Sputtered Stainless Steel on Silicon Photoanode for Stable Seawater Splitting in Photoelectrochemical Flow Cell
Abstract Photoelectrochemical (PEC) seawater splitting is a promising method for the direct utilization of solar energy and abundant seawater resources for hydrogen production. Photoelectrodes are susceptible to various ions in seawater and complicated competitive reactions, resulting in the failure...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhao, Shixuan [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s) 2023 |
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| Übergeordnetes Werk: |
Enthalten in: Transactions of Tianjin University - Tianjin : Univ., 1995, 29(2023), 6 vom: Dez., Seite 473-481 |
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| Übergeordnetes Werk: |
volume:29 ; year:2023 ; number:6 ; month:12 ; pages:473-481 |
| Links: |
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| DOI / URN: |
10.1007/s12209-023-00374-x |
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| Katalog-ID: |
SPR054200199 |
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| 520 | |a Abstract Photoelectrochemical (PEC) seawater splitting is a promising method for the direct utilization of solar energy and abundant seawater resources for hydrogen production. Photoelectrodes are susceptible to various ions in seawater and complicated competitive reactions, resulting in the failure of photoelectrodes. This paper proposes the design and fabrication of different sputtered stainless steel (SS) films deposited on silicon photoanodes, completely isolating the electrolytes and semiconductor substrate. Upon coupling with the PEC flow cell, the back-illuminated photoanode coated with 316 SS cocatalyst achieves stable operation for 70 h in natural seawater with a highly alkaline KOH (30 wt.%, 7.64 mol/L) electrolyte due to the remarkable protection effect of the substrate from stainless steel, while the PEC seawater splitting system achieves a record hydrogen production rate of 600 μmol/(h·$ cm^{2} $). An appropriate Ni/Fe ratio in the SS ensures remarkable oxygen evolution activity, while chromic oxide ensures the effective anticorrosion effect by adjusting the microenvironment of the photoanodes. Moreover, fabricating PEC flow cells with photoanodes coated with SS cocatalysts are a viable strategy for PEC seawater splitting. | ||
| 650 | 4 | |a Flow cell |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Seawater splitting |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Stainless steel |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Chloridion |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Photoelectrochemical |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Liu, Bin |4 aut | |
| 700 | 1 | |a Zhang, Gong |4 aut | |
| 700 | 1 | |a Wang, Qingzhen |4 aut | |
| 700 | 1 | |a Cai, Yuan |4 aut | |
| 700 | 1 | |a Tong, Yuting |4 aut | |
| 700 | 1 | |a Wang, Shujie |4 aut | |
| 700 | 1 | |a Zhang, Peng |4 aut | |
| 700 | 1 | |a Wang, Tuo |4 aut | |
| 700 | 1 | |a Gong, Jinlong |4 aut | |
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10.1007/s12209-023-00374-x doi (DE-627)SPR054200199 (SPR)s12209-023-00374-x-e DE-627 ger DE-627 rakwb eng Zhao, Shixuan verfasserin aut Sputtered Stainless Steel on Silicon Photoanode for Stable Seawater Splitting in Photoelectrochemical Flow Cell 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2023 Abstract Photoelectrochemical (PEC) seawater splitting is a promising method for the direct utilization of solar energy and abundant seawater resources for hydrogen production. Photoelectrodes are susceptible to various ions in seawater and complicated competitive reactions, resulting in the failure of photoelectrodes. This paper proposes the design and fabrication of different sputtered stainless steel (SS) films deposited on silicon photoanodes, completely isolating the electrolytes and semiconductor substrate. Upon coupling with the PEC flow cell, the back-illuminated photoanode coated with 316 SS cocatalyst achieves stable operation for 70 h in natural seawater with a highly alkaline KOH (30 wt.