Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer
Abstract Semi-transparent perovskite solar cells (ST-PSCs) have broad applications in building integrated photovoltaics. However, the stability of ST-PSCs needs to be improved, especially in n-i-p ST-PSCs since the doped 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OM...
Ausführliche Beschreibung
Autor*in: |
Jin, Yongbin [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2023 |
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Anmerkung: |
© Tsinghua University Press 2023 |
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Übergeordnetes Werk: |
Enthalten in: Nano research - [S.l.] : Tsinghua Press, 2008, 17(2023), 3 vom: 22. Aug., Seite 1500-1507 |
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Übergeordnetes Werk: |
volume:17 ; year:2023 ; number:3 ; day:22 ; month:08 ; pages:1500-1507 |
Links: |
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DOI / URN: |
10.1007/s12274-023-5975-5 |
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Katalog-ID: |
SPR054908167 |
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245 | 1 | 0 | |a Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer |
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520 | |a Abstract Semi-transparent perovskite solar cells (ST-PSCs) have broad applications in building integrated photovoltaics. However, the stability of ST-PSCs needs to be improved, especially in n-i-p ST-PSCs since the doped 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OMeTAD) is unstable at elevated temperatures and high humidity. In this work, a π-conjugated polymer poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1,2-b:4,5-b′]dithiophene))-alt-(5,5-(1′,3′-di-2-thienyl-5′,7′-bis(2-ethylhexyl)benzo[1′,2′-c:4′,5′-c′]dithiophene-4,8-dione)] (PBDB-T) is selected to form a polymer composite hole transport layer (HTL) with Spiro-OMeTAD. The sulfur atom of the thiophene unit and the carbonyl group of the polymer interact with the undercoordinated $ Pb^{2+} $ at the perovskite surface, which stabilizes the perovskite/HTL interface and passivates the interfacial defects. The incorporation of the polymer also increases the glass transition temperature and the moisture resistance of Spiro-OMeTAD. As a result, we obtain ST-PSCs with a champion efficiency of 13.71% and an average visible light transmittance of 36.04%. Therefore, a high light utilization efficiency of 4.94% can be obtained. Moreover, the encapsulated device can maintain 84% of the initial efficiency after 751 h under continuous one-sun illumination (at 30% relative humidity) at the open circuit and the unencapsulated device can maintain 80% of the initial efficiency after maximum power tracking for more than 1250 h under continuous one-sun illumination. | ||
650 | 4 | |a semi-transparent solar cells |7 (dpeaa)DE-He213 | |
650 | 4 | |a π-conjugated polymer |7 (dpeaa)DE-He213 | |
650 | 4 | |a composite hole transport layer |7 (dpeaa)DE-He213 | |
650 | 4 | |a building integrated photovoltaics |7 (dpeaa)DE-He213 | |
700 | 1 | |a Feng, Huiping |4 aut | |
700 | 1 | |a Fang, Zheng |4 aut | |
700 | 1 | |a Yang, Liu |4 aut | |
700 | 1 | |a Liu, Kaikai |4 aut | |
700 | 1 | |a Deng, Bingru |4 aut | |
700 | 1 | |a Chen, Jingfu |4 aut | |
700 | 1 | |a Chen, Xueling |4 aut | |
700 | 1 | |a Zhong, Yawen |4 aut | |
700 | 1 | |a Yang, Jinxin |4 aut | |
700 | 1 | |a Tian, Chengbo |4 aut | |
700 | 1 | |a Xie, Liqiang |4 aut | |
700 | 1 | |a Wei, Zhanhua |4 aut | |
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10.1007/s12274-023-5975-5 doi (DE-627)SPR054908167 (SPR)s12274-023-5975-5-e DE-627 ger DE-627 rakwb eng Jin, Yongbin verfasserin aut Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2023 Abstract Semi-transparent perovskite solar cells (ST-PSCs) have broad applications in building integrated photovoltaics. However, the stability of ST-PSCs needs to be improved, especially in n-i-p ST-PSCs since the doped 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OMeTAD) is unstable at elevated temperatures and high humidity. In this work, a π-conjugated polymer poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1,2-b:4,5-b′]dithiophene))-alt-(5,5-(1′,3′-di-2-thienyl-5′,7′-bis(2-ethylhexyl)benzo[1′,2′-c:4′,5′-c′]dithiophene-4,8-dione)] (PBDB-T) is selected to form a polymer composite hole transport layer (HTL) with Spiro-OMeTAD. The sulfur atom of the thiophene unit and the carbonyl group of the polymer interact with the undercoordinated $ Pb^{2+} $ at the perovskite surface, which stabilizes the perovskite/HTL interface and passivates the interfacial defects. The incorporation of the polymer also increases the glass transition temperature and the moisture resistance of Spiro-OMeTAD. As a result, we obtain ST-PSCs with a champion efficiency of 13.71% and an average visible light transmittance of 36.04%. Therefore, a high light utilization efficiency of 4.94% can be obtained. Moreover, the encapsulated device can maintain 84% of the initial efficiency after 751 h under continuous one-sun illumination (at 30% relative humidity) at the open circuit and the unencapsulated device can maintain 80% of the initial efficiency after maximum power tracking for more than 1250 h under continuous one-sun illumination. semi-transparent solar cells (dpeaa)DE-He213 π-conjugated polymer (dpeaa)DE-He213 composite hole transport layer (dpeaa)DE-He213 building integrated photovoltaics (dpeaa)DE-He213 Feng, Huiping aut Fang, Zheng aut Yang, Liu aut Liu, Kaikai aut Deng, Bingru aut Chen, Jingfu aut Chen, Xueling aut Zhong, Yawen aut Yang, Jinxin aut Tian, Chengbo aut Xie, Liqiang aut Wei, Zhanhua aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 17(2023), 3 vom: 22. Aug., Seite 1500-1507 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2023 number:3 day:22 month:08 pages:1500-1507 https://dx.doi.org/10.1007/s12274-023-5975-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2023 3 22 08 1500-1507 |
spelling |
10.1007/s12274-023-5975-5 doi (DE-627)SPR054908167 (SPR)s12274-023-5975-5-e DE-627 ger DE-627 rakwb eng Jin, Yongbin verfasserin aut Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2023 Abstract Semi-transparent perovskite solar cells (ST-PSCs) have broad applications in building integrated photovoltaics. However, the stability of ST-PSCs needs to be improved, especially in n-i-p ST-PSCs since the doped 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OMeTAD) is unstable at elevated temperatures and high humidity. In this work, a π-conjugated polymer poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1,2-b:4,5-b′]dithiophene))-alt-(5,5-(1′,3′-di-2-thienyl-5′,7′-bis(2-ethylhexyl)benzo[1′,2′-c:4′,5′-c′]dithiophene-4,8-dione)] (PBDB-T) is selected to form a polymer composite hole transport layer (HTL) with Spiro-OMeTAD. The sulfur atom of the thiophene unit and the carbonyl group of the polymer interact with the undercoordinated $ Pb^{2+} $ at the perovskite surface, which stabilizes the perovskite/HTL interface and passivates the interfacial defects. The incorporation of the polymer also increases the glass transition temperature and the moisture resistance of Spiro-OMeTAD. As a result, we obtain ST-PSCs with a champion efficiency of 13.71% and an average visible light transmittance of 36.04%. Therefore, a high light utilization efficiency of 4.94% can be obtained. Moreover, the encapsulated device can maintain 84% of the initial efficiency after 751 h under continuous one-sun illumination (at 30% relative humidity) at the open circuit and the unencapsulated device can maintain 80% of the initial efficiency after maximum power tracking for more than 1250 h under continuous one-sun illumination. semi-transparent solar cells (dpeaa)DE-He213 π-conjugated polymer (dpeaa)DE-He213 composite hole transport layer (dpeaa)DE-He213 building integrated photovoltaics (dpeaa)DE-He213 Feng, Huiping aut Fang, Zheng aut Yang, Liu aut Liu, Kaikai aut Deng, Bingru aut Chen, Jingfu aut Chen, Xueling aut Zhong, Yawen aut Yang, Jinxin aut Tian, Chengbo aut Xie, Liqiang aut Wei, Zhanhua aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 17(2023), 3 vom: 22. Aug., Seite 1500-1507 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2023 number:3 day:22 month:08 pages:1500-1507 https://dx.doi.org/10.1007/s12274-023-5975-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2023 3 22 08 1500-1507 |
