Photocatalytic Reduction of $ CO_{2} $ to CO Using Manganese Complexes with Bipyridine Modified Electron-Donating Groups
The present work deals with the Mn-based complex formed after substitution with groups (–$ NH_{2} $ and –Br) on 2, 2′-bipyridine ligand and their photocatalytic activity for $ CO_{2} $ reduction. The photocatalytic system involves [Ru(bpy)3]2+ [Ru] as a photosensitizer (PS) in a mixture of N, N-dime...
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| Autor*in: |
Li, Niang-Xiu [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Catalysis letters - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988, 153(2022), 10 vom: 23. Nov., Seite 2910-2916 |
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| Übergeordnetes Werk: |
volume:153 ; year:2022 ; number:10 ; day:23 ; month:11 ; pages:2910-2916 |
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| DOI / URN: |
10.1007/s10562-022-04226-6 |
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SPR053074890 |
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| 520 | |a The present work deals with the Mn-based complex formed after substitution with groups (–$ NH_{2} $ and –Br) on 2, 2′-bipyridine ligand and their photocatalytic activity for $ CO_{2} $ reduction. The photocatalytic system involves [Ru(bpy)3]2+ [Ru] as a photosensitizer (PS) in a mixture of N, N-dimethylformamide (DMF) and triethanolamine (TEOA) and the 1-benzyl-1,4-dihydronicotinamide (BIH), BIH and TEOA as the sacrificial agent and the auxiliary sacrificial agent in photocatalytic system, respectively. The results revealed that electron-donating groups of the complexes play an essential role in the photocatalytic reaction. Both density functional and high-resolution mass spectrometry supported the process of photocatalytic reduction of $ CO_{2} $ to CO in the presence of manganese complexes. Graphical Abstract Mn-based complex with 4,4′-diamine—2,2′-bipyridine as a ligand was synthesized. The photocatalytic $ CO_{2} $ reduction behaviours of the catalysts were investigated. The plausible mechanisms were proposed based on the main intermediates detected by HRMS and DFT. | ||
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10.1007/s10562-022-04226-6 doi (DE-627)SPR053074890 (SPR)s10562-022-04226-6-e DE-627 ger DE-627 rakwb eng Li, Niang-Xiu verfasserin aut Photocatalytic Reduction of $ CO_{2} $ to CO Using Manganese Complexes with Bipyridine Modified Electron-Donating Groups 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. The present work deals with the Mn-based complex formed after substitution with groups (–$ NH_{2} $ and –Br) on 2, 2′-bipyridine ligand and their photocatalytic activity for $ CO_{2} $ reduction. The photocatalytic system involves [Ru(bpy)3]2+ [Ru] as a photosensitizer (PS) in a mixture of N, N-dimethylformamide (DMF) and triethanolamine (TEOA) and the 1-benzyl-1,4-dihydronicotinamide (BIH), BIH and TEOA as the sacrificial agent and the auxiliary sacrificial agent in photocatalytic system, respectively. The results revealed that electron-donating groups of the complexes play an essential role in the photocatalytic reaction. Both density functional and high-resolution mass spectrometry supported the process of photocatalytic reduction of $ CO_{2} $ to CO in the presence of manganese complexes. Graphical Abstract Mn-based complex with 4,4′-diamine—2,2′-bipyridine as a ligand was synthesized. The photocatalytic $ CO_{2} $ reduction behaviours of the catalysts were investigated. The plausible mechanisms were proposed based on the main intermediates detected by HRMS and DFT. Photocatalytic Reduction CO (dpeaa)DE-He213 CO (dpeaa)DE-He213 Mn-based Complexes (dpeaa)DE-He213 Chen, Yu-Mei aut Xu, Quan-Qing (orcid)0000-0001-5377-901X aut Yang, Zhi aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 153(2022), 10 vom: 23. Nov., Seite 2910-2916 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:153 year:2022 number:10 day:23 month:11 pages:2910-2916 https://dx.doi.org/10.1007/s10562-022-04226-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 153 2022 10 23 11 2910-2916 |
