Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium
Biological soil crusts (BSCs) widely exists in mudflat environment, which is known to be efficient in capturing heavy metals from aqueous solutions; However, their ability to adsorb cadmium (Cd(II)) is limited due to low capacity and selectivity. To address this limitation, manganese ethylenediamine...
Ausführliche Beschreibung
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| Autor*in: |
Song, Ke [verfasserIn] Liu, Bin [verfasserIn] Kuang, Xiaolin [verfasserIn] Song, Huijuan [verfasserIn] Zeng, Qingru [verfasserIn] Peng, Liang [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2024 |
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© The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Water, air & soil pollution - Springer International Publishing, 1971, 235(2024), 7 vom: 20. Juni |
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| Übergeordnetes Werk: |
volume:235 ; year:2024 ; number:7 ; day:20 ; month:06 |
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| DOI / URN: |
10.1007/s11270-024-07249-4 |
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SPR05630479X |
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| 520 | |a Biological soil crusts (BSCs) widely exists in mudflat environment, which is known to be efficient in capturing heavy metals from aqueous solutions; However, their ability to adsorb cadmium (Cd(II)) is limited due to low capacity and selectivity. To address this limitation, manganese ethylenediamine phosphates (MEPs) nanomaterial were incorporated into the BSCs to enhance Cd(II) uptake. The MEPs nanomaterials attached to BSC significantly improved the adsorption capacity, rate, and selection for Cd(II). The adsorption kinetics of Cd(II) by BSCs and BSCs-MEPs was well described by a pseudo-second-order model, with BSCs-MEPs exhibiting a much higher adsorption capacity for Cd(II) (77.00 mg/g) compared to BSCs (55.44 mg/g). The Cd(II) removal by BSCs-MEPs has been accelerated to 2 stages, in which the film diffusion/intraparticle diffusion/chemical reaction participated in the 1st stage. And another stage was dynamic equilibrium process. The adsorption isotherm of BSCs-MEPs demonstrated superior performance for Cd(II) compared to BSCs across a pH range from 2 to 9. Most importantly, even in the presence of high concentration of $ Na^{+} $ or $ Ca^{2+} $ ions, BSCs-MEPs exhibited preferential adsorption for Cd(II), a result not observed with BSCs alone. Analysis of X-ray photoelectron spectroscopy spectra demonstrated that functional groups (-$ NH_{2} $/-COOH/-OH) played an important role in Cd(II) adsorption, while the MEPs attach to BSCs leading to the -$ NH_{3} $+ deprotonation, thus enhanced the BSCs' affinity toward Cd(II). Furthermore, molecular dynamics simulation clearly showed that diffusion coefficients (D) of Cd(II) were much higher than those of $ Ca^{2+} $ in EPS with abundant -$ NH_{2} $, which were responsible for selective adsorption. These findings might provide a valuable approach for treating Cd-contaminated water bodies. Graphical abstract | ||
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10.1007/s11270-024-07249-4 doi (DE-627)SPR05630479X (SPR)s11270-024-07249-4-e DE-627 ger DE-627 rakwb eng 333.7 VZ 43.50 bkl Song, Ke verfasserin aut Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Biological soil crusts (BSCs) widely exists in mudflat environment, which is known to be efficient in capturing heavy metals from aqueous solutions; However, their ability to adsorb cadmium (Cd(II)) is limited due to low capacity and selectivity. To address this limitation, manganese ethylenediamine phosphates (MEPs) nanomaterial were incorporated into the BSCs to enhance Cd(II) uptake. The MEPs nanomaterials attached to BSC significantly improved the adsorption capacity, rate, and selection for Cd(II). The adsorption kinetics of Cd(II) by BSCs and BSCs-MEPs was well described by a pseudo-second-order model, with