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10.1007/s12274-023-5975-5 doi (DE-627)SPR054908167 (SPR)s12274-023-5975-5-e DE-627 ger DE-627 rakwb eng Jin, Yongbin verfasserin aut Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2023 Abstract Semi-transparent perovskite solar cells (ST-PSCs) have broad applications in building integrated photovoltaics. However, the stability of ST-PSCs needs to be improved, especially in n-i-p ST-PSCs since the doped 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OMeTAD) is unstable at elevated temperatures and high humidity. In this work, a π-conjugated polymer poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1,2-b:4,5-b′]dithiophene))-alt-(5,5-(1′,3′-di-2-thienyl-5′,7′-bis(2-ethylhexyl)benzo[1′,2′-c:4′,5′-c′]dithiophene-4,8-dione)] (PBDB-T) is selected to form a polymer composite hole transport layer (HTL) with Spiro-OMeTAD. The sulfur atom of the thiophene unit and the carbonyl group of the polymer interact with the undercoordinated $ Pb^{2+} $ at the perovskite surface, which stabilizes the perovskite/HTL interface and passivates the interfacial defects. The incorporation of the polymer also increases the glass transition temperature and the moisture resistance of Spiro-OMeTAD. As a result, we obtain ST-PSCs with a champion efficiency of 13.71% and an average visible light transmittance of 36.04%. Therefore, a high light utilization efficiency of 4.94% can be obtained. Moreover, the encapsulated device can maintain 84% of the initial efficiency after 751 h under continuous one-sun illumination (at 30% relative humidity) at the open circuit and the unencapsulated device can maintain 80% of the initial efficiency after maximum power tracking for more than 1250 h under continuous one-sun illumination. semi-transparent solar cells (dpeaa)DE-He213 π-conjugated polymer (dpeaa)DE-He213 composite hole transport layer (dpeaa)DE-He213 building integrated photovoltaics (dpeaa)DE-He213 Feng, Huiping aut Fang, Zheng aut Yang, Liu aut Liu, Kaikai aut Deng, Bingru aut Chen, Jingfu aut Chen, Xueling aut Zhong, Yawen aut Yang, Jinxin aut Tian, Chengbo aut Xie, Liqiang aut Wei, Zhanhua aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 17(2023), 3 vom: 22. Aug., Seite 1500-1507 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2023 number:3 day:22 month:08 pages:1500-1507 https://dx.doi.org/10.1007/s12274-023-5975-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2023 3 22 08 1500-1507 |
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10.1007/s12274-023-5975-5 doi (DE-627)SPR054908167 (SPR)s12274-023-5975-5-e DE-627 ger DE-627 rakwb eng Jin, Yongbin verfasserin aut Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2023 Abstract Semi-transparent perovskite solar cells (ST-PSCs) have broad applications in building integrated photovoltaics. However, the stability of ST-PSCs needs to be improved, especially in n-i-p ST-PSCs since the doped 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OMeTAD) is unstable at elevated temperatures and high humidity. In this work, a π-conjugated polymer poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1,2-b:4,5-b′]dithiophene))-alt-(5,5-(1′,3′-di-2-thienyl-5′,7′-bis(2-ethylhexyl)benzo[1′,2′-c:4′,5′-c′]dithiophene-4,8-dione)] (PBDB-T) is selected to form a polymer composite hole transport layer (HTL) with Spiro-OMeTAD. The sulfur atom of the thiophene unit and the carbonyl group of the polymer interact with the undercoordinated $ Pb^{2+} $ at the perovskite surface, which stabilizes the perovskite/HTL interface and passivates the interfacial defects. The incorporation of the polymer also increases the glass transition temperature and the moisture resistance of Spiro-OMeTAD. As a result, we obtain ST-PSCs with a champion efficiency of 13.71% and an average visible light transmittance of 36.04%. Therefore, a high light utilization efficiency of 4.94% can be obtained. Moreover, the encapsulated device can maintain 84% of the initial efficiency after 751 h under continuous one-sun illumination (at 30% relative humidity) at the open circuit and the unencapsulated device can maintain 80% of the initial efficiency after maximum power tracking for more than 1250 h under continuous one-sun illumination. semi-transparent solar cells (dpeaa)DE-He213 π-conjugated polymer (dpeaa)DE-He213 composite hole transport layer (dpeaa)DE-He213 building integrated photovoltaics (dpeaa)DE-He213 Feng, Huiping aut Fang, Zheng aut Yang, Liu aut Liu, Kaikai aut Deng, Bingru aut Chen, Jingfu aut Chen, Xueling aut Zhong, Yawen aut Yang, Jinxin aut Tian, Chengbo aut Xie, Liqiang aut Wei, Zhanhua aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 17(2023), 3 vom: 22. Aug., Seite 1500-1507 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2023 number:3 day:22 month:08 pages:1500-1507 https://dx.doi.org/10.1007/s12274-023-5975-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2023 3 22 08 1500-1507 |
allfieldsSound |
