Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite
The emergence of toxic pollutants due to heavy human intervention in the ecosystem causes serious environmental problems. Therefore, sensors based on material having a strong affinity towards specific environmental gaseous pollutants are urgently needed. The present study deals with chemiresistive g...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Khune, Abhaysinh S. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s) 2023 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of electronic materials - Warrendale, Pa : TMS, 1972, 52(2023), 12 vom: 29. Sept., Seite 8108-8123 |
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| Übergeordnetes Werk: |
volume:52 ; year:2023 ; number:12 ; day:29 ; month:09 ; pages:8108-8123 |
| Links: |
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| DOI / URN: |
10.1007/s11664-023-10711-4 |
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| Katalog-ID: |
SPR053600800 |
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| 245 | 1 | 0 | |a Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite |
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| 520 | |a The emergence of toxic pollutants due to heavy human intervention in the ecosystem causes serious environmental problems. Therefore, sensors based on material having a strong affinity towards specific environmental gaseous pollutants are urgently needed. The present study deals with chemiresistive gas sensors for the detection of sulfur dioxide ($ SO_{2} $) based on a composite of reduced graphene oxide (rGO) and 5,10,15,20-tetrakis(4-aminophenyl) porphyrin (TAPP). The improved Hummers method was used to synthesize graphene oxide (GO); it was further thermally reduced to rGO. The pattern of the copper electrode was coated on glass slides with a shadow mask using thermal evaporation. Then, GO was drop-cast between the two copper electrodes, thermally reduced to obtain rGO, and then modified by TAPP. The spectroscopic, structural, morphological, electrical, and optical studies were carried out using Fourier transform infrared spectroscopy, x-ray diffraction, Raman spectroscopy, atomic force microscopy, field emission scanning electron microscopy, current–voltage (I–V) and UV–visible spectroscopy, respectively. The developed sensor shows high selectivity towards $ SO_{2} $ gas analytes among exposed gaseous analytes. It exhibited reproducible response from 50 ppm to 200 ppm with enhanced repeatability at 50 ppm. The rGO/TAPP sensor exhibited a significant response (57 s) and recovery time (61 s), with a 5 ppm limit of detection. Graphical Abstract | ||
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| 650 | 4 | |a SO |7 (dpeaa)DE-He213 | |
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| 700 | 1 | |a Padghan, Vikky |4 aut | |
| 700 | 1 | |a Bongane, Rameshwar |4 aut | |
| 700 | 1 | |a Narwade, Vijaykiran N. |4 aut | |
| 700 | 1 | |a Dole, B. N. |4 aut | |
| 700 | 1 | |a Ingle, Nikesh N. |4 aut | |
| 700 | 1 | |a Tsai, Meng-Lin |4 aut | |
| 700 | 1 | |a Hianik, Tibor |4 aut | |
| 700 | 1 | |a Shirsat, Mahendra D. |0 (orcid)0000-0002-4216-2919 |4 aut | |
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10.1007/s11664-023-10711-4 doi (DE-627)SPR053600800 (SPR)s11664-023-10711-4-e DE-627 ger DE-627 rakwb eng Khune, Abhaysinh S. verfasserin aut Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2023 The emergence of toxic pollutants due to heavy human intervention in the ecosystem causes serious environmental problems. Therefore, sensors based on material having a strong affinity towards specific environmental gaseous pollutants are urgently needed. The present study deals with chemiresistive gas sensors for the detection of sulfur dioxide ($ SO_{2} $) based on a composite of reduced graphene oxide (rGO) and 5,10,15,20-tetrakis(4-aminophenyl) porphyrin (TAPP). The improved Hummers method was used to synthesize graphene oxide (GO); it was further thermally reduced to rGO. The pattern of the copper electrode was coated on glass slides