BSCs-MEPs exhibiting a much higher adsorption capacity for Cd(II) (77.00 mg/g) compared to BSCs (55.44 mg/g). The Cd(II) removal by BSCs-MEPs has been accelerated to 2 stages, in which the film diffusion/intraparticle diffusion/chemical reaction participated in the 1st stage. And another stage was dynamic equilibrium process. The adsorption isotherm of BSCs-MEPs demonstrated superior performance for Cd(II) compared to BSCs across a pH range from 2 to 9. Most importantly, even in the presence of high concentration of $ Na^{+} $ or $ Ca^{2+} $ ions, BSCs-MEPs exhibited preferential adsorption for Cd(II), a result not observed with BSCs alone. Analysis of X-ray photoelectron spectroscopy spectra demonstrated that functional groups (-$ NH_{2} $/-COOH/-OH) played an important role in Cd(II) adsorption, while the MEPs attach to BSCs leading to the -$ NH_{3} $+ deprotonation, thus enhanced the BSCs' affinity toward Cd(II). Furthermore, molecular dynamics simulation clearly showed that diffusion coefficients (D) of Cd(II) were much higher than those of $ Ca^{2+} $ in EPS with abundant -$ NH_{2} $, which were responsible for selective adsorption. These findings might provide a valuable approach for treating Cd-contaminated water bodies. Graphical abstract Biological soil crusts (dpeaa)DE-He213 Nanomaterial (dpeaa)DE-He213 Cd(II) (dpeaa)DE-He213 Adsorption (dpeaa)DE-He213 Liu, Bin verfasserin aut Kuang, Xiaolin verfasserin aut Song, Huijuan verfasserin aut Zeng, Qingru verfasserin aut Peng, Liang verfasserin aut Enthalten in Water, air & soil pollution Springer International Publishing, 1971 235(2024), 7 vom: 20. Juni (DE-627)271349417 (DE-600)1479824-4 1573-2932 nnns volume:235 year:2024 number:7 day:20 month:06 https://dx.doi.org/10.1007/s11270-024-07249-4 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.50 VZ AR 235 2024 7 20 06 |
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10.1007/s11270-024-07249-4 doi (DE-627)SPR05630479X (SPR)s11270-024-07249-4-e DE-627 ger DE-627 rakwb eng 333.7 VZ 43.50 bkl Song, Ke verfasserin aut Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Biological soil crusts (BSCs) widely exists in mudflat environment, which is known to be efficient in capturing heavy metals from aqueous solutions; However, their ability to adsorb cadmium (Cd(II)) is limited due to low capacity and selectivity. To address this limitation, manganese ethylenediamine phosphates (MEPs) nanomaterial were incorporated into the BSCs to enhance Cd(II) uptake. The MEPs nanomaterials attached to BSC significantly improved the adsorption capacity, rate, and selection for Cd(II). The adsorption kinetics of Cd(II) by BSCs and BSCs-MEPs was well described by a pseudo-second-order model, with BSCs-MEPs exhibiting a much higher adsorption capacity for Cd(II) (77.00 mg/g) compared to BSCs (55.44 mg/g). The Cd(II) removal by BSCs-MEPs has been accelerated to 2 stages, in which the film diffusion/intraparticle diffusion/chemical reaction participated in the 1st stage. And another stage was dynamic equilibrium process. The adsorption isotherm of BSCs-MEPs demonstrated superior performance for Cd(II) compared to BSCs across a pH range from 2 to 9. Most importantly, even in the presence of high concentration of $ Na^{+} $ or $ Ca^{2+} $ ions, BSCs-MEPs exhibited preferential adsorption for Cd(II), a result not observed with BSCs alone. Analysis of X-ray photoelectron spectroscopy spectra demonstrated that functional groups (-$ NH_{2} $/-COOH/-OH) played an important role in Cd(II) adsorption, while the MEPs attach to BSCs leading to the -$ NH_{3} $+ deprotonation, thus enhanced the BSCs' affinity toward Cd(II). Furthermore, molecular dynamics simulation clearly showed that diffusion coefficients (D) of Cd(II) were much higher than those of $ Ca^{2+} $ in EPS with abundant -$ NH_{2} $, which were responsible for selective adsorption. These findings might provide a valuable approach for treating Cd-contaminated water bodies. Graphical abstract Biological soil crusts (dpeaa)DE-He213 Nanomaterial (dpeaa)DE-He213 Cd(II) (dpeaa)DE-He213 Adsorption (dpeaa)DE-He213 Liu, Bin verfasserin aut Kuang, Xiaolin verfasserin aut Song, Huijuan verfasserin aut Zeng, Qingru verfasserin aut Peng, Liang verfasserin aut Enthalten in Water, air & soil pollution Springer International Publishing, 1971 235(2024), 7 vom: 20. Juni (DE-627)271349417 (DE-600)1479824-4 1573-2932 nnns volume:235 year:2024 number:7 day:20 month:06 https://dx.doi.org/10.1007/s11270-024-07249-4 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.50 VZ AR 235 2024 7 20 06 |
