Dispersity Regulation in Photo-controlled Radical Polymerization by Merging Aryl Sulfonyl Chloride Initiators and Mixed Disulfide Agents
Abstract On-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an organocatalyzed photo-controlled radical polymerization (photo-CRP) from the tosyl chloride initiator by combining two disulfides as chain transfer ag...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhang, Lu [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Schlagwörter: |
Reversible deactivation radical polymerization |
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| Anmerkung: |
© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2023 |
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| Übergeordnetes Werk: |
Enthalten in: Chemical Research in Chinese Universities - Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012, 39(2023), 5 vom: 11. Sept., Seite 816-821 |
|---|---|
| Übergeordnetes Werk: |
volume:39 ; year:2023 ; number:5 ; day:11 ; month:09 ; pages:816-821 |
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| DOI / URN: |
10.1007/s40242-023-3171-5 |
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SPR053299086 |
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| 520 | |a Abstract On-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an organocatalyzed photo-controlled radical polymerization (photo-CRP) from the tosyl chloride initiator by combining two disulfides as chain transfer agents. This novel synthetic protocol allows facile access toward well-defined polymers with tunable MWDs and predetermined molecular weights. Experiments including structural characterization, kinetic investigation and chain-extension polymerization exhibited good chain-growth control for polymers of different dispersities. Given the easy accessibility of the initiating site (sulfonyl chloride) on many aromatic sources, this work presents a promising avenue to modify such substances with polymers of tailored MWDs, chain lengths and repeating units under metal-free and mild conditions driven by light. | ||
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10.1007/s40242-023-3171-5 doi (DE-627)SPR053299086 (SPR)s40242-023-3171-5-e DE-627 ger DE-627 rakwb eng Zhang, Lu verfasserin aut Dispersity Regulation in Photo-controlled Radical Polymerization by Merging Aryl Sulfonyl Chloride Initiators and Mixed Disulfide Agents 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2023 Abstract On-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an organocatalyzed photo-controlled radical polymerization (photo-CRP) from the tosyl chloride initiator by combining two disulfides as chain transfer agents. This novel synthetic protocol allows facile access toward well-defined polymers with tunable MWDs and predetermined molecular weights. Experiments including structural characterization, kinetic investigation and chain-extension polymerization exhibited good chain-growth control for polymers of different dispersities. Given the easy accessibility of the initiating site (sulfonyl chloride) on many aromatic sources, this work presents a promising avenue to modify such substances with polymers of tailored MWDs, chain lengths and repeating units under metal-free and mild conditions driven by light. Reversible deactivation radical polymerization (dpeaa)DE-He213 Photo-controlled radical polymerization (dpeaa)DE-He213 Organocatalyst (dpeaa)DE-He213 Molecular weight distribution (dpeaa)DE-He213 Polymer chemistry (dpeaa)DE-He213 Zhang, Zexi aut Chen, Mao aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 39(2023), 5 vom: 11. Sept., Seite 816-821 (DE-627)SPR03290777X nnns volume:39 year:2023 number:5 day:11 month:09 pages:816-821 https://dx.doi.org/10.1007/s40242-023-3171-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER AR 39 2023 5 11 09 816-821 |
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10.1007/s40242-023-3171-5 doi (DE-627)SPR053299086 (SPR)s40242-023-3171-5-e DE-627 ger DE-627 rakwb eng Zhang, Lu verfasserin aut Dispersity Regulation in Photo-controlled Radical Polymerization by Merging Aryl Sulfonyl Chloride Initiators and Mixed Disulfide Agents 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2023 Abstract On-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an organocatalyzed photo-controlled radical polymerization (photo-CRP) from the tosyl chloride initiator by combining two disulfides as chain transfer agents. This novel synthetic protocol allows facile access toward well-defined polymers with tunable MWDs and predetermined molecular weights. Experiments including structural characterization, kinetic investigation and chain-extension polymerization exhibited good chain-growth control for polymers of different dispersities. Given the easy accessibility of the initiating site (sulfonyl chloride) on many aromatic sources, this work presents a promising avenue to modify such substances with polymers of tailored MWDs, chain lengths and repeating units under metal-free and mild conditions driven by light. Reversible deactivation radical polymerization (dpeaa)DE-He213 Photo-controlled radical polymerization (dpeaa)DE-He213 Organocatalyst (dpeaa)DE-He213 Molecular weight distribution (dpeaa)DE-He213 Polymer chemistry (dpeaa)DE-He213 Zhang, Zexi aut Chen, Mao aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 39(2023), 5 vom: 11. Sept., Seite 816-821 (DE-627)SPR03290777X nnns volume:39 year:2023 number:5 day:11 month:09 pages:816-821 https://dx.doi.org/10.1007/s40242-023-3171-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER AR 39 2023 5 11 09 816-821 |
