Reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) composite: highly reproducible and repeatable chemiresistive $ SO_{2} $ sensor
In the current study, a chemiresistive $ SO_{2} $ sensor based on a composite of reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) was developed and extensively studied. Improved Hummers methods were used to synthesize graphene oxide (GO), and a thermally heating...
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| Autor*in: |
Khune, Abhaysinh S. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2024 |
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© The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Applied physics - Berlin : Springer, 1973, 130(2024), 1 vom: Jan. |
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| Übergeordnetes Werk: |
volume:130 ; year:2024 ; number:1 ; month:01 |
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| DOI / URN: |
10.1007/s00339-023-07194-9 |
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SPR054219388 |
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| 245 | 1 | 0 | |a Reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) composite: highly reproducible and repeatable chemiresistive $ SO_{2} $ sensor |
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| 520 | |a In the current study, a chemiresistive $ SO_{2} $ sensor based on a composite of reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) was developed and extensively studied. Improved Hummers methods were used to synthesize graphene oxide (GO), and a thermally heating bottom-up approach was used to reduce GO to rGO. Gold electrodes were thermally coated on the transparent sheet using a thermal evaporator. The composite of rGO/TPTP was synthesized using a simple chemical method. Structural, morphological, spectroscopic, electrical, and optical studies were carried out using X-ray diffraction, atomic force microscopy, field emission scanning electron microscopy, Fourier-transfer infrared spectroscopy, Raman spectroscopy, current–voltage, and UV–vis spectroscopy, respectively. The sensing response of rGO/TPTP for various concentrations of sulfur dioxide ($ SO_{2} $) was investigated in chemiresistive modality. The rGO/TPTP composite chemiresistive sensor displayed exceptional performance, with a consistent response spanning 1 ppm to 10 ppm. It exhibited outstanding repeatability, linearity, stability, and boasted an impressive limit of detection (LOD) of 1 ppm. This LOD is significantly lower than the recommended permissible exposure limit (PEL) of 5 ppm set by OSHA (Occupational Safety and Health Administration), USA. The sensor based on the rGO/TPTP composite exhibited a very fast response and recovery time of 33 s. and 27 s. respectively. Graphical abstract | ||
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10.1007/s00339-023-07194-9 doi (DE-627)SPR054219388 (SPR)s00339-023-07194-9-e DE-627 ger DE-627 rakwb eng Khune, Abhaysinh S. verfasserin aut Reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) composite: highly reproducible and repeatable chemiresistive $ SO_{2} $ sensor 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In the current study, a chemiresistive $ SO_{2} $ sensor based on a composite of reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) was developed and extensively studied. Improved Hummers methods were used to synthesize graphene oxide (GO), and a thermally heating bottom-up approach was used to reduce GO to rGO. Gold electrodes were thermally coated on the transparent sheet using a thermal evaporator. The composite of rGO/TPTP was synthesized using a simple chemical method. Structural, morphological, spectroscopic, electrical, and optical studies were carried out using X-ray diffraction, atomic force microscopy, field emission scanning electron microscopy, Fourier-transfer infrared spectroscopy, Raman spectroscopy, current–voltage, and UV–vis spectroscopy, respectively. The sensing response of rGO/TPTP for various concentrations of sulfur dioxide ($ SO_{2} $) was investigated in chemiresistive modality. The rGO/TPTP composite chemiresistive sensor displayed exceptional performance, with a consistent response spanning 1 ppm to 10 ppm. It exhibited outstanding repeatability, linearity, stability, and boasted an impressive limit of detection (LOD) of 1 ppm. This LOD is significantly lower than the recommended permissible exposure limit (PEL) of 5 ppm set by OSHA (Occupational Safety and Health Administration), USA. The sensor based on the rGO/TPTP composite exhibited a very fast response and recovery time of 33 s. and 27 s. respectively. Graphical abstract Gas sensor (dpeaa)DE-He213 Graphene (dpeaa)DE-He213 Reduced graphene oxide (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Sulfur dioxide (dpeaa)DE-He213 Narwade, Vijaykiran N. aut Dole, B. N. aut Ingle, Nikesh N. aut Tsai, Meng-Lin aut Hianik, Tibor aut Shirsat, Mahendra D. (orcid)0000-0002-4216-2919 aut Enthalten in Applied physics Berlin : Springer, 1973 130(2024), 1 vom: Jan. (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:130 year:2024 number:1 month:01 https://dx.doi.org/10.1007/s00339-023-07194-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 130 2024 1 01 |
