Physical and shielding properties of $ Er_{2} %$ O_{3} $ rare earth oxide compound content on PCL/PEG blend
Rare earth elements (RRE), due to their unique magnetic, electrical, and optical properties, are an important group of elements demanded in many application areas from machine technology to the health industry. In this study, new composites were obtained by mixing Erbium oxide ($ Er_{2} %$ O_{3} $),...
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| Autor*in: |
Taşgin, Yahya [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Polymer bulletin - Berlin : Springer, 1978, 81(2023), 4 vom: 24. Mai, Seite 2915-2931 |
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| Übergeordnetes Werk: |
volume:81 ; year:2023 ; number:4 ; day:24 ; month:05 ; pages:2915-2931 |
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| DOI / URN: |
10.1007/s00289-023-04818-1 |
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| Katalog-ID: |
SPR054444039 |
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| 520 | |a Rare earth elements (RRE), due to their unique magnetic, electrical, and optical properties, are an important group of elements demanded in many application areas from machine technology to the health industry. In this study, new composites were obtained by mixing Erbium oxide ($ Er_{2} %$ O_{3} $), one of the rare earth element oxides, into PCL–PEG blend, which is also an important material group, in different ratios. The characteristic functional groups of the obtained polymer blend/$ Er_{2} %$ O_{3} $ nanocomposites were determined by the ATR-IR, and as the erbium oxide ratio increased, characteristic peaks of the polymers in the blend as well as characteristic signals of the Er–O–Er bond were found. When the thermal behavior of the obtained composites was examined, it was observed that the polymer blend exhibited miscible blend properties and the melting temperature of the polymer blend increased as the $ Er_{2} %$ O_{3} $ ratio increased. In addition, it was determined that the thermal stability of the composite increased significantly. X-ray measurements of composites at room temperature support other measurement results. It was determined that the presence of Er-RRE oxide increased the crystal structure feature in the polymer blend composite. Gamma radiation shielding capabilities of polymer materials containing different erbium ratios were investigated by calculating shielding parameters such as half value layer (HVL), radiation protection efficiency (RPE), and mean free path (MFP). Cs-137 and Co-60 radioactive sources were used as gamma sources. According to the obtained measurement results, Erbium oxide increased the absorption property of the polymer composite material. Graphical abstract | ||
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10.1007/s00289-023-04818-1 doi (DE-627)SPR054444039 (SPR)s00289-023-04818-1-e DE-627 ger DE-627 rakwb eng Taşgin, Yahya verfasserin aut Physical and shielding properties of $ Er_{2} %$ O_{3} $ rare earth oxide compound content on PCL/PEG blend 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Rare earth elements (RRE), due to their unique magnetic, electrical, and optical properties, are an important group of elements demanded in many application areas from machine technology to the health industry. In this study, new composites were obtained by mixing Erbium oxide ($ Er_{2} %$ O_{3} $), one of the rare earth element oxides, into PCL–PEG blend, which is also an important material group, in different ratios. The characteristic functional groups of the obtained polymer blend/$ Er_{2} %$ O_{3} $ nanocomposites were determined by the ATR-IR, and as the erbium oxide ratio increased, characteristic peaks of the polymers in the blend as well as characteristic signals of the Er–O–Er bond were found. When the thermal behavior of the obtained composites was examined, it was observed that the polymer blend exhibited miscible blend properties and the melting temperature of the polymer blend increased as the $ Er_{2} %$ O_{3} $ ratio increased. In addition, it was determined that the thermal stability of the composite increased significantly. X-ray measurements of composites at room temperature support other measurement results. It was determined that the presence of Er-RRE oxide increased the crystal structure feature in the polymer blend composite. Gamma radiation shielding capabilities of polymer materials containing different erbium ratios were investigated by calculating shielding parameters such as half value layer (HVL), radiation protection efficiency (RPE), and mean free path (MFP). Cs-137 and Co-60 radioactive sources were used as gamma sources. According to the obtained measurement results, Erbium oxide increased the absorption property of the polymer composite material. Graphical abstract Rare earth element (dpeaa)DE-He213 Polymer blends (dpeaa)DE-He213 Composite (dpeaa)DE-He213 Thermal stability (dpeaa)DE-He213 Radiation shielding (dpeaa)DE-He213 Pekdemir, Mustafa Ersin (orcid)0000-0002-4979-1777 aut Yilmaz, Mücahit aut Kanca, Muhammed Sait aut Kök, Mediha aut Enthalten in Polymer bulletin Berlin : Springer, 1978 81(2023), 4 vom: 24. Mai, Seite 2915-2931 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:81 year:2023 number:4 day:24 month:05 pages:2915-2931 https://dx.doi.org/10.1007/s00289-023-04818-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 81 2023 4 24 05 2915-2931 |
