Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect
Abstract Glass transition plays a critical role to determine the dynamic behaviors of amorphous shape memory polymers (SMPs). However, the fundamental relationships between shape memory effect (SME) and dynamic glass transition have not been well understood, even though this topic has been studied f...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Liu, JingYun [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2023 |
|---|
| Anmerkung: |
© Science China Press 2023 |
|---|
| Übergeordnetes Werk: |
Enthalten in: Science in China - Heidelberg : Springer, 1997, 66(2023), 8 vom: 18. Juli, Seite 2432-2440 |
|---|---|
| Übergeordnetes Werk: |
volume:66 ; year:2023 ; number:8 ; day:18 ; month:07 ; pages:2432-2440 |
| Links: |
|---|
| DOI / URN: |
10.1007/s11431-022-2263-7 |
|---|
| Katalog-ID: |
SPR052626350 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | SPR052626350 | ||
| 003 | DE-627 | ||
| 005 | 20230804064811.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 230804s2023 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1007/s11431-022-2263-7 |2 doi | |
| 035 | |a (DE-627)SPR052626350 | ||
| 035 | |a (SPR)s11431-022-2263-7-e | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Liu, JingYun |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect |
| 264 | 1 | |c 2023 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a © Science China Press 2023 | ||
| 520 | |a Abstract Glass transition plays a critical role to determine the dynamic behaviors of amorphous shape memory polymers (SMPs). However, the fundamental relationships between shape memory effect (SME) and dynamic glass transition have not been well understood, even though this topic has been studied for decades. In this study, we apply a mean-square displacement function of Adam-Gibbs (AG) domain size model to explore metastable glass transition between normal glass state and rubbery state of amorphous SMPs, based on both mode-coupling theory and mean-field model. A statistic viscosity equation is formulated to study the dynamic glass transition of metastable AG domains in an amorphous SMP. A dynamically spinodal model is also developed to connect dynamic glass transitions to thermomechanical processes, based on statistic viscosity equation and phase transition model. Furthermore, using the spinodal models, multiple shape memory behaviors have been predicted for amorphous SMPs with dual-, triple- and quadruple-SMEs, resulted from their different routes of themomechanical evolutions. Finally, the proposed models are verified using the experimental data reported in literature. | ||
| 700 | 1 | |a Lu, HaiBao |4 aut | |
| 700 | 1 | |a Fu, Yong-Qing |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Science in China |d Heidelberg : Springer, 1997 |g 66(2023), 8 vom: 18. Juli, Seite 2432-2440 |w (DE-627)385614756 |w (DE-600)2142897-9 |x 1862-281X |7 nnns |
| 773 | 1 | 8 | |g volume:66 |g year:2023 |g number:8 |g day:18 |g month:07 |g pages:2432-2440 |
| 856 | 4 | 0 | |u https://dx.doi.org/10.1007/s11431-022-2263-7 |z lizenzpflichtig |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_SPRINGER | ||
| 912 | |a GBV_ILN_20 | ||
| 912 | |a GBV_ILN_22 | ||
| 912 | |a GBV_ILN_23 | ||
| 912 | |a GBV_ILN_24 | ||
| 912 | |a GBV_ILN_31 | ||
| 912 | |a GBV_ILN_32 | ||
| 912 | |a GBV_ILN_39 | ||
| 912 | |a GBV_ILN_40 | ||
| 912 | |a GBV_ILN_60 | ||
| 912 | |a GBV_ILN_62 | ||
| 912 | |a GBV_ILN_65 | ||
| 912 | |a GBV_ILN_69 | ||
| 912 | |a GBV_ILN_70 | ||
| 912 | |a GBV_ILN_73 | ||
| 912 | |a GBV_ILN_74 | ||
| 912 | |a GBV_ILN_90 | ||
| 912 | |a GBV_ILN_95 | ||
| 912 | |a GBV_ILN_100 | ||
| 912 | |a GBV_ILN_105 | ||
| 912 | |a GBV_ILN_110 | ||
| 912 | |a GBV_ILN_120 | ||
| 912 | |a GBV_ILN_138 | ||
| 912 | |a GBV_ILN_152 | ||
| 912 | |a GBV_ILN_161 | ||
| 912 | |a GBV_ILN_171 | ||
| 912 | |a GBV_ILN_187 | ||
| 912 | |a GBV_ILN_224 | ||
| 912 | |a GBV_ILN_250 | ||
| 912 | |a GBV_ILN_281 | ||
| 912 | |a GBV_ILN_285 | ||
| 912 | |a GBV_ILN_293 | ||
| 912 | |a GBV_ILN_370 | ||
| 912 | |a GBV_ILN_602 | ||
| 912 | |a GBV_ILN_702 | ||
| 951 | |a AR | ||
| 952 | |d 66 |j 2023 |e 8 |b 18 |c 07 |h 2432-2440 | ||
| author_variant |
j l jl h l hl y q f yqf |
|---|---|
| matchkey_str |