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10.1007/s11270-024-07249-4 doi (DE-627)SPR05630479X (SPR)s11270-024-07249-4-e DE-627 ger DE-627 rakwb eng 333.7 VZ 43.50 bkl Song, Ke verfasserin aut Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Biological soil crusts (BSCs) widely exists in mudflat environment, which is known to be efficient in capturing heavy metals from aqueous solutions; However, their ability to adsorb cadmium (Cd(II)) is limited due to low capacity and selectivity. To address this limitation, manganese ethylenediamine phosphates (MEPs) nanomaterial were incorporated into the BSCs to enhance Cd(II) uptake. The MEPs nanomaterials attached to BSC significantly improved the adsorption capacity, rate, and selection for Cd(II). The adsorption kinetics of Cd(II) by BSCs and BSCs-MEPs was well described by a pseudo-second-order model, with BSCs-MEPs exhibiting a much higher adsorption capacity for Cd(II) (77.00 mg/g) compared to BSCs (55.44 mg/g). The Cd(II) removal by BSCs-MEPs has been accelerated to 2 stages, in which the film diffusion/intraparticle diffusion/chemical reaction participated in the 1st stage. And another stage was dynamic equilibrium process. The adsorption isotherm of BSCs-MEPs demonstrated superior performance for Cd(II) compared to BSCs across a pH range from 2 to 9. Most importantly, even in the presence of high concentration of $ Na^{+} $ or $ Ca^{2+} $ ions, BSCs-MEPs exhibited preferential adsorption for Cd(II), a result not observed with BSCs alone. Analysis of X-ray photoelectron spectroscopy spectra demonstrated that functional groups (-$ NH_{2} $/-COOH/-OH) played an important role in Cd(II) adsorption, while the MEPs attach to BSCs leading to the -$ NH_{3} $+ deprotonation, thus enhanced the BSCs' affinity toward Cd(II). Furthermore, molecular dynamics simulation clearly showed that diffusion coefficients (D) of Cd(II) were much higher than those of $ Ca^{2+} $ in EPS with abundant -$ NH_{2} $, which were responsible for selective adsorption. These findings might provide a valuable approach for treating Cd-contaminated water bodies. Graphical abstract Biological soil crusts (dpeaa)DE-He213 Nanomaterial (dpeaa)DE-He213 Cd(II) (dpeaa)DE-He213 Adsorption (dpeaa)DE-He213 Liu, Bin verfasserin aut Kuang, Xiaolin verfasserin aut Song, Huijuan verfasserin aut Zeng, Qingru verfasserin aut Peng, Liang verfasserin aut Enthalten in Water, air & soil pollution Springer International Publishing, 1971 235(2024), 7 vom: 20. Juni (DE-627)271349417 (DE-600)1479824-4 1573-2932 nnns volume:235 year:2024 number:7 day:20 month:06 https://dx.doi.org/10.1007/s11270-024-07249-4 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.50 VZ AR 235 2024 7 20 06 |
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10.1007/s11270-024-07249-4 doi (DE-627)SPR05630479X (SPR)s11270-024-07249-4-e DE-627 ger DE-627 rakwb eng 333.7 VZ 43.50 bkl Song, Ke verfasserin aut Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Biological soil crusts (BSCs) widely exists in mudflat environment, which is known to be efficient in capturing heavy metals from aqueous solutions; However, their ability to adsorb cadmium (Cd(II)) is limited due to low capacity and selectivity. To address this limitation, manganese ethylenediamine phosphates (MEPs) nanomaterial were incorporated into the BSCs to enhance Cd(II) uptake. The MEPs nanomaterials