for use in sensing and supercapacitor applications. Polyaniline (dpeaa)DE-He213 PANI (dpeaa)DE-He213 NMP (dpeaa)DE-He213 Bandgap (dpeaa)DE-He213 Thickness (dpeaa)DE-He213 Conductivity (dpeaa)DE-He213 Abdul Rashid, Suraya aut Shafie, Suhaidi aut Lim, Hong Ngee aut Enthalten in Journal of inorganic and organometallic polymers and materials Dordrecht [u.a.] : Springer Science + Business Media B.V., 1991 33(2023), 5 vom: 24. Feb., Seite 1246-1260 (DE-627)320575101 (DE-600)2016951-6 1574-1451 nnns volume:33 year:2023 number:5 day:24 month:02 pages:1246-1260 https://dx.doi.org/10.1007/s10904-023-02574-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 33 2023 5 24 02 1246-1260 |
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10.1007/s10904-023-02574-3 doi (DE-627)SPR05170997X (SPR)s10904-023-02574-3-e DE-627 ger DE-627 rakwb eng Beygisangchin, Mahnoush verfasserin aut Evaluation of N-Methyl-2-pyrrolidone Concentration on Synthesis and Characterization of 1% Toluene-4-Sulfonic Acid Monohydrate Doped Polyaniline Film 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Polyaniline (PANI) is one of the most promising conducting polymers to be used in several applications, owing to its easily synthesized, high surface area, cost-effectiveness, and tremendous electrical conductivity. In this research, 1% toluene-4-sulfonic acid monohydrate (PTSA) doped PANI film was fabricated using twelve different concentrations from 0.5 to 6 wt % contents of N-methyl-2-pyrrolidone (NMP) as a solvent since the amount of NMP is still a vital aspect to recognize optimum combination. The chemical, optical, thermal, morphological, and electrical conductivity properties are investigated through Fourier transform infrared (FT-IR) spectroscopy, photoluminescence (PL) spectroscopy, ultraviolet-visible (UV–vis) spectroscopy, thermal gravity analysis (TGA), field emission scanning electron microscopy (FE-SEM) and Breuneur–Emmet–Teller (BET), then the four-point probe method. The existence of a hydrogen (H) bonding association between the C=O functional group within NMP and the N–H functional group throughout the PANI films will be shown using FT-IR analysis. Bandgap and PL intensity decreased with increasing NMP concentrations. FE-SEM displays the high-quality morphology of PANI can be achieved by increasing NMP concentrations. The specific electrical conductivity of prepared samples did not significantly change. The 1% PTSA and 3% NMP doped PANI is introduced as optimized PANI film with a low bandgap value of 2.54 (eV), high PL intensity, high specific surface area value of 121.457 ($ m^{2} $/g), and stable conductivity value of 2.45 (Ω cm)−1 owing to the arranged design of benzenoid and quinoid parts in its structure which seems a proper candidate to improve PANI film properties for use in sensing and supercapacitor applications. Polyaniline (dpeaa)DE-He213 PANI (dpeaa)DE-He213 NMP (dpeaa)DE-He213 Bandgap (dpeaa)DE-He213 Thickness (dpeaa)DE-He213 Conductivity (dpeaa)DE-He213 Abdul Rashid, Suraya aut Shafie, Suhaidi aut Lim, Hong Ngee aut Enthalten in Journal of inorganic and organometallic polymers and materials Dordrecht [u.a.] : Springer Science + Business Media B.V., 1991 33(2023), 5 vom: 24. Feb., Seite 1246-1260 (DE-627)320575101 (DE-600)2016951-6 1574-1451 nnns volume:33 year:2023 number:5 day:24 month:02 pages:1246-1260 https://dx.doi.org/10.1007/s10904-023-02574-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 33 2023 5 24 02 1246-1260 |
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10.1007/s10904-023-02574-3 doi (DE-627)SPR05170997X (SPR)s10904-023-02574-3-e DE-627 ger DE-627 rakwb eng Beygisangchin, Mahnoush verfasserin aut Evaluation of N-Methyl-2-pyrrolidone Concentration on Synthesis and Characterization of 1% Toluene-4-Sulfonic Acid Monohydrate Doped Polyaniline Film 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Polyaniline (PANI) is one of the most promising conducting polymers to be used in several applications, owing to its easily synthesized, high surface area, cost-effectiveness, and tremendous electrical conductivity. In this research, 1% toluene-4-sulfonic acid monohydrate (PTSA) doped PANI film was fabricated using twelve different concentrations from 0.5 to 6 wt % contents of N-methyl-2-pyrrolidone (NMP) as a solvent since the amount of NMP is still a vital aspect to recognize optimum combination. The chemical, optical, thermal, morphological, and electrical conductivity properties are investigated through Fourier transform infrared (FT-IR) spectroscopy, photoluminescence (PL) spectroscopy, ultraviolet-visible (UV–vis) spectroscopy, thermal gravity analysis (TGA), field emission scanning electron microscopy (FE-SEM) and Breuneur–Emmet–Teller (BET), then the four-point probe method. The existence of a hydrogen (H) bonding association between the C=O functional group within NMP and