article:1862281X:2023----::pndlyaisfeatbelstastodmisnmrhuplmroadtemmcaia |
| hierarchy_sort_str |
2023 |
| publishDate |
2023 |
| allfields |
10.1007/s11431-022-2263-7 doi (DE-627)SPR052626350 (SPR)s11431-022-2263-7-e DE-627 ger DE-627 rakwb eng Liu, JingYun verfasserin aut Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press 2023 Abstract Glass transition plays a critical role to determine the dynamic behaviors of amorphous shape memory polymers (SMPs). However, the fundamental relationships between shape memory effect (SME) and dynamic glass transition have not been well understood, even though this topic has been studied for decades. In this study, we apply a mean-square displacement function of Adam-Gibbs (AG) domain size model to explore metastable glass transition between normal glass state and rubbery state of amorphous SMPs, based on both mode-coupling theory and mean-field model. A statistic viscosity equation is formulated to study the dynamic glass transition of metastable AG domains in an amorphous SMP. A dynamically spinodal model is also developed to connect dynamic glass transitions to thermomechanical processes, based on statistic viscosity equation and phase transition model. Furthermore, using the spinodal models, multiple shape memory behaviors have been predicted for amorphous SMPs with dual-, triple- and quadruple-SMEs, resulted from their different routes of themomechanical evolutions. Finally, the proposed models are verified using the experimental data reported in literature. Lu, HaiBao aut Fu, Yong-Qing aut Enthalten in Science in China Heidelberg : Springer, 1997 66(2023), 8 vom: 18. Juli, Seite 2432-2440 (DE-627)385614756 (DE-600)2142897-9 1862-281X nnns volume:66 year:2023 number:8 day:18 month:07 pages:2432-2440 https://dx.doi.org/10.1007/s11431-022-2263-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 AR 66 2023 8 18 07 2432-2440 |
| spelling |
10.1007/s11431-022-2263-7 doi (DE-627)SPR052626350 (SPR)s11431-022-2263-7-e DE-627 ger DE-627 rakwb eng Liu, JingYun verfasserin aut Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press 2023 Abstract Glass transition plays a critical role to determine the dynamic behaviors of amorphous shape memory polymers (SMPs). However, the fundamental relationships between shape memory effect (SME) and dynamic glass transition have not been well understood, even though this topic has been studied for decades. In this study, we apply a mean-square displacement function of Adam-Gibbs (AG) domain size model to explore metastable glass transition between normal glass state and rubbery state of amorphous SMPs, based on both mode-coupling theory and mean-field model. A statistic viscosity equation is formulated to study the dynamic glass transition of metastable AG domains in an amorphous SMP. A dynamically spinodal model is also developed to connect dynamic glass transitions to thermomechanical processes, based on statistic viscosity equation and phase transition model. Furthermore, using the spinodal models, multiple shape memory behaviors have been predicted for amorphous SMPs with dual-, triple- and quadruple-SMEs, resulted from their different routes of themomechanical evolutions. Finally, the proposed models are verified using the experimental data reported in literature. Lu, HaiBao aut Fu, Yong-Qing aut Enthalten in Science in China Heidelberg : Springer, 1997 66(2023), 8 vom: 18. Juli, Seite 2432-2440 (DE-627)385614756 (DE-600)2142897-9 1862-281X nnns volume:66 year:2023 number:8 day:18 month:07 pages:2432-2440 https://dx.doi.org/10.1007/s11431-022-2263-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 AR 66 2023 8 18 07 2432-2440 |
| allfields_unstemmed |
