Thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations
Thermal runaway accidents have occurred mainly during storage and transportation of azo compounds because large amounts of heat were released during the course of thermal decomposition. In this study, the thermal runaway characteristics of 2,2′-azobis(2-methylbutyronitrile) (AMBN) were first compreh...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhao, Jihe [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Schlagwörter: |
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| Anmerkung: |
© Akadémiai Kiadó, Budapest, Hungary 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Journal of thermal analysis and calorimetry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969, 148(2023), 13 vom: 07. Apr., Seite 6133-6150 |
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| Übergeordnetes Werk: |
volume:148 ; year:2023 ; number:13 ; day:07 ; month:04 ; pages:6133-6150 |
| Links: |
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| DOI / URN: |
10.1007/s10973-023-12113-4 |
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| Katalog-ID: |
SPR051975696 |
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| 520 | |a Thermal runaway accidents have occurred mainly during storage and transportation of azo compounds because large amounts of heat were released during the course of thermal decomposition. In this study, the thermal runaway characteristics of 2,2′-azobis(2-methylbutyronitrile) (AMBN) were first comprehensively investigated via differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), and gas chromatography/mass spectrometry (GC-MS). The onset temperature (Ton), heat of decomposition (Q), and adiabatic temperature rise (ΔTad) were determined, which were involved in the safety of storage and transportation. Corresponding thermokinetic analyses were performed using DSC and ARC data. The data obtained from the experiments and calculation were utilized to predict the self-accelerating decomposition temperature (SADT), the control temperature (TNR), and the emergency temperature (TC,I). In addition, the flammable components in the pyrolysis products of AMBN were studied, particularly mixed with incompatible materials, such as HCl, NaOH, and $ Fe_{2} %$ O_{3} $, which helped predict the risk of thermal runaway during storage and transportation. Graphical Abstract | ||
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| 650 | 4 | |a Thermal hazard assessment |7 (dpeaa)DE-He213 | |
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10.1007/s10973-023-12113-4 doi (DE-627)SPR051975696 (SPR)s10973-023-12113-4-e DE-627 ger DE-627 rakwb eng Zhao, Jihe verfasserin aut Thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Thermal runaway accidents have occurred mainly during storage and transportation of azo compounds because large amounts of heat were released during the course of thermal decomposition. In this study, the thermal runaway characteristics of 2,2′-azobis(2-methylbutyronitrile) (AMBN) were first comprehensively investigated via differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), and gas chromatography/mass spectrometry (GC-MS). The onset temperature (Ton), heat of decomposition (Q), and adiabatic temperature rise (ΔTad) were determined, which were involved in the safety of storage and transportation. Corresponding thermokinetic analyses were performed using DSC and ARC data. The data obtained from the experiments and calculation were utilized to predict the self-accelerating decomposition temperature (SADT), the control temperature (TNR), and the emergency temperature (TC,I). In addition, the flammable components in the pyrolysis products of AMBN were studied, particularly mixed with incompatible materials, such as HCl, NaOH, and $ Fe_{2} %$ O_{3} $, which helped predict the risk of thermal runaway during storage and transportation. Graphical Abstract Thermal risk (dpeaa)DE-He213 Thermal decomposition (dpeaa)DE-He213 Decomposition mechanisms (dpeaa)DE-He213 Thermal hazard assessment (dpeaa)DE-He213 2,2′-Azobis(2-methylbutyronitrile) (dpeaa)DE-He213 Hu, Jiwen (orcid)0000-0002-8473-5797 aut Dong, Yonglu aut He, Daguang aut Gui, Xuefeng aut Cui, Xiaohua aut Tu, Yuanyuan aut Lin, Shudong aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 148(2023), 13 vom: 07. Apr., Seite 6133-6150 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:148 year:2023 number:13 day:07 month:04 pages:6133-6150 https://dx.doi.org/10.1007/s10973-023-12113-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 148 2023 13 07 04 6133-6150 |
