Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption
Abstract In sustainable waste management, reusing coffee waste such as husks or spent coffee grounds helps convert a huge amount of waste into a new resource. In this study, $ H_{3} %$ PO_{4} $-activated filter coffee waste ($ H_{3} %$ PO_{4} $-FCW) and $ ZnCl_{2} $-activated filter coffee waste ($...
Ausführliche Beschreibung
Autor*in: |
Çifçi, Deniz İzlen [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2022 |
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Anmerkung: |
© King Fahd University of Petroleum & Minerals 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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Übergeordnetes Werk: |
Enthalten in: The Arabian journal for science and engineering - Berlin : Springer, 2011, 48(2022), 7 vom: 14. Sept., Seite 8641-8653 |
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Übergeordnetes Werk: |
volume:48 ; year:2022 ; number:7 ; day:14 ; month:09 ; pages:8641-8653 |
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DOI / URN: |
10.1007/s13369-022-07248-9 |
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Katalog-ID: |
SPR051968274 |
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520 | |a Abstract In sustainable waste management, reusing coffee waste such as husks or spent coffee grounds helps convert a huge amount of waste into a new resource. In this study, $ H_{3} %$ PO_{4} $-activated filter coffee waste ($ H_{3} %$ PO_{4} $-FCW) and $ ZnCl_{2} $-activated filter coffee waste ($ ZnCl_{2} $-FCW) were synthesised, and the characterisation of them was revealed by SEM, EDAX, FTIR and XRD analyses. Adsorption isotherms (Langmuir, Freundlich, Temkin and Dubinin–Radushkevich), adsorption kinetics (Elovich, pseudo-second-order kinetics, pseudo-first-order kinetics including error functions) and adsorption thermodynamics were determined and the effect of parameters such as pH, adsorbent dose, initial methylene blue (MB) concentration, adsorption time and temperature on MB removal was evaluated by the ultrasonic-assisted adsorption. It was observed that ultrasonic-assisted adsorption was more suitable for the Langmuir isotherm for both adsorbents and that the adsorption kinetics was better suited to the pseudo-second-order kinetics. In addition, the ultrasonic-assisted adsorption using $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW occurred endothermically and the adsorption mechanism was physisorption. MB removal with $ ZnCl_{2} $-FCW could reach over 90% when pH is between 3 and 7 in the ultrasonic-assisted adsorption process. The maximum adsorption capacity was obtained as 42.7 mg/g and 106.4 mg/g for $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW, respectively. It was seen that the $ q_{max} $ value of $ ZnCl_{2} $-FCW was 2.5 times higher than the $ q_{max} $ of $ H_{3} %$ PO_{4} $-FCW. Moreover, reusability studies showed that MB removal of over 90% could be achieved in the $ 2^{nd} $ use of $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW. In conclusion, high dye removal could be achieved by synthesising low-cost adsorbents. The use of filtered coffee wastes in the adsorption of basic dyes such as MB is, therefore, important in terms of both waste reduction and management. | ||
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10.1007/s13369-022-07248-9 doi (DE-627)SPR051968274 (SPR)s13369-022-07248-9-e DE-627 ger DE-627 rakwb eng Çifçi, Deniz İzlen verfasserin (orcid)0000-0001-7527-6130 aut Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © King Fahd University of Petroleum & Minerals 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract In sustainable waste management, reusing coffee waste such as husks or spent coffee grounds helps convert a huge amount of waste into a new resource. In this study, $ H_{3} %$ PO_{4} $-activated filter coffee waste ($ H_{3} %$ PO_{4} $-FCW) and $ ZnCl_{2} $-activated filter coffee waste ($ ZnCl_{2} $-FCW) were synthesised, and the characterisation of them was revealed by SEM, EDAX, FTIR and XRD analyses. Adsorption isotherms (Langmuir, Freundlich, Temkin and Dubinin–Radushkevich), adsorption kinetics (Elovich, pseudo-second-order kinetics, pseudo-first-order kinetics including error functions) and adsorption thermodynamics