$ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries
Abstract Niobium oxide ($ Nb_{2} %$ O_{5} $) is a promising material in photocatalytic, solar cell, electronic like electron field emitters, and especially lithium-ion batteries (LIBs) because of its adjustable morphologies, controllable crystal type, stable structure, and environmental friendliness...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Wang, Lei [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Anmerkung: |
© Tsinghua University Press 2023 |
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| Übergeordnetes Werk: |
Enthalten in: Nano research - [S.l.] : Tsinghua Press, 2008, 17(2023), 3 vom: 12. Aug., Seite 1535-1541 |
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| Übergeordnetes Werk: |
volume:17 ; year:2023 ; number:3 ; day:12 ; month:08 ; pages:1535-1541 |
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| DOI / URN: |
10.1007/s12274-023-6013-3 |
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| Katalog-ID: |
SPR054908434 |
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| 520 | |a Abstract Niobium oxide ($ Nb_{2} %$ O_{5} $) is a promising material in photocatalytic, solar cell, electronic like electron field emitters, and especially lithium-ion batteries (LIBs) because of its adjustable morphologies, controllable crystal type, stable structure, and environmental friendliness. However, its low electrical conductivity lowers the rate performance and limits the practical applications in LIBs. Herein, we present a one-step solid-state synthesis of orthogonal $ Nb_{2} %$ O_{5} $ nanocrystals/graphene composites ($ Nb_{2} %$ O_{5} $/G) as high-performance anode materials in LIBs. Benefiting from the nanoscale crystalline structure $ Nb_{2} %$ O_{5} $ and highly-conductive graphene substrate, the as-prepared $ Nb_{2} %$ O_{5} $/G exhibits excellent electrochemical performances. Impressively, a reversible structural phase transition between orthogonal $ Nb_{2} %$ O_{5} $ and tetragonal $ Li_{1−x} %$ NbO_{2} $ (0 < x < 1) was verified by ex-situ transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). After coupling with graphite cathode based on $ PF_{6} $-intercalation/deintercalation mechanisms, $ Nb_{2} %$ O_{5} $/G∥graphite dual-ion batteries (DIBs) full cell delivers good electrochemical performance in terms of cyclic performance and rate capability. We believe this work can provide a clear route towards developing advanced transition metal oxide/graphene composite anode and a comprehension of its electrochemical reaction mechanism. | ||
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| 700 | 1 | |a Zhu, Guoyin |4 aut | |
| 700 | 1 | |a Dai, Zhihui |4 aut | |
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10.1007/s12274-023-6013-3 doi (DE-627)SPR054908434 (SPR)s12274-023-6013-3-e DE-627 ger DE-627 rakwb eng Wang, Lei verfasserin aut $ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2023 Abstract Niobium oxide ($ Nb_{2} %$ O_{5} $) is a promising material in photocatalytic, solar cell, electronic like electron field emitters, and especially lithium-ion batteries (LIBs) because of its adjustable morphologies, controllable crystal type, stable structure, and environmental friendliness. However, its low electrical conductivity lowers the rate performance and limits the practical applications in LIBs. Herein, we present a one-step solid-state synthesis of orthogonal $ Nb_{2} %$ O_{5} $ nanocrystals/graphene composites ($ Nb_{2} %$ O_{5} $/G) as high-performance anode materials in LIBs. Benefiting from the nanoscale crystalline structure $ Nb_{2} %$ O_{5} $ and highly-conductive graphene substrate, the as-prepared $ Nb_{2} %$ O_{5} $/G exhibits excellent electrochemical performances. Impressively, a reversible structural phase transition between orthogonal $ Nb_{2} %$ O_{5} $ and tetragonal $ Li_{1−x} %$ NbO_{2} $ (0 < x < 1) was verified by ex-situ transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). After coupling with graphite cathode based on $ PF_{6} $-intercalation/deintercalation mechanisms, $ Nb_{2} %$ O_{5} $/G∥graphite dual-ion batteries (DIBs) full cell delivers good electrochemical performance in terms of cyclic performance and rate capability. We believe this work can provide a clear route towards developing advanced transition metal oxide/graphene composite anode and a comprehension of its electrochemical reaction mechanism. niobium oxide (dpeaa)DE-He213 graphene (dpeaa)DE-He213 anode (dpeaa)DE-He213 dual-ion batteries (dpeaa)DE-He213 graphite intercalation (dpeaa)DE-He213 Huang, Fei aut Zhu, Guoyin aut Dai, Zhihui aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 17(2023), 3 vom: 12. Aug., Seite 1535-1541 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2023 number:3 day:12 month:08 pages:1535-1541 https://dx.doi.org/10.1007/s12274-023-6013-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2023 3 12 08 1535-1541 |