10.1007/s11431-022-2263-7 doi (DE-627)SPR052626350 (SPR)s11431-022-2263-7-e DE-627 ger DE-627 rakwb eng Liu, JingYun verfasserin aut Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press 2023 Abstract Glass transition plays a critical role to determine the dynamic behaviors of amorphous shape memory polymers (SMPs). However, the fundamental relationships between shape memory effect (SME) and dynamic glass transition have not been well understood, even though this topic has been studied for decades. In this study, we apply a mean-square displacement function of Adam-Gibbs (AG) domain size model to explore metastable glass transition between normal glass state and rubbery state of amorphous SMPs, based on both mode-coupling theory and mean-field model. A statistic viscosity equation is formulated to study the dynamic glass transition of metastable AG domains in an amorphous SMP. A dynamically spinodal model is also developed to connect dynamic glass transitions to thermomechanical processes, based on statistic viscosity equation and phase transition model. Furthermore, using the spinodal models, multiple shape memory behaviors have been predicted for amorphous SMPs with dual-, triple- and quadruple-SMEs, resulted from their different routes of themomechanical evolutions. Finally, the proposed models are verified using the experimental data reported in literature. Lu, HaiBao aut Fu, Yong-Qing aut Enthalten in Science in China Heidelberg : Springer, 1997 66(2023), 8 vom: 18. Juli, Seite 2432-2440 (DE-627)385614756 (DE-600)2142897-9 1862-281X nnns volume:66 year:2023 number:8 day:18 month:07 pages:2432-2440 https://dx.doi.org/10.1007/s11431-022-2263-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 AR 66 2023 8 18 07 2432-2440 |
| allfieldsGer |
10.1007/s11431-022-2263-7 doi (DE-627)SPR052626350 (SPR)s11431-022-2263-7-e DE-627 ger DE-627 rakwb eng Liu, JingYun verfasserin aut Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press 2023 Abstract Glass transition plays a critical role to determine the dynamic behaviors of amorphous shape memory polymers (SMPs). However, the fundamental relationships between shape memory effect (SME) and dynamic glass transition have not been well understood, even though this topic has been studied for decades. In this study, we apply a mean-square displacement function of Adam-Gibbs (AG) domain size model to explore metastable glass transition between normal glass state and rubbery state of amorphous SMPs, based on both mode-coupling theory and mean-field model. A statistic viscosity equation is formulated to study the dynamic glass transition of metastable AG domains in an amorphous SMP. A dynamically spinodal model is also developed to connect dynamic glass transitions to thermomechanical processes, based on statistic viscosity equation and phase transition model. Furthermore, using the spinodal models, multiple shape memory behaviors have been predicted for amorphous SMPs with dual-, triple- and quadruple-SMEs, resulted from their different routes of themomechanical evolutions. Finally, the proposed models are verified using the experimental data reported in literature. Lu, HaiBao aut Fu, Yong-Qing aut Enthalten in Science in China Heidelberg : Springer, 1997 66(2023), 8 vom: 18. Juli, Seite 2432-2440 (DE-627)385614756 (DE-600)2142897-9 1862-281X nnns volume:66 year:2023 number:8 day:18 month:07 pages:2432-2440 https://dx.doi.org/10.1007/s11431-022-2263-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 AR 66 2023 8 18 07 2432-2440 |
| allfieldsSound |
10.1007/s11431-022-2263-7 doi (DE-627)SPR052626350 (SPR)s11431-022-2263-7-e DE-627 ger DE-627 rakwb eng Liu, JingYun verfasserin aut Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press 2023 Abstract Glass transition plays a critical role to determine the dynamic behaviors of amorphous shape memory polymers (SMPs). However, the fundamental relationships between shape memory effect (SME) and dynamic glass transition have not been well understood, even though this topic has been studied for decades. In this study, we apply a mean-square displacement function of Adam-Gibbs (AG) domain size model to explore metastable glass transition between normal glass state and rubbery state of amorphous SMPs, based on both mode-coupling theory and mean-field model. A statistic viscosity equation is formulated to study the dynamic glass transition of metastable AG domains in an amorphous SMP. A dynamically spinodal model is also developed to connect dynamic glass transitions to thermomechanical processes, based on statistic viscosity equation and phase transition model. Furthermore, using the spinodal models, multiple shape memory behaviors have been predicted for amorphous SMPs with dual-, triple- and quadruple-SMEs, resulted from their different routes of themomechanical evolutions. Finally, the proposed models are verified using the experimental data reported in literature. Lu, HaiBao aut Fu, Yong-Qing aut Enthalten in Science in China Heidelberg : Springer, 1997 66(2023), 8 vom: 18. Juli, Seite 2432-2440 (DE-627)385614756 (DE-600)2142897-9 1862-281X nnns volume:66 year:2023 number:8 day:18 month:07 pages:2432-2440 https://dx.doi.org/10.1007/s11431-022-2263-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 AR 66 2023 8 18 07 2432-2440 |