with a shadow mask using thermal evaporation. Then, GO was drop-cast between the two copper electrodes, thermally reduced to obtain rGO, and then modified by TAPP. The spectroscopic, structural, morphological, electrical, and optical studies were carried out using Fourier transform infrared spectroscopy, x-ray diffraction, Raman spectroscopy, atomic force microscopy, field emission scanning electron microscopy, current–voltage (I–V) and UV–visible spectroscopy, respectively. The developed sensor shows high selectivity towards $ SO_{2} $ gas analytes among exposed gaseous analytes. It exhibited reproducible response from 50 ppm to 200 ppm with enhanced repeatability at 50 ppm. The rGO/TAPP sensor exhibited a significant response (57 s) and recovery time (61 s), with a 5 ppm limit of detection. Graphical Abstract Gas sensor (dpeaa)DE-He213 graphene (dpeaa)DE-He213 porphyrin (dpeaa)DE-He213 response time (dpeaa)DE-He213 sensitivity (dpeaa)DE-He213 SO (dpeaa)DE-He213 gas (dpeaa)DE-He213 Padghan, Vikky aut Bongane, Rameshwar aut Narwade, Vijaykiran N. aut Dole, B. N. aut Ingle, Nikesh N. aut Tsai, Meng-Lin aut Hianik, Tibor aut Shirsat, Mahendra D. (orcid)0000-0002-4216-2919 aut Enthalten in Journal of electronic materials Warrendale, Pa : TMS, 1972 52(2023), 12 vom: 29. Sept., Seite 8108-8123 (DE-627)324918739 (DE-600)2032868-0 1543-186X nnns volume:52 year:2023 number:12 day:29 month:09 pages:8108-8123 https://dx.doi.org/10.1007/s11664-023-10711-4 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2023 12 29 09 8108-8123 |
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10.1007/s11664-023-10711-4 doi (DE-627)SPR053600800 (SPR)s11664-023-10711-4-e DE-627 ger DE-627 rakwb eng Khune, Abhaysinh S. verfasserin aut Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2023 The emergence of toxic pollutants due to heavy human intervention in the ecosystem causes serious environmental problems. Therefore, sensors based on material having a strong affinity towards specific environmental gaseous pollutants are urgently needed. The present study deals with chemiresistive gas sensors for the detection of sulfur dioxide ($ SO_{2} $) based on a composite of reduced graphene oxide (rGO) and 5,10,15,20-tetrakis(4-aminophenyl) porphyrin (TAPP). The improved Hummers method was used to synthesize graphene oxide (GO); it was further thermally reduced to rGO. The pattern of the copper electrode was coated on glass slides with a shadow mask using thermal evaporation. Then, GO was drop-cast between the two copper electrodes, thermally reduced to obtain rGO, and then modified by TAPP. The spectroscopic, structural, morphological, electrical, and optical studies were carried out using Fourier transform infrared spectroscopy, x-ray diffraction, Raman spectroscopy, atomic force microscopy, field emission scanning electron microscopy, current–voltage (I–V) and UV–visible spectroscopy, respectively. The developed sensor shows high selectivity towards $ SO_{2} $ gas analytes among exposed gaseous analytes. It exhibited reproducible response from 50 ppm to 200 ppm with enhanced repeatability at 50 ppm. The rGO/TAPP sensor exhibited a significant response (57 s) and recovery time (61 s), with a 5 ppm limit of detection. Graphical Abstract Gas sensor (dpeaa)DE-He213 graphene (dpeaa)DE-He213 porphyrin (dpeaa)DE-He213 response time (dpeaa)DE-He213 sensitivity (dpeaa)DE-He213 SO (dpeaa)DE-He213 gas (dpeaa)DE-He213 Padghan, Vikky aut Bongane, Rameshwar aut Narwade, Vijaykiran N. aut Dole, B. N. aut Ingle, Nikesh N. aut Tsai, Meng-Lin aut Hianik, Tibor aut Shirsat, Mahendra D. (orcid)0000-0002-4216-2919 aut Enthalten in Journal of electronic materials Warrendale, Pa : TMS, 1972 52(2023), 12 vom: 29. Sept., Seite 8108-8123 (DE-627)324918739 (DE-600)2032868-0 1543-186X nnns volume:52 year:2023 number:12 day:29 month:09 pages:8108-8123 https://dx.doi.org/10.1007/s11664-023-10711-4 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2023 12 29 09 8108-8123 |