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10.1007/s10973-023-12113-4 doi (DE-627)SPR051975696 (SPR)s10973-023-12113-4-e DE-627 ger DE-627 rakwb eng Zhao, Jihe verfasserin aut Thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Thermal runaway accidents have occurred mainly during storage and transportation of azo compounds because large amounts of heat were released during the course of thermal decomposition. In this study, the thermal runaway characteristics of 2,2′-azobis(2-methylbutyronitrile) (AMBN) were first comprehensively investigated via differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), and gas chromatography/mass spectrometry (GC-MS). The onset temperature (Ton), heat of decomposition (Q), and adiabatic temperature rise (ΔTad) were determined, which were involved in the safety of storage and transportation. Corresponding thermokinetic analyses were performed using DSC and ARC data. The data obtained from the experiments and calculation were utilized to predict the self-accelerating decomposition temperature (SADT), the control temperature (TNR), and the emergency temperature (TC,I). In addition, the flammable components in the pyrolysis products of AMBN were studied, particularly mixed with incompatible materials, such as HCl, NaOH, and $ Fe_{2} %$ O_{3} $, which helped predict the risk of thermal runaway during storage and transportation. Graphical Abstract Thermal risk (dpeaa)DE-He213 Thermal decomposition (dpeaa)DE-He213 Decomposition mechanisms (dpeaa)DE-He213 Thermal hazard assessment (dpeaa)DE-He213 2,2′-Azobis(2-methylbutyronitrile) (dpeaa)DE-He213 Hu, Jiwen (orcid)0000-0002-8473-5797 aut Dong, Yonglu aut He, Daguang aut Gui, Xuefeng aut Cui, Xiaohua aut Tu, Yuanyuan aut Lin, Shudong aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 148(2023), 13 vom: 07. Apr., Seite 6133-6150 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:148 year:2023 number:13 day:07 month:04 pages:6133-6150 https://dx.doi.org/10.1007/s10973-023-12113-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 148 2023 13 07 04 6133-6150 |
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10.1007/s10973-023-12113-4 doi (DE-627)SPR051975696 (SPR)s10973-023-12113-4-e DE-627 ger DE-627 rakwb eng Zhao, Jihe verfasserin aut Thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Thermal runaway accidents have occurred mainly during storage and transportation of azo compounds because large amounts of heat were released during the course of thermal decomposition. In this study, the thermal runaway characteristics of 2,2′-azobis(2-methylbutyronitrile) (AMBN) were first comprehensively investigated via differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), and gas chromatography/mass spectrometry (GC-MS). The onset temperature (Ton), heat of decomposition (Q), and adiabatic temperature rise (ΔTad) were determined, which were involved in the safety of storage and transportation. Corresponding thermokinetic analyses were performed using DSC and ARC data. The data obtained from the experiments and calculation were utilized to predict the self-accelerating decomposition temperature (SADT), the control temperature (TNR), and the emergency temperature (TC,I). In addition, the flammable components in the pyrolysis products of AMBN were studied, particularly mixed with incompatible materials, such as HCl, NaOH, and $ Fe_{2} %$ O_{3} $, which helped predict the risk of thermal runaway during storage and transportation. Graphical Abstract Thermal risk (dpeaa)DE-He213 Thermal decomposition (dpeaa)DE-He213 Decomposition mechanisms (dpeaa)DE-He213 Thermal hazard assessment (dpeaa)DE-He213 2,2′-Azobis(2-methylbutyronitrile) (dpeaa)DE-He213 Hu, Jiwen (orcid)0000-0002-8473-5797 aut Dong, Yonglu aut He, Daguang aut Gui, Xuefeng aut Cui, Xiaohua aut Tu, Yuanyuan aut Lin, Shudong aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 148(2023), 13 vom: 07. Apr., Seite 6133-6150 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:148 year:2023 number:13 day:07 month:04 pages:6133-6150 https://dx.doi.org/10.1007/s10973-023-12113-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 148 2023 13 07 04 6133-6150 |
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10.1007/s10973-023-12113-4 doi (DE-627)SPR051975696 (SPR)s10973-023-12113-4-e DE-627 ger DE-627 rakwb eng Zhao, Jihe verfasserin aut Thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Thermal runaway accidents have occurred mainly during storage and transportation of azo compounds because large amounts of heat were released during the course of thermal decomposition. In this study, the thermal runaway characteristics of 2,2′-azobis(2-methylbutyronitrile) (AMBN) were first comprehensively investigated via differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), and gas chromatography/mass spectrometry (GC-MS). The onset temperature (Ton), heat of decomposition (Q), and adiabatic temperature rise (ΔTad) were determined, which were involved in the safety of storage and transportation. Corresponding thermokinetic analyses were performed using DSC and ARC data. The data obtained from the experiments and calculation were utilized to predict the self-accelerating decomposition temperature (SADT), the control temperature (TNR), and the emergency temperature (TC,I). In addition, the flammable components in the pyrolysis products of AMBN were studied, particularly mixed with incompatible materials, such as HCl, NaOH, and $ Fe_{2} %$ O_{3} $, which helped predict the risk of thermal runaway during storage and transportation. Graphical Abstract Thermal risk (dpeaa)DE-He213 Thermal decomposition (dpeaa)DE-He213 Decomposition mechanisms (dpeaa)DE-He213 Thermal hazard assessment (dpeaa)DE-He213 2,2′-Azobis(2-methylbutyronitrile) (dpeaa)DE-He213 Hu, Jiwen (orcid)0000-0002-8473-5797 aut Dong, Yonglu aut He, Daguang aut Gui, Xuefeng aut Cui, Xiaohua aut Tu, Yuanyuan aut Lin, Shudong aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 148(2023), 13 vom: 07. Apr., Seite 6133-6150 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:148 year:2023 number:13 day:07 month:04 pages:6133-6150 https://dx.doi.org/10.1007/s10973-023-12113-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 148 2023 13 07 04 6133-6150 |