attached to BSC significantly improved the adsorption capacity, rate, and selection for Cd(II). The adsorption kinetics of Cd(II) by BSCs and BSCs-MEPs was well described by a pseudo-second-order model, with BSCs-MEPs exhibiting a much higher adsorption capacity for Cd(II) (77.00 mg/g) compared to BSCs (55.44 mg/g). The Cd(II) removal by BSCs-MEPs has been accelerated to 2 stages, in which the film diffusion/intraparticle diffusion/chemical reaction participated in the 1st stage. And another stage was dynamic equilibrium process. The adsorption isotherm of BSCs-MEPs demonstrated superior performance for Cd(II) compared to BSCs across a pH range from 2 to 9. Most importantly, even in the presence of high concentration of $ Na^{+} $ or $ Ca^{2+} $ ions, BSCs-MEPs exhibited preferential adsorption for Cd(II), a result not observed with BSCs alone. Analysis of X-ray photoelectron spectroscopy spectra demonstrated that functional groups (-$ NH_{2} $/-COOH/-OH) played an important role in Cd(II) adsorption, while the MEPs attach to BSCs leading to the -$ NH_{3} $+ deprotonation, thus enhanced the BSCs' affinity toward Cd(II). Furthermore, molecular dynamics simulation clearly showed that diffusion coefficients (D) of Cd(II) were much higher than those of $ Ca^{2+} $ in EPS with abundant -$ NH_{2} $, which were responsible for selective adsorption. These findings might provide a valuable approach for treating Cd-contaminated water bodies. Graphical abstract Biological soil crusts (dpeaa)DE-He213 Nanomaterial (dpeaa)DE-He213 Cd(II) (dpeaa)DE-He213 Adsorption (dpeaa)DE-He213 Liu, Bin verfasserin aut Kuang, Xiaolin verfasserin aut Song, Huijuan verfasserin aut Zeng, Qingru verfasserin aut Peng, Liang verfasserin aut Enthalten in Water, air & soil pollution Springer International Publishing, 1971 235(2024), 7 vom: 20. Juni (DE-627)271349417 (DE-600)1479824-4 1573-2932 nnns volume:235 year:2024 number:7 day:20 month:06 https://dx.doi.org/10.1007/s11270-024-07249-4 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.50 VZ AR 235 2024 7 20 06 |
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10.1007/s11270-024-07249-4 doi (DE-627)SPR05630479X (SPR)s11270-024-07249-4-e DE-627 ger DE-627 rakwb eng 333.7 VZ 43.50 bkl Song, Ke verfasserin aut Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Biological soil crusts (BSCs) widely exists in mudflat environment, which is known to be efficient in capturing heavy metals from aqueous solutions; However, their ability to adsorb cadmium (Cd(II)) is limited due to low capacity and selectivity. To address this limitation, manganese ethylenediamine phosphates (MEPs) nanomaterial were incorporated into the BSCs to enhance Cd(II) uptake. The MEPs nanomaterials attached to BSC significantly improved the adsorption capacity, rate, and selection for Cd(II). The adsorption kinetics of Cd(II) by BSCs and BSCs-MEPs was well described by a pseudo-second-order model, with BSCs-MEPs exhibiting a much higher adsorption capacity for Cd(II) (77.00 mg/g) compared to BSCs (55.44 mg/g). The Cd(II) removal by BSCs-MEPs has been accelerated to 2 stages, in which the film diffusion/intraparticle diffusion/chemical reaction participated in the 1st stage. And another stage was dynamic equilibrium process. The adsorption isotherm of BSCs-MEPs demonstrated superior performance for Cd(II) compared to BSCs across a pH range from 2 to 9. Most importantly, even in the presence of high concentration of $ Na^{+} $ or $ Ca^{2+} $ ions, BSCs-MEPs exhibited preferential adsorption for Cd(II), a result not observed with BSCs alone. Analysis of X-ray photoelectron spectroscopy spectra demonstrated that functional groups (-$ NH_{2} $/-COOH/-OH) played an important role in Cd(II) adsorption, while the MEPs attach to BSCs leading to the -$ NH_{3} $+ deprotonation, thus enhanced the BSCs' affinity toward Cd(II). Furthermore, molecular dynamics simulation clearly showed that diffusion coefficients (D) of Cd(II) were much higher than those