10.1007/s12274-023-5975-5 doi (DE-627)SPR054908167 (SPR)s12274-023-5975-5-e DE-627 ger DE-627 rakwb eng Jin, Yongbin verfasserin aut Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2023 Abstract Semi-transparent perovskite solar cells (ST-PSCs) have broad applications in building integrated photovoltaics. However, the stability of ST-PSCs needs to be improved, especially in n-i-p ST-PSCs since the doped 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OMeTAD) is unstable at elevated temperatures and high humidity. In this work, a π-conjugated polymer poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1,2-b:4,5-b′]dithiophene))-alt-(5,5-(1′,3′-di-2-thienyl-5′,7′-bis(2-ethylhexyl)benzo[1′,2′-c:4′,5′-c′]dithiophene-4,8-dione)] (PBDB-T) is selected to form a polymer composite hole transport layer (HTL) with Spiro-OMeTAD. The sulfur atom of the thiophene unit and the carbonyl group of the polymer interact with the undercoordinated $ Pb^{2+} $ at the perovskite surface, which stabilizes the perovskite/HTL interface and passivates the interfacial defects. The incorporation of the polymer also increases the glass transition temperature and the moisture resistance of Spiro-OMeTAD. As a result, we obtain ST-PSCs with a champion efficiency of 13.71% and an average visible light transmittance of 36.04%. Therefore, a high light utilization efficiency of 4.94% can be obtained. Moreover, the encapsulated device can maintain 84% of the initial efficiency after 751 h under continuous one-sun illumination (at 30% relative humidity) at the open circuit and the unencapsulated device can maintain 80% of the initial efficiency after maximum power tracking for more than 1250 h under continuous one-sun illumination. semi-transparent solar cells (dpeaa)DE-He213 π-conjugated polymer (dpeaa)DE-He213 composite hole transport layer (dpeaa)DE-He213 building integrated photovoltaics (dpeaa)DE-He213 Feng, Huiping aut Fang, Zheng aut Yang, Liu aut Liu, Kaikai aut Deng, Bingru aut Chen, Jingfu aut Chen, Xueling aut Zhong, Yawen aut Yang, Jinxin aut Tian, Chengbo aut Xie, Liqiang aut Wei, Zhanhua aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 17(2023), 3 vom: 22. Aug., Seite 1500-1507 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2023 number:3 day:22 month:08 pages:1500-1507 https://dx.doi.org/10.1007/s12274-023-5975-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2023 3 22 08 1500-1507 |
language |
English |
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Enthalten in Nano research 17(2023), 3 vom: 22. Aug., Seite 1500-1507 volume:17 year:2023 number:3 day:22 month:08 pages:1500-1507 |
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Enthalten in Nano research 17(2023), 3 vom: 22. Aug., Seite 1500-1507 volume:17 year:2023 number:3 day:22 month:08 pages:1500-1507 |
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semi-transparent solar cells π-conjugated polymer composite hole transport layer building integrated photovoltaics |
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Nano research |
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Jin, Yongbin @@aut@@ Feng, Huiping @@aut@@ Fang, Zheng @@aut@@ Yang, Liu @@aut@@ Liu, Kaikai @@aut@@ Deng, Bingru @@aut@@ Chen, Jingfu @@aut@@ Chen, Xueling @@aut@@ Zhong, Yawen @@aut@@ Yang, Jinxin @@aut@@ Tian, Chengbo @@aut@@ Xie, Liqiang @@aut@@ Wei, Zhanhua @@aut@@ |
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2023-08-22T00:00:00Z |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR054908167</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20240227064733.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">240227s2023 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s12274-023-5975-5</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR054908167</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s12274-023-5975-5-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Jin, Yongbin</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Tsinghua University Press 2023</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Semi-transparent perovskite solar cells (ST-PSCs) have broad applications in building integrated photovoltaics. However, the stability of ST-PSCs needs to be improved, especially in n-i-p ST-PSCs since the doped 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OMeTAD) is unstable at elevated temperatures and high humidity. In this work, a π-conjugated polymer poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1,2-b:4,5-b′]dithiophene))-alt-(5,5-(1′,3′-di-2-thienyl-5′,7′-bis(2-ethylhexyl)benzo[1′,2′-c:4′,5′-c′]dithiophene-4,8-dione)] (PBDB-T) is