%, 7.64 mol/L) electrolyte due to the remarkable protection effect of the substrate from stainless steel, while the PEC seawater splitting system achieves a record hydrogen production rate of 600 μmol/(h·$ cm^{2} $). An appropriate Ni/Fe ratio in the SS ensures remarkable oxygen evolution activity, while chromic oxide ensures the effective anticorrosion effect by adjusting the microenvironment of the photoanodes. Moreover, fabricating PEC flow cells with photoanodes coated with SS cocatalysts are a viable strategy for PEC seawater splitting. Flow cell (dpeaa)DE-He213 Seawater splitting (dpeaa)DE-He213 Stainless steel (dpeaa)DE-He213 Chloridion (dpeaa)DE-He213 Photoelectrochemical (dpeaa)DE-He213 Liu, Bin aut Zhang, Gong aut Wang, Qingzhen aut Cai, Yuan aut Tong, Yuting aut Wang, Shujie aut Zhang, Peng aut Wang, Tuo aut Gong, Jinlong aut Enthalten in Transactions of Tianjin University Tianjin : Univ., 1995 29(2023), 6 vom: Dez., Seite 473-481 (DE-627)592072681 (DE-600)2479763-7 1995-8196 nnns volume:29 year:2023 number:6 month:12 pages:473-481 https://dx.doi.org/10.1007/s12209-023-00374-x kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_636 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2036 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2700 GBV_ILN_2817 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4392 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 AR 29 2023 6 12 473-481 |
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10.1007/s12209-023-00374-x doi (DE-627)SPR054200199 (SPR)s12209-023-00374-x-e DE-627 ger DE-627 rakwb eng Zhao, Shixuan verfasserin aut Sputtered Stainless Steel on Silicon Photoanode for Stable Seawater Splitting in Photoelectrochemical Flow Cell 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2023 Abstract Photoelectrochemical (PEC) seawater splitting is a promising method for the direct utilization of solar energy and abundant seawater resources for hydrogen production. Photoelectrodes are susceptible to various ions in seawater and complicated competitive reactions, resulting in the failure of photoelectrodes. This paper proposes the design and fabrication of different sputtered stainless steel (SS) films deposited on silicon photoanodes, completely isolating the electrolytes and semiconductor substrate. Upon coupling with the PEC flow cell, the back-illuminated photoanode coated with 316 SS cocatalyst achieves stable operation for 70 h in natural seawater with a highly alkaline KOH (30 wt.%, 7.64 mol/L) electrolyte due to the remarkable protection effect of the substrate from stainless steel, while the PEC seawater splitting system achieves a record hydrogen production rate of 600 μmol/(h·$ cm^{2} $). An appropriate Ni/Fe ratio in the SS ensures remarkable oxygen evolution activity, while chromic oxide ensures the effective anticorrosion effect by adjusting the microenvironment of the photoanodes. Moreover, fabricating PEC flow cells with photoanodes coated with SS cocatalysts are a viable strategy for PEC seawater splitting. Flow cell (dpeaa)DE-He213 Seawater splitting (dpeaa)DE-He213 Stainless steel (dpeaa)DE-He213 Chloridion (dpeaa)DE-He213 Photoelectrochemical (dpeaa)DE-He213 Liu, Bin aut Zhang, Gong aut Wang, Qingzhen aut Cai, Yuan aut Tong, Yuting aut Wang, Shujie aut Zhang, Peng aut Wang, Tuo aut Gong, Jinlong aut Enthalten in Transactions of Tianjin University Tianjin : Univ., 1995 29(2023), 6 vom: Dez., Seite 473-481 (DE-627)592072681 (DE-600)2479763-7 1995-8196 nnns volume:29 year:2023 number:6 month:12 pages:473-481 https://dx.doi.org/10.1007/s12209-023-00374-x kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_636 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2036 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2700 GBV_ILN_2817 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4392 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 AR 29 2023 6 12 473-481 |
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10.1007/s12209-023-00374-x doi (DE-627)SPR054200199 (SPR)s12209-023-00374-x-e DE-627 ger DE-627 rakwb eng Zhao, Shixuan verfasserin aut Sputtered Stainless Steel on Silicon Photoanode for Stable Seawater Splitting in Photoelectrochemical Flow Cell 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2023 Abstract Photoelectrochemical (PEC) seawater splitting is a promising method for the direct utilization of solar energy and abundant seawater resources for hydrogen production. Photoelectrodes are susceptible to various ions in seawater and complicated competitive reactions, resulting in the failure of photoelectrodes. This paper proposes the design and fabrication of different sputtered stainless steel (SS) films deposited on silicon photoanodes, completely isolating the electrolytes and semiconductor substrate. Upon coupling with the PEC flow cell, the back-illuminated photoanode coated with 316 SS cocatalyst achieves stable operation for 70 h in natural seawater with a highly alkaline KOH (30 wt.