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10.1007/s11664-023-10711-4 doi (DE-627)SPR053600800 (SPR)s11664-023-10711-4-e DE-627 ger DE-627 rakwb eng Khune, Abhaysinh S. verfasserin aut Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2023 The emergence of toxic pollutants due to heavy human intervention in the ecosystem causes serious environmental problems. Therefore, sensors based on material having a strong affinity towards specific environmental gaseous pollutants are urgently needed. The present study deals with chemiresistive gas sensors for the detection of sulfur dioxide ($ SO_{2} $) based on a composite of reduced graphene oxide (rGO) and 5,10,15,20-tetrakis(4-aminophenyl) porphyrin (TAPP). The improved Hummers method was used to synthesize graphene oxide (GO); it was further thermally reduced to rGO. The pattern of the copper electrode was coated on glass slides with a shadow mask using thermal evaporation. Then, GO was drop-cast between the two copper electrodes, thermally reduced to obtain rGO, and then modified by TAPP. The spectroscopic, structural, morphological, electrical, and optical studies were carried out using Fourier transform infrared spectroscopy, x-ray diffraction, Raman spectroscopy, atomic force microscopy, field emission scanning electron microscopy, current–voltage (I–V) and UV–visible spectroscopy, respectively. The developed sensor shows high selectivity towards $ SO_{2} $ gas analytes among exposed gaseous analytes. It exhibited reproducible response from 50 ppm to 200 ppm with enhanced repeatability at 50 ppm. The rGO/TAPP sensor exhibited a significant response (57 s) and recovery time (61 s), with a 5 ppm limit of detection. Graphical Abstract Gas sensor (dpeaa)DE-He213 graphene (dpeaa)DE-He213 porphyrin (dpeaa)DE-He213 response time (dpeaa)DE-He213 sensitivity (dpeaa)DE-He213 SO (dpeaa)DE-He213 gas (dpeaa)DE-He213 Padghan, Vikky aut Bongane, Rameshwar aut Narwade, Vijaykiran N. aut Dole, B. N. aut Ingle, Nikesh N. aut Tsai, Meng-Lin aut Hianik, Tibor aut Shirsat, Mahendra D. (orcid)0000-0002-4216-2919 aut Enthalten in Journal of electronic materials Warrendale, Pa : TMS, 1972 52(2023), 12 vom: 29. Sept., Seite 8108-8123 (DE-627)324918739 (DE-600)2032868-0 1543-186X nnns volume:52 year:2023 number:12 day:29 month:09 pages:8108-8123 https://dx.doi.org/10.1007/s11664-023-10711-4 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2023 12 29 09 8108-8123 |
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10.1007/s11664-023-10711-4 doi (DE-627)SPR053600800 (SPR)s11664-023-10711-4-e DE-627 ger DE-627 rakwb eng Khune, Abhaysinh S. verfasserin aut Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2023 The emergence of toxic pollutants due to heavy human intervention in the ecosystem causes serious environmental problems. Therefore, sensors based on material having a strong affinity towards specific environmental gaseous pollutants are urgently needed. The present study deals with chemiresistive gas sensors for the detection of sulfur dioxide ($ SO_{2} $) based on a composite of reduced graphene oxide (rGO) and 5,10,15,20-tetrakis(4-aminophenyl) porphyrin (TAPP). The improved Hummers method was used to synthesize graphene oxide (GO); it was further thermally reduced to rGO. The pattern of the copper electrode was coated on glass slides with a shadow mask using thermal evaporation. Then, GO was drop-cast between the two copper electrodes, thermally reduced to obtain rGO, and then modified by TAPP. The spectroscopic, structural, morphological, electrical, and optical studies were carried out using Fourier transform infrared spectroscopy, x-ray diffraction, Raman spectroscopy, atomic force microscopy, field emission scanning electron microscopy, current–voltage (I–V) and UV–visible spectroscopy, respectively. The developed sensor shows high selectivity towards $ SO_{2} $ gas analytes among exposed gaseous analytes. It exhibited reproducible response from 50 ppm to 200 ppm with enhanced repeatability at 50 ppm. The rGO/TAPP sensor exhibited a significant response (57 s) and recovery time (61 s), with a 5 ppm limit of detection. Graphical