were determined and the effect of parameters such as pH, adsorbent dose, initial methylene blue (MB) concentration, adsorption time and temperature on MB removal was evaluated by the ultrasonic-assisted adsorption. It was observed that ultrasonic-assisted adsorption was more suitable for the Langmuir isotherm for both adsorbents and that the adsorption kinetics was better suited to the pseudo-second-order kinetics. In addition, the ultrasonic-assisted adsorption using $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW occurred endothermically and the adsorption mechanism was physisorption. MB removal with $ ZnCl_{2} $-FCW could reach over 90% when pH is between 3 and 7 in the ultrasonic-assisted adsorption process. The maximum adsorption capacity was obtained as 42.7 mg/g and 106.4 mg/g for $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW, respectively. It was seen that the $ q_{max} $ value of $ ZnCl_{2} $-FCW was 2.5 times higher than the $ q_{max} $ of $ H_{3} %$ PO_{4} $-FCW. Moreover, reusability studies showed that MB removal of over 90% could be achieved in the $ 2^{nd} $ use of $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW. In conclusion, high dye removal could be achieved by synthesising low-cost adsorbents. The use of filtered coffee wastes in the adsorption of basic dyes such as MB is, therefore, important in terms of both waste reduction and management. Adsorption isotherm (dpeaa)DE-He213 Adsorption kinetics (dpeaa)DE-He213 Basic dye (dpeaa)DE-He213 Error functions (dpeaa)DE-He213 Ultrasonic-assisted adsorption (dpeaa)DE-He213 Aydın, Nesli aut Enthalten in The Arabian journal for science and engineering Berlin : Springer, 2011 48(2022), 7 vom: 14. Sept., Seite 8641-8653 (DE-627)588780731 (DE-600)2471504-9 2191-4281 nnns volume:48 year:2022 number:7 day:14 month:09 pages:8641-8653 https://dx.doi.org/10.1007/s13369-022-07248-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 48 2022 7 14 09 8641-8653 |
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10.1007/s13369-022-07248-9 doi (DE-627)SPR051968274 (SPR)s13369-022-07248-9-e DE-627 ger DE-627 rakwb eng Çifçi, Deniz İzlen verfasserin (orcid)0000-0001-7527-6130 aut Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © King Fahd University of Petroleum & Minerals 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract In sustainable waste management, reusing coffee waste such as husks or spent coffee grounds helps convert a huge amount of waste into a new resource. In this study, $ H_{3} %$ PO_{4} $-activated filter coffee waste ($ H_{3} %$ PO_{4} $-FCW) and $ ZnCl_{2} $-activated filter coffee waste ($ ZnCl_{2} $-FCW) were synthesised, and the characterisation of them was revealed by SEM, EDAX, FTIR and XRD analyses. Adsorption isotherms (Langmuir, Freundlich, Temkin and Dubinin–Radushkevich), adsorption kinetics (Elovich, pseudo-second-order kinetics, pseudo-first-order kinetics including error functions) and adsorption thermodynamics were determined and the effect of parameters such as pH, adsorbent dose, initial methylene blue (MB) concentration, adsorption time and temperature on MB removal was evaluated by the ultrasonic-assisted adsorption. It was observed that ultrasonic-assisted adsorption was more suitable for the Langmuir isotherm for both adsorbents and that the adsorption kinetics was better suited to the pseudo-second-order kinetics. In addition, the ultrasonic-assisted adsorption using $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW occurred endothermically and the adsorption mechanism was physisorption. MB removal with $ ZnCl_{2} $-FCW could reach over 90% when pH is between 3 and 7 in the ultrasonic-assisted adsorption process. The maximum adsorption capacity was obtained as 42.7 mg/g and 106.4 mg/g for $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW, respectively. It was seen that the $ q_{max} $ value of $ ZnCl_{2} $-FCW was 2.5 times higher than the $ q_{max} $ of $ H_{3} %$ PO_{4} $-FCW. Moreover, reusability studies showed that MB removal of over 90% could be achieved in the $ 2^{nd} $ use of $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW. In conclusion, high dye removal could be achieved by synthesising low-cost adsorbents. The use of filtered coffee wastes in the adsorption of basic