%, 7.64 mol/L) electrolyte due to the remarkable protection effect of the substrate from stainless steel, while the PEC seawater splitting system achieves a record hydrogen production rate of 600 μmol/(h·$ cm^{2} $). An appropriate Ni/Fe ratio in the SS ensures remarkable oxygen evolution activity, while chromic oxide ensures the effective anticorrosion effect by adjusting the microenvironment of the photoanodes. Moreover, fabricating PEC flow cells with photoanodes coated with SS cocatalysts are a viable strategy for PEC seawater splitting. Flow cell (dpeaa)DE-He213 Seawater splitting (dpeaa)DE-He213 Stainless steel (dpeaa)DE-He213 Chloridion (dpeaa)DE-He213 Photoelectrochemical (dpeaa)DE-He213 Liu, Bin aut Zhang, Gong aut Wang, Qingzhen aut Cai, Yuan aut Tong, Yuting aut Wang, Shujie aut Zhang, Peng aut Wang, Tuo aut Gong, Jinlong aut Enthalten in Transactions of Tianjin University Tianjin : Univ., 1995 29(2023), 6 vom: Dez., Seite 473-481 (DE-627)592072681 (DE-600)2479763-7 1995-8196 nnns volume:29 year:2023 number:6 month:12 pages:473-481 https://dx.doi.org/10.1007/s12209-023-00374-x kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_636 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2036 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2700 GBV_ILN_2817 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4392 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 AR 29 2023 6 12 473-481 |
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10.1007/s12209-023-00374-x doi (DE-627)SPR054200199 (SPR)s12209-023-00374-x-e DE-627 ger DE-627 rakwb eng Zhao, Shixuan verfasserin aut Sputtered Stainless Steel on Silicon Photoanode for Stable Seawater Splitting in Photoelectrochemical Flow Cell 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2023 Abstract Photoelectrochemical (PEC) seawater splitting is a promising method for the direct utilization of solar energy and abundant seawater resources for hydrogen production. Photoelectrodes are susceptible to various ions in seawater and complicated competitive reactions, resulting in the failure of photoelectrodes. This paper proposes the design and fabrication of different sputtered stainless steel (SS) films deposited on silicon photoanodes, completely isolating the electrolytes and semiconductor substrate. Upon coupling with the PEC flow cell, the back-illuminated photoanode coated with 316 SS cocatalyst achieves stable operation for 70 h in natural seawater with a highly alkaline KOH (30 wt.%, 7.64 mol/L) electrolyte due to the remarkable protection effect of the substrate from stainless steel, while the PEC seawater splitting system achieves a record hydrogen production rate of 600 μmol/(h·$ cm^{2} $). An appropriate Ni/Fe ratio in the SS ensures remarkable oxygen evolution activity, while chromic oxide ensures the effective anticorrosion effect by adjusting the microenvironment of the photoanodes. Moreover, fabricating PEC flow cells with photoanodes coated with SS cocatalysts are a viable strategy for PEC seawater splitting. Flow cell (dpeaa)DE-He213 Seawater splitting (dpeaa)DE-He213 Stainless steel (dpeaa)DE-He213 Chloridion (dpeaa)DE-He213 Photoelectrochemical (dpeaa)DE-He213 Liu, Bin aut Zhang, Gong aut Wang, Qingzhen aut Cai, Yuan aut Tong, Yuting aut Wang, Shujie aut Zhang, Peng aut Wang, Tuo aut Gong, Jinlong aut Enthalten in Transactions of Tianjin University Tianjin : Univ., 1995 29(2023), 6 vom: Dez., Seite 473-481 (DE-627)592072681 (DE-600)2479763-7 1995-8196 nnns volume:29 year:2023 number:6 month:12 pages:473-481 https://dx.doi.org/10.1007/s12209-023-00374-x kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_636 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2036 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2700 GBV_ILN_2817 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4392 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 AR 29 2023 6 12 473-481 |