Abstract Gas sensor (dpeaa)DE-He213 graphene (dpeaa)DE-He213 porphyrin (dpeaa)DE-He213 response time (dpeaa)DE-He213 sensitivity (dpeaa)DE-He213 SO (dpeaa)DE-He213 gas (dpeaa)DE-He213 Padghan, Vikky aut Bongane, Rameshwar aut Narwade, Vijaykiran N. aut Dole, B. N. aut Ingle, Nikesh N. aut Tsai, Meng-Lin aut Hianik, Tibor aut Shirsat, Mahendra D. (orcid)0000-0002-4216-2919 aut Enthalten in Journal of electronic materials Warrendale, Pa : TMS, 1972 52(2023), 12 vom: 29. Sept., Seite 8108-8123 (DE-627)324918739 (DE-600)2032868-0 1543-186X nnns volume:52 year:2023 number:12 day:29 month:09 pages:8108-8123 https://dx.doi.org/10.1007/s11664-023-10711-4 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2023 12 29 09 8108-8123 |
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10.1007/s11664-023-10711-4 doi (DE-627)SPR053600800 (SPR)s11664-023-10711-4-e DE-627 ger DE-627 rakwb eng Khune, Abhaysinh S. verfasserin aut Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2023 The emergence of toxic pollutants due to heavy human intervention in the ecosystem causes serious environmental problems. Therefore, sensors based on material having a strong affinity towards specific environmental gaseous pollutants are urgently needed. The present study deals with chemiresistive gas sensors for the detection of sulfur dioxide ($ SO_{2} $) based on a composite of reduced graphene oxide (rGO) and 5,10,15,20-tetrakis(4-aminophenyl) porphyrin (TAPP). The improved Hummers method was used to synthesize graphene oxide (GO); it was further thermally reduced to rGO. The pattern of the copper electrode was coated on glass slides with a shadow mask using thermal evaporation. Then, GO was drop-cast between the two copper electrodes, thermally reduced to obtain rGO, and then modified by TAPP. The spectroscopic, structural, morphological, electrical, and optical studies were carried out using Fourier transform infrared spectroscopy, x-ray diffraction, Raman spectroscopy, atomic force microscopy, field emission scanning electron microscopy, current–voltage (I–V) and UV–visible spectroscopy, respectively. The developed sensor shows high selectivity towards $ SO_{2} $ gas analytes among exposed gaseous analytes. It exhibited reproducible response from 50 ppm to 200 ppm with enhanced repeatability at 50 ppm. The rGO/TAPP sensor exhibited a significant response (57 s) and recovery time (61 s), with a 5 ppm limit of detection. Graphical Abstract Gas sensor (dpeaa)DE-He213 graphene (dpeaa)DE-He213 porphyrin (dpeaa)DE-He213 response time (dpeaa)DE-He213 sensitivity (dpeaa)DE-He213 SO (dpeaa)DE-He213 gas (dpeaa)DE-He213 Padghan, Vikky aut Bongane, Rameshwar aut Narwade, Vijaykiran N. aut Dole, B. N. aut Ingle, Nikesh N. aut Tsai, Meng-Lin aut Hianik, Tibor aut Shirsat, Mahendra D. (orcid)0000-0002-4216-2919 aut Enthalten in Journal of electronic materials Warrendale, Pa : TMS, 1972 52(2023), 12 vom: 29. Sept., Seite 8108-8123 (DE-627)324918739 (DE-600)2032868-0 1543-186X nnns volume:52 year:2023 number:12 day:29 month:09 pages:8108-8123 https://dx.doi.org/10.1007/s11664-023-10711-4 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2023 12 29 09 8108-8123 |
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Enthalten in Journal of electronic materials 52(2023), 12 vom: 29. Sept., Seite 8108-8123 volume:52 year:2023 number:12 day:29 month:09 pages:8108-8123 |
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Khune, Abhaysinh S. @@aut@@ Padghan, Vikky @@aut@@ Bongane, Rameshwar @@aut@@ Narwade, Vijaykiran N. @@aut@@ Dole, B. N. @@aut@@ Ingle, Nikesh N. @@aut@@ Tsai, Meng-Lin @@aut@@ Hianik, Tibor @@aut@@ Shirsat, Mahendra D. @@aut@@ |
