Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene
Abstract A mild, efficient, and green approach for highly selective synthesis of 1,5-dinitronaphthalene (1,5-DNN) has been devolved from catalytic nitration of 1-nitronaphthalene (1-NN) with $ NO_{2} $ combined with $ O_{2} $-$ Ac_{2} $O over solid superacid $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $. The...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yan, Jiaqi [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Research on chemical intermediates - Dordrecht : Springer Netherlands, 1989, 49(2023), 7 vom: 13. Mai, Seite 3065-3078 |
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| Übergeordnetes Werk: |
volume:49 ; year:2023 ; number:7 ; day:13 ; month:05 ; pages:3065-3078 |
| Links: |
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| DOI / URN: |
10.1007/s11164-023-05029-z |
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| Katalog-ID: |
SPR051976803 |
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| 245 | 1 | 0 | |a Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene |
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| 520 | |a Abstract A mild, efficient, and green approach for highly selective synthesis of 1,5-dinitronaphthalene (1,5-DNN) has been devolved from catalytic nitration of 1-nitronaphthalene (1-NN) with $ NO_{2} $ combined with $ O_{2} $-$ Ac_{2} $O over solid superacid $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $. The prepared $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ catalyst presents better catalytic performance than most of the reported catalysts for this purpose, with 96.8% conversion of 1-NN and 62.6% selectivity of 1,5-DNN under the optimized reaction conditions. The excellent catalytic activity of $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ can be attributed to its remarkable Lewis acid sites and strong acidity. A possible catalytic nitration reaction pathway of 1-NN with $ NO_{2} $ over $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ in the $ O_{2} $-$ Ac_{2} $O system was proposed. This work provides a practical strategy for the cost-effective, environmentally friendly, and efficient synthesis of 1,5-DNN with significant industrial application prospects. | ||
| 650 | 4 | |a Solid superacid |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Nitration reaction |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a 1,5-Dinitronaphthalene |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a 1-Nitronaphthalene |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Nitrogen dioxide |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Zhang, Xiaowen |4 aut | |
| 700 | 1 | |a Yin, Jiahong |4 aut | |
| 700 | 1 | |a Zhao, Fangfang |4 aut | |
| 700 | 1 | |a You, Kuiyi |4 aut | |
| 700 | 1 | |a Luo, He’an |4 aut | |
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10.1007/s11164-023-05029-z doi (DE-627)SPR051976803 (SPR)s11164-023-05029-z-e DE-627 ger DE-627 rakwb eng Yan, Jiaqi verfasserin aut Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract A mild, efficient, and green approach for highly selective synthesis of 1,5-dinitronaphthalene (1,5-DNN) has been devolved from catalytic nitration of 1-nitronaphthalene (1-NN) with $ NO_{2} $ combined with $ O_{2} $-$ Ac_{2} $O over solid superacid $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $. The prepared $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ catalyst presents better catalytic performance than most of the reported catalysts for this purpose, with 96.8% conversion of 1-NN and 62.6% selectivity of 1,5-DNN under the optimized reaction conditions. The excellent catalytic activity of $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ can be attributed to its remarkable Lewis acid sites and strong acidity. A possible catalytic nitration reaction pathway of 1-NN with $ NO_{2} $ over $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ in the $ O_{2} $-$ Ac_{2} $O system was proposed. This work provides a practical strategy for the cost-effective, environmentally friendly, and efficient synthesis of 1,5-DNN with significant industrial application prospects. Solid superacid (dpeaa)DE-He213 Nitration reaction (dpeaa)DE-He213 1,5-Dinitronaphthalene (dpeaa)DE-He213 1-Nitronaphthalene (dpeaa)DE-He213 Nitrogen dioxide (dpeaa)DE-He213 Zhang, Xiaowen aut Yin, Jiahong aut Zhao, Fangfang aut You, Kuiyi aut Luo, He’an aut Enthalten in Research on chemical intermediates Dordrecht : Springer Netherlands, 1989 49(2023), 7 vom: 13. Mai, Seite 3065-3078 (DE-627)328186511 (DE-600)2045085-0 1568-5675 nnns volume:49 year:2023 number:7 day:13 month:05 pages:3065-3078 https://dx.doi.org/10.1007/s11164-023-05029-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 49 2023 7 13 05 3065-3078 |