| language |
English |
| source |
Enthalten in Science in China 66(2023), 8 vom: 18. Juli, Seite 2432-2440 volume:66 year:2023 number:8 day:18 month:07 pages:2432-2440 |
| sourceStr |
Enthalten in Science in China 66(2023), 8 vom: 18. Juli, Seite 2432-2440 volume:66 year:2023 number:8 day:18 month:07 pages:2432-2440 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| isfreeaccess_bool |
false |
| container_title |
Science in China |
| authorswithroles_txt_mv |
Liu, JingYun @@aut@@ Lu, HaiBao @@aut@@ Fu, Yong-Qing @@aut@@ |
| publishDateDaySort_date |
2023-07-18T00:00:00Z |
| hierarchy_top_id |
385614756 |
| id |
SPR052626350 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR052626350</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230804064811.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230804s2023 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11431-022-2263-7</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR052626350</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11431-022-2263-7-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Liu, JingYun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Science China Press 2023</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Glass transition plays a critical role to determine the dynamic behaviors of amorphous shape memory polymers (SMPs). However, the fundamental relationships between shape memory effect (SME) and dynamic glass transition have not been well understood, even though this topic has been studied for decades. In this study, we apply a mean-square displacement function of Adam-Gibbs (AG) domain size model to explore metastable glass transition between normal glass state and rubbery state of amorphous SMPs, based on both mode-coupling theory and mean-field model. A statistic viscosity equation is formulated to study the dynamic glass transition of metastable AG domains in an amorphous SMP. A dynamically spinodal model is also developed to connect dynamic glass transitions to thermomechanical processes, based on statistic viscosity equation and phase transition model. Furthermore, using the spinodal models, multiple shape memory behaviors have been predicted for amorphous SMPs with dual-, triple- and quadruple-SMEs, resulted from their different routes of themomechanical evolutions. Finally, the proposed models are verified using the experimental data reported in literature.</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lu, HaiBao</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Fu, Yong-Qing</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Science in China</subfield><subfield code="d">Heidelberg : Springer, 1997</subfield><subfield code="g">66(2023), 8 vom: 18. Juli, Seite 2432-2440</subfield><subfield code="w">(DE-627)385614756</subfield><subfield code="w">(DE-600)2142897-9</subfield><subfield code="x">1862-281X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:66</subfield><subfield code="g">year:2023</subfield><subfield code="g">number:8</subfield><subfield code="g">day:18</subfield><subfield code="g">month:07</subfield><subfield code="g">pages:2432-2440</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s11431-022-2263-7</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">66</subfield><subfield code="j">2023</subfield><subfield code="e">8</subfield><subfield code="b">18</subfield><subfield code="c">07</subfield><subfield code="h">2432-2440</subfield></datafield></record></collection>
|
| author |
Liu, JingYun |
| spellingShingle |
Liu, JingYun Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect |
| authorStr |
Liu, JingYun |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)385614756 |
| format |
electronic Article |
| delete_txt_mv |
keep |
| author_role |
aut aut aut |
| collection |
springer |
| remote_str |
