Heterostructure $ Cu_{3} $P−$ Ni_{2} $P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia
Abstract Electrochemical nitrate reduction reaction ($ NO_{3} $RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were ev...
Ausführliche Beschreibung
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| Autor*in: |
Jin, Meng [verfasserIn] Liu, Jiafang [verfasserIn] Zhang, Xian [verfasserIn] Zhang, Shengbo [verfasserIn] Li, Wenyi [verfasserIn] Sun, Dianding [verfasserIn] Zhang, Yunxia [verfasserIn] Wang, Guozhong [verfasserIn] Zhang, Haimin [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2024 |
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| Schlagwörter: |
electrocatalytic nitrate reduction to ammonia |
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| Anmerkung: |
© Tsinghua University Press 2024 |
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| Übergeordnetes Werk: |
Enthalten in: Nano research - Tsinghua University Press, 2008, 17(2024), 6 vom: 08. Feb., Seite 4872-4881 |
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| Übergeordnetes Werk: |
volume:17 ; year:2024 ; number:6 ; day:08 ; month:02 ; pages:4872-4881 |
| Links: |
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| DOI / URN: |
10.1007/s12274-024-6474-z |
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| Katalog-ID: |
SPR05585138X |
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| 520 | |a Abstract Electrochemical nitrate reduction reaction ($ NO_{3} $RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia ($ NH_{3} $) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous $ Cu_{3} $P−$ Ni_{2} $P/CP−x for $ NO_{3} $RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the $ Cu_{3} $P−$ Ni_{2} $P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (RNH3) of 1.9 mmol·$ h^{−1} $·$ cm^{−2} $, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and in-situ spectroscopy characterizations uncover that the formed heterointerface in $ Cu_{3} $P−$ Ni_{2} $P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway. | ||
| 650 | 4 | |a electrocatalytic nitrate reduction to ammonia |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a three-type reactors |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a membrane-electrode-assemblies system |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a operando ATR-IRRAS |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a successive hydrodeoxygenation pathway |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Liu, Jiafang |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Xian |e verfasserin |4 aut | |
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| 700 | 1 | |a Li, Wenyi |e verfasserin |4 aut | |
| 700 | 1 | |a Sun, Dianding |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Yunxia |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Guozhong |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Haimin |e verfasserin |4 aut | |
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10.1007/s12274-024-6474-z doi (DE-627)SPR05585138X (SPR)s12274-024-6474-z-e DE-627 ger DE-627 rakwb eng 540 660 VZ Jin, Meng verfasserin aut Heterostructure $ Cu_{3} $P−$ Ni_{2} $P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2024 Abstract Electrochemical nitrate reduction reaction ($ NO_{3} $RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia ($ NH_{3} $) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous $ Cu_{3} $P−$ Ni_{2} $P/CP−x for $ NO_{3} $RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the $ Cu_{3} $P−$ Ni_{2} $P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (RNH3) of 1.9 mmol·$ h^{−1} $·$ cm^{−2} $, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and in-situ spectroscopy characterizations uncover that the formed heterointerface in $ Cu_{3} $P−$ Ni_{2} $P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway. electrocatalytic nitrate reduction to ammonia (dpeaa)DE-He213 three-type reactors (dpeaa)DE-He213 membrane-electrode-assemblies system (dpeaa)DE-He213 operando ATR-IRRAS (dpeaa)DE-He213 successive hydrodeoxygenation pathway (dpeaa)DE-He213 Liu, Jiafang verfasserin aut Zhang, Xian verfasserin aut Zhang, Shengbo verfasserin aut Li, Wenyi verfasserin aut Sun, Dianding verfasserin aut Zhang, Yunxia verfasserin aut Wang, Guozhong verfasserin aut Zhang, Haimin verfasserin aut Enthalten in Nano research Tsinghua University Press, 2008 17(2024), 6 vom: 08. Feb., Seite 4872-4881 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2024 number:6 day:08 month:02 pages:4872-4881 https://dx.doi.org/10.1007/s12274-024-6474-z X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2024 6 08 02 4872-4881 |