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10.1007/s10562-022-04226-6 doi (DE-627)SPR053074890 (SPR)s10562-022-04226-6-e DE-627 ger DE-627 rakwb eng Li, Niang-Xiu verfasserin aut Photocatalytic Reduction of $ CO_{2} $ to CO Using Manganese Complexes with Bipyridine Modified Electron-Donating Groups 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. The present work deals with the Mn-based complex formed after substitution with groups (–$ NH_{2} $ and –Br) on 2, 2′-bipyridine ligand and their photocatalytic activity for $ CO_{2} $ reduction. The photocatalytic system involves [Ru(bpy)3]2+ [Ru] as a photosensitizer (PS) in a mixture of N, N-dimethylformamide (DMF) and triethanolamine (TEOA) and the 1-benzyl-1,4-dihydronicotinamide (BIH), BIH and TEOA as the sacrificial agent and the auxiliary sacrificial agent in photocatalytic system, respectively. The results revealed that electron-donating groups of the complexes play an essential role in the photocatalytic reaction. Both density functional and high-resolution mass spectrometry supported the process of photocatalytic reduction of $ CO_{2} $ to CO in the presence of manganese complexes. Graphical Abstract Mn-based complex with 4,4′-diamine—2,2′-bipyridine as a ligand was synthesized. The photocatalytic $ CO_{2} $ reduction behaviours of the catalysts were investigated. The plausible mechanisms were proposed based on the main intermediates detected by HRMS and DFT. Photocatalytic Reduction CO (dpeaa)DE-He213 CO (dpeaa)DE-He213 Mn-based Complexes (dpeaa)DE-He213 Chen, Yu-Mei aut Xu, Quan-Qing (orcid)0000-0001-5377-901X aut Yang, Zhi aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 153(2022), 10 vom: 23. Nov., Seite 2910-2916 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:153 year:2022 number:10 day:23 month:11 pages:2910-2916 https://dx.doi.org/10.1007/s10562-022-04226-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 153 2022 10 23 11 2910-2916 |
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10.1007/s10562-022-04226-6 doi (DE-627)SPR053074890 (SPR)s10562-022-04226-6-e DE-627 ger DE-627 rakwb eng Li, Niang-Xiu verfasserin aut Photocatalytic Reduction of $ CO_{2} $ to CO Using Manganese Complexes with Bipyridine Modified Electron-Donating Groups 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. The present work deals with the Mn-based complex formed after substitution with groups (–$ NH_{2} $ and –Br) on 2, 2′-bipyridine ligand and their photocatalytic activity for $ CO_{2} $ reduction. The photocatalytic system involves [Ru(bpy)3]2+ [Ru] as a photosensitizer (PS) in a mixture of N, N-dimethylformamide (DMF) and triethanolamine (TEOA) and the 1-benzyl-1,4-dihydronicotinamide (BIH), BIH and TEOA as the sacrificial agent and the auxiliary sacrificial agent in photocatalytic system, respectively. The results revealed that electron-donating groups of the complexes play an essential role in the photocatalytic reaction. Both density functional and high-resolution mass spectrometry supported the process of photocatalytic reduction of $ CO_{2} $ to CO in the presence of manganese complexes. Graphical Abstract Mn-based complex with 4,4′-diamine—2,2′-bipyridine as a ligand was synthesized. The photocatalytic $ CO_{2} $ reduction behaviours of the catalysts were investigated. The plausible mechanisms were proposed based on the main intermediates detected by HRMS and DFT. Photocatalytic Reduction CO (dpeaa)DE-He213 CO (dpeaa)DE-He213 Mn-based Complexes (dpeaa)DE-He213 Chen, Yu-Mei aut Xu, Quan-Qing (orcid)0000-0001-5377-901X aut Yang, Zhi aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 153(2022), 10 vom: 23. Nov., Seite 2910-2916 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:153 year:2022 number:10 day:23 month:11 pages:2910-2916 https://dx.doi.org/10.1007/s10562-022-04226-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 153 2022 10 23 11 2910-2916 |
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10.1007/s10562-022-04226-6 doi (DE-627)SPR053074890 (SPR)s10562-022-04226-6-e DE-627 ger DE-627 rakwb eng Li, Niang-Xiu verfasserin aut Photocatalytic Reduction of $ CO_{2} $ to CO Using Manganese Complexes with Bipyridine Modified Electron-Donating Groups 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. The present work deals with the Mn-based complex formed after substitution with groups (–$ NH_{2} $ and –Br) on 2, 2′-bipyridine ligand and their photocatalytic activity for $ CO_{2} $ reduction. The photocatalytic system involves [Ru(bpy)3]2+ [Ru] as a photosensitizer (PS) in a mixture of N, N-dimethylformamide (DMF) and triethanolamine (TEOA) and the 1-benzyl-1,4-dihydronicotinamide (BIH), BIH and TEOA as the sacrificial agent and the auxiliary sacrificial agent in photocatalytic system, respectively. The results revealed that electron-donating groups of the complexes play an essential role in the photocatalytic reaction. Both density functional and high-resolution mass spectrometry supported the process of photocatalytic reduction of $ CO_{2} $ to CO in the presence of manganese complexes. Graphical Abstract Mn-based complex with 4,4′-diamine—2,2′-bipyridine as a ligand was synthesized. The photocatalytic $ CO_{2} $ reduction behaviours of the catalysts were investigated. The plausible mechanisms were proposed based on the main intermediates detected by HRMS and DFT. Photocatalytic Reduction CO (dpeaa)DE-He213 CO (dpeaa)DE-He213 Mn-based Complexes (dpeaa)DE-He213 Chen, Yu-Mei aut Xu, Quan-Qing (orcid)0000-0001-5377-901X aut Yang, Zhi aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 153(2022), 10 vom: 23. Nov., Seite 2910-2916 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:153 year:2022 number:10 day:23 month:11 pages:2910-2916 https://dx.doi.org/10.1007/s10562-022-04226-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 153 2022 10 23 11 2910-2916 |