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10.1007/s12274-023-6013-3 doi (DE-627)SPR054908434 (SPR)s12274-023-6013-3-e DE-627 ger DE-627 rakwb eng Wang, Lei verfasserin aut $ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2023 Abstract Niobium oxide ($ Nb_{2} %$ O_{5} $) is a promising material in photocatalytic, solar cell, electronic like electron field emitters, and especially lithium-ion batteries (LIBs) because of its adjustable morphologies, controllable crystal type, stable structure, and environmental friendliness. However, its low electrical conductivity lowers the rate performance and limits the practical applications in LIBs. Herein, we present a one-step solid-state synthesis of orthogonal $ Nb_{2} %$ O_{5} $ nanocrystals/graphene composites ($ Nb_{2} %$ O_{5} $/G) as high-performance anode materials in LIBs. Benefiting from the nanoscale crystalline structure $ Nb_{2} %$ O_{5} $ and highly-conductive graphene substrate, the as-prepared $ Nb_{2} %$ O_{5} $/G exhibits excellent electrochemical performances. Impressively, a reversible structural phase transition between orthogonal $ Nb_{2} %$ O_{5} $ and tetragonal $ Li_{1−x} %$ NbO_{2} $ (0 < x < 1) was verified by ex-situ transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). After coupling with graphite cathode based on $ PF_{6} $-intercalation/deintercalation mechanisms, $ Nb_{2} %$ O_{5} $/G∥graphite dual-ion batteries (DIBs) full cell delivers good electrochemical performance in terms of cyclic performance and rate capability. We believe this work can provide a clear route towards developing advanced transition metal oxide/graphene composite anode and a comprehension of its electrochemical reaction mechanism. niobium oxide (dpeaa)DE-He213 graphene (dpeaa)DE-He213 anode (dpeaa)DE-He213 dual-ion batteries (dpeaa)DE-He213 graphite intercalation (dpeaa)DE-He213 Huang, Fei aut Zhu, Guoyin aut Dai, Zhihui aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 17(2023), 3 vom: 12. Aug., Seite 1535-1541 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2023 number:3 day:12 month:08 pages:1535-1541 https://dx.doi.org/10.1007/s12274-023-6013-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2023 3 12 08 1535-1541 |
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10.1007/s12274-023-6013-3 doi (DE-627)SPR054908434 (SPR)s12274-023-6013-3-e DE-627 ger DE-627 rakwb eng Wang, Lei verfasserin aut $ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2023 Abstract Niobium oxide ($ Nb_{2} %$ O_{5} $) is a promising material in photocatalytic, solar cell, electronic like electron field emitters, and especially lithium-ion batteries (LIBs) because of its adjustable morphologies, controllable crystal type, stable structure, and environmental friendliness. However, its low electrical conductivity lowers the rate performance and limits the practical applications in LIBs. Herein, we present a one-step solid-state synthesis of orthogonal $ Nb_{2} %$ O_{5} $ nanocrystals/graphene composites ($ Nb_{2} %$ O_{5} $/G) as high-performance anode materials in LIBs. Benefiting from the nanoscale crystalline structure $ Nb_{2} %$ O_{5} $ and highly-conductive graphene substrate, the as-prepared $ Nb_{2} %$ O_{5} $/G exhibits excellent electrochemical performances. Impressively, a reversible structural phase transition between orthogonal $ Nb_{2} %$ O_{5} $ and tetragonal $ Li_{1−x} %$ NbO_{2} $ (0 < x < 1) was verified by ex-situ transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). After coupling with graphite cathode based on $ PF_{6} $-intercalation/deintercalation mechanisms, $ Nb_{2} %$ O_{5} $/G∥graphite dual-ion batteries (DIBs) full cell delivers good electrochemical performance in terms of cyclic performance and rate capability. We believe this work can provide a clear route towards developing advanced transition metal oxide/graphene composite anode and a comprehension of its electrochemical reaction mechanism. niobium oxide (dpeaa)DE-He213 graphene (dpeaa)DE-He213 anode (dpeaa)DE-He213 dual-ion batteries (dpeaa)DE-He213 graphite intercalation (dpeaa)DE-He213 Huang, Fei aut Zhu, Guoyin aut Dai, Zhihui aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 17(2023), 3 vom: 12. Aug., Seite 1535-1541 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2023 number:3 day:12 month:08 pages:1535-1541 https://dx.doi.org/10.1007/s12274-023-6013-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2023 3 12 08 1535-1541 |