dyes such as MB is, therefore, important in terms of both waste reduction and management. Adsorption isotherm (dpeaa)DE-He213 Adsorption kinetics (dpeaa)DE-He213 Basic dye (dpeaa)DE-He213 Error functions (dpeaa)DE-He213 Ultrasonic-assisted adsorption (dpeaa)DE-He213 Aydın, Nesli aut Enthalten in The Arabian journal for science and engineering Berlin : Springer, 2011 48(2022), 7 vom: 14. Sept., Seite 8641-8653 (DE-627)588780731 (DE-600)2471504-9 2191-4281 nnns volume:48 year:2022 number:7 day:14 month:09 pages:8641-8653 https://dx.doi.org/10.1007/s13369-022-07248-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 48 2022 7 14 09 8641-8653 |
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10.1007/s13369-022-07248-9 doi (DE-627)SPR051968274 (SPR)s13369-022-07248-9-e DE-627 ger DE-627 rakwb eng Çifçi, Deniz İzlen verfasserin (orcid)0000-0001-7527-6130 aut Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © King Fahd University of Petroleum & Minerals 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract In sustainable waste management, reusing coffee waste such as husks or spent coffee grounds helps convert a huge amount of waste into a new resource. In this study, $ H_{3} %$ PO_{4} $-activated filter coffee waste ($ H_{3} %$ PO_{4} $-FCW) and $ ZnCl_{2} $-activated filter coffee waste ($ ZnCl_{2} $-FCW) were synthesised, and the characterisation of them was revealed by SEM, EDAX, FTIR and XRD analyses. Adsorption isotherms (Langmuir, Freundlich, Temkin and Dubinin–Radushkevich), adsorption kinetics (Elovich, pseudo-second-order kinetics, pseudo-first-order kinetics including error functions) and adsorption thermodynamics were determined and the effect of parameters such as pH, adsorbent dose, initial methylene blue (MB) concentration, adsorption time and temperature on MB removal was evaluated by the ultrasonic-assisted adsorption. It was observed that ultrasonic-assisted adsorption was more suitable for the Langmuir isotherm for both adsorbents and that the adsorption kinetics was better suited to the pseudo-second-order kinetics. In addition, the ultrasonic-assisted adsorption using $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW occurred endothermically and the adsorption mechanism was physisorption. MB removal with $ ZnCl_{2} $-FCW could reach over 90% when pH is between 3 and 7 in the ultrasonic-assisted adsorption process. The maximum adsorption capacity was obtained as 42.7 mg/g and 106.4 mg/g for $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW, respectively. It was seen that the $ q_{max} $ value of $ ZnCl_{2} $-FCW was 2.5 times higher than the $ q_{max} $ of $ H_{3} %$ PO_{4} $-FCW. Moreover, reusability studies showed that MB removal of over 90% could be achieved in the $ 2^{nd} $ use of $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW. In conclusion, high dye removal could be achieved by synthesising low-cost adsorbents. The use of filtered coffee wastes in the adsorption of basic dyes such as MB is, therefore, important in terms of both waste reduction and management. Adsorption isotherm (dpeaa)DE-He213 Adsorption kinetics (dpeaa)DE-He213 Basic dye (dpeaa)DE-He213 Error functions (dpeaa)DE-He213 Ultrasonic-assisted adsorption (dpeaa)DE-He213 Aydın, Nesli aut Enthalten in The Arabian journal for science and engineering Berlin : Springer, 2011 48(2022), 7 vom: 14. Sept., Seite 8641-8653 (DE-627)588780731 (DE-600)2471504-9 2191-4281 nnns volume:48 year:2022 number:7 day:14 month:09 pages:8641-8653 https://dx.doi.org/10.1007/s13369-022-07248-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 48 2022 7 14 09 8641-8653 |
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10.1007/s13369-022-07248-9 doi (DE-627)SPR051968274 (SPR)s13369-022-07248-9-e DE-627 ger DE-627 rakwb eng Çifçi, Deniz İzlen verfasserin (orcid)0000-0001-7527-6130 aut Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © King Fahd University of Petroleum & Minerals 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract In sustainable waste management, reusing coffee waste such as husks or spent coffee grounds helps convert a huge amount of waste into a new resource. In this study, $ H_{3} %$ PO_{4} $-activated filter coffee waste ($ H_{3} %$ PO_{4} $-FCW) and $ ZnCl_{2} $-activated filter coffee waste ($ ZnCl_{2} $-FCW) were synthesised, and the characterisation of them was revealed by SEM, EDAX, FTIR and XRD analyses. Adsorption isotherms (Langmuir, Freundlich, Temkin and Dubinin–Radushkevich), adsorption kinetics (Elovich, pseudo-second-order kinetics, pseudo-first-order kinetics including error functions) and adsorption thermodynamics were determined and the effect of parameters such as pH, adsorbent dose, initial methylene blue (MB) concentration, adsorption time and temperature on MB removal was evaluated by the ultrasonic-assisted adsorption. It was observed that ultrasonic-assisted adsorption was more suitable for the Langmuir isotherm for both adsorbents and that the adsorption kinetics was better suited to the pseudo-second-order kinetics. In addition, the ultrasonic-assisted adsorption using $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW occurred endothermically and the adsorption mechanism was physisorption. MB removal with $ ZnCl_{2} $-FCW could reach over 90% when pH is between 3 and 7 in the ultrasonic-assisted adsorption process. The maximum adsorption capacity was obtained as 42.7 mg/g and 106.4 mg/g for $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW, respectively. It was seen that the $ q_{max} $ value of $ ZnCl_{2} $-FCW was 2.5 times higher than the $ q_{max} $ of $ H_{3} %$ PO_{4} $-FCW. Moreover, reusability studies showed that MB removal of over 90% could be achieved in the $ 2^{nd} $ use of $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW. In conclusion, high dye removal could be achieved by synthesising low-cost adsorbents. The use of filtered coffee wastes in the adsorption of basic dyes such as MB is, therefore, important in terms of both waste reduction and management. Adsorption isotherm (dpeaa)DE-He213 Adsorption kinetics (dpeaa)DE-He213 Basic dye (dpeaa)DE-He213 Error functions (dpeaa)DE-He213 Ultrasonic-assisted adsorption (dpeaa)DE-He213 Aydın, Nesli aut Enthalten in The Arabian journal for science and engineering Berlin : Springer, 2011 48(2022), 7 vom: 14. Sept., Seite 8641-8653 (DE-627)588780731 (DE-600)2471504-9 2191-4281 nnns volume:48 year:2022 number:7 day:14 month:09 pages:8641-8653 https://dx.doi.org/10.1007/s13369-022-07248-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 48 2022 7 14 09 8641-8653 |
allfieldsSound |
10.1007/s13369-022-07248-9 doi (DE-627)SPR051968274 (SPR)s13369-022-07248-9-e DE-627 ger DE-627 rakwb eng Çifçi, Deniz İzlen verfasserin (orcid)0000-0001-7527-6130 aut Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © King Fahd University of Petroleum & Minerals 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract In sustainable waste management, reusing coffee waste such as husks or spent coffee grounds helps convert a huge amount of waste into a new resource. In this study, $ H_{3} %$ PO_{4} $-activated filter coffee waste ($ H_{3} %$ PO_{4} $-FCW) and $ ZnCl_{2} $-activated filter coffee waste ($ ZnCl_{2} $-FCW) were synthesised, and the characterisation of them was revealed by SEM, EDAX, FTIR and XRD analyses. Adsorption isotherms (Langmuir, Freundlich, Temkin and Dubinin–Radushkevich), adsorption kinetics (Elovich, pseudo-second-order kinetics, pseudo-first-order kinetics including error functions) and adsorption thermodynamics were determined and the effect of parameters such as pH, adsorbent dose, initial methylene blue (MB) concentration, adsorption time and temperature on MB removal was evaluated by the ultrasonic-assisted adsorption. It was observed that ultrasonic-assisted adsorption was more suitable for the Langmuir isotherm for both adsorbents and that the adsorption kinetics was better suited to the pseudo-second-order kinetics. In addition, the ultrasonic-assisted adsorption using $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW occurred endothermically and the adsorption mechanism was physisorption. MB removal with $ ZnCl_{2} $-FCW could reach over 90% when pH is between 3 and 7 in the ultrasonic-assisted adsorption process. The maximum adsorption capacity was obtained as 42.7 mg/g and 106.4 mg/g for $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW, respectively. It was seen that the $ q_{max} $ value of $ ZnCl_{2} $-FCW was 2.5 times higher than the $ q_{max} $ of $ H_{3} %$ PO_{4} $-FCW. Moreover, reusability