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10.1007/s00339-023-07194-9 doi (DE-627)SPR054219388 (SPR)s00339-023-07194-9-e DE-627 ger DE-627 rakwb eng Khune, Abhaysinh S. verfasserin aut Reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) composite: highly reproducible and repeatable chemiresistive $ SO_{2} $ sensor 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In the current study, a chemiresistive $ SO_{2} $ sensor based on a composite of reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) was developed and extensively studied. Improved Hummers methods were used to synthesize graphene oxide (GO), and a thermally heating bottom-up approach was used to reduce GO to rGO. Gold electrodes were thermally coated on the transparent sheet using a thermal evaporator. The composite of rGO/TPTP was synthesized using a simple chemical method. Structural, morphological, spectroscopic, electrical, and optical studies were carried out using X-ray diffraction, atomic force microscopy, field emission scanning electron microscopy, Fourier-transfer infrared spectroscopy, Raman spectroscopy, current–voltage, and UV–vis spectroscopy, respectively. The sensing response of rGO/TPTP for various concentrations of sulfur dioxide ($ SO_{2} $) was investigated in chemiresistive modality. The rGO/TPTP composite chemiresistive sensor displayed exceptional performance, with a consistent response spanning 1 ppm to 10 ppm. It exhibited outstanding repeatability, linearity, stability, and boasted an impressive limit of detection (LOD) of 1 ppm. This LOD is significantly lower than the recommended permissible exposure limit (PEL) of 5 ppm set by OSHA (Occupational Safety and Health Administration), USA. The sensor based on the rGO/TPTP composite exhibited a very fast response and recovery time of 33 s. and 27 s. respectively. Graphical abstract Gas sensor (dpeaa)DE-He213 Graphene (dpeaa)DE-He213 Reduced graphene oxide (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Sulfur dioxide (dpeaa)DE-He213 Narwade, Vijaykiran N. aut Dole, B. N. aut Ingle, Nikesh N. aut Tsai, Meng-Lin aut Hianik, Tibor aut Shirsat, Mahendra D. (orcid)0000-0002-4216-2919 aut Enthalten in Applied physics Berlin : Springer, 1973 130(2024), 1 vom: Jan. (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:130 year:2024 number:1 month:01 https://dx.doi.org/10.1007/s00339-023-07194-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 130 2024 1 01 |
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10.1007/s00339-023-07194-9 doi (DE-627)SPR054219388 (SPR)s00339-023-07194-9-e DE-627 ger DE-627 rakwb eng Khune, Abhaysinh S. verfasserin aut Reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) composite: highly reproducible and repeatable chemiresistive $ SO_{2} $ sensor 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In the current study, a chemiresistive $ SO_{2} $ sensor based on a composite of reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) was developed and extensively studied. Improved Hummers methods were used to synthesize graphene oxide (GO), and a thermally heating bottom-up approach was used to reduce GO to rGO. Gold electrodes were thermally coated on the transparent sheet using a thermal evaporator. The composite of rGO/TPTP was synthesized using a simple chemical method. Structural, morphological, spectroscopic, electrical, and optical studies were carried out using X-ray diffraction, atomic force microscopy, field emission scanning electron microscopy, Fourier-transfer infrared spectroscopy, Raman spectroscopy, current–voltage, and UV–vis spectroscopy, respectively. The sensing response of rGO/TPTP for various concentrations of sulfur dioxide ($ SO_{2} $) was investigated in chemiresistive modality. The rGO/TPTP composite chemiresistive sensor displayed exceptional performance, with a consistent response spanning 1 ppm to 10 ppm. It exhibited outstanding repeatability, linearity, stability, and boasted an impressive limit of detection (LOD) of 1 ppm. This LOD is significantly lower than the recommended permissible exposure limit (PEL) of 5 ppm set by OSHA (Occupational Safety and Health Administration), USA. The sensor