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10.1007/s11164-023-05029-z doi (DE-627)SPR051976803 (SPR)s11164-023-05029-z-e DE-627 ger DE-627 rakwb eng Yan, Jiaqi verfasserin aut Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract A mild, efficient, and green approach for highly selective synthesis of 1,5-dinitronaphthalene (1,5-DNN) has been devolved from catalytic nitration of 1-nitronaphthalene (1-NN) with $ NO_{2} $ combined with $ O_{2} $-$ Ac_{2} $O over solid superacid $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $. The prepared $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ catalyst presents better catalytic performance than most of the reported catalysts for this purpose, with 96.8% conversion of 1-NN and 62.6% selectivity of 1,5-DNN under the optimized reaction conditions. The excellent catalytic activity of $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ can be attributed to its remarkable Lewis acid sites and strong acidity. A possible catalytic nitration reaction pathway of 1-NN with $ NO_{2} $ over $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ in the $ O_{2} $-$ Ac_{2} $O system was proposed. This work provides a practical strategy for the cost-effective, environmentally friendly, and efficient synthesis of 1,5-DNN with significant industrial application prospects. Solid superacid (dpeaa)DE-He213 Nitration reaction (dpeaa)DE-He213 1,5-Dinitronaphthalene (dpeaa)DE-He213 1-Nitronaphthalene (dpeaa)DE-He213 Nitrogen dioxide (dpeaa)DE-He213 Zhang, Xiaowen aut Yin, Jiahong aut Zhao, Fangfang aut You, Kuiyi aut Luo, He’an aut Enthalten in Research on chemical intermediates Dordrecht : Springer Netherlands, 1989 49(2023), 7 vom: 13. Mai, Seite 3065-3078 (DE-627)328186511 (DE-600)2045085-0 1568-5675 nnns volume:49 year:2023 number:7 day:13 month:05 pages:3065-3078 https://dx.doi.org/10.1007/s11164-023-05029-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 49 2023 7 13 05 3065-3078 |
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10.1007/s11164-023-05029-z doi (DE-627)SPR051976803 (SPR)s11164-023-05029-z-e DE-627 ger DE-627 rakwb eng Yan, Jiaqi verfasserin aut Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract A mild, efficient, and green approach for highly selective synthesis of 1,5-dinitronaphthalene (1,5-DNN) has been devolved from catalytic nitration of 1-nitronaphthalene (1-NN) with $ NO_{2} $ combined with $ O_{2} $-$ Ac_{2} $O over solid superacid $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $. The prepared $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ catalyst presents better catalytic performance than most of the reported catalysts for this purpose, with 96.8% conversion of 1-NN and 62.6% selectivity of 1,5-DNN under the optimized reaction conditions. The excellent catalytic activity of $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ can be attributed to its remarkable Lewis acid sites and strong acidity. A possible catalytic nitration reaction pathway of 1-NN with $ NO_{2} $ over $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ in the $ O_{2} $-$ Ac_{2} $O system was proposed. This work provides a practical strategy for the cost-effective, environmentally friendly, and efficient synthesis of 1,5-DNN with significant industrial application prospects. Solid superacid (dpeaa)DE-He213 Nitration reaction (dpeaa)DE-He213 1,5-Dinitronaphthalene (dpeaa)DE-He213 1-Nitronaphthalene (dpeaa)DE-He213 Nitrogen dioxide (dpeaa)DE-He213 Zhang, Xiaowen aut Yin, Jiahong aut Zhao, Fangfang aut You, Kuiyi aut Luo, He’an aut Enthalten in Research on chemical intermediates Dordrecht : Springer Netherlands, 1989 49(2023), 7 vom: 13. Mai, Seite 3065-3078 (DE-627)328186511 (DE-600)2045085-0 1568-5675 nnns volume:49 year:2023 number:7 day:13 month:05 pages:3065-3078 https://dx.doi.org/10.1007/s11164-023-05029-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 49 2023 7 13 05 3065-3078 |
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10.1007/s11164-023-05029-z doi (DE-627)SPR051976803 (SPR)s11164-023-05029-z-e DE-627 ger DE-627 rakwb eng Yan, Jiaqi verfasserin aut Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract A mild, efficient, and green approach for highly selective synthesis of 1,5-dinitronaphthalene (1,5-DNN) has been devolved from catalytic nitration of 1-nitronaphthalene (1-NN) with $ NO_{2} $ combined with $ O_{2} $-$ Ac_{2} $O over solid superacid $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $. The prepared $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ catalyst presents better catalytic performance than most of the reported catalysts for this purpose, with 96.8% conversion of 1-NN and 62.6% selectivity of 1,5-DNN under the optimized reaction conditions. The excellent catalytic activity of $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ can be attributed to its remarkable Lewis acid sites and strong acidity. A possible catalytic nitration reaction pathway of 1-NN with $ NO_{2} $ over $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ in the $ O_{2} $-$ Ac_{2} $O system was proposed. This work provides a practical strategy for the cost-effective, environmentally friendly, and efficient synthesis of 1,5-DNN with significant industrial application prospects. Solid superacid (dpeaa)DE-He213 Nitration reaction (dpeaa)DE-He213 1,5-Dinitronaphthalene (dpeaa)DE-He213 1-Nitronaphthalene (dpeaa)DE-He213 Nitrogen dioxide (dpeaa)DE-He213 Zhang, Xiaowen aut Yin, Jiahong aut Zhao, Fangfang aut You, Kuiyi aut Luo, He’an aut Enthalten in Research on chemical intermediates Dordrecht : Springer Netherlands, 1989 49(2023), 7 vom: 13. Mai, Seite 3065-3078 (DE-627)328186511 (DE-600)2045085-0 1568-5675 nnns volume:49 year:2023 number:7 day:13 month:05 pages:3065-3078 https://dx.doi.org/10.1007/s11164-023-05029-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 49 2023 7 13 05 3065-3078 |