of $ Ca^{2+} $ in EPS with abundant -$ NH_{2} $, which were responsible for selective adsorption. These findings might provide a valuable approach for treating Cd-contaminated water bodies. Graphical abstract Biological soil crusts (dpeaa)DE-He213 Nanomaterial (dpeaa)DE-He213 Cd(II) (dpeaa)DE-He213 Adsorption (dpeaa)DE-He213 Liu, Bin verfasserin aut Kuang, Xiaolin verfasserin aut Song, Huijuan verfasserin aut Zeng, Qingru verfasserin aut Peng, Liang verfasserin aut Enthalten in Water, air & soil pollution Springer International Publishing, 1971 235(2024), 7 vom: 20. Juni (DE-627)271349417 (DE-600)1479824-4 1573-2932 nnns volume:235 year:2024 number:7 day:20 month:06 https://dx.doi.org/10.1007/s11270-024-07249-4 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.50 VZ AR 235 2024 7 20 06 |
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Enthalten in Water, air & soil pollution 235(2024), 7 vom: 20. Juni volume:235 year:2024 number:7 day:20 month:06 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR05630479X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20240705064654.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">240621s2024 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11270-024-07249-4</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR05630479X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11270-024-07249-4-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">333.7</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">43.50</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Song, Ke</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2024</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Biological soil crusts (BSCs) widely exists in mudflat environment, which is known to be efficient in capturing heavy metals from aqueous solutions; However, their ability to adsorb cadmium (Cd(II)) is limited due to low capacity and selectivity. To address this limitation, manganese ethylenediamine phosphates (MEPs) nanomaterial were incorporated into the BSCs to enhance Cd(II) uptake. The MEPs nanomaterials attached to BSC significantly improved the adsorption capacity, rate, and selection for Cd(II). The adsorption kinetics of Cd(II) by BSCs and BSCs-MEPs was well described by a pseudo-second-order model, with BSCs-MEPs exhibiting a much higher adsorption capacity for Cd(II) (77.00 mg/g) compared to BSCs (55.44 mg/g). The Cd(II) removal by BSCs-MEPs has been accelerated to 2 stages, in which the film diffusion/intraparticle diffusion/chemical reaction participated in the 1st stage. And another stage was dynamic equilibrium process. The adsorption isotherm of BSCs-MEPs demonstrated superior performance for Cd(II) compared to BSCs across a pH range from 2 to 9. Most importantly, even in the presence of high concentration of $ Na^{+} $ or $ Ca^{2+} $ ions, BSCs-MEPs exhibited preferential adsorption for Cd(II), a result not observed with BSCs alone. Analysis of X-ray photoelectron spectroscopy spectra demonstrated that functional groups (-$ NH_{2} $/-COOH/-OH) played an important role in Cd(II) adsorption, while the MEPs attach to BSCs leading to the -$ NH_{3} $+ deprotonation, thus enhanced the BSCs' affinity toward Cd(II). Furthermore, molecular dynamics simulation clearly showed that diffusion coefficients (D) of Cd(II) were much higher than those of $ Ca^{2+} $ in EPS with abundant -$ NH_{2} $, which were responsible for selective adsorption. These findings might provide a valuable approach for treating Cd-contaminated water bodies. Graphical abstract</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Biological soil crusts</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nanomaterial</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Cd(II)</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Adsorption</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Liu, Bin</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kuang, Xiaolin</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Song, Huijuan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zeng, Qingru</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Peng, Liang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Water, air & soil pollution</subfield><subfield code="d">Springer International Publishing, 1971</subfield><subfield code="g">235(2024), 7 vom: 20. 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Song, Ke |
