Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites

Abstract This study reports the synthesis of ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{2−x} %$ Ru_{x} %$ O_{4} $ nanoparticles (NPs), where x = 0.00, 0.005, 0.01, 0.015, 0.02, and 0.04, via co-precipitation method. The synthesized samples were characterized by X-ray diffraction (XRD), transmission...
Ausführliche Beschreibung

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Autor*in:	Kassem, Serine [verfasserIn] Aridi, Amani Awad, Ramadan

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	(Cd Ni Mn )Fe Ru O nanoparticles Ru doping Photoluminescence Photocatalytic performance Nitrobenzene degradation

Anmerkung:	© The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Übergeordnetes Werk:	Enthalten in: Environmental science and pollution research - Berlin : Springer, 1994, 30(2023), 54 vom: 01. Nov., Seite 116202-116213
Übergeordnetes Werk:	volume:30 ; year:2023 ; number:54 ; day:01 ; month:11 ; pages:116202-116213

Links:	Volltext

DOI / URN:	10.1007/s11356-023-30718-y

Katalog-ID:	SPR053874536

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245	1	0	\|a Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites
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520			\|a Abstract This study reports the synthesis of ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{2−x} %$ Ru_{x} %$ O_{4} $ nanoparticles (NPs), where x = 0.00, 0.005, 0.01, 0.015, 0.02, and 0.04, via co-precipitation method. The synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), and photoluminescence (PL) spectroscopy. The results confirmed the purity of the samples with the presence of a very small fraction of the hematite phase. Pseudo-spherical morphology was recognized from TEM images. Then, the prepared samples were further used as effective photocatalysts for the degradation of nitrobenzene under UV irradiation to examine the effect of doping on the photocatalytic activity. Among the synthesized samples, ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs exhibited superior photocatalytic activity. This result is in good agreement with photoluminescence (PL) analysis in which ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs revealed the slowest recombination rate of the electron-hole pair. To further improve the photocatalytic performance, different weight % of graphene was incorporated with ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs. Finally, 81.41% of nitrobenzene was degraded after 180 min in the presence of 5 wt% graphene/($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ nanocomposites, and the degradation rate constant was estimated as 8.4 × $ 10^{−3} $ $ min^{−1} $.
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allfields	10.1007/s11356-023-30718-y doi (DE-627)SPR053874536 (SPR)s11356-023-30718-y-e DE-627 ger DE-627 rakwb eng Kassem, Serine verfasserin aut Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract This study reports the synthesis of ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{2−x} %$ Ru_{x} %$ O_{4} $ nanoparticles (NPs), where x = 0.00, 0.005, 0.01, 0.015, 0.02, and 0.04, via co-precipitation method. The synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), and photoluminescence (PL) spectroscopy. The results confirmed the purity of the samples with the presence of a very small fraction of the hematite phase. Pseudo-spherical morphology was recognized from TEM images. Then, the prepared samples were further used as effective photocatalysts for the degradation of nitrobenzene under UV irradiation to examine the effect of doping on the photocatalytic activity. Among the synthesized samples, ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs exhibited superior photocatalytic activity. This result is in good agreement with photoluminescence (PL) analysis in which ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs revealed the slowest recombination rate of the electron-hole pair. To further improve the photocatalytic performance, different weight % of graphene was incorporated with ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs. Finally, 81.41% of nitrobenzene was degraded after 180 min in the presence of 5 wt% graphene/($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ nanocomposites, and the degradation rate constant was estimated as 8.4 × $ 10^{−3} $ $ min^{−1} $. (Cd (dpeaa)DE-He213 Ni (dpeaa)DE-He213 Mn (dpeaa)DE-He213 )Fe (dpeaa)DE-He213 Ru (dpeaa)DE-He213 O (dpeaa)DE-He213 nanoparticles (dpeaa)DE-He213 Ru doping (dpeaa)DE-He213 Photoluminescence (dpeaa)DE-He213 Photocatalytic performance (dpeaa)DE-He213 Nitrobenzene degradation (dpeaa)DE-He213 Aridi, Amani (orcid)0000-0002-6946-1839 aut Awad, Ramadan aut Enthalten in Environmental science and pollution research Berlin : Springer, 1994 30(2023), 54 vom: 01. Nov., Seite 116202-116213 (DE-627)320517926 (DE-600)2014192-0 1614-7499 nnns volume:30 year:2023 number:54 day:01 month:11 pages:116202-116213 https://dx.doi.org/10.1007/s11356-023-30718-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2023 54 01 11 116202-116213
