Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels
Abstract Pharmaceutically active compounds (PhACs) are frequently detected emerging pollutants in water resources worldwide that provoke pernicious influences on human health and the ecosystem. Developing effective carbonaceous adsorbents from biomass for the efficient removal of PhACs has lately dr...
Ausführliche Beschreibung
Autor*in: |
Saied, Mohamed El [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2022 |
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Schlagwörter: |
Acetaminophen removal, Adsorption |
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Anmerkung: |
© The Author(s) 2022 |
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Übergeordnetes Werk: |
Enthalten in: Biomass Conversion and Biorefinery - Berlin : Springer, 2011, 14(2022), 2 vom: 30. März, Seite 2155-2172 |
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Übergeordnetes Werk: |
volume:14 ; year:2022 ; number:2 ; day:30 ; month:03 ; pages:2155-2172 |
Links: |
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DOI / URN: |
10.1007/s13399-022-02541-x |
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Katalog-ID: |
SPR054480752 |
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245 | 1 | 0 | |a Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels |
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520 | |a Abstract Pharmaceutically active compounds (PhACs) are frequently detected emerging pollutants in water resources worldwide that provoke pernicious influences on human health and the ecosystem. Developing effective carbonaceous adsorbents from biomass for the efficient removal of PhACs has lately drawn significant research attention. Herein, an efficient and cost-effective activated carbon was produced via $ ZnCl_{2} $-activation, employing orange peels as a precursor (named hereafter as OPAC). OPAC was well-characterized and applied in the sequestration of acetaminophen (N-acetyl-para-aminophenol, APAP), a broadly used non-steroidal anti-inflammatory drug, from water media using the batch technique. OPAC exhibited excellent performance, and more than 95.5% APAP was removed after 90 min, in the pH range of 2.0–8.0, using 1 g/l adsorbent at 25 °C. Additionally, the equilibrium and the kinetic studies outcomes unveiled the suitability of the Langmuir and the pseudo-second-order kinetic models, respectively, to describe the adsorption process. Based on the pH-adsorption dependence and OPAC properties, the presumable mechanism was mainly dominated by non-electrostatic interactions, including hydrogen bonding, π-π interactions, and pore diffusion. Thermodynamically, the process was found to be spontaneous and endothermic. Ultimately, OPAC manifested outstanding recyclability, with at least 95% of the initial efficiency being preserved after five cycles, making it more attractive from the environmental and economic perspectives. | ||
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10.1007/s13399-022-02541-x doi (DE-627)SPR054480752 (SPR)s13399-022-02541-x-e DE-627 ger DE-627 rakwb eng Saied, Mohamed El verfasserin aut Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2022 Abstract Pharmaceutically active compounds (PhACs) are frequently detected emerging pollutants in water resources worldwide that provoke pernicious influences on human health and the ecosystem. Developing effective carbonaceous adsorbents from biomass for the efficient removal of PhACs has lately drawn significant research attention. Herein, an efficient and cost-effective activated carbon was produced via $ ZnCl_{2} $-activation, employing orange peels as a precursor (named hereafter as OPAC). OPAC was well-characterized and applied in the sequestration of acetaminophen (N-acetyl-para-aminophenol, APAP), a broadly used non-steroidal anti-inflammatory drug, from water media using the batch technique. OPAC exhibited excellent performance, and more than 95.5% APAP was removed after 90 min, in the pH range of 2.0–8.0, using 1 g/l adsorbent at 25 °C. Additionally, the equilibrium and the kinetic studies outcomes unveiled the suitability of the Langmuir and the pseudo-second-order kinetic models, respectively, to describe the adsorption process. Based on the pH-adsorption dependence and OPAC properties, the presumable mechanism was mainly dominated by non-electrostatic interactions, including hydrogen bonding, π-π interactions, and pore diffusion. Thermodynamically, the process was found to be spontaneous and endothermic. Ultimately, OPAC manifested outstanding recyclability, with at least 95% of the initial efficiency being preserved after five cycles, making it more attractive from the environmental and economic perspectives. Acetaminophen removal, Adsorption (dpeaa)DE-He213 Orange peels (dpeaa)DE-He213 Orange peel-derived activated carbon (dpeaa)DE-He213 ZnCl (dpeaa)DE-He213 activation (dpeaa)DE-He213 Paracetamol (dpeaa)DE-He213 Shaban, Seham A. aut Mostafa, Mohsen S. aut Naga, Ahmed O. Abo El (orcid)0000-0001-9822-0703 aut Enthalten in Biomass Conversion and Biorefinery Berlin : Springer, 2011 14(2022), 2 vom: 30. März, Seite 2155-2172 (DE-627)645092843 (DE-600)2592298-1 2190-6823 nnns volume:14 year:2022 number:2 day:30 month:03 pages:2155-2172 https://dx.doi.org/10.1007/s13399-022-02541-x kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 14 2022 2 30 03 2155-2172 |
