Fenton-like oxidation of pinewood to produce cellulose nanoparticles in one pot treatment
The conventional production of nanocellulose from biomass demands multiple steps involving numerous chemicals like corrosive acids, bases, halogenated bleaching agents, and mechanical energy. This research aims to find a greener approach to producing nanocellulose particles from biomass. In nature,...
Ausführliche Beschreibung
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| Autor*in: |
Vijay, Poornima [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2024 |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Cellulose - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994, 31(2024), 2 vom: Jan., Seite 953-967 |
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| Übergeordnetes Werk: |
volume:31 ; year:2024 ; number:2 ; month:01 ; pages:953-967 |
| Links: |
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| DOI / URN: |
10.1007/s10570-023-05573-2 |
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SPR054581257 |
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| 520 | |a The conventional production of nanocellulose from biomass demands multiple steps involving numerous chemicals like corrosive acids, bases, halogenated bleaching agents, and mechanical energy. This research aims to find a greener approach to producing nanocellulose particles from biomass. In nature, the brown rot fungi utilize iron complex and hydrogen peroxide to overcome the lignin boundary and approach cellulose in biomass. This fact encouraged us to use the same oxidative catalytic system on biomass in a one-pot process. Pinewood sawdust was taken as starting material, and the iron oxide, hydrogen peroxide oxidation system was applied with varying the concentration of hydrogen peroxide and the reaction time. In 6 h, a one-pot system obtained a 95% pure cellulose with an aspect ratio of 1–15 from pinewood sawdust. The yield of the process was very high, i.e., from the total cellulose content in pinewood, 85% of cellulose was recovered in this process. The degree of polymerization of the obtained cellulose product was 100 ± 20, with an aspect ratio of 1–20. The particles were sphere and ellipsoidal-shaped, with the majority having a diameter of 120–180 nm. It had a crystallinity of 81%, an increase of 26% crystallinity was observed compared to the untreated pinewood sawdust. These nanocellulose particles would be a promising material for different derivatizing reactions, with their high surface area (15.0 ± 0.5 $ m^{2} $/g) and low degree of polymerization. This developed one-pot process has avoided using hazardous chemicals to produce nanocellulose particles. Graphical abstract | ||
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10.1007/s10570-023-05573-2 doi (DE-627)SPR054581257 (SPR)s10570-023-05573-2-e DE-627 ger DE-627 rakwb eng Vijay, Poornima verfasserin aut Fenton-like oxidation of pinewood to produce cellulose nanoparticles in one pot treatment 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. The conventional production of nanocellulose from biomass demands multiple steps involving numerous chemicals like corrosive acids, bases, halogenated bleaching agents, and mechanical energy. This research aims to find a greener approach to producing nanocellulose particles from biomass. In nature, the brown rot fungi utilize iron complex and hydrogen peroxide to overcome the lignin boundary and approach cellulose in biomass. This fact encouraged us to use the same oxidative catalytic system on biomass in a one-pot process. Pinewood sawdust was taken as starting material, and the iron oxide, hydrogen peroxide oxidation system was applied with varying the concentration of hydrogen peroxide and the reaction time. In 6 h, a one-pot system obtained a 95% pure cellulose with an aspect ratio of 1–15 from pinewood sawdust. The yield of the process was very high, i.e., from the total cellulose content in pinewood, 85% of cellulose was recovered in this process. The degree of polymerization of the obtained cellulose product was 100 ± 20, with an aspect ratio of 1–20. The particles were sphere and ellipsoidal-shaped, with the majority having a diameter of 120–180 nm. It had a crystallinity of 81%, an increase of 26% crystallinity was observed compared to the untreated pinewood sawdust. These nanocellulose particles would be a promising material for different derivatizing reactions, with their high surface area (15.0 ± 0.5 $ m^{2} $/g) and low degree of polymerization. This developed one-pot process has avoided using hazardous chemicals to produce nanocellulose particles. Graphical abstract Green treatment (dpeaa)DE-He213 Non-hazardous materials (dpeaa)DE-He213 Non-halogenated materials (dpeaa)DE-He213 Biomass treatment (dpeaa)DE-He213 Fenton reagent (dpeaa)DE-He213 Nanocellulose (dpeaa)DE-He213 Raghuwanshi, Vikram Singh aut Ma, Jisheng aut Batchelor, Warren aut Saito, Kei aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 31(2024), 2 vom: Jan., Seite 953-967 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:31 year:2024 number:2 month:01 pages:953-967 https://dx.doi.org/10.1007/s10570-023-05573-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 31 2024 2 01 953-967 |