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10.1007/s40242-023-3171-5 doi (DE-627)SPR053299086 (SPR)s40242-023-3171-5-e DE-627 ger DE-627 rakwb eng Zhang, Lu verfasserin aut Dispersity Regulation in Photo-controlled Radical Polymerization by Merging Aryl Sulfonyl Chloride Initiators and Mixed Disulfide Agents 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2023 Abstract On-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an organocatalyzed photo-controlled radical polymerization (photo-CRP) from the tosyl chloride initiator by combining two disulfides as chain transfer agents. This novel synthetic protocol allows facile access toward well-defined polymers with tunable MWDs and predetermined molecular weights. Experiments including structural characterization, kinetic investigation and chain-extension polymerization exhibited good chain-growth control for polymers of different dispersities. Given the easy accessibility of the initiating site (sulfonyl chloride) on many aromatic sources, this work presents a promising avenue to modify such substances with polymers of tailored MWDs, chain lengths and repeating units under metal-free and mild conditions driven by light. Reversible deactivation radical polymerization (dpeaa)DE-He213 Photo-controlled radical polymerization (dpeaa)DE-He213 Organocatalyst (dpeaa)DE-He213 Molecular weight distribution (dpeaa)DE-He213 Polymer chemistry (dpeaa)DE-He213 Zhang, Zexi aut Chen, Mao aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 39(2023), 5 vom: 11. Sept., Seite 816-821 (DE-627)SPR03290777X nnns volume:39 year:2023 number:5 day:11 month:09 pages:816-821 https://dx.doi.org/10.1007/s40242-023-3171-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER AR 39 2023 5 11 09 816-821 |
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10.1007/s40242-023-3171-5 doi (DE-627)SPR053299086 (SPR)s40242-023-3171-5-e DE-627 ger DE-627 rakwb eng Zhang, Lu verfasserin aut Dispersity Regulation in Photo-controlled Radical Polymerization by Merging Aryl Sulfonyl Chloride Initiators and Mixed Disulfide Agents 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2023 Abstract On-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an organocatalyzed photo-controlled radical polymerization (photo-CRP) from the tosyl chloride initiator by combining two disulfides as chain transfer agents. This novel synthetic protocol allows facile access toward well-defined polymers with tunable MWDs and predetermined molecular weights. Experiments including structural characterization, kinetic investigation and chain-extension polymerization exhibited good chain-growth control for polymers of different dispersities. Given the easy accessibility of the initiating site (sulfonyl chloride) on many aromatic sources, this work presents a promising avenue to modify such substances with polymers of tailored MWDs, chain lengths and repeating units under metal-free and mild conditions driven by light. Reversible deactivation radical polymerization (dpeaa)DE-He213 Photo-controlled radical polymerization (dpeaa)DE-He213 Organocatalyst (dpeaa)DE-He213 Molecular weight distribution (dpeaa)DE-He213 Polymer chemistry (dpeaa)DE-He213 Zhang, Zexi aut Chen, Mao aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 39(2023), 5 vom: 11. Sept., Seite 816-821 (DE-627)SPR03290777X nnns volume:39 year:2023 number:5 day:11 month:09 pages:816-821 https://dx.doi.org/10.1007/s40242-023-3171-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER AR 39 2023 5 11 09 816-821 |
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10.1007/s40242-023-3171-5 doi (DE-627)SPR053299086 (SPR)s40242-023-3171-5-e DE-627 ger DE-627 rakwb eng Zhang, Lu verfasserin aut Dispersity Regulation in Photo-controlled Radical Polymerization by Merging Aryl Sulfonyl Chloride Initiators and Mixed Disulfide Agents 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2023 Abstract On-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an organocatalyzed photo-controlled radical polymerization (photo-CRP) from the tosyl chloride initiator by combining two disulfides as chain transfer agents. This novel synthetic protocol allows facile access toward well-defined polymers with tunable MWDs and predetermined molecular weights. Experiments including structural characterization, kinetic investigation and chain-extension polymerization exhibited good chain-growth control for polymers of different dispersities. Given the easy accessibility of the initiating site (sulfonyl chloride) on many aromatic sources, this work presents a promising avenue to modify such substances with polymers of tailored MWDs, chain lengths and repeating units under metal-free and mild conditions driven by light. Reversible deactivation radical polymerization (dpeaa)DE-He213 Photo-controlled radical polymerization (dpeaa)DE-He213 Organocatalyst (dpeaa)DE-He213 Molecular weight distribution (dpeaa)DE-He213 Polymer chemistry (dpeaa)DE-He213 Zhang, Zexi aut Chen, Mao aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 39(2023), 5 vom: 11. Sept., Seite 816-821 (DE-627)SPR03290777X nnns volume:39 year:2023 number:5 day:11 month:09 pages:816-821 https://dx.doi.org/10.1007/s40242-023-3171-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER AR 39 2023 5 11 09 816-821 |
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Dispersity Regulation in Photo-controlled Radical Polymerization by Merging Aryl Sulfonyl Chloride Initiators and Mixed Disulfide Agents Reversible deactivation radical polymerization (dpeaa)DE-He213 Photo-controlled radical polymerization (dpeaa)DE-He213 Organocatalyst (dpeaa)DE-He213 Molecular weight distribution (dpeaa)DE-He213 Polymer chemistry (dpeaa)DE-He213 |
