SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II)

Abstract Using a solvothermal method, we have synthesized two coordination polymers of Cu(II). One is a 1D polymer {[Cu(bpy)(NDC)($ H_{2} $O)]·$ 2H_{2} $O}n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid ($ H_{2} $NDC) and 2,2′-bipyridine (bpy) as an auxiliary ligand, while the other is a 2D...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Nath, J. K. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	coordination polymer copper carboxylate water cluster supramolecular structure solvothermal Hirshfield.

Anmerkung:	© Pleiades Publishing, Ltd. 2023

Übergeordnetes Werk:	Enthalten in: Journal of structural chemistry - New York, NY [u.a.] : Consultants Bureau, 1960, 64(2023), 9 vom: Sept., Seite 1664-1676
Übergeordnetes Werk:	volume:64 ; year:2023 ; number:9 ; month:09 ; pages:1664-1676

Links:	Volltext

DOI / URN:	10.1134/S002247662309010X

Katalog-ID:	SPR053248848

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245	1	0	\|a SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II)
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520			\|a Abstract Using a solvothermal method, we have synthesized two coordination polymers of Cu(II). One is a 1D polymer {[Cu(bpy)(NDC)($ H_{2} $O)]·$ 2H_{2} $O}n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid ($ H_{2} $NDC) and 2,2′-bipyridine (bpy) as an auxiliary ligand, while the other is a 2D polymer {[$ Cu_{3} $(TMA) (Imd)3]·$ 5H_{2} $O·2DMF}n (2, 2D) formed with trimellitic acid ($ H_{3} $TMA) and imidazole (Imd) as an auxiliary ligand. Both coordination polymers 1 and 2 were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride and trimelitic anhydride with bipyridine and imidazole ligands, respectively. The asymmetric unit of polymer 1 contains asymmetric $ η^{1} $ binding mode (one of the carboxylate) linking distorted square-pyramidal [Cu(NDC)(bpy)($ H_{2} $O)]2+ coordination units. The syn-syn-$ η^{1} $:$ η^{1} $ linear polymeric conformation exist in the 1D coordination polymer with adjacent Cu…Cu distance is 6.849 Å. A chain of cyclic tetrameric water clusters is present between the stacked layers of the 3D supramolecular structure. The formation of the 3D supramolecular structure is guided by various weak interactions such as O–H…O, C–H…O, C–H…π and π…π interactions. The coordination polymer 2 forms 3D supramolecular architecture guided by various weak interactions such as O–H…O, C–H…O and N–H…O interactions. The crystal structures of both coordination polymers have been determined using single crystal X-ray diffraction and their structural features are described.
650		4	\|a coordination polymer \|7 (dpeaa)DE-He213
650		4	\|a copper carboxylate \|7 (dpeaa)DE-He213
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650		4	\|a supramolecular structure \|7 (dpeaa)DE-He213
650		4	\|a solvothermal \|7 (dpeaa)DE-He213
650		4	\|a Hirshfield. \|7 (dpeaa)DE-He213
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773	1	8	\|g volume:64 \|g year:2023 \|g number:9 \|g month:09 \|g pages:1664-1676
856	4	0	\|u https://dx.doi.org/10.1134/S002247662309010X \|z lizenzpflichtig \|3 Volltext
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912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_206
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
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912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
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912			\|a GBV_ILN_2025
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912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
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author_variant	j k n jk jkn
matchkey_str	article:15738779:2023----::yteesrcuaisgtnhrhedufcaayiotoeeoet
hierarchy_sort_str	2023
publishDate	2023