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Therefore, sensors based on material having a strong affinity towards specific environmental gaseous pollutants are urgently needed. The present study deals with chemiresistive gas sensors for the detection of sulfur dioxide ($ SO_{2} $) based on a composite of reduced graphene oxide (rGO) and 5,10,15,20-tetrakis(4-aminophenyl) porphyrin (TAPP). The improved Hummers method was used to synthesize graphene oxide (GO); it was further thermally reduced to rGO. The pattern of the copper electrode was coated on glass slides with a shadow mask using thermal evaporation. Then, GO was drop-cast between the two copper electrodes, thermally reduced to obtain rGO, and then modified by TAPP. The spectroscopic, structural, morphological, electrical, and optical studies were carried out using Fourier transform infrared spectroscopy, x-ray diffraction, Raman spectroscopy, atomic force microscopy, field emission scanning electron microscopy, current–voltage (I–V) and UV–visible spectroscopy, respectively. The developed sensor shows high selectivity towards $ SO_{2} $ gas analytes among exposed gaseous analytes. It exhibited reproducible response from 50 ppm to 200 ppm with enhanced repeatability at 50 ppm. The rGO/TAPP sensor exhibited a significant response (57 s) and recovery time (61 s), with a 5 ppm limit of detection. 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|
| author |
Khune, Abhaysinh S. |
| spellingShingle |
Khune, Abhaysinh S. misc Gas sensor misc graphene misc porphyrin misc response time misc sensitivity misc SO misc gas Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite |
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Khune, Abhaysinh S. |
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1543-186X |
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Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite Gas sensor (dpeaa)DE-He213 graphene (dpeaa)DE-He213 porphyrin (dpeaa)DE-He213 response time (dpeaa)DE-He213 sensitivity (dpeaa)DE-He213 SO (dpeaa)DE-He213 gas (dpeaa)DE-He213 |
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misc Gas sensor misc graphene misc porphyrin misc response time misc sensitivity misc SO misc gas |
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Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite |
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Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite |
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Khune, Abhaysinh S. |
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Khune, Abhaysinh S. Padghan, Vikky Bongane, Rameshwar Narwade, Vijaykiran N. Dole, B. N. Ingle, Nikesh N. Tsai, Meng-Lin Hianik, Tibor Shirsat, Mahendra D. |
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Elektronische Aufsätze |
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Khune, Abhaysinh S. |
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10.1007/s11664-023-10711-4 |
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highly selective chemiresistive $ so_{2} $ sensor based on a reduced graphene oxide/porphyrin (rgo/tapp) composite |
| title_auth |
Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite |
| abstract |
The emergence of toxic pollutants due to heavy human intervention in the ecosystem causes serious environmental problems. Therefore, sensors based on material having a strong affinity towards specific environmental gaseous pollutants are urgently needed. The present study deals with chemiresistive gas sensors for the detection of sulfur dioxide ($ SO_{2} $) based on a composite of reduced graphene oxide (rGO) and 5,10,15,20-tetrakis(4-aminophenyl) porphyrin (TAPP). The improved Hummers method was used to synthesize graphene oxide (GO); it was further thermally reduced to rGO. The pattern of the copper electrode was coated on glass slides with a shadow mask using thermal evaporation. Then, GO was drop-cast between the two copper electrodes, thermally reduced to obtain rGO, and then modified by TAPP. The spectroscopic, structural, morphological, electrical, and optical studies were carried out using Fourier transform infrared spectroscopy, x-ray diffraction, Raman spectroscopy, atomic force microscopy, field emission scanning electron microscopy, current–voltage (I–V) and UV–visible spectroscopy, respectively. The developed sensor shows high selectivity towards $ SO_{2} $ gas analytes among exposed gaseous analytes. It exhibited reproducible response from 50 ppm to 200 ppm with enhanced repeatability at 50 ppm. The rGO/TAPP sensor exhibited a significant response (57 s) and recovery time (61 s), with a 5 ppm limit of detection. Graphical Abstract © The Author(s) 2023 |