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10.1007/s10570-023-05573-2 doi (DE-627)SPR054581257 (SPR)s10570-023-05573-2-e DE-627 ger DE-627 rakwb eng Vijay, Poornima verfasserin aut Fenton-like oxidation of pinewood to produce cellulose nanoparticles in one pot treatment 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. The conventional production of nanocellulose from biomass demands multiple steps involving numerous chemicals like corrosive acids, bases, halogenated bleaching agents, and mechanical energy. This research aims to find a greener approach to producing nanocellulose particles from biomass. In nature, the brown rot fungi utilize iron complex and hydrogen peroxide to overcome the lignin boundary and approach cellulose in biomass. This fact encouraged us to use the same oxidative catalytic system on biomass in a one-pot process. Pinewood sawdust was taken as starting material, and the iron oxide, hydrogen peroxide oxidation system was applied with varying the concentration of hydrogen peroxide and the reaction time. In 6 h, a one-pot system obtained a 95% pure cellulose with an aspect ratio of 1–15 from pinewood sawdust. The yield of the process was very high, i.e., from the total cellulose content in pinewood, 85% of cellulose was recovered in this process. The degree of polymerization of the obtained cellulose product was 100 ± 20, with an aspect ratio of 1–20. The particles were sphere and ellipsoidal-shaped, with the majority having a diameter of 120–180 nm. It had a crystallinity of 81%, an increase of 26% crystallinity was observed compared to the untreated pinewood sawdust. These nanocellulose particles would be a promising material for different derivatizing reactions, with their high surface area (15.0 ± 0.5 $ m^{2} $/g) and low degree of polymerization. This developed one-pot process has avoided using hazardous chemicals to produce nanocellulose particles. Graphical abstract Green treatment (dpeaa)DE-He213 Non-hazardous materials (dpeaa)DE-He213 Non-halogenated materials (dpeaa)DE-He213 Biomass treatment (dpeaa)DE-He213 Fenton reagent (dpeaa)DE-He213 Nanocellulose (dpeaa)DE-He213 Raghuwanshi, Vikram Singh aut Ma, Jisheng aut Batchelor, Warren aut Saito, Kei aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 31(2024), 2 vom: Jan., Seite 953-967 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:31 year:2024 number:2 month:01 pages:953-967 https://dx.doi.org/10.1007/s10570-023-05573-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 31 2024 2 01 953-967 |
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10.1007/s10570-023-05573-2 doi (DE-627)SPR054581257 (SPR)s10570-023-05573-2-e DE-627 ger DE-627 rakwb eng Vijay, Poornima verfasserin aut Fenton-like oxidation of pinewood to produce cellulose nanoparticles in one pot treatment 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. The conventional production of nanocellulose from biomass demands multiple steps involving numerous chemicals like corrosive acids, bases, halogenated bleaching agents, and mechanical energy. This research aims to find a greener approach to producing nanocellulose particles from biomass. In nature, the brown rot fungi utilize iron complex and hydrogen peroxide to overcome the lignin boundary and approach cellulose in biomass. This fact encouraged us to use the same oxidative catalytic system on biomass in a one-pot process. Pinewood sawdust was taken as starting material, and the iron oxide, hydrogen peroxide oxidation system was applied with varying the concentration of hydrogen peroxide and the reaction time. In 6 h, a one-pot system obtained a 95% pure cellulose with an aspect ratio of 1–15 from pinewood sawdust. The yield of the process was very high, i.e., from the total cellulose content in pinewood, 85% of cellulose was recovered in this process. The degree of polymerization of the obtained cellulose product was 100 ± 20, with an aspect ratio of 1–20. The particles were sphere and ellipsoidal-shaped, with the majority having a diameter of 120–180 nm. It had a crystallinity of 81%, an increase of 26% crystallinity was observed