spelling	10.1007/s11356-023-30718-y doi (DE-627)SPR053874536 (SPR)s11356-023-30718-y-e DE-627 ger DE-627 rakwb eng Kassem, Serine verfasserin aut Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract This study reports the synthesis of ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{2−x} %$ Ru_{x} %$ O_{4} $ nanoparticles (NPs), where x = 0.00, 0.005, 0.01, 0.015, 0.02, and 0.04, via co-precipitation method. The synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), and photoluminescence (PL) spectroscopy. The results confirmed the purity of the samples with the presence of a very small fraction of the hematite phase. Pseudo-spherical morphology was recognized from TEM images. Then, the prepared samples were further used as effective photocatalysts for the degradation of nitrobenzene under UV irradiation to examine the effect of doping on the photocatalytic activity. Among the synthesized samples, ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs exhibited superior photocatalytic activity. This result is in good agreement with photoluminescence (PL) analysis in which ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs revealed the slowest recombination rate of the electron-hole pair. To further improve the photocatalytic performance, different weight % of graphene was incorporated with ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs. Finally, 81.41% of nitrobenzene was degraded after 180 min in the presence of 5 wt% graphene/($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ nanocomposites, and the degradation rate constant was estimated as 8.4 × $ 10^{−3} $ $ min^{−1} $. (Cd (dpeaa)DE-He213 Ni (dpeaa)DE-He213 Mn (dpeaa)DE-He213 )Fe (dpeaa)DE-He213 Ru (dpeaa)DE-He213 O (dpeaa)DE-He213 nanoparticles (dpeaa)DE-He213 Ru doping (dpeaa)DE-He213 Photoluminescence (dpeaa)DE-He213 Photocatalytic performance (dpeaa)DE-He213 Nitrobenzene degradation (dpeaa)DE-He213 Aridi, Amani (orcid)0000-0002-6946-1839 aut Awad, Ramadan aut Enthalten in Environmental science and pollution research Berlin : Springer, 1994 30(2023), 54 vom: 01. Nov., Seite 116202-116213 (DE-627)320517926 (DE-600)2014192-0 1614-7499 nnns volume:30 year:2023 number:54 day:01 month:11 pages:116202-116213 https://dx.doi.org/10.1007/s11356-023-30718-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2023 54 01 11 116202-116213
allfields_unstemmed	10.1007/s11356-023-30718-y doi (DE-627)SPR053874536 (SPR)s11356-023-30718-y-e DE-627 ger DE-627 rakwb eng Kassem, Serine verfasserin aut Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract This study reports the synthesis of ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{2−x} %$ Ru_{x} %$ O_{4} $ nanoparticles (NPs), where x = 0.00, 0.005, 0.01, 0.015, 0.02, and 0.04, via co-precipitation method. The synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), and photoluminescence (PL) spectroscopy. The results confirmed the purity of the samples with the presence of a very small fraction of the hematite phase. Pseudo-spherical morphology was recognized from TEM images. Then, the prepared samples were further used as effective photocatalysts for the degradation of nitrobenzene under UV irradiation to examine the effect of doping on the photocatalytic activity. Among the synthesized samples, ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs exhibited superior photocatalytic activity. This result is in good agreement with photoluminescence (PL) analysis in which ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs revealed the slowest recombination rate of the electron-hole pair. To further improve the photocatalytic performance, different weight % of graphene was incorporated with ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs. Finally, 81.41% of nitrobenzene was degraded after 180 min in the presence of 5 wt% graphene/($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ nanocomposites, and the degradation rate constant was estimated as 8.4 × $ 10^{−3} $ $ min^{−1} $. (Cd (dpeaa)DE-He213 Ni (dpeaa)DE-He213 Mn (dpeaa)DE-He213 )Fe (dpeaa)DE-He213 Ru (dpeaa)DE-He213 O (dpeaa)DE-He213 nanoparticles (dpeaa)DE-He213 Ru doping (dpeaa)DE-He213 Photoluminescence (dpeaa)DE-He213 Photocatalytic performance (dpeaa)DE-He213 Nitrobenzene degradation (dpeaa)DE-He213 Aridi, Amani (orcid)0000-0002-6946-1839 aut Awad, Ramadan aut Enthalten in Environmental science and pollution research Berlin : Springer, 1994 30(2023), 54 vom: 01. Nov., Seite 116202-116213 (DE-627)320517926 (DE-600)2014192-0 1614-7499 nnns volume:30 year:2023 number:54 day:01 month:11 pages:116202-116213 https://dx.doi.org/10.1007/s11356-023-30718-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2023 54 01 11 116202-116213