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10.1007/s13399-022-02541-x doi (DE-627)SPR054480752 (SPR)s13399-022-02541-x-e DE-627 ger DE-627 rakwb eng Saied, Mohamed El verfasserin aut Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2022 Abstract Pharmaceutically active compounds (PhACs) are frequently detected emerging pollutants in water resources worldwide that provoke pernicious influences on human health and the ecosystem. Developing effective carbonaceous adsorbents from biomass for the efficient removal of PhACs has lately drawn significant research attention. Herein, an efficient and cost-effective activated carbon was produced via $ ZnCl_{2} $-activation, employing orange peels as a precursor (named hereafter as OPAC). OPAC was well-characterized and applied in the sequestration of acetaminophen (N-acetyl-para-aminophenol, APAP), a broadly used non-steroidal anti-inflammatory drug, from water media using the batch technique. OPAC exhibited excellent performance, and more than 95.5% APAP was removed after 90 min, in the pH range of 2.0–8.0, using 1 g/l adsorbent at 25 °C. Additionally, the equilibrium and the kinetic studies outcomes unveiled the suitability of the Langmuir and the pseudo-second-order kinetic models, respectively, to describe the adsorption process. Based on the pH-adsorption dependence and OPAC properties, the presumable mechanism was mainly dominated by non-electrostatic interactions, including hydrogen bonding, π-π interactions, and pore diffusion. Thermodynamically, the process was found to be spontaneous and endothermic. Ultimately, OPAC manifested outstanding recyclability, with at least 95% of the initial efficiency being preserved after five cycles, making it more attractive from the environmental and economic perspectives. Acetaminophen removal, Adsorption (dpeaa)DE-He213 Orange peels (dpeaa)DE-He213 Orange peel-derived activated carbon (dpeaa)DE-He213 ZnCl (dpeaa)DE-He213 activation (dpeaa)DE-He213 Paracetamol (dpeaa)DE-He213 Shaban, Seham A. aut Mostafa, Mohsen S. aut Naga, Ahmed O. Abo El (orcid)0000-0001-9822-0703 aut Enthalten in Biomass Conversion and Biorefinery Berlin : Springer, 2011 14(2022), 2 vom: 30. März, Seite 2155-2172 (DE-627)645092843 (DE-600)2592298-1 2190-6823 nnns volume:14 year:2022 number:2 day:30 month:03 pages:2155-2172 https://dx.doi.org/10.1007/s13399-022-02541-x kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 14 2022 2 30 03 2155-2172 |
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10.1007/s13399-022-02541-x doi (DE-627)SPR054480752 (SPR)s13399-022-02541-x-e DE-627 ger DE-627 rakwb eng Saied, Mohamed El verfasserin aut Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2022 Abstract Pharmaceutically active compounds (PhACs) are frequently detected emerging pollutants in water resources worldwide that provoke pernicious influences on human health and the ecosystem. Developing effective carbonaceous adsorbents from biomass for the efficient removal of PhACs has lately drawn significant research attention. Herein, an efficient and cost-effective activated carbon was produced via $ ZnCl_{2} $-activation, employing orange peels as a precursor (named hereafter as OPAC). OPAC was well-characterized and applied in the sequestration of acetaminophen (N-acetyl-para-aminophenol, APAP), a broadly used non-steroidal anti-inflammatory drug, from water media using the batch technique. OPAC exhibited excellent performance, and more than 95.5% APAP was removed after 90 min, in the pH range of 2.0–8.0, using 1 g/l adsorbent at 25 °C. Additionally, the equilibrium and the kinetic studies outcomes unveiled the suitability of the Langmuir and the pseudo-second-order kinetic models, respectively, to describe the adsorption process. Based on the pH-adsorption dependence and OPAC properties, the presumable mechanism was mainly dominated by non-electrostatic interactions, including hydrogen bonding, π-π interactions, and pore diffusion. Thermodynamically, the process was found to be spontaneous and endothermic. Ultimately, OPAC manifested outstanding recyclability, with at least 95% of the initial efficiency being preserved after five cycles, making it more attractive from the environmental and economic perspectives. Acetaminophen removal, Adsorption (dpeaa)DE-He213 Orange peels (dpeaa)DE-He213 Orange peel-derived activated carbon (dpeaa)DE-He213 ZnCl (dpeaa)DE-He213 activation (dpeaa)DE-He213 Paracetamol (dpeaa)DE-He213 Shaban, Seham A. aut Mostafa, Mohsen S. aut Naga, Ahmed O. Abo El (orcid)0000-0001-9822-0703 aut Enthalten in Biomass Conversion and Biorefinery Berlin : Springer, 2011 14(2022), 2 vom: 30. März, Seite 2155-2172 (DE-627)645092843 (DE-600)2592298-1 2190-6823 nnns volume:14 year:2022 number:2 day:30 month:03 pages:2155-2172 https://dx.doi.org/10.1007/s13399-022-02541-x kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 14 2022 2 30 03 2155-2172 |