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10.1007/s12274-024-6474-z doi (DE-627)SPR05585138X (SPR)s12274-024-6474-z-e DE-627 ger DE-627 rakwb eng 540 660 VZ Jin, Meng verfasserin aut Heterostructure $ Cu_{3} $P−$ Ni_{2} $P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2024 Abstract Electrochemical nitrate reduction reaction ($ NO_{3} $RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia ($ NH_{3} $) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous $ Cu_{3} $P−$ Ni_{2} $P/CP−x for $ NO_{3} $RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the $ Cu_{3} $P−$ Ni_{2} $P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (RNH3) of 1.9 mmol·$ h^{−1} $·$ cm^{−2} $, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and in-situ spectroscopy characterizations uncover that the formed heterointerface in $ Cu_{3} $P−$ Ni_{2} $P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway. electrocatalytic nitrate reduction to ammonia (dpeaa)DE-He213 three-type reactors (dpeaa)DE-He213 membrane-electrode-assemblies system (dpeaa)DE-He213 operando ATR-IRRAS (dpeaa)DE-He213 successive hydrodeoxygenation pathway (dpeaa)DE-He213 Liu, Jiafang verfasserin aut Zhang, Xian verfasserin aut Zhang, Shengbo verfasserin aut Li, Wenyi verfasserin aut Sun, Dianding verfasserin aut Zhang, Yunxia verfasserin aut Wang, Guozhong verfasserin aut Zhang, Haimin verfasserin aut Enthalten in Nano research Tsinghua University Press, 2008 17(2024), 6 vom: 08. Feb., Seite 4872-4881 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2024 number:6 day:08 month:02 pages:4872-4881 https://dx.doi.org/10.1007/s12274-024-6474-z X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2024 6 08 02 4872-4881 |
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10.1007/s12274-024-6474-z doi (DE-627)SPR05585138X (SPR)s12274-024-6474-z-e DE-627 ger DE-627 rakwb eng 540 660 VZ Jin, Meng verfasserin aut Heterostructure $ Cu_{3} $P−$ Ni_{2} $P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2024 Abstract Electrochemical nitrate reduction reaction ($ NO_{3} $RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia ($ NH_{3} $) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous $ Cu_{3} $P−$ Ni_{2} $P/CP−x for $ NO_{3} $RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the $ Cu_{3} $P−$ Ni_{2} $P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (RNH3) of 1.9 mmol·$ h^{−1} $·$ cm^{−2} $, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and in-situ spectroscopy characterizations uncover that the formed heterointerface in $ Cu_{3} $P−$ Ni_{2} $P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway. electrocatalytic nitrate reduction to ammonia (dpeaa)DE-He213 three-type reactors (dpeaa)DE-He213 membrane-electrode-assemblies system (dpeaa)DE-He213 operando ATR-IRRAS (dpeaa)DE-He213 successive hydrodeoxygenation pathway (dpeaa)DE-He213 Liu, Jiafang verfasserin aut Zhang, Xian verfasserin aut Zhang, Shengbo verfasserin aut Li, Wenyi verfasserin aut Sun, Dianding verfasserin aut Zhang, Yunxia verfasserin aut Wang, Guozhong verfasserin aut Zhang, Haimin verfasserin aut Enthalten in Nano research Tsinghua University Press, 2008 17(2024), 6 vom: 08. Feb., Seite 4872-4881 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2024 number:6 day:08 month:02 pages:4872-4881 https://dx.doi.org/10.1007/s12274-024-6474-z X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2024 6 08 02 4872-4881 |
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10.1007/s12274-024-6474-z doi (DE-627)SPR05585138X (SPR)s12274-024-6474-z-e DE-627 ger DE-627 rakwb eng 540 660 VZ Jin, Meng verfasserin aut Heterostructure $ Cu_{3} $P−$ Ni_{2} $P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2024 Abstract Electrochemical nitrate reduction reaction ($ NO_{3} $RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia ($ NH_{3} $) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous $ Cu_{3} $P−$ Ni_{2} $P/CP−x for $ NO_{3} $RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the $ Cu_{3} $P−$ Ni_{2} $P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (RNH3) of 1.9 mmol·$ h^{−1} $·$ cm^{−2} $, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and in-situ spectroscopy characterizations uncover that the formed heterointerface in $ Cu_{3} $P−$ Ni_{2} $P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway. electrocatalytic nitrate reduction to ammonia (dpeaa)DE-He213 three-type reactors (dpeaa)DE-He213 membrane-electrode-assemblies system (dpeaa)DE-He213 operando ATR-IRRAS (dpeaa)DE-He213 successive hydrodeoxygenation pathway (dpeaa)DE-He213 Liu, Jiafang verfasserin aut Zhang, Xian verfasserin aut Zhang, Shengbo verfasserin aut Li, Wenyi verfasserin aut Sun, Dianding verfasserin aut Zhang, Yunxia verfasserin aut Wang, Guozhong verfasserin aut Zhang, Haimin verfasserin aut Enthalten in Nano research Tsinghua University Press, 2008 17(2024), 6 vom: 08. Feb., Seite 4872-4881 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2024 number:6 day:08 month:02 pages:4872-4881 https://dx.doi.org/10.1007/s12274-024-6474-z X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2024 6 08 02 4872-4881 |
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10.1007/s12274-024-6474-z doi (DE-627)SPR05585138X (SPR)s12274-024-6474-z-e DE-627 ger DE-627 rakwb eng 540 660 VZ Jin, Meng verfasserin aut Heterostructure $ Cu_{3} $P−$ Ni_{2} $P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press 2024 Abstract Electrochemical nitrate reduction reaction ($ NO_{3} $RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia ($ NH_{3} $) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous $ Cu_{3} $P−$ Ni_{2} $P/CP−x for $ NO_{3} $RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the $ Cu_{3} $P−$ Ni_{2} $P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (RNH3) of 1.9 mmol·$ h^{−1} $·$ cm^{−2} $, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and in-situ spectroscopy characterizations uncover that the formed heterointerface in $ Cu_{3} $P−$ Ni_{2} $P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway. electrocatalytic nitrate reduction to ammonia (dpeaa)DE-He213 three-type reactors (dpeaa)DE-He213 membrane-electrode-assemblies system (dpeaa)DE-He213 operando ATR-IRRAS (dpeaa)DE-He213 successive hydrodeoxygenation pathway (dpeaa)DE-He213 Liu, Jiafang verfasserin aut Zhang, Xian verfasserin aut Zhang, Shengbo verfasserin aut Li, Wenyi verfasserin aut Sun, Dianding verfasserin aut Zhang, Yunxia verfasserin aut Wang, Guozhong verfasserin aut Zhang, Haimin verfasserin aut Enthalten in Nano research Tsinghua University Press, 2008 17(2024), 6 vom: 08. Feb., Seite 4872-4881 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:17 year:2024 number:6 day:08 month:02 pages:4872-4881 https://dx.doi.org/10.1007/s12274-024-6474-z X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2024 6 08 02 4872-4881 |
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Enthalten in Nano research 17(2024), 6 vom: 08. Feb., Seite 4872-4881 volume:17 year:2024 number:6 day:08 month:02 pages:4872-4881 |
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Jin, Meng @@aut@@ Liu, Jiafang @@aut@@ Zhang, Xian @@aut@@ Zhang, Shengbo @@aut@@ Li, Wenyi @@aut@@ Sun, Dianding @@aut@@ Zhang, Yunxia @@aut@@ Wang, Guozhong @@aut@@ Zhang, Haimin @@aut@@ |
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Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia ($ NH_{3} $) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous $ Cu_{3} $P−$ Ni_{2} $P/CP−x for $ NO_{3} $RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the $ Cu_{3} $P−$ Ni_{2} $P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (RNH3) of 1.9 mmol·$ h^{−1} $·$ cm^{−2} $, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. 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|
| author |
Jin, Meng |
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Jin, Meng ddc 540 misc electrocatalytic nitrate reduction to ammonia misc three-type reactors misc membrane-electrode-assemblies system misc operando ATR-IRRAS misc successive hydrodeoxygenation pathway Heterostructure $ Cu_{3} $P−$ Ni_{2} $P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia |
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Jin, Meng |
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540 - Chemistry & allied sciences 660 - Chemical engineering |
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1998-0000 |
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540 660 VZ Heterostructure $ Cu_{3} $P−$ Ni_{2} $P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia electrocatalytic nitrate reduction to ammonia (dpeaa)DE-He213 three-type reactors (dpeaa)DE-He213 membrane-electrode-assemblies system (dpeaa)DE-He213 operando ATR-IRRAS (dpeaa)DE-He213 successive hydrodeoxygenation pathway (dpeaa)DE-He213 |