compared to the untreated pinewood sawdust. These nanocellulose particles would be a promising material for different derivatizing reactions, with their high surface area (15.0 ± 0.5 $ m^{2} $/g) and low degree of polymerization. This developed one-pot process has avoided using hazardous chemicals to produce nanocellulose particles. Graphical abstract Green treatment (dpeaa)DE-He213 Non-hazardous materials (dpeaa)DE-He213 Non-halogenated materials (dpeaa)DE-He213 Biomass treatment (dpeaa)DE-He213 Fenton reagent (dpeaa)DE-He213 Nanocellulose (dpeaa)DE-He213 Raghuwanshi, Vikram Singh aut Ma, Jisheng aut Batchelor, Warren aut Saito, Kei aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 31(2024), 2 vom: Jan., Seite 953-967 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:31 year:2024 number:2 month:01 pages:953-967 https://dx.doi.org/10.1007/s10570-023-05573-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 31 2024 2 01 953-967 |
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10.1007/s10570-023-05573-2 doi (DE-627)SPR054581257 (SPR)s10570-023-05573-2-e DE-627 ger DE-627 rakwb eng Vijay, Poornima verfasserin aut Fenton-like oxidation of pinewood to produce cellulose nanoparticles in one pot treatment 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. The conventional production of nanocellulose from biomass demands multiple steps involving numerous chemicals like corrosive acids, bases, halogenated bleaching agents, and mechanical energy. This research aims to find a greener approach to producing nanocellulose particles from biomass. In nature, the brown rot fungi utilize iron complex and hydrogen peroxide to overcome the lignin boundary and approach cellulose in biomass. This fact encouraged us to use the same oxidative catalytic system on biomass in a one-pot process. Pinewood sawdust was taken as starting material, and the iron oxide, hydrogen peroxide oxidation system was applied with varying the concentration of hydrogen peroxide and the reaction time. In 6 h, a one-pot system obtained a 95% pure cellulose with an aspect ratio of 1–15 from pinewood sawdust. The yield of the process was very high, i.e., from the total cellulose content in pinewood, 85% of cellulose was recovered in this process. The degree of polymerization of the obtained cellulose product was 100 ± 20, with an aspect ratio of 1–20. The particles were sphere and ellipsoidal-shaped, with the majority having a diameter of 120–180 nm. It had a crystallinity of 81%, an increase of 26% crystallinity was observed compared to the untreated pinewood sawdust. These nanocellulose particles would be a promising material for different derivatizing reactions, with their high surface area (15.0 ± 0.5 $ m^{2} $/g) and low degree of polymerization. This developed one-pot process has avoided using hazardous chemicals to produce nanocellulose particles. Graphical abstract Green treatment (dpeaa)DE-He213 Non-hazardous materials (dpeaa)DE-He213 Non-halogenated materials (dpeaa)DE-He213 Biomass treatment (dpeaa)DE-He213 Fenton reagent (dpeaa)DE-He213 Nanocellulose (dpeaa)DE-He213 Raghuwanshi, Vikram Singh aut Ma, Jisheng aut Batchelor, Warren aut Saito, Kei aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 31(2024), 2 vom: Jan., Seite 953-967 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:31 year:2024 number:2 month:01 pages:953-967 https://dx.doi.org/10.1007/s10570-023-05573-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 31 2024 2 01 953-967 |
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10.1007/s10570-023-05573-2 doi (DE-627)SPR054581257 (SPR)s10570-023-05573-2-e DE-627 ger DE-627 rakwb eng Vijay, Poornima verfasserin aut Fenton-like oxidation of pinewood to produce cellulose nanoparticles in one pot treatment 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. The conventional production of nanocellulose from biomass demands multiple steps involving numerous chemicals like corrosive acids, bases, halogenated bleaching agents, and mechanical energy. This research aims to find a greener approach to producing nanocellulose particles from biomass. In nature, the brown rot fungi utilize iron complex and hydrogen peroxide to overcome the lignin boundary and approach cellulose in biomass. This fact encouraged us to use the same oxidative catalytic system on biomass in a one-pot process. Pinewood sawdust was taken as starting material, and the iron oxide, hydrogen peroxide oxidation system was applied with varying the concentration of hydrogen peroxide and the reaction time. In 6 h, a one-pot system obtained a 95% pure cellulose with an aspect ratio of 1–15 from pinewood sawdust. The yield of the process was very