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10.1007/s13399-022-02541-x doi (DE-627)SPR054480752 (SPR)s13399-022-02541-x-e DE-627 ger DE-627 rakwb eng Saied, Mohamed El verfasserin aut Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2022 Abstract Pharmaceutically active compounds (PhACs) are frequently detected emerging pollutants in water resources worldwide that provoke pernicious influences on human health and the ecosystem. Developing effective carbonaceous adsorbents from biomass for the efficient removal of PhACs has lately drawn significant research attention. Herein, an efficient and cost-effective activated carbon was produced via $ ZnCl_{2} $-activation, employing orange peels as a precursor (named hereafter as OPAC). OPAC was well-characterized and applied in the sequestration of acetaminophen (N-acetyl-para-aminophenol, APAP), a broadly used non-steroidal anti-inflammatory drug, from water media using the batch technique. OPAC exhibited excellent performance, and more than 95.5% APAP was removed after 90 min, in the pH range of 2.0–8.0, using 1 g/l adsorbent at 25 °C. Additionally, the equilibrium and the kinetic studies outcomes unveiled the suitability of the Langmuir and the pseudo-second-order kinetic models, respectively, to describe the adsorption process. Based on the pH-adsorption dependence and OPAC properties, the presumable mechanism was mainly dominated by non-electrostatic interactions, including hydrogen bonding, π-π interactions, and pore diffusion. Thermodynamically, the process was found to be spontaneous and endothermic. Ultimately, OPAC manifested outstanding recyclability, with at least 95% of the initial efficiency being preserved after five cycles, making it more attractive from the environmental and economic perspectives. Acetaminophen removal, Adsorption (dpeaa)DE-He213 Orange peels (dpeaa)DE-He213 Orange peel-derived activated carbon (dpeaa)DE-He213 ZnCl (dpeaa)DE-He213 activation (dpeaa)DE-He213 Paracetamol (dpeaa)DE-He213 Shaban, Seham A. aut Mostafa, Mohsen S. aut Naga, Ahmed O. Abo El (orcid)0000-0001-9822-0703 aut Enthalten in Biomass Conversion and Biorefinery Berlin : Springer, 2011 14(2022), 2 vom: 30. März, Seite 2155-2172 (DE-627)645092843 (DE-600)2592298-1 2190-6823 nnns volume:14 year:2022 number:2 day:30 month:03 pages:2155-2172 https://dx.doi.org/10.1007/s13399-022-02541-x kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 14 2022 2 30 03 2155-2172 |
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10.1007/s13399-022-02541-x doi (DE-627)SPR054480752 (SPR)s13399-022-02541-x-e DE-627 ger DE-627 rakwb eng Saied, Mohamed El verfasserin aut Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2022 Abstract Pharmaceutically active compounds (PhACs) are frequently detected emerging pollutants in water resources worldwide that provoke pernicious influences on human health and the ecosystem. Developing effective carbonaceous adsorbents from biomass for the efficient removal of PhACs has lately drawn significant research attention. Herein, an efficient and cost-effective activated carbon was produced via $ ZnCl_{2} $-activation, employing orange peels as a precursor (named hereafter as OPAC). OPAC was well-characterized and applied in the sequestration of acetaminophen (N-acetyl-para-aminophenol, APAP), a broadly used non-steroidal anti-inflammatory drug, from water media using the batch technique. OPAC exhibited excellent performance, and more than 95.5% APAP was removed after 90 min, in the pH range of 2.0–8.0, using 1 g/l adsorbent at 25 °C. Additionally, the equilibrium and the kinetic studies outcomes unveiled the suitability of the Langmuir and the pseudo-second-order kinetic models, respectively, to describe the adsorption process. Based on the pH-adsorption dependence and OPAC properties, the presumable mechanism was mainly dominated by non-electrostatic interactions, including hydrogen bonding, π-π interactions, and pore diffusion. Thermodynamically, the process was found to be spontaneous and endothermic. Ultimately, OPAC manifested outstanding recyclability, with at least 95% of the initial efficiency being preserved after five cycles, making it more attractive from the environmental and economic perspectives. Acetaminophen removal, Adsorption (dpeaa)DE-He213 Orange peels (dpeaa)DE-He213 Orange peel-derived activated carbon (dpeaa)DE-He213 ZnCl (dpeaa)DE-He213 activation (dpeaa)DE-He213 Paracetamol (dpeaa)DE-He213 Shaban, Seham A. aut Mostafa, Mohsen S. aut Naga, Ahmed O. Abo El (orcid)0000-0001-9822-0703 aut Enthalten in Biomass Conversion and Biorefinery Berlin : Springer, 2011 14(2022), 2 vom: 30. März, Seite 2155-2172 (DE-627)645092843 (DE-600)2592298-1 2190-6823 nnns volume:14 year:2022 number:2 day:30 month:03 pages:2155-2172 https://dx.doi.org/10.1007/s13399-022-02541-x kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 14 2022 2 30 03 2155-2172 |