based on the rGO/TPTP composite exhibited a very fast response and recovery time of 33 s. and 27 s. respectively. Graphical abstract Gas sensor (dpeaa)DE-He213 Graphene (dpeaa)DE-He213 Reduced graphene oxide (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Sulfur dioxide (dpeaa)DE-He213 Narwade, Vijaykiran N. aut Dole, B. N. aut Ingle, Nikesh N. aut Tsai, Meng-Lin aut Hianik, Tibor aut Shirsat, Mahendra D. (orcid)0000-0002-4216-2919 aut Enthalten in Applied physics Berlin : Springer, 1973 130(2024), 1 vom: Jan. (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:130 year:2024 number:1 month:01 https://dx.doi.org/10.1007/s00339-023-07194-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 130 2024 1 01 |
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10.1007/s00339-023-07194-9 doi (DE-627)SPR054219388 (SPR)s00339-023-07194-9-e DE-627 ger DE-627 rakwb eng Khune, Abhaysinh S. verfasserin aut Reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) composite: highly reproducible and repeatable chemiresistive $ SO_{2} $ sensor 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In the current study, a chemiresistive $ SO_{2} $ sensor based on a composite of reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) was developed and extensively studied. Improved Hummers methods were used to synthesize graphene oxide (GO), and a thermally heating bottom-up approach was used to reduce GO to rGO. Gold electrodes were thermally coated on the transparent sheet using a thermal evaporator. The composite of rGO/TPTP was synthesized using a simple chemical method. Structural, morphological, spectroscopic, electrical, and optical studies were carried out using X-ray diffraction, atomic force microscopy, field emission scanning electron microscopy, Fourier-transfer infrared spectroscopy, Raman spectroscopy, current–voltage, and UV–vis spectroscopy, respectively. The sensing response of rGO/TPTP for various concentrations of sulfur dioxide ($ SO_{2} $) was investigated in chemiresistive modality. The rGO/TPTP composite chemiresistive sensor displayed exceptional performance, with a consistent response spanning 1 ppm to 10 ppm. It exhibited outstanding repeatability, linearity, stability, and boasted an impressive limit of detection (LOD) of 1 ppm. This LOD is significantly lower than the recommended permissible exposure limit (PEL) of 5 ppm set by OSHA (Occupational Safety and Health Administration), USA. The sensor based on the rGO/TPTP composite exhibited a very fast response and recovery time of 33 s. and 27 s. respectively. Graphical abstract Gas sensor (dpeaa)DE-He213 Graphene (dpeaa)DE-He213 Reduced graphene oxide (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Sulfur dioxide (dpeaa)DE-He213 Narwade, Vijaykiran N. aut Dole, B. N. aut Ingle, Nikesh N. aut Tsai, Meng-Lin aut Hianik, Tibor aut Shirsat, Mahendra D. (orcid)0000-0002-4216-2919 aut Enthalten in Applied physics Berlin : Springer, 1973 130(2024), 1 vom: Jan. (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:130 year:2024 number:1 month:01 https://dx.doi.org/10.1007/s00339-023-07194-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 130 2024 1 01 |
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10.1007/s00339-023-07194-9 doi (DE-627)SPR054219388 (SPR)s00339-023-07194-9-e DE-627 ger DE-627 rakwb eng Khune, Abhaysinh S. verfasserin aut Reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) composite: highly reproducible and repeatable chemiresistive $ SO_{2} $ sensor 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In the current study, a chemiresistive $ SO_{2} $ sensor based on a composite of reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) was developed and extensively studied. Improved Hummers methods were used to synthesize graphene oxide (GO), and a thermally heating bottom-up approach was used to reduce GO to rGO. Gold electrodes were thermally coated on the transparent sheet using a thermal evaporator. The composite of rGO/TPTP was synthesized using a simple chemical method. Structural, morphological, spectroscopic, electrical, and optical studies were carried out using X-ray diffraction, atomic force microscopy, field emission scanning electron microscopy, Fourier-transfer infrared spectroscopy, Raman spectroscopy, current–voltage, and UV–vis spectroscopy, respectively. The sensing response of rGO/TPTP for various concentrations of sulfur dioxide ($ SO_{2} $) was investigated in chemiresistive modality. The rGO/TPTP composite chemiresistive sensor displayed exceptional performance, with a consistent response spanning 1 ppm to 10 ppm. It exhibited outstanding repeatability, linearity, stability, and boasted an impressive limit of