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10.1007/s11164-023-05029-z doi (DE-627)SPR051976803 (SPR)s11164-023-05029-z-e DE-627 ger DE-627 rakwb eng Yan, Jiaqi verfasserin aut Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract A mild, efficient, and green approach for highly selective synthesis of 1,5-dinitronaphthalene (1,5-DNN) has been devolved from catalytic nitration of 1-nitronaphthalene (1-NN) with $ NO_{2} $ combined with $ O_{2} $-$ Ac_{2} $O over solid superacid $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $. The prepared $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ catalyst presents better catalytic performance than most of the reported catalysts for this purpose, with 96.8% conversion of 1-NN and 62.6% selectivity of 1,5-DNN under the optimized reaction conditions. The excellent catalytic activity of $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ can be attributed to its remarkable Lewis acid sites and strong acidity. A possible catalytic nitration reaction pathway of 1-NN with $ NO_{2} $ over $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ in the $ O_{2} $-$ Ac_{2} $O system was proposed. This work provides a practical strategy for the cost-effective, environmentally friendly, and efficient synthesis of 1,5-DNN with significant industrial application prospects. Solid superacid (dpeaa)DE-He213 Nitration reaction (dpeaa)DE-He213 1,5-Dinitronaphthalene (dpeaa)DE-He213 1-Nitronaphthalene (dpeaa)DE-He213 Nitrogen dioxide (dpeaa)DE-He213 Zhang, Xiaowen aut Yin, Jiahong aut Zhao, Fangfang aut You, Kuiyi aut Luo, He’an aut Enthalten in Research on chemical intermediates Dordrecht : Springer Netherlands, 1989 49(2023), 7 vom: 13. Mai, Seite 3065-3078 (DE-627)328186511 (DE-600)2045085-0 1568-5675 nnns volume:49 year:2023 number:7 day:13 month:05 pages:3065-3078 https://dx.doi.org/10.1007/s11164-023-05029-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 49 2023 7 13 05 3065-3078 |
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Enthalten in Research on chemical intermediates 49(2023), 7 vom: 13. Mai, Seite 3065-3078 volume:49 year:2023 number:7 day:13 month:05 pages:3065-3078 |
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Solid superacid Nitration reaction 1,5-Dinitronaphthalene 1-Nitronaphthalene Nitrogen dioxide |
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Yan, Jiaqi @@aut@@ Zhang, Xiaowen @@aut@@ Yin, Jiahong @@aut@@ Zhao, Fangfang @@aut@@ You, Kuiyi @@aut@@ Luo, He’an @@aut@@ |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract A mild, efficient, and green approach for highly selective synthesis of 1,5-dinitronaphthalene (1,5-DNN) has been devolved from catalytic nitration of 1-nitronaphthalene (1-NN) with $ NO_{2} $ combined with $ O_{2} $-$ Ac_{2} $O over solid superacid $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $. The prepared $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ catalyst presents better catalytic performance than most of the reported catalysts for this purpose, with 96.8% conversion of 1-NN and 62.6% selectivity of 1,5-DNN under the optimized reaction conditions. The excellent catalytic activity of $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ can be attributed to its remarkable Lewis acid sites and strong acidity. A possible catalytic nitration reaction pathway of 1-NN with $ NO_{2} $ over $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ in the $ O_{2} $-$ Ac_{2} $O system was proposed. This work provides a practical strategy for the cost-effective, environmentally friendly, and efficient synthesis of 1,5-DNN with significant industrial application prospects.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Solid superacid</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nitration reaction</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">1,5-Dinitronaphthalene</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">1-Nitronaphthalene</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nitrogen dioxide</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Xiaowen</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yin, Jiahong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhao, Fangfang</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">You, Kuiyi</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Luo, He’an</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Research on chemical intermediates</subfield><subfield code="d">Dordrecht : Springer Netherlands, 1989</subfield><subfield code="g">49(2023), 7 vom: 13. 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Yan, Jiaqi |
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Yan, Jiaqi misc Solid superacid misc Nitration reaction misc 1,5-Dinitronaphthalene misc 1-Nitronaphthalene misc Nitrogen dioxide Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene |
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Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene Solid superacid (dpeaa)DE-He213 Nitration reaction (dpeaa)DE-He213 1,5-Dinitronaphthalene (dpeaa)DE-He213 1-Nitronaphthalene (dpeaa)DE-He213 Nitrogen dioxide (dpeaa)DE-He213 |
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misc Solid superacid misc Nitration reaction misc 1,5-Dinitronaphthalene misc 1-Nitronaphthalene misc Nitrogen dioxide |
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Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene |
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Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene |
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Yan, Jiaqi Zhang, Xiaowen Yin, Jiahong Zhao, Fangfang You, Kuiyi Luo, He’an |
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Yan, Jiaqi |
| doi_str_mv |
10.1007/s11164-023-05029-z |
| title_sort |
novel $ s_{2} %$ o_{8} $2−/fe-$ zro_{2} $ solid superacid catalyst combined with $ o_{2} $-$ ac_{2} $o for highly efficient catalytic nitration of 1-nitronaphthalene with $ no_{2} $ to 1,5-dinitronaphthalene |
| title_auth |
Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene |
| abstract |
Abstract A mild, efficient, and green approach for highly selective synthesis of 1,5-dinitronaphthalene (1,5-DNN) has been devolved from catalytic nitration of 1-nitronaphthalene (1-NN) with $ NO_{2} $ combined with $ O_{2} $-$ Ac_{2} $O over solid superacid $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $. The prepared $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ catalyst presents better catalytic performance than most of the reported catalysts for this purpose, with 96.8% conversion of 1-NN and 62.6% selectivity of 1,5-DNN under the optimized reaction conditions. The excellent catalytic activity of $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ can be attributed to its remarkable Lewis acid sites and strong acidity. A possible catalytic nitration reaction pathway of 1-NN with $ NO_{2} $ over $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ in the $ O_{2} $-$ Ac_{2} $O system was proposed. This work provides a practical strategy for the cost-effective, environmentally friendly, and efficient synthesis of 1,5-DNN with significant industrial application prospects. © The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Abstract A mild, efficient, and green approach for highly selective synthesis of 1,5-dinitronaphthalene (1,5-DNN) has been devolved from catalytic nitration of 1-nitronaphthalene (1-NN) with $ NO_{2} $ combined with $ O_{2} $-$ Ac_{2} $O over solid superacid $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $. The prepared $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ catalyst presents better catalytic performance than most of the reported catalysts for this purpose, with 96.8% conversion of 1-NN and 62.6% selectivity of 1,5-DNN under the optimized reaction conditions. The excellent catalytic activity of $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ can be attributed to its remarkable Lewis acid sites and strong acidity. A possible catalytic nitration reaction pathway of 1-NN with $ NO_{2} $ over $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ in the $ O_{2} $-$ Ac_{2} $O system was proposed. This work provides a practical strategy for the cost-effective, environmentally friendly, and efficient synthesis of 1,5-DNN with significant industrial application prospects. © The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Abstract A mild, efficient, and green approach for highly selective synthesis of 1,5-dinitronaphthalene (1,5-DNN) has been devolved from catalytic nitration of 1-nitronaphthalene (1-NN) with $ NO_{2} $ combined with $ O_{2} $-$ Ac_{2} $O over solid superacid $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $. The prepared $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ catalyst presents better catalytic performance than most of the reported catalysts for this purpose, with 96.8% conversion of 1-NN and 62.6% selectivity of 1,5-DNN under the optimized reaction conditions. The excellent catalytic activity of $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ can be attributed to its remarkable Lewis acid sites and strong acidity. A possible catalytic nitration reaction pathway of 1-NN with $ NO_{2} $ over $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ in the $ O_{2} $-$ Ac_{2} $O system was proposed. This work provides a practical strategy for the cost-effective, environmentally friendly, and efficient synthesis of 1,5-DNN with significant industrial application prospects. © The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| title_short |
Novel $ S_{2} %$ O_{8} $2−/Fe-$ ZrO_{2} $ solid superacid catalyst combined with $ O_{2} $-$ Ac_{2} $O for highly efficient catalytic nitration of 1-nitronaphthalene with $ NO_{2} $ to 1,5-dinitronaphthalene |
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https://dx.doi.org/10.1007/s11164-023-05029-z |
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Zhang, Xiaowen Yin, Jiahong Zhao, Fangfang You, Kuiyi Luo, He’an |
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| score |
7.400687 |