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10.1007/s12209-023-00374-x doi (DE-627)SPR054200199 (SPR)s12209-023-00374-x-e DE-627 ger DE-627 rakwb eng Zhao, Shixuan verfasserin aut Sputtered Stainless Steel on Silicon Photoanode for Stable Seawater Splitting in Photoelectrochemical Flow Cell 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2023 Abstract Photoelectrochemical (PEC) seawater splitting is a promising method for the direct utilization of solar energy and abundant seawater resources for hydrogen production. Photoelectrodes are susceptible to various ions in seawater and complicated competitive reactions, resulting in the failure of photoelectrodes. This paper proposes the design and fabrication of different sputtered stainless steel (SS) films deposited on silicon photoanodes, completely isolating the electrolytes and semiconductor substrate. Upon coupling with the PEC flow cell, the back-illuminated photoanode coated with 316 SS cocatalyst achieves stable operation for 70 h in natural seawater with a highly alkaline KOH (30 wt.%, 7.64 mol/L) electrolyte due to the remarkable protection effect of the substrate from stainless steel, while the PEC seawater splitting system achieves a record hydrogen production rate of 600 μmol/(h·$ cm^{2} $). An appropriate Ni/Fe ratio in the SS ensures remarkable oxygen evolution activity, while chromic oxide ensures the effective anticorrosion effect by adjusting the microenvironment of the photoanodes. Moreover, fabricating PEC flow cells with photoanodes coated with SS cocatalysts are a viable strategy for PEC seawater splitting. Flow cell (dpeaa)DE-He213 Seawater splitting (dpeaa)DE-He213 Stainless steel (dpeaa)DE-He213 Chloridion (dpeaa)DE-He213 Photoelectrochemical (dpeaa)DE-He213 Liu, Bin aut Zhang, Gong aut Wang, Qingzhen aut Cai, Yuan aut Tong, Yuting aut Wang, Shujie aut Zhang, Peng aut Wang, Tuo aut Gong, Jinlong aut Enthalten in Transactions of Tianjin University Tianjin : Univ., 1995 29(2023), 6 vom: Dez., Seite 473-481 (DE-627)592072681 (DE-600)2479763-7 1995-8196 nnns volume:29 year:2023 number:6 month:12 pages:473-481 https://dx.doi.org/10.1007/s12209-023-00374-x kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_636 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2036 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2700 GBV_ILN_2817 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4392 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 AR 29 2023 6 12 473-481 |
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Enthalten in Transactions of Tianjin University 29(2023), 6 vom: Dez., Seite 473-481 volume:29 year:2023 number:6 month:12 pages:473-481 |
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Zhao, Shixuan @@aut@@ Liu, Bin @@aut@@ Zhang, Gong @@aut@@ Wang, Qingzhen @@aut@@ Cai, Yuan @@aut@@ Tong, Yuting @@aut@@ Wang, Shujie @@aut@@ Zhang, Peng @@aut@@ Wang, Tuo @@aut@@ Gong, Jinlong @@aut@@ |
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Photoelectrodes are susceptible to various ions in seawater and complicated competitive reactions, resulting in the failure of photoelectrodes. This paper proposes the design and fabrication of different sputtered stainless steel (SS) films deposited on silicon photoanodes, completely isolating the electrolytes and semiconductor substrate. Upon coupling with the PEC flow cell, the back-illuminated photoanode coated with 316 SS cocatalyst achieves stable operation for 70 h in natural seawater with a highly alkaline KOH (30 wt.%, 7.64 mol/L) electrolyte due to the remarkable protection effect of the substrate from stainless steel, while the PEC seawater splitting system achieves a record hydrogen production rate of 600 μmol/(h·$ cm^{2} $). An appropriate Ni/Fe ratio in the SS ensures remarkable oxygen evolution activity, while chromic oxide ensures the effective anticorrosion effect by adjusting the microenvironment of the photoanodes. 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Zhao, Shixuan |
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Zhao, Shixuan misc Flow cell misc Seawater splitting misc Stainless steel misc Chloridion misc Photoelectrochemical Sputtered Stainless Steel on Silicon Photoanode for Stable Seawater Splitting in Photoelectrochemical Flow Cell |
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Sputtered Stainless Steel on Silicon Photoanode for Stable Seawater Splitting in Photoelectrochemical Flow Cell Flow cell (dpeaa)DE-He213 Seawater splitting (dpeaa)DE-He213 Stainless steel (dpeaa)DE-He213 Chloridion (dpeaa)DE-He213 Photoelectrochemical (dpeaa)DE-He213 |
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Zhao, Shixuan Liu, Bin Zhang, Gong Wang, Qingzhen Cai, Yuan Tong, Yuting Wang, Shujie Zhang, Peng Wang, Tuo Gong, Jinlong |
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Zhao, Shixuan |