detection (LOD) of 1 ppm. This LOD is significantly lower than the recommended permissible exposure limit (PEL) of 5 ppm set by OSHA (Occupational Safety and Health Administration), USA. The sensor based on the rGO/TPTP composite exhibited a very fast response and recovery time of 33 s. and 27 s. respectively. Graphical abstract Gas sensor (dpeaa)DE-He213 Graphene (dpeaa)DE-He213 Reduced graphene oxide (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Sulfur dioxide (dpeaa)DE-He213 Narwade, Vijaykiran N. aut Dole, B. N. aut Ingle, Nikesh N. aut Tsai, Meng-Lin aut Hianik, Tibor aut Shirsat, Mahendra D. (orcid)0000-0002-4216-2919 aut Enthalten in Applied physics Berlin : Springer, 1973 130(2024), 1 vom: Jan. (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:130 year:2024 number:1 month:01 https://dx.doi.org/10.1007/s00339-023-07194-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 130 2024 1 01 |
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Khune, Abhaysinh S. @@aut@@ Narwade, Vijaykiran N. @@aut@@ Dole, B. N. @@aut@@ Ingle, Nikesh N. @@aut@@ Tsai, Meng-Lin @@aut@@ Hianik, Tibor @@aut@@ Shirsat, Mahendra D. @@aut@@ |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">In the current study, a chemiresistive $ SO_{2} $ sensor based on a composite of reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) was developed and extensively studied. Improved Hummers methods were used to synthesize graphene oxide (GO), and a thermally heating bottom-up approach was used to reduce GO to rGO. Gold electrodes were thermally coated on the transparent sheet using a thermal evaporator. The composite of rGO/TPTP was synthesized using a simple chemical method. Structural, morphological, spectroscopic, electrical, and optical studies were carried out using X-ray diffraction, atomic force microscopy, field emission scanning electron microscopy, Fourier-transfer infrared spectroscopy, Raman spectroscopy, current–voltage, and UV–vis spectroscopy, respectively. The sensing response of rGO/TPTP for various concentrations of sulfur dioxide ($ SO_{2} $) was investigated in chemiresistive modality. The rGO/TPTP composite chemiresistive sensor displayed exceptional performance, with a consistent response spanning 1 ppm to 10 ppm. It exhibited outstanding repeatability, linearity, stability, and boasted an impressive limit of detection (LOD) of 1 ppm. This LOD is significantly lower than the recommended permissible exposure limit (PEL) of 5 ppm set by OSHA (Occupational Safety and Health Administration), USA. The sensor based on the rGO/TPTP composite exhibited a very fast response and recovery time of 33 s. and 27 s. respectively. 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Khune, Abhaysinh S. |
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Khune, Abhaysinh S. misc Gas sensor misc Graphene misc Reduced graphene oxide misc Porphyrin misc Sulfur dioxide Reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) composite: highly reproducible and repeatable chemiresistive $ SO_{2} $ sensor |
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Reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) composite: highly reproducible and repeatable chemiresistive $ SO_{2} $ sensor Gas sensor (dpeaa)DE-He213 Graphene (dpeaa)DE-He213 Reduced graphene oxide (dpeaa)DE-He213 Porphyrin (dpeaa)DE-He213 Sulfur dioxide (dpeaa)DE-He213 |
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Reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) composite: highly reproducible and repeatable chemiresistive $ SO_{2} $ sensor |
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Khune, Abhaysinh S. Narwade, Vijaykiran N. Dole, B. N. Ingle, Nikesh N. Tsai, Meng-Lin Hianik, Tibor Shirsat, Mahendra D. |
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reduced graphene oxide (rgo) and 5, 10, 15, 20-tetra-p-tolyl-21h, 23h-porphine (tptp) composite: highly reproducible and repeatable chemiresistive $ so_{2} $ sensor |
| title_auth |
Reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) composite: highly reproducible and repeatable chemiresistive $ SO_{2} $ sensor |
| abstract |