true |
| illustrated |
Not Illustrated |
| issn |
1862-281X |
| topic_title |
Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect |
| format_facet |
Elektronische Aufsätze Aufsätze Elektronische Ressource |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
cr |
| hierarchy_parent_title |
Science in China |
| hierarchy_parent_id |
385614756 |
| hierarchy_top_title |
Science in China |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)385614756 (DE-600)2142897-9 |
| title |
Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect |
| ctrlnum |
(DE-627)SPR052626350 (SPR)s11431-022-2263-7-e |
| title_full |
Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect |
| author_sort |
Liu, JingYun |
| journal |
Science in China |
| journalStr |
Science in China |
| lang_code |
eng |
| isOA_bool |
false |
| recordtype |
marc |
| publishDateSort |
2023 |
| contenttype_str_mv |
txt |
| container_start_page |
2432 |
| author_browse |
Liu, JingYun Lu, HaiBao Fu, Yong-Qing |
| container_volume |
66 |
| format_se |
Elektronische Aufsätze |
| author-letter |
Liu, JingYun |
| doi_str_mv |
10.1007/s11431-022-2263-7 |
| title_sort |
spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect |
| title_auth |
Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect |
| abstract |
Abstract Glass transition plays a critical role to determine the dynamic behaviors of amorphous shape memory polymers (SMPs). However, the fundamental relationships between shape memory effect (SME) and dynamic glass transition have not been well understood, even though this topic has been studied for decades. In this study, we apply a mean-square displacement function of Adam-Gibbs (AG) domain size model to explore metastable glass transition between normal glass state and rubbery state of amorphous SMPs, based on both mode-coupling theory and mean-field model. A statistic viscosity equation is formulated to study the dynamic glass transition of metastable AG domains in an amorphous SMP. A dynamically spinodal model is also developed to connect dynamic glass transitions to thermomechanical processes, based on statistic viscosity equation and phase transition model. Furthermore, using the spinodal models, multiple shape memory behaviors have been predicted for amorphous SMPs with dual-, triple- and quadruple-SMEs, resulted from their different routes of themomechanical evolutions. Finally, the proposed models are verified using the experimental data reported in literature. © Science China Press 2023 |
| abstractGer |
Abstract Glass transition plays a critical role to determine the dynamic behaviors of amorphous shape memory polymers (SMPs). However, the fundamental relationships between shape memory effect (SME) and dynamic glass transition have not been well understood, even though this topic has been studied for decades. In this study, we apply a mean-square displacement function of Adam-Gibbs (AG) domain size model to explore metastable glass transition between normal glass state and rubbery state of amorphous SMPs, based on both mode-coupling theory and mean-field model. A statistic viscosity equation is formulated to study the dynamic glass transition of metastable AG domains in an amorphous SMP. A dynamically spinodal model is also developed to connect dynamic glass transitions to thermomechanical processes, based on statistic viscosity equation and phase transition model. Furthermore, using the spinodal models, multiple shape memory behaviors have been predicted for amorphous SMPs with dual-, triple- and quadruple-SMEs, resulted from their different routes of themomechanical evolutions. Finally, the proposed models are verified using the experimental data reported in literature. © Science China Press 2023 |
| abstract_unstemmed |