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Enthalten in Biomass Conversion and Biorefinery 14(2022), 2 vom: 30. März, Seite 2155-2172 volume:14 year:2022 number:2 day:30 month:03 pages:2155-2172 |
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Developing effective carbonaceous adsorbents from biomass for the efficient removal of PhACs has lately drawn significant research attention. Herein, an efficient and cost-effective activated carbon was produced via $ ZnCl_{2} $-activation, employing orange peels as a precursor (named hereafter as OPAC). OPAC was well-characterized and applied in the sequestration of acetaminophen (N-acetyl-para-aminophenol, APAP), a broadly used non-steroidal anti-inflammatory drug, from water media using the batch technique. OPAC exhibited excellent performance, and more than 95.5% APAP was removed after 90 min, in the pH range of 2.0–8.0, using 1 g/l adsorbent at 25 °C. Additionally, the equilibrium and the kinetic studies outcomes unveiled the suitability of the Langmuir and the pseudo-second-order kinetic models, respectively, to describe the adsorption process. Based on the pH-adsorption dependence and OPAC properties, the presumable mechanism was mainly dominated by non-electrostatic interactions, including hydrogen bonding, π-π interactions, and pore diffusion. Thermodynamically, the process was found to be spontaneous and endothermic. Ultimately, OPAC manifested outstanding recyclability, with at least 95% of the initial efficiency being preserved after five cycles, making it more attractive from the environmental and economic perspectives.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Acetaminophen removal, Adsorption</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Orange peels</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Orange peel-derived activated carbon</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">ZnCl</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">activation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Paracetamol</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Shaban, Seham A.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mostafa, Mohsen S.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Naga, Ahmed O. 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|
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Saied, Mohamed El |
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Saied, Mohamed El misc Acetaminophen removal, Adsorption misc Orange peels misc Orange peel-derived activated carbon misc ZnCl misc activation misc Paracetamol Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels |
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Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels Acetaminophen removal, Adsorption (dpeaa)DE-He213 Orange peels (dpeaa)DE-He213 Orange peel-derived activated carbon (dpeaa)DE-He213 ZnCl (dpeaa)DE-He213 activation (dpeaa)DE-He213 Paracetamol (dpeaa)DE-He213 |
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misc Acetaminophen removal, Adsorption misc Orange peels misc Orange peel-derived activated carbon misc ZnCl misc activation misc Paracetamol |
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misc Acetaminophen removal, Adsorption misc Orange peels misc Orange peel-derived activated carbon misc ZnCl misc activation misc Paracetamol |
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Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels |
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Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels |
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Saied, Mohamed El |
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Biomass Conversion and Biorefinery |
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Saied, Mohamed El Shaban, Seham A. Mostafa, Mohsen S. Naga, Ahmed O. Abo El |
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title_sort |
efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels |
title_auth |
Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels |
abstract |