allfieldsGer	10.1007/s11356-023-30718-y doi (DE-627)SPR053874536 (SPR)s11356-023-30718-y-e DE-627 ger DE-627 rakwb eng Kassem, Serine verfasserin aut Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract This study reports the synthesis of ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{2−x} %$ Ru_{x} %$ O_{4} $ nanoparticles (NPs), where x = 0.00, 0.005, 0.01, 0.015, 0.02, and 0.04, via co-precipitation method. The synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), and photoluminescence (PL) spectroscopy. The results confirmed the purity of the samples with the presence of a very small fraction of the hematite phase. Pseudo-spherical morphology was recognized from TEM images. Then, the prepared samples were further used as effective photocatalysts for the degradation of nitrobenzene under UV irradiation to examine the effect of doping on the photocatalytic activity. Among the synthesized samples, ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs exhibited superior photocatalytic activity. This result is in good agreement with photoluminescence (PL) analysis in which ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs revealed the slowest recombination rate of the electron-hole pair. To further improve the photocatalytic performance, different weight % of graphene was incorporated with ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs. Finally, 81.41% of nitrobenzene was degraded after 180 min in the presence of 5 wt% graphene/($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ nanocomposites, and the degradation rate constant was estimated as 8.4 × $ 10^{−3} $ $ min^{−1} $. (Cd (dpeaa)DE-He213 Ni (dpeaa)DE-He213 Mn (dpeaa)DE-He213 )Fe (dpeaa)DE-He213 Ru (dpeaa)DE-He213 O (dpeaa)DE-He213 nanoparticles (dpeaa)DE-He213 Ru doping (dpeaa)DE-He213 Photoluminescence (dpeaa)DE-He213 Photocatalytic performance (dpeaa)DE-He213 Nitrobenzene degradation (dpeaa)DE-He213 Aridi, Amani (orcid)0000-0002-6946-1839 aut Awad, Ramadan aut Enthalten in Environmental science and pollution research Berlin : Springer, 1994 30(2023), 54 vom: 01. Nov., Seite 116202-116213 (DE-627)320517926 (DE-600)2014192-0 1614-7499 nnns volume:30 year:2023 number:54 day:01 month:11 pages:116202-116213 https://dx.doi.org/10.1007/s11356-023-30718-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2023 54 01 11 116202-116213
allfieldsSound	10.1007/s11356-023-30718-y doi (DE-627)SPR053874536 (SPR)s11356-023-30718-y-e DE-627 ger DE-627 rakwb eng Kassem, Serine verfasserin aut Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract This study reports the synthesis of ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{2−x} %$ Ru_{x} %$ O_{4} $ nanoparticles (NPs), where x = 0.00, 0.005, 0.01, 0.015, 0.02, and 0.04, via co-precipitation method. The synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), and photoluminescence (PL) spectroscopy. The results confirmed the purity of the samples with the presence of a very small fraction of the hematite phase. Pseudo-spherical morphology was recognized from TEM images. Then, the prepared samples were further used as effective photocatalysts for the degradation of nitrobenzene under UV irradiation to examine the effect of doping on the photocatalytic activity. Among the synthesized samples, ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs exhibited superior photocatalytic activity. This result is in good agreement with photoluminescence (PL) analysis in which ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs revealed the slowest recombination rate of the electron-hole pair. To further improve the photocatalytic performance, different weight % of graphene was incorporated with ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs. Finally, 81.41% of nitrobenzene was degraded after 180 min in the presence of 5 wt% graphene/($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ nanocomposites, and the degradation rate constant was estimated as 8.4 × $ 10^{−3} $ $ min^{−1} $. (Cd (dpeaa)DE-He213 Ni (dpeaa)DE-He213 Mn (dpeaa)DE-He213 )Fe (dpeaa)DE-He213 Ru (dpeaa)DE-He213 O (dpeaa)DE-He213 nanoparticles (dpeaa)DE-He213 Ru doping (dpeaa)DE-He213 Photoluminescence (dpeaa)DE-He213 Photocatalytic performance (dpeaa)DE-He213 Nitrobenzene degradation (dpeaa)DE-He213 Aridi, Amani (orcid)0000-0002-6946-1839 aut Awad, Ramadan aut Enthalten in Environmental science and pollution research Berlin : Springer, 1994 30(2023), 54 vom: 01. Nov., Seite 116202-116213 (DE-627)320517926 (DE-600)2014192-0 1614-7499 nnns volume:30 year:2023 number:54 day:01 month:11 pages:116202-116213 https://dx.doi.org/10.1007/s11356-023-30718-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 30 2023 54 01 11 116202-116213
language	English
source	Enthalten in Environmental science and pollution research 30(2023), 54 vom: 01. Nov., Seite 116202-116213 volume:30 year:2023 number:54 day:01 month:11 pages:116202-116213
sourceStr	Enthalten in Environmental science and pollution research 30(2023), 54 vom: 01. Nov., Seite 116202-116213 volume:30 year:2023 number:54 day:01 month:11 pages:116202-116213
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	(Cd Ni Mn )Fe Ru O nanoparticles Ru doping Photoluminescence Photocatalytic performance Nitrobenzene degradation