allfields	10.1134/S002247662309010X doi (DE-627)SPR053248848 (SPR)S002247662309010X-e DE-627 ger DE-627 rakwb eng Nath, J. K. verfasserin aut SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II) 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2023 Abstract Using a solvothermal method, we have synthesized two coordination polymers of Cu(II). One is a 1D polymer {[Cu(bpy)(NDC)($ H_{2} $O)]·$ 2H_{2} $O}n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid ($ H_{2} $NDC) and 2,2′-bipyridine (bpy) as an auxiliary ligand, while the other is a 2D polymer {[$ Cu_{3} $(TMA) (Imd)3]·$ 5H_{2} $O·2DMF}n (2, 2D) formed with trimellitic acid ($ H_{3} $TMA) and imidazole (Imd) as an auxiliary ligand. Both coordination polymers 1 and 2 were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride and trimelitic anhydride with bipyridine and imidazole ligands, respectively. The asymmetric unit of polymer 1 contains asymmetric $ η^{1} $ binding mode (one of the carboxylate) linking distorted square-pyramidal [Cu(NDC)(bpy)($ H_{2} $O)]2+ coordination units. The syn-syn-$ η^{1} $:$ η^{1} $ linear polymeric conformation exist in the 1D coordination polymer with adjacent Cu…Cu distance is 6.849 Å. A chain of cyclic tetrameric water clusters is present between the stacked layers of the 3D supramolecular structure. The formation of the 3D supramolecular structure is guided by various weak interactions such as O–H…O, C–H…O, C–H…π and π…π interactions. The coordination polymer 2 forms 3D supramolecular architecture guided by various weak interactions such as O–H…O, C–H…O and N–H…O interactions. The crystal structures of both coordination polymers have been determined using single crystal X-ray diffraction and their structural features are described. coordination polymer (dpeaa)DE-He213 copper carboxylate (dpeaa)DE-He213 water cluster (dpeaa)DE-He213 supramolecular structure (dpeaa)DE-He213 solvothermal (dpeaa)DE-He213 Hirshfield. (dpeaa)DE-He213 Enthalten in Journal of structural chemistry New York, NY [u.a.] : Consultants Bureau, 1960 64(2023), 9 vom: Sept., Seite 1664-1676 (DE-627)325573530 (DE-600)2037691-1 1573-8779 nnns volume:64 year:2023 number:9 month:09 pages:1664-1676 https://dx.doi.org/10.1134/S002247662309010X lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 64 2023 9 09 1664-1676
spelling	10.1134/S002247662309010X doi (DE-627)SPR053248848 (SPR)S002247662309010X-e DE-627 ger DE-627 rakwb eng Nath, J. K. verfasserin aut SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II) 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2023 Abstract Using a solvothermal method, we have synthesized two coordination polymers of Cu(II). One is a 1D polymer {[Cu(bpy)(NDC)($ H_{2} $O)]·$ 2H_{2} $O}n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid ($ H_{2} $NDC) and 2,2′-bipyridine (bpy) as an auxiliary ligand, while the other is a 2D polymer {[$ Cu_{3} $(TMA) (Imd)3]·$ 5H_{2} $O·2DMF}n (2, 2D) formed with trimellitic acid ($ H_{3} $TMA) and imidazole (Imd) as an auxiliary ligand. Both coordination polymers 1 and 2 were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride and trimelitic anhydride with bipyridine and imidazole ligands, respectively. The asymmetric unit of polymer 1 contains asymmetric $ η^{1} $ binding mode (one of the carboxylate) linking distorted square-pyramidal [Cu(NDC)(bpy)($ H_{2} $O)]2+ coordination units. The syn-syn-$ η^{1} $:$ η^{1} $ linear polymeric conformation exist in the 1D coordination polymer with adjacent Cu…Cu distance is 6.849 Å. A chain of cyclic tetrameric water clusters is present between the stacked layers of the 3D supramolecular structure. The formation of the 3D supramolecular structure is guided by various weak interactions such as O–H…O, C–H…O, C–H…π and π…π interactions. The coordination polymer 2 forms 3D supramolecular architecture guided by various weak interactions such as O–H…O, C–H…O and N–H…O interactions. The crystal structures of both coordination polymers have been determined using single crystal X-ray diffraction and their structural features are described. coordination polymer (dpeaa)DE-He213 copper carboxylate (dpeaa)DE-He213 water cluster (dpeaa)DE-He213 supramolecular structure (dpeaa)DE-He213 solvothermal (dpeaa)DE-He213 Hirshfield. (dpeaa)DE-He213 Enthalten in Journal of structural chemistry New York, NY [u.a.] : Consultants Bureau, 1960 64(2023), 9 vom: Sept., Seite 1664-1676 (DE-627)325573530 (DE-600)2037691-1 1573-8779 nnns volume:64 year:2023 number:9 month:09 pages:1664-1676 https://dx.doi.org/10.1134/S002247662309010X lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 64 2023 9 09 1664-1676