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10.1007/s00289-023-04818-1 doi (DE-627)SPR054444039 (SPR)s00289-023-04818-1-e DE-627 ger DE-627 rakwb eng Taşgin, Yahya verfasserin aut Physical and shielding properties of $ Er_{2} %$ O_{3} $ rare earth oxide compound content on PCL/PEG blend 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Rare earth elements (RRE), due to their unique magnetic, electrical, and optical properties, are an important group of elements demanded in many application areas from machine technology to the health industry. In this study, new composites were obtained by mixing Erbium oxide ($ Er_{2} %$ O_{3} $), one of the rare earth element oxides, into PCL–PEG blend, which is also an important material group, in different ratios. The characteristic functional groups of the obtained polymer blend/$ Er_{2} %$ O_{3} $ nanocomposites were determined by the ATR-IR, and as the erbium oxide ratio increased, characteristic peaks of the polymers in the blend as well as characteristic signals of the Er–O–Er bond were found. When the thermal behavior of the obtained composites was examined, it was observed that the polymer blend exhibited miscible blend properties and the melting temperature of the polymer blend increased as the $ Er_{2} %$ O_{3} $ ratio increased. In addition, it was determined that the thermal stability of the composite increased significantly. X-ray measurements of composites at room temperature support other measurement results. It was determined that the presence of Er-RRE oxide increased the crystal structure feature in the polymer blend composite. Gamma radiation shielding capabilities of polymer materials containing different erbium ratios were investigated by calculating shielding parameters such as half value layer (HVL), radiation protection efficiency (RPE), and mean free path (MFP). Cs-137 and Co-60 radioactive sources were used as gamma sources. According to the obtained measurement results, Erbium oxide increased the absorption property of the polymer composite material. Graphical abstract Rare earth element (dpeaa)DE-He213 Polymer blends (dpeaa)DE-He213 Composite (dpeaa)DE-He213 Thermal stability (dpeaa)DE-He213 Radiation shielding (dpeaa)DE-He213 Pekdemir, Mustafa Ersin (orcid)0000-0002-4979-1777 aut Yilmaz, Mücahit aut Kanca, Muhammed Sait aut Kök, Mediha aut Enthalten in Polymer bulletin Berlin : Springer, 1978 81(2023), 4 vom: 24. Mai, Seite 2915-2931 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:81 year:2023 number:4 day:24 month:05 pages:2915-2931 https://dx.doi.org/10.1007/s00289-023-04818-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 81 2023 4 24 05 2915-2931 |
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10.1007/s00289-023-04818-1 doi (DE-627)SPR054444039 (SPR)s00289-023-04818-1-e DE-627 ger DE-627 rakwb eng Taşgin, Yahya verfasserin aut Physical and shielding properties of $ Er_{2} %$ O_{3} $ rare earth oxide compound content on PCL/PEG blend 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Rare earth elements (RRE), due to their unique magnetic, electrical, and optical properties, are an important group of elements demanded in many application areas from machine technology to the health industry. In this study, new composites were obtained by mixing Erbium oxide ($ Er_{2} %$ O_{3} $), one of the rare earth element oxides, into PCL–PEG blend, which is also an important material group, in different ratios. The characteristic functional groups of the obtained polymer blend/$ Er_{2} %$ O_{3} $ nanocomposites were determined by the ATR-IR, and as the erbium oxide ratio increased, characteristic peaks of the polymers in the blend as well as characteristic signals of the Er–O–Er bond were found. When the thermal behavior of the obtained composites was examined, it was observed that the polymer blend exhibited miscible blend properties and the melting temperature of the polymer blend increased as the $ Er_{2} %$ O_{3} $ ratio increased. In addition, it was determined that the thermal stability of the composite increased significantly. X-ray measurements of composites at room temperature support other measurement results. It was determined that the presence of Er-RRE oxide increased the crystal structure feature in the polymer blend composite. Gamma radiation shielding capabilities of polymer materials containing different erbium ratios were investigated by calculating shielding parameters such as half value layer (HVL), radiation protection efficiency (RPE), and mean free path (MFP). Cs-137 and Co-60 radioactive sources were used as gamma sources. According to the obtained measurement results, Erbium oxide increased the absorption property of the polymer composite material. Graphical abstract Rare earth element (dpeaa)DE-He213 Polymer blends (dpeaa)DE-He213 Composite (dpeaa)DE-He213 Thermal stability (dpeaa)DE-He213 Radiation shielding (dpeaa)DE-He213 Pekdemir, Mustafa Ersin (orcid)0000-0002-4979-1777 aut Yilmaz, Mücahit aut Kanca, Muhammed Sait aut Kök, Mediha aut Enthalten in Polymer bulletin Berlin : Springer, 1978 81(2023), 4 vom: 24. Mai, Seite 2915-2931 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:81 year:2023 number:4 day:24 month:05 pages:2915-2931 https://dx.doi.org/10.1007/s00289-023-04818-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 81 2023 4 24 05 2915-2931 |