studies showed that MB removal of over 90% could be achieved in the $ 2^{nd} $ use of $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW. In conclusion, high dye removal could be achieved by synthesising low-cost adsorbents. The use of filtered coffee wastes in the adsorption of basic dyes such as MB is, therefore, important in terms of both waste reduction and management. Adsorption isotherm (dpeaa)DE-He213 Adsorption kinetics (dpeaa)DE-He213 Basic dye (dpeaa)DE-He213 Error functions (dpeaa)DE-He213 Ultrasonic-assisted adsorption (dpeaa)DE-He213 Aydın, Nesli aut Enthalten in The Arabian journal for science and engineering Berlin : Springer, 2011 48(2022), 7 vom: 14. Sept., Seite 8641-8653 (DE-627)588780731 (DE-600)2471504-9 2191-4281 nnns volume:48 year:2022 number:7 day:14 month:09 pages:8641-8653 https://dx.doi.org/10.1007/s13369-022-07248-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 48 2022 7 14 09 8641-8653 |
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Enthalten in The Arabian journal for science and engineering 48(2022), 7 vom: 14. Sept., Seite 8641-8653 volume:48 year:2022 number:7 day:14 month:09 pages:8641-8653 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR051968274</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230621064813.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230621s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s13369-022-07248-9</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR051968274</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s13369-022-07248-9-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Çifçi, Deniz İzlen</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0001-7527-6130</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© King Fahd University of Petroleum & Minerals 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract In sustainable waste management, reusing coffee waste such as husks or spent coffee grounds helps convert a huge amount of waste into a new resource. In this study, $ H_{3} %$ PO_{4} $-activated filter coffee waste ($ H_{3} %$ PO_{4} $-FCW) and $ ZnCl_{2} $-activated filter coffee waste ($ ZnCl_{2} $-FCW) were synthesised, and the characterisation of them was revealed by SEM, EDAX, FTIR and XRD analyses. Adsorption isotherms (Langmuir, Freundlich, Temkin and Dubinin–Radushkevich), adsorption kinetics (Elovich, pseudo-second-order kinetics, pseudo-first-order kinetics including error functions) and adsorption thermodynamics were determined and the effect of parameters such as pH, adsorbent dose, initial methylene blue (MB) concentration, adsorption time and temperature on MB removal was evaluated by the ultrasonic-assisted adsorption. It was observed that ultrasonic-assisted adsorption was more suitable for the Langmuir isotherm for both adsorbents and that the adsorption kinetics was better suited to the pseudo-second-order kinetics. In addition, the ultrasonic-assisted adsorption using $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW occurred endothermically and the adsorption mechanism was physisorption. MB removal with $ ZnCl_{2} $-FCW could reach over 90% when pH is between 3 and 7 in the ultrasonic-assisted adsorption process. The maximum adsorption capacity was obtained as 42.7 mg/g and 106.4 mg/g for $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW, respectively. It was seen that the $ q_{max} $ value of $ ZnCl_{2} $-FCW was 2.5 times higher than the $ q_{max} $ of $ H_{3} %$ PO_{4} $-FCW. Moreover, reusability studies showed that MB removal of over 90% could be achieved in the $ 2^{nd} $ use of $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW. In conclusion, high dye removal could be achieved by synthesising low-cost adsorbents. The use of filtered coffee wastes in the adsorption of basic dyes such as MB is, therefore, important in terms of both waste reduction and management.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Adsorption isotherm</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Adsorption kinetics</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Basic dye</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Error functions</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ultrasonic-assisted adsorption</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Aydın, Nesli</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">The Arabian journal for science and engineering</subfield><subfield code="d">Berlin : Springer, 2011</subfield><subfield code="g">48(2022), 7 vom: 14. 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Çifçi, Deniz İzlen |