allfields_unstemmed	10.1134/S002247662309010X doi (DE-627)SPR053248848 (SPR)S002247662309010X-e DE-627 ger DE-627 rakwb eng Nath, J. K. verfasserin aut SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II) 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2023 Abstract Using a solvothermal method, we have synthesized two coordination polymers of Cu(II). One is a 1D polymer {[Cu(bpy)(NDC)($ H_{2} $O)]·$ 2H_{2} $O}n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid ($ H_{2} $NDC) and 2,2′-bipyridine (bpy) as an auxiliary ligand, while the other is a 2D polymer {[$ Cu_{3} $(TMA) (Imd)3]·$ 5H_{2} $O·2DMF}n (2, 2D) formed with trimellitic acid ($ H_{3} $TMA) and imidazole (Imd) as an auxiliary ligand. Both coordination polymers 1 and 2 were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride and trimelitic anhydride with bipyridine and imidazole ligands, respectively. The asymmetric unit of polymer 1 contains asymmetric $ η^{1} $ binding mode (one of the carboxylate) linking distorted square-pyramidal [Cu(NDC)(bpy)($ H_{2} $O)]2+ coordination units. The syn-syn-$ η^{1} $:$ η^{1} $ linear polymeric conformation exist in the 1D coordination polymer with adjacent Cu…Cu distance is 6.849 Å. A chain of cyclic tetrameric water clusters is present between the stacked layers of the 3D supramolecular structure. The formation of the 3D supramolecular structure is guided by various weak interactions such as O–H…O, C–H…O, C–H…π and π…π interactions. The coordination polymer 2 forms 3D supramolecular architecture guided by various weak interactions such as O–H…O, C–H…O and N–H…O interactions. The crystal structures of both coordination polymers have been determined using single crystal X-ray diffraction and their structural features are described. coordination polymer (dpeaa)DE-He213 copper carboxylate (dpeaa)DE-He213 water cluster (dpeaa)DE-He213 supramolecular structure (dpeaa)DE-He213 solvothermal (dpeaa)DE-He213 Hirshfield. (dpeaa)DE-He213 Enthalten in Journal of structural chemistry New York, NY [u.a.] : Consultants Bureau, 1960 64(2023), 9 vom: Sept., Seite 1664-1676 (DE-627)325573530 (DE-600)2037691-1 1573-8779 nnns volume:64 year:2023 number:9 month:09 pages:1664-1676 https://dx.doi.org/10.1134/S002247662309010X lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 64 2023 9 09 1664-1676
allfieldsGer	10.1134/S002247662309010X doi (DE-627)SPR053248848 (SPR)S002247662309010X-e DE-627 ger DE-627 rakwb eng Nath, J. K. verfasserin aut SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II) 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2023 Abstract Using a solvothermal method, we have synthesized two coordination polymers of Cu(II). One is a 1D polymer {[Cu(bpy)(NDC)($ H_{2} $O)]·$ 2H_{2} $O}n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid ($ H_{2} $NDC) and 2,2′-bipyridine (bpy) as an auxiliary ligand, while the other is a 2D polymer {[$ Cu_{3} $(TMA) (Imd)3]·$ 5H_{2} $O·2DMF}n (2, 2D) formed with trimellitic acid ($ H_{3} $TMA) and imidazole (Imd) as an auxiliary ligand. Both coordination polymers 1 and 2 were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride and trimelitic anhydride with bipyridine and imidazole ligands, respectively. The asymmetric unit of polymer 1 contains asymmetric $ η^{1} $ binding mode (one of the carboxylate) linking distorted square-pyramidal [Cu(NDC)(bpy)($ H_{2} $O)]2+ coordination units. The syn-syn-$ η^{1} $:$ η^{1} $ linear polymeric conformation exist in