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10.1007/s12274-023-6013-3 doi (DE-627)SPR054908434 (SPR)s12274-023-6013-3-e DE-627 ger DE-627 rakwb eng Wang, Lei verfasserin aut $ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2023 Abstract Niobium oxide ($ Nb_{2} %$ O_{5} $) is a promising material in photocatalytic, solar cell, electronic like electron field emitters, and especially lithium-ion batteries (LIBs) because of its adjustable morphologies, controllable crystal type, stable structure, and environmental friendliness. However, its low electrical conductivity lowers the rate performance and limits the practical applications in LIBs. Herein, we present a one-step solid-state synthesis of orthogonal $ Nb_{2} %$ O_{5} $ nanocrystals/graphene composites ($ Nb_{2} %$ O_{5} $/G) as high-performance anode materials in LIBs. Benefiting from the nanoscale crystalline structure $ Nb_{2} %$ O_{5} $ and highly-conductive graphene substrate, the as-prepared $ Nb_{2} %$ O_{5} $/G exhibits excellent electrochemical performances. Impressively, a reversible structural phase transition between orthogonal $ Nb_{2} %$ O_{5} $ and tetragonal $ Li_{1−x} %$ NbO_{2} $ (0 < x < 1) was verified by ex-situ transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). After coupling with graphite cathode based on $ PF_{6} $-intercalation/deintercalation mechanisms, $ Nb_{2} %$ O_{5} $/G∥graphite dual-ion batteries (DIBs) full cell delivers good electrochemical performance in terms of cyclic performance and rate capability. We believe this work can provide a clear route towards developing advanced transition metal oxide/graphene composite anode and a comprehension of its electrochemical reaction mechanism. niobium oxide (dpeaa)DE-He213 graphene (dpeaa)DE-He213 anode (dpeaa)DE-He213 dual-ion batteries (dpeaa)DE-He213 graphite intercalation (dpeaa)DE-He213 Huang, Fei aut Zhu, Guoyin aut Dai, Zhihui aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 17(2023), 3 vom: 12. Aug., Seite 1535-1541 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2023 number:3 day:12 month:08 pages:1535-1541 https://dx.doi.org/10.1007/s12274-023-6013-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2023 3 12 08 1535-1541 |
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10.1007/s12274-023-6013-3 doi (DE-627)SPR054908434 (SPR)s12274-023-6013-3-e DE-627 ger DE-627 rakwb eng Wang, Lei verfasserin aut $ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2023 Abstract Niobium oxide ($ Nb_{2} %$ O_{5} $) is a promising material in photocatalytic, solar cell, electronic like electron field emitters, and especially lithium-ion batteries (LIBs) because of its adjustable morphologies, controllable crystal type, stable structure, and environmental friendliness. However, its low electrical conductivity lowers the rate performance and limits the practical applications in LIBs. Herein, we present a one-step solid-state synthesis of orthogonal $ Nb_{2} %$ O_{5} $ nanocrystals/graphene composites ($ Nb_{2} %$ O_{5} $/G) as high-performance anode materials in LIBs. Benefiting from the nanoscale crystalline structure $ Nb_{2} %$ O_{5} $ and highly-conductive graphene substrate, the as-prepared $ Nb_{2} %$ O_{5} $/G exhibits excellent electrochemical performances. Impressively, a reversible structural phase transition between orthogonal $ Nb_{2} %$ O_{5} $ and tetragonal $ Li_{1−x} %$ NbO_{2} $ (0 < x < 1) was verified by ex-situ transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). After coupling with graphite cathode based on $ PF_{6} $-intercalation/deintercalation mechanisms, $ Nb_{2} %$ O_{5} $/G∥graphite dual-ion batteries (DIBs) full cell delivers good electrochemical performance in terms of cyclic performance and rate capability. We believe this work can provide a clear route towards developing advanced transition metal oxide/graphene composite anode and a comprehension of its electrochemical reaction mechanism. niobium oxide (dpeaa)DE-He213 graphene (dpeaa)DE-He213 anode (dpeaa)DE-He213 dual-ion batteries (dpeaa)DE-He213 graphite intercalation (dpeaa)DE-He213 Huang, Fei aut Zhu, Guoyin aut Dai, Zhihui aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 17(2023), 3 vom: 12. Aug., Seite 1535-1541 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2023 number:3 day:12 month:08 pages:1535-1541 https://dx.doi.org/10.1007/s12274-023-6013-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2023 3 12 08 1535-1541 |