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10.1007/s00289-023-04818-1 doi (DE-627)SPR054444039 (SPR)s00289-023-04818-1-e DE-627 ger DE-627 rakwb eng Taşgin, Yahya verfasserin aut Physical and shielding properties of $ Er_{2} %$ O_{3} $ rare earth oxide compound content on PCL/PEG blend 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Rare earth elements (RRE), due to their unique magnetic, electrical, and optical properties, are an important group of elements demanded in many application areas from machine technology to the health industry. In this study, new composites were obtained by mixing Erbium oxide ($ Er_{2} %$ O_{3} $), one of the rare earth element oxides, into PCL–PEG blend, which is also an important material group, in different ratios. The characteristic functional groups of the obtained polymer blend/$ Er_{2} %$ O_{3} $ nanocomposites were determined by the ATR-IR, and as the erbium oxide ratio increased, characteristic peaks of the polymers in the blend as well as characteristic signals of the Er–O–Er bond were found. When the thermal behavior of the obtained composites was examined, it was observed that the polymer blend exhibited miscible blend properties and the melting temperature of the polymer blend increased as the $ Er_{2} %$ O_{3} $ ratio increased. In addition, it was determined that the thermal stability of the composite increased significantly. X-ray measurements of composites at room temperature support other measurement results. It was determined that the presence of Er-RRE oxide increased the crystal structure feature in the polymer blend composite. Gamma radiation shielding capabilities of polymer materials containing different erbium ratios were investigated by calculating shielding parameters such as half value layer (HVL), radiation protection efficiency (RPE), and mean free path (MFP). Cs-137 and Co-60 radioactive sources were used as gamma sources. According to the obtained measurement results, Erbium oxide increased the absorption property of the polymer composite material. Graphical abstract Rare earth element (dpeaa)DE-He213 Polymer blends (dpeaa)DE-He213 Composite (dpeaa)DE-He213 Thermal stability (dpeaa)DE-He213 Radiation shielding (dpeaa)DE-He213 Pekdemir, Mustafa Ersin (orcid)0000-0002-4979-1777 aut Yilmaz, Mücahit aut Kanca, Muhammed Sait aut Kök, Mediha aut Enthalten in Polymer bulletin Berlin : Springer, 1978 81(2023), 4 vom: 24. Mai, Seite 2915-2931 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:81 year:2023 number:4 day:24 month:05 pages:2915-2931 https://dx.doi.org/10.1007/s00289-023-04818-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 81 2023 4 24 05 2915-2931 |
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10.1007/s00289-023-04818-1 doi (DE-627)SPR054444039 (SPR)s00289-023-04818-1-e DE-627 ger DE-627 rakwb eng Taşgin, Yahya verfasserin aut Physical and shielding properties of $ Er_{2} %$ O_{3} $ rare earth oxide compound content on PCL/PEG blend 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Rare earth elements (RRE), due to their unique magnetic, electrical, and optical properties, are an important group of elements demanded in many application areas from machine technology to the health industry. In this study, new composites were obtained by mixing Erbium oxide ($ Er_{2} %$ O_{3} $), one of the rare earth element oxides, into PCL–PEG blend, which is also an important material group, in different ratios. The characteristic functional groups of the obtained polymer blend/$ Er_{2} %$ O_{3} $ nanocomposites were determined by the ATR-IR, and as the erbium oxide ratio increased, characteristic peaks of the polymers in the blend as well as characteristic signals of the Er–O–Er bond were found. When the thermal behavior of the obtained composites was examined, it was observed that the polymer blend exhibited miscible blend properties and the melting temperature of the polymer blend increased as the $ Er_{2} %$ O_{3} $ ratio increased. In addition, it was determined that the thermal stability of the composite increased significantly. X-ray measurements of composites at room temperature support other measurement results. It was determined that the presence of Er-RRE oxide increased the crystal structure feature in the polymer blend composite. Gamma radiation shielding capabilities of polymer materials containing different erbium