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sputtered stainless steel on silicon photoanode for stable seawater splitting in photoelectrochemical flow cell |
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Sputtered Stainless Steel on Silicon Photoanode for Stable Seawater Splitting in Photoelectrochemical Flow Cell |
| abstract |
Abstract Photoelectrochemical (PEC) seawater splitting is a promising method for the direct utilization of solar energy and abundant seawater resources for hydrogen production. Photoelectrodes are susceptible to various ions in seawater and complicated competitive reactions, resulting in the failure of photoelectrodes. This paper proposes the design and fabrication of different sputtered stainless steel (SS) films deposited on silicon photoanodes, completely isolating the electrolytes and semiconductor substrate. Upon coupling with the PEC flow cell, the back-illuminated photoanode coated with 316 SS cocatalyst achieves stable operation for 70 h in natural seawater with a highly alkaline KOH (30 wt.%, 7.64 mol/L) electrolyte due to the remarkable protection effect of the substrate from stainless steel, while the PEC seawater splitting system achieves a record hydrogen production rate of 600 μmol/(h·$ cm^{2} $). An appropriate Ni/Fe ratio in the SS ensures remarkable oxygen evolution activity, while chromic oxide ensures the effective anticorrosion effect by adjusting the microenvironment of the photoanodes. Moreover, fabricating PEC flow cells with photoanodes coated with SS cocatalysts are a viable strategy for PEC seawater splitting. © The Author(s) 2023 |
| abstractGer |
Abstract Photoelectrochemical (PEC) seawater splitting is a promising method for the direct utilization of solar energy and abundant seawater resources for hydrogen production. Photoelectrodes are susceptible to various ions in seawater and complicated competitive reactions, resulting in the failure of photoelectrodes. This paper proposes the design and fabrication of different sputtered stainless steel (SS) films deposited on silicon photoanodes, completely isolating the electrolytes and semiconductor substrate. Upon coupling with the PEC flow cell, the back-illuminated photoanode coated with 316 SS cocatalyst achieves stable operation for 70 h in natural seawater with a highly alkaline KOH (30 wt.%, 7.64 mol/L) electrolyte due to the remarkable protection effect of the substrate from stainless steel, while the PEC seawater splitting system achieves a record hydrogen production rate of 600 μmol/(h·$ cm^{2} $). An appropriate Ni/Fe ratio in the SS ensures remarkable oxygen evolution activity, while chromic oxide ensures the effective anticorrosion effect by adjusting the microenvironment of the photoanodes. Moreover, fabricating PEC flow cells with photoanodes coated with SS cocatalysts are a viable strategy for PEC seawater splitting. © The Author(s) 2023 |
| abstract_unstemmed |
Abstract Photoelectrochemical (PEC) seawater splitting is a promising method for the direct utilization of solar energy and abundant seawater resources for hydrogen production. Photoelectrodes are susceptible to various ions in seawater and complicated competitive reactions, resulting in the failure of photoelectrodes. This paper proposes the design and fabrication of different sputtered stainless steel (SS) films deposited on silicon photoanodes, completely isolating the electrolytes and semiconductor substrate. Upon coupling with the PEC flow cell, the back-illuminated photoanode coated with 316 SS cocatalyst achieves stable operation for 70 h in natural seawater with a highly alkaline KOH (30 wt.%, 7.64 mol/L) electrolyte due to the remarkable protection effect of the substrate from stainless steel, while the PEC seawater splitting system achieves a record hydrogen production rate of 600 μmol/(h·$ cm^{2} $). An appropriate Ni/Fe ratio in the SS ensures remarkable oxygen evolution activity, while chromic oxide ensures the effective anticorrosion effect by adjusting the microenvironment of the photoanodes. Moreover, fabricating PEC flow cells with photoanodes coated with SS cocatalysts are a viable strategy for PEC seawater splitting. © The Author(s) 2023 |
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Sputtered Stainless Steel on Silicon Photoanode for Stable Seawater Splitting in Photoelectrochemical Flow Cell |
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| score |
7.3998117 |