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ddc 540 misc electrocatalytic nitrate reduction to ammonia misc three-type reactors misc membrane-electrode-assemblies system misc operando ATR-IRRAS misc successive hydrodeoxygenation pathway |
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ddc 540 misc electrocatalytic nitrate reduction to ammonia misc three-type reactors misc membrane-electrode-assemblies system misc operando ATR-IRRAS misc successive hydrodeoxygenation pathway |
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ddc 540 misc electrocatalytic nitrate reduction to ammonia misc three-type reactors misc membrane-electrode-assemblies system misc operando ATR-IRRAS misc successive hydrodeoxygenation pathway |
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Elektronische Aufsätze Aufsätze Elektronische Ressource |
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Heterostructure $ Cu_{3} $P−$ Ni_{2} $P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia |
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(DE-627)SPR05585138X (SPR)s12274-024-6474-z-e |
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Heterostructure $ Cu_{3} $P−$ Ni_{2} $P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia |
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Jin, Meng |
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Jin, Meng Liu, Jiafang Zhang, Xian Zhang, Shengbo Li, Wenyi Sun, Dianding Zhang, Yunxia Wang, Guozhong Zhang, Haimin |
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Elektronische Aufsätze |
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Jin, Meng |
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10.1007/s12274-024-6474-z |
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heterostructure $ cu_{3} $p−$ ni_{2} $p/cp catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia |
| title_auth |
Heterostructure $ Cu_{3} $P−$ Ni_{2} $P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia |
| abstract |
Abstract Electrochemical nitrate reduction reaction ($ NO_{3} $RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia ($ NH_{3} $) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous $ Cu_{3} $P−$ Ni_{2} $P/CP−x for $ NO_{3} $RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the $ Cu_{3} $P−$ Ni_{2} $P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (RNH3) of 1.9 mmol·$ h^{−1} $·$ cm^{−2} $, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and in-situ spectroscopy characterizations uncover that the formed heterointerface in $ Cu_{3} $P−$ Ni_{2} $P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway. © Tsinghua University Press 2024 |
| abstractGer |
Abstract Electrochemical nitrate reduction reaction ($ NO_{3} $RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia ($ NH_{3} $) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous $ Cu_{3} $P−$ Ni_{2} $P/CP−x for $ NO_{3} $RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the $ Cu_{3} $P−$ Ni_{2} $P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (RNH3) of 1.9 mmol·$ h^{−1} $·$ cm^{−2} $, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and in-situ spectroscopy characterizations uncover that the formed heterointerface in $ Cu_{3} $P−$ Ni_{2} $P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway. © Tsinghua University Press 2024 |
| abstract_unstemmed |
Abstract Electrochemical nitrate reduction reaction ($ NO_{3} $RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia ($ NH_{3} $) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous $ Cu_{3} $P−$ Ni_{2} $P/CP−x for $ NO_{3} $RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the $ Cu_{3} $P−$ Ni_{2} $P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (RNH3) of 1.9 mmol·$ h^{−1} $·$ cm^{−2} $, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and in-situ spectroscopy characterizations uncover that the formed heterointerface in $ Cu_{3} $P−$ Ni_{2} $P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway. © Tsinghua University Press 2024 |
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Heterostructure $ Cu_{3} $P−$ Ni_{2} $P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia |
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Liu, Jiafang Zhang, Xian Zhang, Shengbo Li, Wenyi Sun, Dianding Zhang, Yunxia Wang, Guozhong Zhang, Haimin |
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| score |
7.400154 |