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Enthalten in Nano research 17(2023), 3 vom: 12. Aug., Seite 1535-1541 volume:17 year:2023 number:3 day:12 month:08 pages:1535-1541 |
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Enthalten in Nano research 17(2023), 3 vom: 12. Aug., Seite 1535-1541 volume:17 year:2023 number:3 day:12 month:08 pages:1535-1541 |
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Wang, Lei @@aut@@ Huang, Fei @@aut@@ Zhu, Guoyin @@aut@@ Dai, Zhihui @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR054908434</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20240227064733.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">240227s2023 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s12274-023-6013-3</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR054908434</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s12274-023-6013-3-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Wang, Lei</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">$ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Tsinghua University Press 2023</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Niobium oxide ($ Nb_{2} %$ O_{5} $) is a promising material in photocatalytic, solar cell, electronic like electron field emitters, and especially lithium-ion batteries (LIBs) because of its adjustable morphologies, controllable crystal type, stable structure, and environmental friendliness. However, its low electrical conductivity lowers the rate performance and limits the practical applications in LIBs. Herein, we present a one-step solid-state synthesis of orthogonal $ Nb_{2} %$ O_{5} $ nanocrystals/graphene composites ($ Nb_{2} %$ O_{5} $/G) as high-performance anode materials in LIBs. Benefiting from the nanoscale crystalline structure $ Nb_{2} %$ O_{5} $ and highly-conductive graphene substrate, the as-prepared $ Nb_{2} %$ O_{5} $/G exhibits excellent electrochemical performances. Impressively, a reversible structural phase transition between orthogonal $ Nb_{2} %$ O_{5} $ and tetragonal $ Li_{1−x} %$ NbO_{2} $ (0 < x < 1) was verified by ex-situ transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). After coupling with graphite cathode based on $ PF_{6} $-intercalation/deintercalation mechanisms, $ Nb_{2} %$ O_{5} $/G∥graphite dual-ion batteries (DIBs) full cell delivers good electrochemical performance in terms of cyclic performance and rate capability. 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Wang, Lei |
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Wang, Lei misc niobium oxide misc graphene misc anode misc dual-ion batteries misc graphite intercalation $ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries |
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$ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries niobium oxide (dpeaa)DE-He213 graphene (dpeaa)DE-He213 anode (dpeaa)DE-He213 dual-ion batteries (dpeaa)DE-He213 graphite intercalation (dpeaa)DE-He213 |
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$ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries |
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$ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries |
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$ nb_{2} %$ o_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries |
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$ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries |
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Abstract Niobium oxide ($ Nb_{2} %$ O_{5} $) is a promising material in photocatalytic, solar cell, electronic like electron field emitters, and especially lithium-ion batteries (LIBs) because of its adjustable morphologies, controllable crystal type, stable structure, and environmental friendliness. However, its low electrical conductivity lowers the rate performance and limits the practical applications in LIBs. Herein, we present a one-step solid-state synthesis of orthogonal $ Nb_{2} %$ O_{5} $ nanocrystals/graphene composites ($ Nb_{2} %$ O_{5} $/G) as high-performance anode materials in LIBs. Benefiting from the nanoscale crystalline structure $ Nb_{2} %$ O_{5} $ and highly-conductive graphene substrate, the as-prepared $ Nb_{2} %$ O_{5} $/G