the 1D coordination polymer with adjacent Cu…Cu distance is 6.849 Å. A chain of cyclic tetrameric water clusters is present between the stacked layers of the 3D supramolecular structure. The formation of the 3D supramolecular structure is guided by various weak interactions such as O–H…O, C–H…O, C–H…π and π…π interactions. The coordination polymer 2 forms 3D supramolecular architecture guided by various weak interactions such as O–H…O, C–H…O and N–H…O interactions. The crystal structures of both coordination polymers have been determined using single crystal X-ray diffraction and their structural features are described. coordination polymer (dpeaa)DE-He213 copper carboxylate (dpeaa)DE-He213 water cluster (dpeaa)DE-He213 supramolecular structure (dpeaa)DE-He213 solvothermal (dpeaa)DE-He213 Hirshfield. (dpeaa)DE-He213 Enthalten in Journal of structural chemistry New York, NY [u.a.] : Consultants Bureau, 1960 64(2023), 9 vom: Sept., Seite 1664-1676 (DE-627)325573530 (DE-600)2037691-1 1573-8779 nnns volume:64 year:2023 number:9 month:09 pages:1664-1676 https://dx.doi.org/10.1134/S002247662309010X lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 64 2023 9 09 1664-1676
allfieldsSound	10.1134/S002247662309010X doi (DE-627)SPR053248848 (SPR)S002247662309010X-e DE-627 ger DE-627 rakwb eng Nath, J. K. verfasserin aut SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II) 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2023 Abstract Using a solvothermal method, we have synthesized two coordination polymers of Cu(II). One is a 1D polymer {[Cu(bpy)(NDC)($ H_{2} $O)]·$ 2H_{2} $O}n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid ($ H_{2} $NDC) and 2,2′-bipyridine (bpy) as an auxiliary ligand, while the other is a 2D polymer {[$ Cu_{3} $(TMA) (Imd)3]·$ 5H_{2} $O·2DMF}n (2, 2D) formed with trimellitic acid ($ H_{3} $TMA) and imidazole (Imd) as an auxiliary ligand. Both coordination polymers 1 and 2 were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride and trimelitic anhydride with bipyridine and imidazole ligands, respectively. The asymmetric unit of polymer 1 contains asymmetric $ η^{1} $ binding mode (one of the carboxylate) linking distorted square-pyramidal [Cu(NDC)(bpy)($ H_{2} $O)]2+ coordination units. The syn-syn-$ η^{1} $:$ η^{1} $ linear polymeric conformation exist in the 1D coordination polymer with adjacent Cu…Cu distance is 6.849 Å. A chain of cyclic tetrameric water clusters is present between the stacked layers of the 3D supramolecular structure. The formation of the 3D supramolecular structure is guided by various weak interactions such as O–H…O, C–H…O, C–H…π and π…π interactions. The coordination polymer 2 forms 3D supramolecular architecture guided by various weak interactions such as O–H…O, C–H…O and N–H…O interactions. The crystal structures of both coordination polymers have been determined using single crystal X-ray diffraction and their structural features are described. coordination polymer (dpeaa)DE-He213 copper carboxylate (dpeaa)DE-He213 water cluster (dpeaa)DE-He213 supramolecular structure (dpeaa)DE-He213 solvothermal (dpeaa)DE-He213 Hirshfield. (dpeaa)DE-He213 Enthalten in Journal of structural chemistry New York, NY [u.a.] : Consultants Bureau, 1960 64(2023), 9 vom: Sept., Seite 1664-1676 (DE-627)325573530 (DE-600)2037691-1 1573-8779 nnns volume:64 year:2023 number:9 month:09 pages:1664-1676 https://dx.doi.org/10.1134/S002247662309010X lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 64 2023 9 09 1664-1676
language	English
source	Enthalten in Journal of structural chemistry 64(2023), 9 vom: Sept., Seite 1664-1676 volume:64 year:2023 number:9 month:09 pages:1664-1676
sourceStr	Enthalten in Journal of structural chemistry 64(2023), 9 vom: Sept., Seite 1664-1676 volume:64 year:2023 number:9 month:09 pages:1664-1676
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	coordination polymer copper carboxylate water cluster supramolecular structure solvothermal Hirshfield.