Abstract Pharmaceutically active compounds (PhACs) are frequently detected emerging pollutants in water resources worldwide that provoke pernicious influences on human health and the ecosystem. Developing effective carbonaceous adsorbents from biomass for the efficient removal of PhACs has lately drawn significant research attention. Herein, an efficient and cost-effective activated carbon was produced via $ ZnCl_{2} $-activation, employing orange peels as a precursor (named hereafter as OPAC). OPAC was well-characterized and applied in the sequestration of acetaminophen (N-acetyl-para-aminophenol, APAP), a broadly used non-steroidal anti-inflammatory drug, from water media using the batch technique. OPAC exhibited excellent performance, and more than 95.5% APAP was removed after 90 min, in the pH range of 2.0–8.0, using 1 g/l adsorbent at 25 °C. Additionally, the equilibrium and the kinetic studies outcomes unveiled the suitability of the Langmuir and the pseudo-second-order kinetic models, respectively, to describe the adsorption process. Based on the pH-adsorption dependence and OPAC properties, the presumable mechanism was mainly dominated by non-electrostatic interactions, including hydrogen bonding, π-π interactions, and pore diffusion. Thermodynamically, the process was found to be spontaneous and endothermic. Ultimately, OPAC manifested outstanding recyclability, with at least 95% of the initial efficiency being preserved after five cycles, making it more attractive from the environmental and economic perspectives. © The Author(s) 2022 |
abstractGer |
Abstract Pharmaceutically active compounds (PhACs) are frequently detected emerging pollutants in water resources worldwide that provoke pernicious influences on human health and the ecosystem. Developing effective carbonaceous adsorbents from biomass for the efficient removal of PhACs has lately drawn significant research attention. Herein, an efficient and cost-effective activated carbon was produced via $ ZnCl_{2} $-activation, employing orange peels as a precursor (named hereafter as OPAC). OPAC was well-characterized and applied in the sequestration of acetaminophen (N-acetyl-para-aminophenol, APAP), a broadly used non-steroidal anti-inflammatory drug, from water media using the batch technique. OPAC exhibited excellent performance, and more than 95.5% APAP was removed after 90 min, in the pH range of 2.0–8.0, using 1 g/l adsorbent at 25 °C. Additionally, the equilibrium and the kinetic studies outcomes unveiled the suitability of the Langmuir and the pseudo-second-order kinetic models, respectively, to describe the adsorption process. Based on the pH-adsorption dependence and OPAC properties, the presumable mechanism was mainly dominated by non-electrostatic interactions, including hydrogen bonding, π-π interactions, and pore diffusion. Thermodynamically, the process was found to be spontaneous and endothermic. Ultimately, OPAC manifested outstanding recyclability, with at least 95% of the initial efficiency being preserved after five cycles, making it more attractive from the environmental and economic perspectives. © The Author(s) 2022 |
abstract_unstemmed |
Abstract Pharmaceutically active compounds (PhACs) are frequently detected emerging pollutants in water resources worldwide that provoke pernicious influences on human health and the ecosystem. Developing effective carbonaceous adsorbents from biomass for the efficient removal of PhACs has lately drawn significant research attention. Herein, an efficient and cost-effective activated carbon was produced via $ ZnCl_{2} $-activation, employing orange peels as a precursor (named hereafter as OPAC). OPAC was well-characterized and applied in the sequestration of acetaminophen (N-acetyl-para-aminophenol, APAP), a broadly used non-steroidal anti-inflammatory drug, from water media using the batch technique. OPAC exhibited excellent performance, and more than 95.5% APAP was removed after 90 min, in the pH range of 2.0–8.0, using 1 g/l adsorbent at 25 °C. Additionally, the equilibrium and the kinetic studies outcomes unveiled the suitability of the Langmuir and the pseudo-second-order kinetic models, respectively, to describe the adsorption process. Based on the pH-adsorption dependence and OPAC properties, the presumable mechanism was mainly dominated by non-electrostatic interactions, including hydrogen bonding, π-π interactions, and pore diffusion. Thermodynamically, the process was found to be spontaneous and endothermic. Ultimately, OPAC manifested outstanding recyclability, with at least 95% of the initial efficiency being preserved after five cycles, making it more attractive from the environmental and economic perspectives. © The Author(s) 2022 |
collection_details |
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container_issue |
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title_short |
Efficient adsorption of acetaminophen from the aqueous phase using low-cost and renewable adsorbent derived from orange peels |
url |
https://dx.doi.org/10.1007/s13399-022-02541-x |
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author2 |
Shaban, Seham A. Mostafa, Mohsen S. Naga, Ahmed O. Abo El |
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Shaban, Seham A. Mostafa, Mohsen S. Naga, Ahmed O. Abo El |
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doi_str |
10.1007/s13399-022-02541-x |
up_date |
2024-07-04T01:49:20.903Z |
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|
score |
7.400529 |