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Çifçi, Deniz İzlen misc Adsorption isotherm misc Adsorption kinetics misc Basic dye misc Error functions misc Ultrasonic-assisted adsorption Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption |
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Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption Adsorption isotherm (dpeaa)DE-He213 Adsorption kinetics (dpeaa)DE-He213 Basic dye (dpeaa)DE-He213 Error functions (dpeaa)DE-He213 Ultrasonic-assisted adsorption (dpeaa)DE-He213 |
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misc Adsorption isotherm misc Adsorption kinetics misc Basic dye misc Error functions misc Ultrasonic-assisted adsorption |
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Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption |
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Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption |
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title_sort |
comparison of $ h_{3} %$ po_{4} $ and $ zncl_{2} $ activated filtered coffee waste carbon-based adsorbents in methylene blue removal by using ultrasonic-assisted adsorption |
title_auth |
Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption |
abstract |
Abstract In sustainable waste management, reusing coffee waste such as husks or spent coffee grounds helps convert a huge amount of waste into a new resource. In this study, $ H_{3} %$ PO_{4} $-activated filter coffee waste ($ H_{3} %$ PO_{4} $-FCW) and $ ZnCl_{2} $-activated filter coffee waste ($ ZnCl_{2} $-FCW) were synthesised, and the characterisation of them was revealed by SEM, EDAX, FTIR and XRD analyses. Adsorption isotherms (Langmuir, Freundlich, Temkin and Dubinin–Radushkevich), adsorption kinetics (Elovich, pseudo-second-order kinetics, pseudo-first-order kinetics including error functions) and adsorption thermodynamics were determined and the effect of parameters such as pH, adsorbent dose, initial methylene blue (MB) concentration, adsorption time and temperature on MB removal was evaluated by the ultrasonic-assisted adsorption. It was observed that ultrasonic-assisted adsorption was more suitable for the Langmuir isotherm for both adsorbents and that the adsorption kinetics was better suited to the pseudo-second-order kinetics. In addition, the ultrasonic-assisted adsorption using $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW occurred endothermically and the adsorption mechanism was physisorption. MB removal with $ ZnCl_{2} $-FCW could reach over 90% when pH is between 3 and 7 in the ultrasonic-assisted adsorption process. The maximum adsorption capacity was obtained as 42.7 mg/g and 106.4 mg/g for $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW, respectively. It was seen that the $ q_{max} $ value of $ ZnCl_{2} $-FCW was 2.5 times higher than the $ q_{max} $ of $ H_{3} %$ PO_{4} $-FCW. Moreover, reusability studies showed that MB removal of over 90% could be achieved in the $ 2^{nd} $ use of $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW. In conclusion, high dye removal could be achieved by synthesising low-cost adsorbents. The use of filtered coffee wastes in the adsorption of basic dyes such as MB is, therefore, important in terms of both waste reduction and management. © King Fahd University of Petroleum & Minerals 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
abstractGer |