isfreeaccess_bool	false
container_title	Journal of structural chemistry
authorswithroles_txt_mv	Nath, J. K. @@aut@@
publishDateDaySort_date	2023-09-01T00:00:00Z
hierarchy_top_id	325573530
id	SPR053248848
language_de	englisch
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One is a 1D polymer {[Cu(bpy)(NDC)($ H_{2} $O)]·$ 2H_{2} $O}n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid ($ H_{2} $NDC) and 2,2′-bipyridine (bpy) as an auxiliary ligand, while the other is a 2D polymer {[$ Cu_{3} $(TMA) (Imd)3]·$ 5H_{2} $O·2DMF}n (2, 2D) formed with trimellitic acid ($ H_{3} $TMA) and imidazole (Imd) as an auxiliary ligand. Both coordination polymers 1 and 2 were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride and trimelitic anhydride with bipyridine and imidazole ligands, respectively. The asymmetric unit of polymer 1 contains asymmetric $ η^{1} $ binding mode (one of the carboxylate) linking distorted square-pyramidal [Cu(NDC)(bpy)($ H_{2} $O)]2+ coordination units. The syn-syn-$ η^{1} $:$ η^{1} $ linear polymeric conformation exist in the 1D coordination polymer with adjacent Cu…Cu distance is 6.849 Å. A chain of cyclic tetrameric water clusters is present between the stacked layers of the 3D supramolecular structure. The formation of the 3D supramolecular structure is guided by various weak interactions such as O–H…O, C–H…O, C–H…π and π…π interactions. The coordination polymer 2 forms 3D supramolecular architecture guided by various weak interactions such as O–H…O, C–H…O and N–H…O interactions. 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author	Nath, J. K.
spellingShingle	Nath, J. K. misc coordination polymer misc copper carboxylate misc water cluster misc supramolecular structure misc solvothermal misc Hirshfield. SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II)
authorStr	Nath, J. K.
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topic_title	SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II) coordination polymer (dpeaa)DE-He213 copper carboxylate (dpeaa)DE-He213 water cluster (dpeaa)DE-He213 supramolecular structure (dpeaa)DE-He213 solvothermal (dpeaa)DE-He213 Hirshfield. (dpeaa)DE-He213
topic	misc coordination polymer misc copper carboxylate misc water cluster misc supramolecular structure misc solvothermal misc Hirshfield.
topic_unstemmed	misc coordination polymer misc copper carboxylate misc water cluster misc supramolecular structure misc solvothermal misc Hirshfield.
topic_browse	misc coordination polymer misc copper carboxylate misc water cluster misc supramolecular structure misc solvothermal misc Hirshfield.
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title	SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II)
ctrlnum	(DE-627)SPR053248848 (SPR)S002247662309010X-e
title_full	SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II)
author_sort	Nath, J. K.
journal	Journal of structural chemistry
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author_browse	Nath, J. K.
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author-letter	Nath, J. K.
doi_str_mv	10.1134/S002247662309010X
title_sort	syntheses, structural insight and hirshfeld surface analysis of two heteroleptic coordination polymer of cu(ii)
title_auth	SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II)
abstract	Abstract Using a solvothermal method, we have synthesized two coordination polymers of Cu(II). One is a 1D polymer {[Cu(bpy)(NDC)($ H_{2} $O)]·$ 2H_{2} $O}n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid ($ H_{2} $NDC) and 2,2′-bipyridine (bpy) as an auxiliary ligand, while the other is a 2D polymer {[$ Cu_{3} $(TMA) (Imd)3]·$ 5H_{2} $O·2DMF}n (2, 2D) formed with trimellitic acid ($ H_{3} $TMA) and imidazole (Imd) as an auxiliary ligand. Both coordination polymers 1 and 2 were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride and trimelitic anhydride with bipyridine and imidazole ligands, respectively. The asymmetric unit of polymer 1 contains asymmetric $ η^{1} $ binding mode (one of the carboxylate) linking distorted square-pyramidal [Cu(NDC)(bpy)($ H_{2} $O)]2+ coordination units. The syn-syn-$ η^{1} $:$ η^{1} $ linear polymeric conformation exist in the 1D coordination polymer with adjacent Cu…Cu distance is 6.849 Å. A chain of cyclic tetrameric water clusters is present between the stacked layers of the 3D supramolecular structure. The formation of the 3D supramolecular structure is guided by various weak interactions such as O–H…O, C–H…O, C–H…π and π…π interactions. The coordination polymer 2 forms 3D supramolecular architecture guided by various weak interactions such as O–H…O, C–H…O and N–H…O interactions. The crystal structures of both coordination polymers have been determined using single crystal X-ray diffraction and their structural features are described. © Pleiades Publishing, Ltd. 2023