selected to form a polymer composite hole transport layer (HTL) with Spiro-OMeTAD. The sulfur atom of the thiophene unit and the carbonyl group of the polymer interact with the undercoordinated $ Pb^{2+} $ at the perovskite surface, which stabilizes the perovskite/HTL interface and passivates the interfacial defects. The incorporation of the polymer also increases the glass transition temperature and the moisture resistance of Spiro-OMeTAD. As a result, we obtain ST-PSCs with a champion efficiency of 13.71% and an average visible light transmittance of 36.04%. Therefore, a high light utilization efficiency of 4.94% can be obtained. Moreover, the encapsulated device can maintain 84% of the initial efficiency after 751 h under continuous one-sun illumination (at 30% relative humidity) at the open circuit and the unencapsulated device can maintain 80% of the initial efficiency after maximum power tracking for more than 1250 h under continuous one-sun illumination.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">semi-transparent solar cells</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">π-conjugated polymer</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">composite hole transport layer</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">building integrated photovoltaics</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Feng, Huiping</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Fang, Zheng</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yang, Liu</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Liu, Kaikai</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Deng, Bingru</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chen, Jingfu</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chen, Xueling</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhong, Yawen</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yang, Jinxin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Tian, Chengbo</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Xie, Liqiang</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wei, Zhanhua</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Nano research</subfield><subfield code="d">[S.l.] : Tsinghua Press, 2008</subfield><subfield code="g">17(2023), 3 vom: 22. 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Jin, Yongbin |
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Jin, Yongbin misc semi-transparent solar cells misc π-conjugated polymer misc composite hole transport layer misc building integrated photovoltaics Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer |
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Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer semi-transparent solar cells (dpeaa)DE-He213 π-conjugated polymer (dpeaa)DE-He213 composite hole transport layer (dpeaa)DE-He213 building integrated photovoltaics (dpeaa)DE-He213 |
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Jin, Yongbin Feng, Huiping Fang, Zheng Yang, Liu Liu, Kaikai Deng, Bingru Chen, Jingfu Chen, Xueling Zhong, Yawen Yang, Jinxin Tian, Chengbo Xie, Liqiang Wei, Zhanhua |
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stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer |
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Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer |
abstract |
Abstract Semi-transparent perovskite solar cells (ST-PSCs) have broad applications in building integrated photovoltaics. However, the stability of ST-PSCs needs to be improved, especially in n-i-p ST-PSCs since the doped 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OMeTAD) is unstable at elevated temperatures and high humidity. In this work, a π-conjugated polymer poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1,2-b:4,5-b′]dithiophene))-alt-(5,5-(1′,3′-di-2-thienyl-5′,7′-bis(2-ethylhexyl)benzo[1′,2′-c:4′,5′-c′]dithiophene-4,8-dione)] (PBDB-T) is selected to form a polymer composite hole transport layer (HTL) with Spiro-OMeTAD. The sulfur atom of the thiophene unit and the carbonyl group of the polymer interact with the undercoordinated $ Pb^{2+} $ at the perovskite surface, which stabilizes the perovskite/HTL interface and passivates the interfacial defects. The incorporation of the polymer also increases the glass transition temperature and the moisture resistance of Spiro-OMeTAD. As a result, we obtain ST-PSCs with a champion efficiency of 13.71% and an average visible light transmittance of 36.04%. Therefore, a high light utilization efficiency of 4.94% can be obtained. Moreover, the encapsulated device can maintain 84% of the initial efficiency after 751 h under continuous one-sun illumination (at 30% relative humidity) at the open circuit and the unencapsulated device can maintain 80% of the initial efficiency after maximum power tracking for more than 1250 h under continuous one-sun illumination. © Tsinghua University Press 2023 |