| abstractGer |
The emergence of toxic pollutants due to heavy human intervention in the ecosystem causes serious environmental problems. Therefore, sensors based on material having a strong affinity towards specific environmental gaseous pollutants are urgently needed. The present study deals with chemiresistive gas sensors for the detection of sulfur dioxide ($ SO_{2} $) based on a composite of reduced graphene oxide (rGO) and 5,10,15,20-tetrakis(4-aminophenyl) porphyrin (TAPP). The improved Hummers method was used to synthesize graphene oxide (GO); it was further thermally reduced to rGO. The pattern of the copper electrode was coated on glass slides with a shadow mask using thermal evaporation. Then, GO was drop-cast between the two copper electrodes, thermally reduced to obtain rGO, and then modified by TAPP. The spectroscopic, structural, morphological, electrical, and optical studies were carried out using Fourier transform infrared spectroscopy, x-ray diffraction, Raman spectroscopy, atomic force microscopy, field emission scanning electron microscopy, current–voltage (I–V) and UV–visible spectroscopy, respectively. The developed sensor shows high selectivity towards $ SO_{2} $ gas analytes among exposed gaseous analytes. It exhibited reproducible response from 50 ppm to 200 ppm with enhanced repeatability at 50 ppm. The rGO/TAPP sensor exhibited a significant response (57 s) and recovery time (61 s), with a 5 ppm limit of detection. Graphical Abstract © The Author(s) 2023 |
| abstract_unstemmed |
The emergence of toxic pollutants due to heavy human intervention in the ecosystem causes serious environmental problems. Therefore, sensors based on material having a strong affinity towards specific environmental gaseous pollutants are urgently needed. The present study deals with chemiresistive gas sensors for the detection of sulfur dioxide ($ SO_{2} $) based on a composite of reduced graphene oxide (rGO) and 5,10,15,20-tetrakis(4-aminophenyl) porphyrin (TAPP). The improved Hummers method was used to synthesize graphene oxide (GO); it was further thermally reduced to rGO. The pattern of the copper electrode was coated on glass slides with a shadow mask using thermal evaporation. Then, GO was drop-cast between the two copper electrodes, thermally reduced to obtain rGO, and then modified by TAPP. The spectroscopic, structural, morphological, electrical, and optical studies were carried out using Fourier transform infrared spectroscopy, x-ray diffraction, Raman spectroscopy, atomic force microscopy, field emission scanning electron microscopy, current–voltage (I–V) and UV–visible spectroscopy, respectively. The developed sensor shows high selectivity towards $ SO_{2} $ gas analytes among exposed gaseous analytes. It exhibited reproducible response from 50 ppm to 200 ppm with enhanced repeatability at 50 ppm. The rGO/TAPP sensor exhibited a significant response (57 s) and recovery time (61 s), with a 5 ppm limit of detection. Graphical Abstract © The Author(s) 2023 |
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Highly Selective Chemiresistive $ SO_{2} $ Sensor Based on a Reduced Graphene Oxide/Porphyrin (rGO/TAPP) Composite |
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https://dx.doi.org/10.1007/s11664-023-10711-4 |
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Padghan, Vikky Bongane, Rameshwar Narwade, Vijaykiran N. Dole, B. N. Ingle, Nikesh N. Tsai, Meng-Lin Hianik, Tibor Shirsat, Mahendra D. |
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Padghan, Vikky Bongane, Rameshwar Narwade, Vijaykiran N. Dole, B. N. Ingle, Nikesh N. Tsai, Meng-Lin Hianik, Tibor Shirsat, Mahendra D. |
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2024-07-03T20:42:16.538Z |
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| score |
7.3986807 |