abstractGer	Abstract Using a solvothermal method, we have synthesized two coordination polymers of Cu(II). One is a 1D polymer {[Cu(bpy)(NDC)($ H_{2} $O)]·$ 2H_{2} $O}n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid ($ H_{2} $NDC) and 2,2′-bipyridine (bpy) as an auxiliary ligand, while the other is a 2D polymer {[$ Cu_{3} $(TMA) (Imd)3]·$ 5H_{2} $O·2DMF}n (2, 2D) formed with trimellitic acid ($ H_{3} $TMA) and imidazole (Imd) as an auxiliary ligand. Both coordination polymers 1 and 2 were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride and trimelitic anhydride with bipyridine and imidazole ligands, respectively. The asymmetric unit of polymer 1 contains asymmetric $ η^{1} $ binding mode (one of the carboxylate) linking distorted square-pyramidal [Cu(NDC)(bpy)($ H_{2} $O)]2+ coordination units. The syn-syn-$ η^{1} $:$ η^{1} $ linear polymeric conformation exist in the 1D coordination polymer with adjacent Cu…Cu distance is 6.849 Å. A chain of cyclic tetrameric water clusters is present between the stacked layers of the 3D supramolecular structure. The formation of the 3D supramolecular structure is guided by various weak interactions such as O–H…O, C–H…O, C–H…π and π…π interactions. The coordination polymer 2 forms 3D supramolecular architecture guided by various weak interactions such as O–H…O, C–H…O and N–H…O interactions. The crystal structures of both coordination polymers have been determined using single crystal X-ray diffraction and their structural features are described. © Pleiades Publishing, Ltd. 2023
abstract_unstemmed	Abstract Using a solvothermal method, we have synthesized two coordination polymers of Cu(II). One is a 1D polymer {[Cu(bpy)(NDC)($ H_{2} $O)]·$ 2H_{2} $O}n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid ($ H_{2} $NDC) and 2,2′-bipyridine (bpy) as an auxiliary ligand, while the other is a 2D polymer {[$ Cu_{3} $(TMA) (Imd)3]·$ 5H_{2} $O·2DMF}n (2, 2D) formed with trimellitic acid ($ H_{3} $TMA) and imidazole (Imd) as an auxiliary ligand. Both coordination polymers 1 and 2 were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride and trimelitic anhydride with bipyridine and imidazole ligands, respectively. The asymmetric unit of polymer 1 contains asymmetric $ η^{1} $ binding mode (one of the carboxylate) linking distorted square-pyramidal [Cu(NDC)(bpy)($ H_{2} $O)]2+ coordination units. The syn-syn-$ η^{1} $:$ η^{1} $ linear polymeric conformation exist in the 1D coordination polymer with adjacent Cu…Cu distance is 6.849 Å. A chain of cyclic tetrameric water clusters is present between the stacked layers of the 3D supramolecular structure. The formation of the 3D supramolecular structure is guided by various weak interactions such as O–H…O, C–H…O, C–H…π and π…π interactions. The coordination polymer 2 forms 3D supramolecular architecture guided by various weak interactions such as O–H…O, C–H…O and N–H…O interactions. The crystal structures of both coordination polymers have been determined using single crystal X-ray diffraction and their structural features are described. © Pleiades Publishing, Ltd. 2023
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container_issue	9
title_short	SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II)
url	https://dx.doi.org/10.1134/S002247662309010X
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doi_str	10.1134/S002247662309010X
up_date	2024-07-03T18:08:57.611Z
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One is a 1D polymer {[Cu(bpy)(NDC)($ H_{2} $O)]·$ 2H_{2} $O}n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid ($ H_{2} $NDC) and 2,2′-bipyridine (bpy) as an auxiliary ligand, while the other is a 2D polymer {[$ Cu_{3} $(TMA) (Imd)3]·$ 5H_{2} $O·2DMF}n (2, 2D) formed with trimellitic acid ($ H_{3} $TMA) and imidazole (Imd) as an auxiliary ligand. Both coordination polymers 1 and 2 were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride and trimelitic anhydride with bipyridine and imidazole ligands, respectively. The asymmetric unit of polymer 1 contains asymmetric $ η^{1} $ binding mode (one of the carboxylate) linking distorted square-pyramidal [Cu(NDC)(bpy)($ H_{2} $O)]2+ coordination units. The syn-syn-$ η^{1} $:$ η^{1} $ linear polymeric conformation exist in the 1D coordination polymer with adjacent Cu…Cu distance is 6.849 Å. 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SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II)

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