ratios were investigated by calculating shielding parameters such as half value layer (HVL), radiation protection efficiency (RPE), and mean free path (MFP). Cs-137 and Co-60 radioactive sources were used as gamma sources. According to the obtained measurement results, Erbium oxide increased the absorption property of the polymer composite material. Graphical abstract Rare earth element (dpeaa)DE-He213 Polymer blends (dpeaa)DE-He213 Composite (dpeaa)DE-He213 Thermal stability (dpeaa)DE-He213 Radiation shielding (dpeaa)DE-He213 Pekdemir, Mustafa Ersin (orcid)0000-0002-4979-1777 aut Yilmaz, Mücahit aut Kanca, Muhammed Sait aut Kök, Mediha aut Enthalten in Polymer bulletin Berlin : Springer, 1978 81(2023), 4 vom: 24. Mai, Seite 2915-2931 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:81 year:2023 number:4 day:24 month:05 pages:2915-2931 https://dx.doi.org/10.1007/s00289-023-04818-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 81 2023 4 24 05 2915-2931 |
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Enthalten in Polymer bulletin 81(2023), 4 vom: 24. Mai, Seite 2915-2931 volume:81 year:2023 number:4 day:24 month:05 pages:2915-2931 |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Rare earth elements (RRE), due to their unique magnetic, electrical, and optical properties, are an important group of elements demanded in many application areas from machine technology to the health industry. In this study, new composites were obtained by mixing Erbium oxide ($ Er_{2} %$ O_{3} $), one of the rare earth element oxides, into PCL–PEG blend, which is also an important material group, in different ratios. The characteristic functional groups of the obtained polymer blend/$ Er_{2} %$ O_{3} $ nanocomposites were determined by the ATR-IR, and as the erbium oxide ratio increased, characteristic peaks of the polymers in the blend as well as characteristic signals of the Er–O–Er bond were found. When the thermal behavior of the obtained composites was examined, it was observed that the polymer blend exhibited miscible blend properties and the melting temperature of the polymer blend increased as the $ Er_{2} %$ O_{3} $ ratio increased. In addition, it was determined that the thermal stability of the composite increased significantly. X-ray measurements of composites at room temperature support other measurement results. It was determined that the presence of Er-RRE oxide increased the crystal structure feature in the polymer blend composite. Gamma radiation shielding capabilities of polymer materials containing different erbium ratios were investigated by calculating shielding parameters such as half value layer (HVL), radiation protection efficiency (RPE), and mean free path (MFP). Cs-137 and Co-60 radioactive sources were used as gamma sources. According to the obtained measurement results, Erbium oxide increased the absorption property of the polymer composite material. 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Taşgin, Yahya |
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Taşgin, Yahya misc Rare earth element misc Polymer blends misc Composite misc Thermal stability misc Radiation shielding Physical and shielding properties of $ Er_{2} %$ O_{3} $ rare earth oxide compound content on PCL/PEG blend |
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Physical and shielding properties of $ Er_{2} %$ O_{3} $ rare earth oxide compound content on PCL/PEG blend Rare earth element (dpeaa)DE-He213 Polymer blends (dpeaa)DE-He213 Composite (dpeaa)DE-He213 Thermal stability (dpeaa)DE-He213 Radiation shielding (dpeaa)DE-He213 |
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Physical and shielding properties of $ Er_{2} %$ O_{3} $ rare earth oxide compound content on PCL/PEG blend |
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physical and shielding properties of $ er_{2} %$ o_{3} $ rare earth oxide compound content on pcl/peg blend |
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Physical and shielding properties of $ Er_{2} %$ O_{3} $ rare earth oxide compound content on PCL/PEG blend |
| abstract |
Rare earth elements (RRE), due to their unique magnetic, electrical, and optical properties, are an important group of elements demanded in many application areas from machine technology to the health industry. In this study, new composites were obtained by mixing Erbium oxide ($ Er_{2} %$ O_{3} $), one of the rare earth element oxides, into PCL–PEG blend, which is also an important material group, in different ratios. The characteristic functional groups of the obtained polymer blend/$ Er_{2} %$ O_{3} $ nanocomposites were determined by the ATR-IR, and as the erbium oxide ratio increased, characteristic peaks of the polymers in the blend as well as characteristic signals of the Er–O–Er bond were found. When the thermal behavior of the obtained composites was examined, it was observed that the polymer blend exhibited miscible blend properties and the melting temperature of the polymer blend increased as the $ Er_{2} %$ O_{3} $ ratio increased. In addition, it