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10.1007/s10562-022-04226-6 doi (DE-627)SPR053074890 (SPR)s10562-022-04226-6-e DE-627 ger DE-627 rakwb eng Li, Niang-Xiu verfasserin aut Photocatalytic Reduction of $ CO_{2} $ to CO Using Manganese Complexes with Bipyridine Modified Electron-Donating Groups 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. The present work deals with the Mn-based complex formed after substitution with groups (–$ NH_{2} $ and –Br) on 2, 2′-bipyridine ligand and their photocatalytic activity for $ CO_{2} $ reduction. The photocatalytic system involves [Ru(bpy)3]2+ [Ru] as a photosensitizer (PS) in a mixture of N, N-dimethylformamide (DMF) and triethanolamine (TEOA) and the 1-benzyl-1,4-dihydronicotinamide (BIH), BIH and TEOA as the sacrificial agent and the auxiliary sacrificial agent in photocatalytic system, respectively. The results revealed that electron-donating groups of the complexes play an essential role in the photocatalytic reaction. Both density functional and high-resolution mass spectrometry supported the process of photocatalytic reduction of $ CO_{2} $ to CO in the presence of manganese complexes. Graphical Abstract Mn-based complex with 4,4′-diamine—2,2′-bipyridine as a ligand was synthesized. The photocatalytic $ CO_{2} $ reduction behaviours of the catalysts were investigated. The plausible mechanisms were proposed based on the main intermediates detected by HRMS and DFT. Photocatalytic Reduction CO (dpeaa)DE-He213 CO (dpeaa)DE-He213 Mn-based Complexes (dpeaa)DE-He213 Chen, Yu-Mei aut Xu, Quan-Qing (orcid)0000-0001-5377-901X aut Yang, Zhi aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 153(2022), 10 vom: 23. Nov., Seite 2910-2916 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:153 year:2022 number:10 day:23 month:11 pages:2910-2916 https://dx.doi.org/10.1007/s10562-022-04226-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 153 2022 10 23 11 2910-2916 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR053074890</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230915064642.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230915s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10562-022-04226-6</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR053074890</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10562-022-04226-6-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Li, Niang-Xiu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Photocatalytic Reduction of $ CO_{2} $ to CO Using Manganese Complexes with Bipyridine Modified Electron-Donating Groups</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The present work deals with the Mn-based complex formed after substitution with groups (–$ NH_{2} $ and –Br) on 2, 2′-bipyridine ligand and their photocatalytic activity for $ CO_{2} $ reduction. The photocatalytic system involves [Ru(bpy)3]2+ [Ru] as a photosensitizer (PS) in a mixture of N, N-dimethylformamide (DMF) and triethanolamine (TEOA) and the 1-benzyl-1,4-dihydronicotinamide (BIH), BIH and TEOA as the sacrificial agent and the auxiliary sacrificial agent in photocatalytic system, respectively. The results revealed that electron-donating groups of the complexes play an essential role in the photocatalytic reaction. Both density functional and high-resolution mass spectrometry supported the process of photocatalytic reduction of $ CO_{2} $ to CO in the presence of manganese complexes. Graphical Abstract Mn-based complex with 4,4′-diamine—2,2′-bipyridine as a ligand was synthesized. The photocatalytic $ CO_{2} $ reduction behaviours of the catalysts were investigated. 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Li, Niang-Xiu |
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Photocatalytic Reduction of $ CO_{2} $ to CO Using Manganese Complexes with Bipyridine Modified Electron-Donating Groups Photocatalytic Reduction CO (dpeaa)DE-He213 CO (dpeaa)DE-He213 Mn-based Complexes (dpeaa)DE-He213 |