Abstract In sustainable waste management, reusing coffee waste such as husks or spent coffee grounds helps convert a huge amount of waste into a new resource. In this study, $ H_{3} %$ PO_{4} $-activated filter coffee waste ($ H_{3} %$ PO_{4} $-FCW) and $ ZnCl_{2} $-activated filter coffee waste ($ ZnCl_{2} $-FCW) were synthesised, and the characterisation of them was revealed by SEM, EDAX, FTIR and XRD analyses. Adsorption isotherms (Langmuir, Freundlich, Temkin and Dubinin–Radushkevich), adsorption kinetics (Elovich, pseudo-second-order kinetics, pseudo-first-order kinetics including error functions) and adsorption thermodynamics were determined and the effect of parameters such as pH, adsorbent dose, initial methylene blue (MB) concentration, adsorption time and temperature on MB removal was evaluated by the ultrasonic-assisted adsorption. It was observed that ultrasonic-assisted adsorption was more suitable for the Langmuir isotherm for both adsorbents and that the adsorption kinetics was better suited to the pseudo-second-order kinetics. In addition, the ultrasonic-assisted adsorption using $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW occurred endothermically and the adsorption mechanism was physisorption. MB removal with $ ZnCl_{2} $-FCW could reach over 90% when pH is between 3 and 7 in the ultrasonic-assisted adsorption process. The maximum adsorption capacity was obtained as 42.7 mg/g and 106.4 mg/g for $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW, respectively. It was seen that the $ q_{max} $ value of $ ZnCl_{2} $-FCW was 2.5 times higher than the $ q_{max} $ of $ H_{3} %$ PO_{4} $-FCW. Moreover, reusability studies showed that MB removal of over 90% could be achieved in the $ 2^{nd} $ use of $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW. In conclusion, high dye removal could be achieved by synthesising low-cost adsorbents. The use of filtered coffee wastes in the adsorption of basic dyes such as MB is, therefore, important in terms of both waste reduction and management. © King Fahd University of Petroleum & Minerals 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
abstract_unstemmed |
Abstract In sustainable waste management, reusing coffee waste such as husks or spent coffee grounds helps convert a huge amount of waste into a new resource. In this study, $ H_{3} %$ PO_{4} $-activated filter coffee waste ($ H_{3} %$ PO_{4} $-FCW) and $ ZnCl_{2} $-activated filter coffee waste ($ ZnCl_{2} $-FCW) were synthesised, and the characterisation of them was revealed by SEM, EDAX, FTIR and XRD analyses. Adsorption isotherms (Langmuir, Freundlich, Temkin and Dubinin–Radushkevich), adsorption kinetics (Elovich, pseudo-second-order kinetics, pseudo-first-order kinetics including error functions) and adsorption thermodynamics were determined and the effect of parameters such as pH, adsorbent dose, initial methylene blue (MB) concentration, adsorption time and temperature on MB removal was evaluated by the ultrasonic-assisted adsorption. It was observed that ultrasonic-assisted adsorption was more suitable for the Langmuir isotherm for both adsorbents and that the adsorption kinetics was better suited to the pseudo-second-order kinetics. In addition, the ultrasonic-assisted adsorption using $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW occurred endothermically and the adsorption mechanism was physisorption. MB removal with $ ZnCl_{2} $-FCW could reach over 90% when pH is between 3 and 7 in the ultrasonic-assisted adsorption process. The maximum adsorption capacity was obtained as 42.7 mg/g and 106.4 mg/g for $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW, respectively. It was seen that the $ q_{max} $ value of $ ZnCl_{2} $-FCW was 2.5 times higher than the $ q_{max} $ of $ H_{3} %$ PO_{4} $-FCW. Moreover, reusability studies showed that MB removal of over 90% could be achieved in the $ 2^{nd} $ use of $ H_{3} %$ PO_{4} $-FCW and $ ZnCl_{2} $-FCW. In conclusion, high dye removal could be achieved by synthesising low-cost adsorbents. The use of filtered coffee wastes in the adsorption of basic dyes such as MB is, therefore, important in terms of both waste reduction and management. © King Fahd University of Petroleum & Minerals 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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container_issue |
7 |
title_short |
Comparison of $ H_{3} %$ PO_{4} $ and $ ZnCl_{2} $ Activated Filtered Coffee Waste Carbon-Based Adsorbents in Methylene Blue Removal by Using Ultrasonic-Assisted Adsorption |
url |
https://dx.doi.org/10.1007/s13369-022-07248-9 |
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Aydın, Nesli |
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2024-07-04T00:40:37.213Z |
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score |
7.3982153 |