In the current study, a chemiresistive $ SO_{2} $ sensor based on a composite of reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) was developed and extensively studied. Improved Hummers methods were used to synthesize graphene oxide (GO), and a thermally heating bottom-up approach was used to reduce GO to rGO. Gold electrodes were thermally coated on the transparent sheet using a thermal evaporator. The composite of rGO/TPTP was synthesized using a simple chemical method. Structural, morphological, spectroscopic, electrical, and optical studies were carried out using X-ray diffraction, atomic force microscopy, field emission scanning electron microscopy, Fourier-transfer infrared spectroscopy, Raman spectroscopy, current–voltage, and UV–vis spectroscopy, respectively. The sensing response of rGO/TPTP for various concentrations of sulfur dioxide ($ SO_{2} $) was investigated in chemiresistive modality. The rGO/TPTP composite chemiresistive sensor displayed exceptional performance, with a consistent response spanning 1 ppm to 10 ppm. It exhibited outstanding repeatability, linearity, stability, and boasted an impressive limit of detection (LOD) of 1 ppm. This LOD is significantly lower than the recommended permissible exposure limit (PEL) of 5 ppm set by OSHA (Occupational Safety and Health Administration), USA. The sensor based on the rGO/TPTP composite exhibited a very fast response and recovery time of 33 s. and 27 s. respectively. Graphical abstract © The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
In the current study, a chemiresistive $ SO_{2} $ sensor based on a composite of reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) was developed and extensively studied. Improved Hummers methods were used to synthesize graphene oxide (GO), and a thermally heating bottom-up approach was used to reduce GO to rGO. Gold electrodes were thermally coated on the transparent sheet using a thermal evaporator. The composite of rGO/TPTP was synthesized using a simple chemical method. Structural, morphological, spectroscopic, electrical, and optical studies were carried out using X-ray diffraction, atomic force microscopy, field emission scanning electron microscopy, Fourier-transfer infrared spectroscopy, Raman spectroscopy, current–voltage, and UV–vis spectroscopy, respectively. The sensing response of rGO/TPTP for various concentrations of sulfur dioxide ($ SO_{2} $) was investigated in chemiresistive modality. The rGO/TPTP composite chemiresistive sensor displayed exceptional performance, with a consistent response spanning 1 ppm to 10 ppm. It exhibited outstanding repeatability, linearity, stability, and boasted an impressive limit of detection (LOD) of 1 ppm. This LOD is significantly lower than the recommended permissible exposure limit (PEL) of 5 ppm set by OSHA (Occupational Safety and Health Administration), USA. The sensor based on the rGO/TPTP composite exhibited a very fast response and recovery time of 33 s. and 27 s. respectively. Graphical abstract © The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
In the current study, a chemiresistive $ SO_{2} $ sensor based on a composite of reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) was developed and extensively studied. Improved Hummers methods were used to synthesize graphene oxide (GO), and a thermally heating bottom-up approach was used to reduce GO to rGO. Gold electrodes were thermally coated on the transparent sheet using a thermal evaporator. The composite of rGO/TPTP was synthesized using a simple chemical method. Structural, morphological, spectroscopic, electrical, and optical studies were carried out using X-ray diffraction, atomic force microscopy, field emission scanning electron microscopy, Fourier-transfer infrared spectroscopy, Raman spectroscopy, current–voltage, and UV–vis spectroscopy, respectively. The sensing response of rGO/TPTP for various concentrations of sulfur dioxide ($ SO_{2} $) was investigated in chemiresistive modality. The rGO/TPTP composite chemiresistive sensor displayed exceptional performance, with a consistent response spanning 1 ppm to 10 ppm. It exhibited outstanding repeatability, linearity, stability, and boasted an impressive limit of detection (LOD) of 1 ppm. This LOD is significantly lower than the recommended permissible exposure limit (PEL) of 5 ppm set by OSHA (Occupational Safety and Health Administration), USA. The sensor based on the rGO/TPTP composite exhibited a very fast response and recovery time of 33 s. and 27 s. respectively. Graphical abstract © The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| title_short |
Reduced graphene oxide (rGO) and 5, 10, 15, 20-tetra-p-tolyl-21H, 23H-porphine (TPTP) composite: highly reproducible and repeatable chemiresistive $ SO_{2} $ sensor |
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https://dx.doi.org/10.1007/s00339-023-07194-9 |
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Narwade, Vijaykiran N. Dole, B. N. Ingle, Nikesh N. Tsai, Meng-Lin Hianik, Tibor Shirsat, Mahendra D. |
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Narwade, Vijaykiran N. Dole, B. N. Ingle, Nikesh N. Tsai, Meng-Lin Hianik, Tibor Shirsat, Mahendra D. |
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|
| score |
7.39999 |