isfreeaccess_bool	false
container_title	Environmental science and pollution research
authorswithroles_txt_mv	Kassem, Serine @@aut@@ Aridi, Amani @@aut@@ Awad, Ramadan @@aut@@
publishDateDaySort_date	2023-11-01T00:00:00Z
hierarchy_top_id	320517926
id	SPR053874536
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR053874536</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20231128064652.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">231128s2023 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11356-023-30718-y</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR053874536</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11356-023-30718-y-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Kassem, Serine</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract This study reports the synthesis of ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{2−x} %$ Ru_{x} %$ O_{4} $ nanoparticles (NPs), where x = 0.00, 0.005, 0.01, 0.015, 0.02, and 0.04, via co-precipitation method. The synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), and photoluminescence (PL) spectroscopy. The results confirmed the purity of the samples with the presence of a very small fraction of the hematite phase. Pseudo-spherical morphology was recognized from TEM images. Then, the prepared samples were further used as effective photocatalysts for the degradation of nitrobenzene under UV irradiation to examine the effect of doping on the photocatalytic activity. Among the synthesized samples, ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs exhibited superior photocatalytic activity. This result is in good agreement with photoluminescence (PL) analysis in which ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs revealed the slowest recombination rate of the electron-hole pair. To further improve the photocatalytic performance, different weight % of graphene was incorporated with ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs. Finally, 81.41% of nitrobenzene was degraded after 180 min in the presence of 5 wt% graphene/($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ nanocomposites, and the degradation rate constant was estimated as 8.4 × $ 10^{−3} $ $ min^{−1} $.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">(Cd</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ni</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mn</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">)Fe</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ru</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">O</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">nanoparticles</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ru doping</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Photoluminescence</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Photocatalytic performance</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nitrobenzene degradation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Aridi, Amani</subfield><subfield code="0">(orcid)0000-0002-6946-1839</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Awad, Ramadan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Environmental science and pollution research</subfield><subfield code="d">Berlin : Springer, 1994</subfield><subfield code="g">30(2023), 54 vom: 01. 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author	Kassem, Serine
spellingShingle	Kassem, Serine misc (Cd misc Ni misc Mn misc )Fe misc Ru misc O misc nanoparticles misc Ru doping misc Photoluminescence misc Photocatalytic performance misc Nitrobenzene degradation Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites
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topic_title	Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites (Cd (dpeaa)DE-He213 Ni (dpeaa)DE-He213 Mn (dpeaa)DE-He213 )Fe (dpeaa)DE-He213 Ru (dpeaa)DE-He213 O (dpeaa)DE-He213 nanoparticles (dpeaa)DE-He213 Ru doping (dpeaa)DE-He213 Photoluminescence (dpeaa)DE-He213 Photocatalytic performance (dpeaa)DE-He213 Nitrobenzene degradation (dpeaa)DE-He213
topic	misc (Cd misc Ni misc Mn misc )Fe misc Ru misc O misc nanoparticles misc Ru doping misc Photoluminescence misc Photocatalytic performance misc Nitrobenzene degradation
topic_unstemmed	misc (Cd misc Ni misc Mn misc )Fe misc Ru misc O misc nanoparticles misc Ru doping misc Photoluminescence misc Photocatalytic performance misc Nitrobenzene degradation
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title	Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites
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title_full	Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites
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title_sort	influence of ru doping on structural, optical, and photocatalytic properties of (cd-ni-mn) nanoferrites
title_auth	Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites
abstract	Abstract This study reports the synthesis of ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{2−x} %$ Ru_{x} %$ O_{4} $ nanoparticles (NPs), where x = 0.00, 0.005, 0.01, 0.015, 0.02, and 0.04, via co-precipitation method. The synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), and photoluminescence (PL) spectroscopy. The results confirmed the purity of the samples with the presence of a very small fraction of the hematite phase. Pseudo-spherical morphology was recognized from TEM images. Then, the prepared samples were further used as effective photocatalysts for the degradation of nitrobenzene under UV irradiation to examine the effect of doping on the photocatalytic activity. Among the synthesized samples, ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs exhibited superior photocatalytic activity. This result is in good agreement with photoluminescence (PL) analysis in which ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs revealed the slowest recombination rate of the electron-hole pair. To further improve the photocatalytic performance, different weight % of graphene was incorporated with ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs. Finally, 81.41% of nitrobenzene was degraded after 180 min in the presence of 5 wt% graphene/($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ nanocomposites, and the degradation rate constant was estimated as 8.4 × $ 10^{−3} $ $ min^{−1} $. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
abstractGer	Abstract This study reports the synthesis of ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{2−x} %$ Ru_{x} %$ O_{4} $ nanoparticles (NPs), where x = 0.00, 0.005, 0.01, 0.015, 0.02, and 0.04, via co-precipitation method. The synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), and photoluminescence (PL) spectroscopy. The results confirmed the purity of the samples with the presence of a very small fraction of the hematite phase. Pseudo-spherical morphology was recognized from TEM images. Then, the prepared samples were further used as effective photocatalysts for the degradation of nitrobenzene under UV irradiation to examine the effect of doping on the photocatalytic activity. Among the synthesized samples, ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs exhibited superior photocatalytic activity. This result is in good agreement with photoluminescence (PL) analysis in which ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs revealed the slowest recombination rate of the electron-hole pair. To further improve the photocatalytic performance, different weight % of graphene was incorporated with ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs. Finally, 81.41% of nitrobenzene was degraded after 180 min in the presence of 5 wt% graphene/($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ nanocomposites, and the degradation rate constant was estimated as 8.4 × $ 10^{−3} $ $ min^{−1} $. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
abstract_unstemmed	Abstract This study reports the synthesis of ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{2−x} %$ Ru_{x} %$ O_{4} $ nanoparticles (NPs), where x = 0.00, 0.005, 0.01, 0.015, 0.02, and 0.04, via co-precipitation method. The synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), and photoluminescence (PL) spectroscopy. The results confirmed the purity of the samples with the presence of a very small fraction of the hematite phase. Pseudo-spherical morphology was recognized from TEM images. Then, the prepared samples were further used as effective photocatalysts for the degradation of nitrobenzene under UV irradiation to examine the effect of doping on the photocatalytic activity. Among the synthesized samples, ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs exhibited superior photocatalytic activity. This result is in good agreement with photoluminescence (PL) analysis in which ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs revealed the slowest recombination rate of the electron-hole pair. To further improve the photocatalytic performance, different weight % of graphene was incorporated with ($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ NPs. Finally, 81.41% of nitrobenzene was degraded after 180 min in the presence of 5 wt% graphene/($ Cd_{0.4} %$ Ni_{0.4} %$ Mn_{0.2} $)$ Fe_{1.985} %$ Ru_{0.015} %$ O_{4} $ nanocomposites, and the degradation rate constant was estimated as 8.4 × $ 10^{−3} $ $ min^{−1} $. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
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container_issue	54
title_short	Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites
url	https://dx.doi.org/10.1007/s11356-023-30718-y
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author2	Aridi, Amani Awad, Ramadan
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doi_str	10.1007/s11356-023-30718-y
up_date	2024-07-03T22:37:12.288Z
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Influence of Ru doping on structural, optical, and photocatalytic properties of (Cd-Ni-Mn) nanoferrites

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