was determined that the thermal stability of the composite increased significantly. X-ray measurements of composites at room temperature support other measurement results. It was determined that the presence of Er-RRE oxide increased the crystal structure feature in the polymer blend composite. Gamma radiation shielding capabilities of polymer materials containing different erbium ratios were investigated by calculating shielding parameters such as half value layer (HVL), radiation protection efficiency (RPE), and mean free path (MFP). Cs-137 and Co-60 radioactive sources were used as gamma sources. According to the obtained measurement results, Erbium oxide increased the absorption property of the polymer composite material. Graphical abstract © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Rare earth elements (RRE), due to their unique magnetic, electrical, and optical properties, are an important group of elements demanded in many application areas from machine technology to the health industry. In this study, new composites were obtained by mixing Erbium oxide ($ Er_{2} %$ O_{3} $), one of the rare earth element oxides, into PCL–PEG blend, which is also an important material group, in different ratios. The characteristic functional groups of the obtained polymer blend/$ Er_{2} %$ O_{3} $ nanocomposites were determined by the ATR-IR, and as the erbium oxide ratio increased, characteristic peaks of the polymers in the blend as well as characteristic signals of the Er–O–Er bond were found. When the thermal behavior of the obtained composites was examined, it was observed that the polymer blend exhibited miscible blend properties and the melting temperature of the polymer blend increased as the $ Er_{2} %$ O_{3} $ ratio increased. In addition, it was determined that the thermal stability of the composite increased significantly. X-ray measurements of composites at room temperature support other measurement results. It was determined that the presence of Er-RRE oxide increased the crystal structure feature in the polymer blend composite. Gamma radiation shielding capabilities of polymer materials containing different erbium ratios were investigated by calculating shielding parameters such as half value layer (HVL), radiation protection efficiency (RPE), and mean free path (MFP). Cs-137 and Co-60 radioactive sources were used as gamma sources. According to the obtained measurement results, Erbium oxide increased the absorption property of the polymer composite material. Graphical abstract © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Rare earth elements (RRE), due to their unique magnetic, electrical, and optical properties, are an important group of elements demanded in many application areas from machine technology to the health industry. In this study, new composites were obtained by mixing Erbium oxide ($ Er_{2} %$ O_{3} $), one of the rare earth element oxides, into PCL–PEG blend, which is also an important material group, in different ratios. The characteristic functional groups of the obtained polymer blend/$ Er_{2} %$ O_{3} $ nanocomposites were determined by the ATR-IR, and as the erbium oxide ratio increased, characteristic peaks of the polymers in the blend as well as characteristic signals of the Er–O–Er bond were found. When the thermal behavior of the obtained composites was examined, it was observed that the polymer blend exhibited miscible blend properties and the melting temperature of the polymer blend increased as the $ Er_{2} %$ O_{3} $ ratio increased. In addition, it was determined that the thermal stability of the composite increased significantly. X-ray measurements of composites at room temperature support other measurement results. It was determined that the presence of Er-RRE oxide increased the crystal structure feature in the polymer blend composite. Gamma radiation shielding capabilities of polymer materials containing different erbium ratios were investigated by calculating shielding parameters such as half value layer (HVL), radiation protection efficiency (RPE), and mean free path (MFP). Cs-137 and Co-60 radioactive sources were used as gamma sources. According to the obtained measurement results, Erbium oxide increased the absorption property of the polymer composite material. Graphical abstract © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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4 |
| title_short |
Physical and shielding properties of $ Er_{2} %$ O_{3} $ rare earth oxide compound content on PCL/PEG blend |
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https://dx.doi.org/10.1007/s00289-023-04818-1 |
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Pekdemir, Mustafa Ersin Yilmaz, Mücahit Kanca, Muhammed Sait Kök, Mediha |
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Pekdemir, Mustafa Ersin Yilmaz, Mücahit Kanca, Muhammed Sait Kök, Mediha |
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10.1007/s00289-023-04818-1 |
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| score |
7.399315 |