high, i.e., from the total cellulose content in pinewood, 85% of cellulose was recovered in this process. The degree of polymerization of the obtained cellulose product was 100 ± 20, with an aspect ratio of 1–20. The particles were sphere and ellipsoidal-shaped, with the majority having a diameter of 120–180 nm. It had a crystallinity of 81%, an increase of 26% crystallinity was observed compared to the untreated pinewood sawdust. These nanocellulose particles would be a promising material for different derivatizing reactions, with their high surface area (15.0 ± 0.5 $ m^{2} $/g) and low degree of polymerization. This developed one-pot process has avoided using hazardous chemicals to produce nanocellulose particles. Graphical abstract Green treatment (dpeaa)DE-He213 Non-hazardous materials (dpeaa)DE-He213 Non-halogenated materials (dpeaa)DE-He213 Biomass treatment (dpeaa)DE-He213 Fenton reagent (dpeaa)DE-He213 Nanocellulose (dpeaa)DE-He213 Raghuwanshi, Vikram Singh aut Ma, Jisheng aut Batchelor, Warren aut Saito, Kei aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 31(2024), 2 vom: Jan., Seite 953-967 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:31 year:2024 number:2 month:01 pages:953-967 https://dx.doi.org/10.1007/s10570-023-05573-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 31 2024 2 01 953-967 |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The conventional production of nanocellulose from biomass demands multiple steps involving numerous chemicals like corrosive acids, bases, halogenated bleaching agents, and mechanical energy. This research aims to find a greener approach to producing nanocellulose particles from biomass. In nature, the brown rot fungi utilize iron complex and hydrogen peroxide to overcome the lignin boundary and approach cellulose in biomass. This fact encouraged us to use the same oxidative catalytic system on biomass in a one-pot process. Pinewood sawdust was taken as starting material, and the iron oxide, hydrogen peroxide oxidation system was applied with varying the concentration of hydrogen peroxide and the reaction time. In 6 h, a one-pot system obtained a 95% pure cellulose with an aspect ratio of 1–15 from pinewood sawdust. The yield of the process was very high, i.e., from the total cellulose content in pinewood, 85% of cellulose was recovered in this process. The degree of polymerization of the obtained cellulose product was 100 ± 20, with an aspect ratio of 1–20. The particles were sphere and ellipsoidal-shaped, with the majority having a diameter of 120–180 nm. It had a crystallinity of 81%, an increase of 26% crystallinity was observed compared to the untreated pinewood sawdust. These nanocellulose particles would be a promising material for different derivatizing reactions, with their high surface area (15.0 ± 0.5 $ m^{2} $/g) and low degree of polymerization. This developed one-pot process has avoided using hazardous chemicals to produce nanocellulose particles. 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Vijay, Poornima |
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Fenton-like oxidation of pinewood to produce cellulose nanoparticles in one pot treatment Green treatment (dpeaa)DE-He213 Non-hazardous materials (dpeaa)DE-He213 Non-halogenated materials (dpeaa)DE-He213 Biomass treatment (dpeaa)DE-He213 Fenton reagent (dpeaa)DE-He213 Nanocellulose (dpeaa)DE-He213 |
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fenton-like oxidation of pinewood to produce cellulose nanoparticles in one pot treatment |
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Fenton-like oxidation of pinewood to produce cellulose nanoparticles in one pot treatment |
| abstract |
The conventional production of nanocellulose from biomass demands multiple steps involving numerous chemicals like corrosive acids, bases, halogenated bleaching agents, and mechanical energy. This research aims to find a greener approach to producing nanocellulose particles from biomass. In nature, the brown rot fungi utilize iron complex and hydrogen peroxide to overcome the lignin boundary and approach cellulose in biomass. This fact encouraged us to use the same oxidative catalytic system on biomass in a one-pot process. Pinewood sawdust was taken as starting material, and the iron oxide, hydrogen peroxide oxidation system was applied with varying the concentration of hydrogen peroxide and the reaction time. In 6 h, a one-pot system obtained a 95% pure cellulose with an aspect ratio of 1–15 from pinewood sawdust. The yield of the process was very high, i.e., from the total cellulose content in pinewood, 85% of cellulose was recovered in this process. The degree of polymerization of the obtained cellulose product was 100 ± 20, with an aspect ratio of 1–20. The particles were sphere and ellipsoidal-shaped, with the majority having a diameter of 120–180 nm. It had a crystallinity of 81%, an increase of 26% crystallinity was observed compared to the untreated pinewood sawdust. These nanocellulose particles would be a promising material for different derivatizing reactions, with their high surface area (15.0 ± 0.5 $ m^{2} $/g) and low degree of polymerization. This developed one-pot process has avoided using hazardous chemicals to produce nanocellulose particles. Graphical abstract © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