the N–H functional group throughout the PANI films will be shown using FT-IR analysis. Bandgap and PL intensity decreased with increasing NMP concentrations. FE-SEM displays the high-quality morphology of PANI can be achieved by increasing NMP concentrations. The specific electrical conductivity of prepared samples did not significantly change. The 1% PTSA and 3% NMP doped PANI is introduced as optimized PANI film with a low bandgap value of 2.54 (eV), high PL intensity, high specific surface area value of 121.457 ($ m^{2} $/g), and stable conductivity value of 2.45 (Ω cm)−1 owing to the arranged design of benzenoid and quinoid parts in its structure which seems a proper candidate to improve PANI film properties for use in sensing and supercapacitor applications. Polyaniline (dpeaa)DE-He213 PANI (dpeaa)DE-He213 NMP (dpeaa)DE-He213 Bandgap (dpeaa)DE-He213 Thickness (dpeaa)DE-He213 Conductivity (dpeaa)DE-He213 Abdul Rashid, Suraya aut Shafie, Suhaidi aut Lim, Hong Ngee aut Enthalten in Journal of inorganic and organometallic polymers and materials Dordrecht [u.a.] : Springer Science + Business Media B.V., 1991 33(2023), 5 vom: 24. Feb., Seite 1246-1260 (DE-627)320575101 (DE-600)2016951-6 1574-1451 nnns volume:33 year:2023 number:5 day:24 month:02 pages:1246-1260 https://dx.doi.org/10.1007/s10904-023-02574-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 33 2023 5 24 02 1246-1260 |
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10.1007/s10904-023-02574-3 doi (DE-627)SPR05170997X (SPR)s10904-023-02574-3-e DE-627 ger DE-627 rakwb eng Beygisangchin, Mahnoush verfasserin aut Evaluation of N-Methyl-2-pyrrolidone Concentration on Synthesis and Characterization of 1% Toluene-4-Sulfonic Acid Monohydrate Doped Polyaniline Film 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Polyaniline (PANI) is one of the most promising conducting polymers to be used in several applications, owing to its easily synthesized, high surface area, cost-effectiveness, and tremendous electrical conductivity. In this research, 1% toluene-4-sulfonic acid monohydrate (PTSA) doped PANI film was fabricated using twelve different concentrations from 0.5 to 6 wt % contents of N-methyl-2-pyrrolidone (NMP) as a solvent since the amount of NMP is still a vital aspect to recognize optimum combination. The chemical, optical, thermal, morphological, and electrical conductivity properties are investigated through Fourier transform infrared (FT-IR) spectroscopy, photoluminescence (PL) spectroscopy, ultraviolet-visible (UV–vis) spectroscopy, thermal gravity analysis (TGA), field emission scanning electron microscopy (FE-SEM) and Breuneur–Emmet–Teller (BET), then the four-point probe method. The existence of a hydrogen (H) bonding association between the C=O functional group within NMP and the N–H functional group throughout the PANI films will be shown using FT-IR analysis. Bandgap and PL intensity decreased with increasing NMP concentrations. FE-SEM displays the high-quality morphology of PANI can be achieved by increasing NMP concentrations. The specific electrical conductivity of prepared samples did not significantly change. The 1% PTSA and 3% NMP doped PANI is introduced as optimized PANI film with a low bandgap value of 2.54 (eV), high PL intensity, high specific surface area value of 121.457 ($ m^{2} $/g), and stable conductivity value of 2.45 (Ω cm)−1 owing to the arranged design of benzenoid and quinoid parts in its structure which seems a proper candidate to improve PANI film properties for use in sensing and supercapacitor applications. Polyaniline (dpeaa)DE-He213 PANI (dpeaa)DE-He213 NMP (dpeaa)DE-He213 Bandgap (dpeaa)DE-He213 Thickness (dpeaa)DE-He213 Conductivity (dpeaa)DE-He213 Abdul Rashid, Suraya aut Shafie, Suhaidi aut Lim, Hong Ngee aut Enthalten in Journal of inorganic and organometallic polymers and materials Dordrecht [u.a.] : Springer Science + Business Media B.V., 1991 33(2023), 5 vom: 24. Feb., Seite 1246-1260 (DE-627)320575101 (DE-600)2016951-6 1574-1451 nnns volume:33 year:2023 number:5 day:24 month:02 pages:1246-1260 https://dx.doi.org/10.1007/s10904-023-02574-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 33 2023 5 24 02 1246-1260 |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Polyaniline (PANI) is one of the most promising conducting polymers to be used in several applications, owing to its easily synthesized, high surface area, cost-effectiveness, and tremendous electrical conductivity. In this research, 1% toluene-4-sulfonic acid monohydrate (PTSA) doped PANI film was fabricated using twelve different concentrations from 0.5 to 6 wt % contents of N-methyl-2-pyrrolidone (NMP) as a solvent since the amount of NMP is still a vital aspect to recognize optimum combination. The chemical, optical, thermal, morphological, and electrical conductivity properties are investigated through Fourier