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Abstract On-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an organocatalyzed photo-controlled radical polymerization (photo-CRP) from the tosyl chloride initiator by combining two disulfides as chain transfer agents. This novel synthetic protocol allows facile access toward well-defined polymers with tunable MWDs and predetermined molecular weights. Experiments including structural characterization, kinetic investigation and chain-extension polymerization exhibited good chain-growth control for polymers of different dispersities. Given the easy accessibility of the initiating site (sulfonyl chloride) on many aromatic sources, this work presents a promising avenue to modify such substances with polymers of tailored MWDs, chain lengths and repeating units under metal-free and mild conditions driven by light. © Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2023 |
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Abstract On-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an organocatalyzed photo-controlled radical polymerization (photo-CRP) from the tosyl chloride initiator by combining two disulfides as chain transfer agents. This novel synthetic protocol allows facile access toward well-defined polymers with tunable MWDs and predetermined molecular weights. Experiments including structural characterization, kinetic investigation and chain-extension polymerization exhibited good chain-growth control for polymers of different dispersities. Given the easy accessibility of the initiating site (sulfonyl chloride) on many aromatic sources, this work presents a promising avenue to modify such substances with polymers of tailored MWDs, chain lengths and repeating units under metal-free and mild conditions driven by light. © Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2023 |
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Abstract On-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an organocatalyzed photo-controlled radical polymerization (photo-CRP) from the tosyl chloride initiator by combining two disulfides as chain transfer agents. This novel synthetic protocol allows facile access toward well-defined polymers with tunable MWDs and predetermined molecular weights. Experiments including structural characterization, kinetic investigation and chain-extension polymerization exhibited good chain-growth control for polymers of different dispersities. Given the easy accessibility of the initiating site (sulfonyl chloride) on many aromatic sources, this work presents a promising avenue to modify such substances with polymers of tailored MWDs, chain lengths and repeating units under metal-free and mild conditions driven by light. © Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2023 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR053299086</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20231006062610.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">231006s2023 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s40242-023-3171-5</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR053299086</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s40242-023-3171-5-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zhang, Lu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Dispersity Regulation in Photo-controlled Radical Polymerization by Merging Aryl Sulfonyl Chloride Initiators and Mixed Disulfide Agents</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2023</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract On-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an organocatalyzed photo-controlled radical polymerization (photo-CRP) from the tosyl chloride initiator by combining two disulfides as chain transfer agents. This novel synthetic protocol allows facile access toward well-defined polymers with tunable MWDs and predetermined molecular weights. Experiments including structural characterization, kinetic investigation and chain-extension polymerization exhibited good chain-growth control for polymers of different dispersities. Given the easy accessibility of the initiating site (sulfonyl chloride) on many aromatic sources, this work presents a promising avenue to modify such substances with polymers of tailored MWDs, chain lengths and repeating units under metal-free and mild conditions driven by light.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Reversible deactivation radical polymerization</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Photo-controlled radical polymerization</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Organocatalyst</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Molecular weight distribution</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polymer chemistry</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Zexi</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chen, Mao</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Chemical Research in Chinese Universities</subfield><subfield code="d">Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012</subfield><subfield code="g">39(2023), 5 vom: 11. Sept., Seite 816-821</subfield><subfield code="w">(DE-627)SPR03290777X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:39</subfield><subfield code="g">year:2023</subfield><subfield code="g">number:5</subfield><subfield code="g">day:11</subfield><subfield code="g">month:09</subfield><subfield code="g">pages:816-821</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s40242-023-3171-5</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">39</subfield><subfield code="j">2023</subfield><subfield code="e">5</subfield><subfield code="b">11</subfield><subfield code="c">09</subfield><subfield code="h">816-821</subfield></datafield></record></collection>
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