The conventional production of nanocellulose from biomass demands multiple steps involving numerous chemicals like corrosive acids, bases, halogenated bleaching agents, and mechanical energy. This research aims to find a greener approach to producing nanocellulose particles from biomass. In nature, the brown rot fungi utilize iron complex and hydrogen peroxide to overcome the lignin boundary and approach cellulose in biomass. This fact encouraged us to use the same oxidative catalytic system on biomass in a one-pot process. Pinewood sawdust was taken as starting material, and the iron oxide, hydrogen peroxide oxidation system was applied with varying the concentration of hydrogen peroxide and the reaction time. In 6 h, a one-pot system obtained a 95% pure cellulose with an aspect ratio of 1–15 from pinewood sawdust. The yield of the process was very high, i.e., from the total cellulose content in pinewood, 85% of cellulose was recovered in this process. The degree of polymerization of the obtained cellulose product was 100 ± 20, with an aspect ratio of 1–20. The particles were sphere and ellipsoidal-shaped, with the majority having a diameter of 120–180 nm. It had a crystallinity of 81%, an increase of 26% crystallinity was observed compared to the untreated pinewood sawdust. These nanocellulose particles would be a promising material for different derivatizing reactions, with their high surface area (15.0 ± 0.5 $ m^{2} $/g) and low degree of polymerization. This developed one-pot process has avoided using hazardous chemicals to produce nanocellulose particles. Graphical abstract © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
The conventional production of nanocellulose from biomass demands multiple steps involving numerous chemicals like corrosive acids, bases, halogenated bleaching agents, and mechanical energy. This research aims to find a greener approach to producing nanocellulose particles from biomass. In nature, the brown rot fungi utilize iron complex and hydrogen peroxide to overcome the lignin boundary and approach cellulose in biomass. This fact encouraged us to use the same oxidative catalytic system on biomass in a one-pot process. Pinewood sawdust was taken as starting material, and the iron oxide, hydrogen peroxide oxidation system was applied with varying the concentration of hydrogen peroxide and the reaction time. In 6 h, a one-pot system obtained a 95% pure cellulose with an aspect ratio of 1–15 from pinewood sawdust. The yield of the process was very high, i.e., from the total cellulose content in pinewood, 85% of cellulose was recovered in this process. The degree of polymerization of the obtained cellulose product was 100 ± 20, with an aspect ratio of 1–20. The particles were sphere and ellipsoidal-shaped, with the majority having a diameter of 120–180 nm. It had a crystallinity of 81%, an increase of 26% crystallinity was observed compared to the untreated pinewood sawdust. These nanocellulose particles would be a promising material for different derivatizing reactions, with their high surface area (15.0 ± 0.5 $ m^{2} $/g) and low degree of polymerization. This developed one-pot process has avoided using hazardous chemicals to produce nanocellulose particles. Graphical abstract © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| title_short |
Fenton-like oxidation of pinewood to produce cellulose nanoparticles in one pot treatment |
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https://dx.doi.org/10.1007/s10570-023-05573-2 |
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Raghuwanshi, Vikram Singh Ma, Jisheng Batchelor, Warren Saito, Kei |
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Raghuwanshi, Vikram Singh Ma, Jisheng Batchelor, Warren Saito, Kei |
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10.1007/s10570-023-05573-2 |
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2024-07-04T02:15:42.083Z |
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| score |
7.3983965 |