transform infrared (FT-IR) spectroscopy, photoluminescence (PL) spectroscopy, ultraviolet-visible (UV–vis) spectroscopy, thermal gravity analysis (TGA), field emission scanning electron microscopy (FE-SEM) and Breuneur–Emmet–Teller (BET), then the four-point probe method. The existence of a hydrogen (H) bonding association between the C=O functional group within NMP and the N–H functional group throughout the PANI films will be shown using FT-IR analysis. Bandgap and PL intensity decreased with increasing NMP concentrations. FE-SEM displays the high-quality morphology of PANI can be achieved by increasing NMP concentrations. The specific electrical conductivity of prepared samples did not significantly change. The 1% PTSA and 3% NMP doped PANI is introduced as optimized PANI film with a low bandgap value of 2.54 (eV), high PL intensity, high specific surface area value of 121.457 ($ m^{2} $/g), and stable conductivity value of 2.45 (Ω cm)−1 owing to the arranged design of benzenoid and quinoid parts in its structure which seems a proper candidate to improve PANI film properties for use in sensing and supercapacitor applications.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polyaniline</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">PANI</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">NMP</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Bandgap</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thickness</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Conductivity</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Abdul Rashid, Suraya</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Shafie, Suhaidi</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lim, Hong Ngee</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of inorganic and organometallic polymers and materials</subfield><subfield code="d">Dordrecht [u.a.] : Springer Science + Business Media B.V., 1991</subfield><subfield code="g">33(2023), 5 vom: 24. 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Beygisangchin, Mahnoush |
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Beygisangchin, Mahnoush misc Polyaniline misc PANI misc NMP misc Bandgap misc Thickness misc Conductivity Evaluation of N-Methyl-2-pyrrolidone Concentration on Synthesis and Characterization of 1% Toluene-4-Sulfonic Acid Monohydrate Doped Polyaniline Film |
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Evaluation of N-Methyl-2-pyrrolidone Concentration on Synthesis and Characterization of 1% Toluene-4-Sulfonic Acid Monohydrate Doped Polyaniline Film Polyaniline (dpeaa)DE-He213 PANI (dpeaa)DE-He213 NMP (dpeaa)DE-He213 Bandgap (dpeaa)DE-He213 Thickness (dpeaa)DE-He213 Conductivity (dpeaa)DE-He213 |
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Evaluation of N-Methyl-2-pyrrolidone Concentration on Synthesis and Characterization of 1% Toluene-4-Sulfonic Acid Monohydrate Doped Polyaniline Film |
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Evaluation of N-Methyl-2-pyrrolidone Concentration on Synthesis and Characterization of 1% Toluene-4-Sulfonic Acid Monohydrate Doped Polyaniline Film |
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Beygisangchin, Mahnoush Abdul Rashid, Suraya Shafie, Suhaidi Lim, Hong Ngee |
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evaluation of n-methyl-2-pyrrolidone concentration on synthesis and characterization of 1% toluene-4-sulfonic acid monohydrate doped polyaniline film |
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Evaluation of N-Methyl-2-pyrrolidone Concentration on Synthesis and Characterization of 1% Toluene-4-Sulfonic Acid Monohydrate Doped Polyaniline Film |
| abstract |
Abstract Polyaniline (PANI) is one of the most promising conducting polymers to be used in several applications, owing to its easily synthesized, high surface area, cost-effectiveness, and tremendous electrical conductivity. In this research, 1% toluene-4-sulfonic acid monohydrate (PTSA) doped PANI film was fabricated using twelve different concentrations from 0.5 to 6 wt % contents of N-methyl-2-pyrrolidone (NMP) as a solvent since the amount of NMP is still a vital aspect to recognize optimum combination. The chemical, optical, thermal, morphological, and electrical conductivity properties are investigated through Fourier transform infrared (FT-IR) spectroscopy, photoluminescence (PL) spectroscopy, ultraviolet-visible (UV–vis) spectroscopy, thermal gravity analysis (TGA), field emission scanning electron microscopy (FE-SEM) and Breuneur–Emmet–Teller (BET), then the four-point probe method. The existence of a hydrogen (H) bonding association between the C=O functional group within NMP and the N–H functional group throughout the PANI films will be shown using FT-IR analysis. Bandgap and PL intensity decreased with increasing NMP concentrations. FE-SEM displays the high-quality morphology of PANI can be achieved by increasing NMP concentrations. The specific electrical conductivity of prepared samples did not significantly change. The 1% PTSA and 3% NMP doped PANI is introduced as optimized PANI film with a low bandgap value of 2.54 (eV), high PL intensity, high specific surface area value of 121.457 ($ m^{2} $/g), and stable conductivity value of 2.45 (Ω cm)−1 owing to the arranged design of benzenoid and quinoid parts in its structure which seems a proper candidate to improve PANI film properties for use in sensing and supercapacitor applications. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Abstract Polyaniline (PANI) is one of the most promising conducting polymers to be used in several applications, owing to its easily synthesized, high surface area, cost-effectiveness, and tremendous electrical conductivity. In this research, 1% toluene-4-sulfonic acid monohydrate (PTSA) doped PANI film was fabricated using twelve different concentrations from 0.5 to 6 wt % contents of N-methyl-2-pyrrolidone (NMP) as a solvent since the amount of NMP is still a vital aspect to recognize optimum combination. The chemical, optical, thermal, morphological, and electrical conductivity properties are investigated through Fourier transform infrared (FT-IR) spectroscopy, photoluminescence (PL) spectroscopy, ultraviolet-visible (UV–vis) spectroscopy, thermal gravity analysis (TGA), field emission scanning electron microscopy (FE-SEM) and Breuneur–Emmet–Teller (BET), then the four-point probe method. The existence of a hydrogen (H) bonding association between the C=O functional group within NMP and the N–H functional group throughout the PANI films will be shown using FT-IR analysis. Bandgap and PL intensity decreased with increasing NMP concentrations. FE-SEM displays the high-quality morphology of PANI can be achieved by increasing NMP concentrations. The specific electrical conductivity of prepared samples did not significantly change. The 1% PTSA and 3% NMP doped PANI is introduced as optimized PANI film with a low bandgap value of 2.54 (eV), high PL intensity, high specific surface area value of 121.457 ($ m^{2} $/g), and stable conductivity value of 2.45 (Ω cm)−1 owing to the arranged design of benzenoid and quinoid parts in its structure which seems a proper candidate to improve PANI film properties for use in sensing and supercapacitor applications. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Abstract Polyaniline (PANI) is one of the most promising conducting polymers to be used in several applications, owing to its easily synthesized, high surface area, cost-effectiveness, and tremendous electrical conductivity. In this research, 1% toluene-4-sulfonic acid monohydrate (PTSA) doped PANI film was fabricated using twelve different concentrations from 0.5 to 6 wt % contents of N-methyl-2-pyrrolidone (NMP) as a solvent since the amount of NMP is still a vital aspect to recognize optimum combination. The chemical, optical, thermal, morphological, and electrical conductivity properties are investigated through Fourier transform infrared (FT-IR) spectroscopy, photoluminescence (PL) spectroscopy, ultraviolet-visible (UV–vis) spectroscopy, thermal gravity analysis (TGA), field emission scanning electron microscopy (FE-SEM) and Breuneur–Emmet–Teller (BET), then the four-point probe method. The existence of a hydrogen (H) bonding association between the C=O functional group within NMP and the N–H functional group throughout the PANI films will be shown using FT-IR analysis. Bandgap and PL intensity decreased with increasing NMP concentrations. FE-SEM displays the high-quality morphology of PANI can be achieved by increasing NMP concentrations. The specific electrical conductivity of prepared samples did not significantly change. The 1% PTSA and 3% NMP doped PANI is introduced as optimized PANI film with a low bandgap value of 2.54 (eV), high PL intensity, high specific surface area value of 121.457 ($ m^{2} $/g), and stable conductivity value of 2.45 (Ω cm)−1 owing to the arranged design of benzenoid and quinoid parts in its structure which seems a proper candidate to improve PANI film properties for use in sensing and supercapacitor applications. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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5 |
| title_short |
Evaluation of N-Methyl-2-pyrrolidone Concentration on Synthesis and Characterization of 1% Toluene-4-Sulfonic Acid Monohydrate Doped Polyaniline Film |
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https://dx.doi.org/10.1007/s10904-023-02574-3 |
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Abdul Rashid, Suraya Shafie, Suhaidi Lim, Hong Ngee |
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2024-07-03T23:22:46.843Z |
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| score |
7.398883 |