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10.1007/s10973-023-12113-4 doi (DE-627)SPR051975696 (SPR)s10973-023-12113-4-e DE-627 ger DE-627 rakwb eng Zhao, Jihe verfasserin aut Thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Thermal runaway accidents have occurred mainly during storage and transportation of azo compounds because large amounts of heat were released during the course of thermal decomposition. In this study, the thermal runaway characteristics of 2,2′-azobis(2-methylbutyronitrile) (AMBN) were first comprehensively investigated via differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), and gas chromatography/mass spectrometry (GC-MS). The onset temperature (Ton), heat of decomposition (Q), and adiabatic temperature rise (ΔTad) were determined, which were involved in the safety of storage and transportation. Corresponding thermokinetic analyses were performed using DSC and ARC data. The data obtained from the experiments and calculation were utilized to predict the self-accelerating decomposition temperature (SADT), the control temperature (TNR), and the emergency temperature (TC,I). In addition, the flammable components in the pyrolysis products of AMBN were studied, particularly mixed with incompatible materials, such as HCl, NaOH, and $ Fe_{2} %$ O_{3} $, which helped predict the risk of thermal runaway during storage and transportation. Graphical Abstract Thermal risk (dpeaa)DE-He213 Thermal decomposition (dpeaa)DE-He213 Decomposition mechanisms (dpeaa)DE-He213 Thermal hazard assessment (dpeaa)DE-He213 2,2′-Azobis(2-methylbutyronitrile) (dpeaa)DE-He213 Hu, Jiwen (orcid)0000-0002-8473-5797 aut Dong, Yonglu aut He, Daguang aut Gui, Xuefeng aut Cui, Xiaohua aut Tu, Yuanyuan aut Lin, Shudong aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 148(2023), 13 vom: 07. Apr., Seite 6133-6150 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:148 year:2023 number:13 day:07 month:04 pages:6133-6150 https://dx.doi.org/10.1007/s10973-023-12113-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 148 2023 13 07 04 6133-6150 |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Thermal runaway accidents have occurred mainly during storage and transportation of azo compounds because large amounts of heat were released during the course of thermal decomposition. In this study, the thermal runaway characteristics of 2,2′-azobis(2-methylbutyronitrile) (AMBN) were first comprehensively investigated via differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), and gas chromatography/mass spectrometry (GC-MS). The onset temperature (Ton), heat of decomposition (Q), and adiabatic temperature rise (ΔTad) were determined, which were involved in the safety of storage and transportation. Corresponding thermokinetic analyses were performed using DSC and ARC data. The data obtained from the experiments and calculation were utilized to predict the self-accelerating decomposition temperature (SADT), the control temperature (TNR), and the emergency temperature (TC,I). In addition, the flammable components in the pyrolysis products of AMBN were studied, particularly mixed with incompatible materials, such as HCl, NaOH, and $ Fe_{2} %$ O_{3} $, which helped predict the risk of thermal runaway during storage and transportation. 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|
| author |
Zhao, Jihe |
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Zhao, Jihe misc Thermal risk misc Thermal decomposition misc Decomposition mechanisms misc Thermal hazard assessment misc 2,2′-Azobis(2-methylbutyronitrile) Thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations |
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Thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations Thermal risk (dpeaa)DE-He213 Thermal decomposition (dpeaa)DE-He213 Decomposition mechanisms (dpeaa)DE-He213 Thermal hazard assessment (dpeaa)DE-He213 2,2′-Azobis(2-methylbutyronitrile) (dpeaa)DE-He213 |
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misc Thermal risk misc Thermal decomposition misc Decomposition mechanisms misc Thermal hazard assessment misc 2,2′-Azobis(2-methylbutyronitrile) |
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misc Thermal risk misc Thermal decomposition misc Decomposition mechanisms misc Thermal hazard assessment misc 2,2′-Azobis(2-methylbutyronitrile) |
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Thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations |
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Thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations |
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Zhao, Jihe |
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Journal of thermal analysis and calorimetry |
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Zhao, Jihe Hu, Jiwen Dong, Yonglu He, Daguang Gui, Xuefeng Cui, Xiaohua Tu, Yuanyuan Lin, Shudong |
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Elektronische Aufsätze |
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Zhao, Jihe |
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thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations |
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Thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations |
| abstract |
Thermal runaway accidents have occurred mainly during storage and transportation of azo compounds because large amounts of heat were released during the course of thermal decomposition. In this study, the thermal runaway characteristics of 2,2′-azobis(2-methylbutyronitrile) (AMBN) were first comprehensively investigated via differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), and gas chromatography/mass spectrometry (GC-MS). The onset temperature (Ton), heat of decomposition (Q), and adiabatic temperature rise (ΔTad) were determined, which were involved in the safety of storage and transportation. Corresponding thermokinetic analyses were performed using DSC and ARC data. The data obtained from the experiments and calculation were utilized to predict the self-accelerating decomposition temperature (SADT), the control temperature (TNR), and the emergency temperature (TC,I). In addition, the flammable components in the pyrolysis products of AMBN were studied, particularly mixed with incompatible materials, such as HCl, NaOH, and $ Fe_{2} %$ O_{3} $, which helped predict the risk of thermal runaway during storage and transportation. Graphical Abstract © Akadémiai Kiadó, Budapest, Hungary 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Thermal runaway accidents have occurred mainly during storage and transportation of azo compounds because large amounts of heat were released during the course of thermal decomposition. In this study, the thermal runaway characteristics of 2,2′-azobis(2-methylbutyronitrile) (AMBN) were first comprehensively investigated via differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), and gas chromatography/mass spectrometry (GC-MS). The onset temperature (Ton), heat of decomposition (Q), and adiabatic temperature rise (ΔTad) were determined, which were involved in the safety of storage and transportation. Corresponding thermokinetic analyses were performed using DSC and ARC data. The data obtained from the experiments and calculation were utilized to predict the self-accelerating decomposition temperature (SADT), the control temperature (TNR), and the emergency temperature (TC,I). In addition, the flammable components in the pyrolysis products of AMBN were studied, particularly mixed with incompatible materials, such as HCl, NaOH, and $ Fe_{2} %$ O_{3} $, which helped predict the risk of thermal runaway during storage and transportation. Graphical Abstract © Akadémiai Kiadó, Budapest, Hungary 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Thermal runaway accidents have occurred mainly during storage and transportation of azo compounds because large amounts of heat were released during the course of thermal decomposition. In this study, the thermal runaway characteristics of 2,2′-azobis(2-methylbutyronitrile) (AMBN) were first comprehensively investigated via differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), and gas chromatography/mass spectrometry (GC-MS). The onset temperature (Ton), heat of decomposition (Q), and adiabatic temperature rise (ΔTad) were determined, which were involved in the safety of storage and transportation. Corresponding thermokinetic analyses were performed using DSC and ARC data. The data obtained from the experiments and calculation were utilized to predict the self-accelerating decomposition temperature (SADT), the control temperature (TNR), and the emergency temperature (TC,I). In addition, the flammable components in the pyrolysis products of AMBN were studied, particularly mixed with incompatible materials, such as HCl, NaOH, and $ Fe_{2} %$ O_{3} $, which helped predict the risk of thermal runaway during storage and transportation. Graphical Abstract © Akadémiai Kiadó, Budapest, Hungary 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| title_short |
Thermal runaway risk of 2,2′-azobis(2-methylbutyronitrile) under the process situations |
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https://dx.doi.org/10.1007/s10973-023-12113-4 |
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Hu, Jiwen Dong, Yonglu He, Daguang Gui, Xuefeng Cui, Xiaohua Tu, Yuanyuan Lin, Shudong |
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Hu, Jiwen Dong, Yonglu He, Daguang Gui, Xuefeng Cui, Xiaohua Tu, Yuanyuan Lin, Shudong |
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10.1007/s10973-023-12113-4 |
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| score |
7.3984184 |