Abstract Glass transition plays a critical role to determine the dynamic behaviors of amorphous shape memory polymers (SMPs). However, the fundamental relationships between shape memory effect (SME) and dynamic glass transition have not been well understood, even though this topic has been studied for decades. In this study, we apply a mean-square displacement function of Adam-Gibbs (AG) domain size model to explore metastable glass transition between normal glass state and rubbery state of amorphous SMPs, based on both mode-coupling theory and mean-field model. A statistic viscosity equation is formulated to study the dynamic glass transition of metastable AG domains in an amorphous SMP. A dynamically spinodal model is also developed to connect dynamic glass transitions to thermomechanical processes, based on statistic viscosity equation and phase transition model. Furthermore, using the spinodal models, multiple shape memory behaviors have been predicted for amorphous SMPs with dual-, triple- and quadruple-SMEs, resulted from their different routes of themomechanical evolutions. Finally, the proposed models are verified using the experimental data reported in literature. © Science China Press 2023 |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 |
| container_issue |
8 |
| title_short |
Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect |
| url |
https://dx.doi.org/10.1007/s11431-022-2263-7 |
| remote_bool |
true |
| author2 |
Lu, HaiBao Fu, Yong-Qing |
| author2Str |
Lu, HaiBao Fu, Yong-Qing |
| ppnlink |
385614756 |
| mediatype_str_mv |
c |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1007/s11431-022-2263-7 |
| up_date |
2024-07-03T13:37:10.742Z |
| _version_ |
1803565222588317697 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR052626350</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230804064811.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230804s2023 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11431-022-2263-7</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR052626350</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11431-022-2263-7-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Liu, JingYun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Spinodal dynamics of metastable glass transition domains in amorphous polymer towards thermomechanically tailorable shape memory effect</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Science China Press 2023</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Glass transition plays a critical role to determine the dynamic behaviors of amorphous shape memory polymers (SMPs). However, the fundamental relationships between shape memory effect (SME) and dynamic glass transition have not been well understood, even though this topic has been studied for decades. In this study, we apply a mean-square displacement function of Adam-Gibbs (AG) domain size model to explore metastable glass transition between normal glass state and rubbery state of amorphous SMPs, based on both mode-coupling theory and mean-field model. A statistic viscosity equation is formulated to study the dynamic glass transition of metastable AG domains in an amorphous SMP. A dynamically spinodal model is also developed to connect dynamic glass transitions to thermomechanical processes, based on statistic viscosity equation and phase transition model. Furthermore, using the spinodal models, multiple shape memory behaviors have been predicted for amorphous SMPs with dual-, triple- and quadruple-SMEs, resulted from their different routes of themomechanical evolutions. Finally, the proposed models are verified using the experimental data reported in literature.</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lu, HaiBao</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Fu, Yong-Qing</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Science in China</subfield><subfield code="d">Heidelberg : Springer, 1997</subfield><subfield code="g">66(2023), 8 vom: 18. Juli, Seite 2432-2440</subfield><subfield code="w">(DE-627)385614756</subfield><subfield code="w">(DE-600)2142897-9</subfield><subfield code="x">1862-281X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:66</subfield><subfield code="g">year:2023</subfield><subfield code="g">number:8</subfield><subfield code="g">day:18</subfield><subfield code="g">month:07</subfield><subfield code="g">pages:2432-2440</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s11431-022-2263-7</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">66</subfield><subfield code="j">2023</subfield><subfield code="e">8</subfield><subfield code="b">18</subfield><subfield code="c">07</subfield><subfield code="h">2432-2440</subfield></datafield></record></collection>
|
| score |
7.40096 |