exhibits excellent electrochemical performances. Impressively, a reversible structural phase transition between orthogonal $ Nb_{2} %$ O_{5} $ and tetragonal $ Li_{1−x} %$ NbO_{2} $ (0 < x < 1) was verified by ex-situ transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). After coupling with graphite cathode based on $ PF_{6} $-intercalation/deintercalation mechanisms, $ Nb_{2} %$ O_{5} $/G∥graphite dual-ion batteries (DIBs) full cell delivers good electrochemical performance in terms of cyclic performance and rate capability. We believe this work can provide a clear route towards developing advanced transition metal oxide/graphene composite anode and a comprehension of its electrochemical reaction mechanism. © Tsinghua University Press 2023 |
| abstractGer |
Abstract Niobium oxide ($ Nb_{2} %$ O_{5} $) is a promising material in photocatalytic, solar cell, electronic like electron field emitters, and especially lithium-ion batteries (LIBs) because of its adjustable morphologies, controllable crystal type, stable structure, and environmental friendliness. However, its low electrical conductivity lowers the rate performance and limits the practical applications in LIBs. Herein, we present a one-step solid-state synthesis of orthogonal $ Nb_{2} %$ O_{5} $ nanocrystals/graphene composites ($ Nb_{2} %$ O_{5} $/G) as high-performance anode materials in LIBs. Benefiting from the nanoscale crystalline structure $ Nb_{2} %$ O_{5} $ and highly-conductive graphene substrate, the as-prepared $ Nb_{2} %$ O_{5} $/G exhibits excellent electrochemical performances. Impressively, a reversible structural phase transition between orthogonal $ Nb_{2} %$ O_{5} $ and tetragonal $ Li_{1−x} %$ NbO_{2} $ (0 < x < 1) was verified by ex-situ transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). After coupling with graphite cathode based on $ PF_{6} $-intercalation/deintercalation mechanisms, $ Nb_{2} %$ O_{5} $/G∥graphite dual-ion batteries (DIBs) full cell delivers good electrochemical performance in terms of cyclic performance and rate capability. We believe this work can provide a clear route towards developing advanced transition metal oxide/graphene composite anode and a comprehension of its electrochemical reaction mechanism. © Tsinghua University Press 2023 |
| abstract_unstemmed |
Abstract Niobium oxide ($ Nb_{2} %$ O_{5} $) is a promising material in photocatalytic, solar cell, electronic like electron field emitters, and especially lithium-ion batteries (LIBs) because of its adjustable morphologies, controllable crystal type, stable structure, and environmental friendliness. However, its low electrical conductivity lowers the rate performance and limits the practical applications in LIBs. Herein, we present a one-step solid-state synthesis of orthogonal $ Nb_{2} %$ O_{5} $ nanocrystals/graphene composites ($ Nb_{2} %$ O_{5} $/G) as high-performance anode materials in LIBs. Benefiting from the nanoscale crystalline structure $ Nb_{2} %$ O_{5} $ and highly-conductive graphene substrate, the as-prepared $ Nb_{2} %$ O_{5} $/G exhibits excellent electrochemical performances. Impressively, a reversible structural phase transition between orthogonal $ Nb_{2} %$ O_{5} $ and tetragonal $ Li_{1−x} %$ NbO_{2} $ (0 < x < 1) was verified by ex-situ transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). After coupling with graphite cathode based on $ PF_{6} $-intercalation/deintercalation mechanisms, $ Nb_{2} %$ O_{5} $/G∥graphite dual-ion batteries (DIBs) full cell delivers good electrochemical performance in terms of cyclic performance and rate capability. We believe this work can provide a clear route towards developing advanced transition metal oxide/graphene composite anode and a comprehension of its electrochemical reaction mechanism. © Tsinghua University Press 2023 |
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3 |
| title_short |
$ Nb_{2} %$ O_{5} $ nanocrystals decorated graphene composites as anode materials for high-performance dual-ion batteries |
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https://dx.doi.org/10.1007/s12274-023-6013-3 |
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Huang, Fei Zhu, Guoyin Dai, Zhihui |
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Huang, Fei Zhu, Guoyin Dai, Zhihui |
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10.1007/s12274-023-6013-3 |
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2024-07-04T03:28:19.337Z |
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| score |
7.4000654 |