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Photocatalytic Reduction of $ CO_{2} $ to CO Using Manganese Complexes with Bipyridine Modified Electron-Donating Groups |
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Photocatalytic Reduction of $ CO_{2} $ to CO Using Manganese Complexes with Bipyridine Modified Electron-Donating Groups |
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photocatalytic reduction of $ co_{2} $ to co using manganese complexes with bipyridine modified electron-donating groups |
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Photocatalytic Reduction of $ CO_{2} $ to CO Using Manganese Complexes with Bipyridine Modified Electron-Donating Groups |
| abstract |
The present work deals with the Mn-based complex formed after substitution with groups (–$ NH_{2} $ and –Br) on 2, 2′-bipyridine ligand and their photocatalytic activity for $ CO_{2} $ reduction. The photocatalytic system involves [Ru(bpy)3]2+ [Ru] as a photosensitizer (PS) in a mixture of N, N-dimethylformamide (DMF) and triethanolamine (TEOA) and the 1-benzyl-1,4-dihydronicotinamide (BIH), BIH and TEOA as the sacrificial agent and the auxiliary sacrificial agent in photocatalytic system, respectively. The results revealed that electron-donating groups of the complexes play an essential role in the photocatalytic reaction. Both density functional and high-resolution mass spectrometry supported the process of photocatalytic reduction of $ CO_{2} $ to CO in the presence of manganese complexes. Graphical Abstract Mn-based complex with 4,4′-diamine—2,2′-bipyridine as a ligand was synthesized. The photocatalytic $ CO_{2} $ reduction behaviours of the catalysts were investigated. The plausible mechanisms were proposed based on the main intermediates detected by HRMS and DFT. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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The present work deals with the Mn-based complex formed after substitution with groups (–$ NH_{2} $ and –Br) on 2, 2′-bipyridine ligand and their photocatalytic activity for $ CO_{2} $ reduction. The photocatalytic system involves [Ru(bpy)3]2+ [Ru] as a photosensitizer (PS) in a mixture of N, N-dimethylformamide (DMF) and triethanolamine (TEOA) and the 1-benzyl-1,4-dihydronicotinamide (BIH), BIH and TEOA as the sacrificial agent and the auxiliary sacrificial agent in photocatalytic system, respectively. The results revealed that electron-donating groups of the complexes play an essential role in the photocatalytic reaction. Both density functional and high-resolution mass spectrometry supported the process of photocatalytic reduction of $ CO_{2} $ to CO in the presence of manganese complexes. Graphical Abstract Mn-based complex with 4,4′-diamine—2,2′-bipyridine as a ligand was synthesized. The photocatalytic $ CO_{2} $ reduction behaviours of the catalysts were investigated. The plausible mechanisms were proposed based on the main intermediates detected by HRMS and DFT. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
The present work deals with the Mn-based complex formed after substitution with groups (–$ NH_{2} $ and –Br) on 2, 2′-bipyridine ligand and their photocatalytic activity for $ CO_{2} $ reduction. The photocatalytic system involves [Ru(bpy)3]2+ [Ru] as a photosensitizer (PS) in a mixture of N, N-dimethylformamide (DMF) and triethanolamine (TEOA) and the 1-benzyl-1,4-dihydronicotinamide (BIH), BIH and TEOA as the sacrificial agent and the auxiliary sacrificial agent in photocatalytic system, respectively. The results revealed that electron-donating groups of the complexes play an essential role in the photocatalytic reaction. Both density functional and high-resolution mass spectrometry supported the process of photocatalytic reduction of $ CO_{2} $ to CO in the presence of manganese complexes. Graphical Abstract Mn-based complex with 4,4′-diamine—2,2′-bipyridine as a ligand was synthesized. The photocatalytic $ CO_{2} $ reduction behaviours of the catalysts were investigated. The plausible mechanisms were proposed based on the main intermediates detected by HRMS and DFT. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| title_short |
Photocatalytic Reduction of $ CO_{2} $ to CO Using Manganese Complexes with Bipyridine Modified Electron-Donating Groups |
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https://dx.doi.org/10.1007/s10562-022-04226-6 |
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Chen, Yu-Mei Xu, Quan-Qing Yang, Zhi |
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10.1007/s10562-022-04226-6 |
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| score |
7.3974237 |