abstractGer |
Abstract Semi-transparent perovskite solar cells (ST-PSCs) have broad applications in building integrated photovoltaics. However, the stability of ST-PSCs needs to be improved, especially in n-i-p ST-PSCs since the doped 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OMeTAD) is unstable at elevated temperatures and high humidity. In this work, a π-conjugated polymer poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1,2-b:4,5-b′]dithiophene))-alt-(5,5-(1′,3′-di-2-thienyl-5′,7′-bis(2-ethylhexyl)benzo[1′,2′-c:4′,5′-c′]dithiophene-4,8-dione)] (PBDB-T) is selected to form a polymer composite hole transport layer (HTL) with Spiro-OMeTAD. The sulfur atom of the thiophene unit and the carbonyl group of the polymer interact with the undercoordinated $ Pb^{2+} $ at the perovskite surface, which stabilizes the perovskite/HTL interface and passivates the interfacial defects. The incorporation of the polymer also increases the glass transition temperature and the moisture resistance of Spiro-OMeTAD. As a result, we obtain ST-PSCs with a champion efficiency of 13.71% and an average visible light transmittance of 36.04%. Therefore, a high light utilization efficiency of 4.94% can be obtained. Moreover, the encapsulated device can maintain 84% of the initial efficiency after 751 h under continuous one-sun illumination (at 30% relative humidity) at the open circuit and the unencapsulated device can maintain 80% of the initial efficiency after maximum power tracking for more than 1250 h under continuous one-sun illumination. © Tsinghua University Press 2023 |
abstract_unstemmed |
Abstract Semi-transparent perovskite solar cells (ST-PSCs) have broad applications in building integrated photovoltaics. However, the stability of ST-PSCs needs to be improved, especially in n-i-p ST-PSCs since the doped 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OMeTAD) is unstable at elevated temperatures and high humidity. In this work, a π-conjugated polymer poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1,2-b:4,5-b′]dithiophene))-alt-(5,5-(1′,3′-di-2-thienyl-5′,7′-bis(2-ethylhexyl)benzo[1′,2′-c:4′,5′-c′]dithiophene-4,8-dione)] (PBDB-T) is selected to form a polymer composite hole transport layer (HTL) with Spiro-OMeTAD. The sulfur atom of the thiophene unit and the carbonyl group of the polymer interact with the undercoordinated $ Pb^{2+} $ at the perovskite surface, which stabilizes the perovskite/HTL interface and passivates the interfacial defects. The incorporation of the polymer also increases the glass transition temperature and the moisture resistance of Spiro-OMeTAD. As a result, we obtain ST-PSCs with a champion efficiency of 13.71% and an average visible light transmittance of 36.04%. Therefore, a high light utilization efficiency of 4.94% can be obtained. Moreover, the encapsulated device can maintain 84% of the initial efficiency after 751 h under continuous one-sun illumination (at 30% relative humidity) at the open circuit and the unencapsulated device can maintain 80% of the initial efficiency after maximum power tracking for more than 1250 h under continuous one-sun illumination. © Tsinghua University Press 2023 |
collection_details |
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container_issue |
3 |
title_short |
Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer |
url |
https://dx.doi.org/10.1007/s12274-023-5975-5 |
remote_bool |
true |
author2 |
Feng, Huiping Fang, Zheng Yang, Liu Liu, Kaikai Deng, Bingru Chen, Jingfu Chen, Xueling Zhong, Yawen Yang, Jinxin Tian, Chengbo Xie, Liqiang Wei, Zhanhua |
author2Str |
Feng, Huiping Fang, Zheng Yang, Liu Liu, Kaikai Deng, Bingru Chen, Jingfu Chen, Xueling Zhong, Yawen Yang, Jinxin Tian, Chengbo Xie, Liqiang Wei, Zhanhua |
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hochschulschrift_bool |
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doi_str |
10.1007/s12274-023-5975-5 |
up_date |
2024-07-04T03:28:15.475Z |
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score |
7.399682 |