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Song, Ke ddc 333.7 bkl 43.50 misc Biological soil crusts misc Nanomaterial misc Cd(II) misc Adsorption Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium |
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333.7 VZ 43.50 bkl Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium Biological soil crusts (dpeaa)DE-He213 Nanomaterial (dpeaa)DE-He213 Cd(II) (dpeaa)DE-He213 Adsorption (dpeaa)DE-He213 |
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ddc 333.7 bkl 43.50 misc Biological soil crusts misc Nanomaterial misc Cd(II) misc Adsorption |
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Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium |
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Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium |
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Song, Ke Liu, Bin Kuang, Xiaolin Song, Huijuan Zeng, Qingru Peng, Liang |
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manganese ethylenediamine phosphates enhanced the adsorption capacity and selectivity of biological soil crusts for cadmium |
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Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium |
| abstract |
Biological soil crusts (BSCs) widely exists in mudflat environment, which is known to be efficient in capturing heavy metals from aqueous solutions; However, their ability to adsorb cadmium (Cd(II)) is limited due to low capacity and selectivity. To address this limitation, manganese ethylenediamine phosphates (MEPs) nanomaterial were incorporated into the BSCs to enhance Cd(II) uptake. The MEPs nanomaterials attached to BSC significantly improved the adsorption capacity, rate, and selection for Cd(II). The adsorption kinetics of Cd(II) by BSCs and BSCs-MEPs was well described by a pseudo-second-order model, with BSCs-MEPs exhibiting a much higher adsorption capacity for Cd(II) (77.00 mg/g) compared to BSCs (55.44 mg/g). The Cd(II) removal by BSCs-MEPs has been accelerated to 2 stages, in which the film diffusion/intraparticle diffusion/chemical reaction participated in the 1st stage. And another stage was dynamic equilibrium process. The adsorption isotherm of BSCs-MEPs demonstrated superior performance for Cd(II) compared to BSCs across a pH range from 2 to 9. Most importantly, even in the presence of high concentration of $ Na^{+} $ or $ Ca^{2+} $ ions, BSCs-MEPs exhibited preferential adsorption for Cd(II), a result not observed with BSCs alone. Analysis of X-ray photoelectron spectroscopy spectra demonstrated that functional groups (-$ NH_{2} $/-COOH/-OH) played an important role in Cd(II) adsorption, while the MEPs attach to BSCs leading to the -$ NH_{3} $+ deprotonation, thus enhanced the BSCs' affinity toward Cd(II). Furthermore, molecular dynamics simulation clearly showed that diffusion coefficients (D) of Cd(II) were much higher than those of $ Ca^{2+} $ in EPS with abundant -$ NH_{2} $, which were responsible for selective adsorption. These findings might provide a valuable approach for treating Cd-contaminated water bodies. Graphical abstract © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Biological soil crusts (BSCs) widely exists in mudflat environment, which is known to be efficient in capturing heavy metals from aqueous solutions; However, their ability to adsorb cadmium (Cd(II)) is limited due to low capacity and selectivity. To address this limitation, manganese ethylenediamine phosphates (MEPs) nanomaterial were incorporated into the BSCs to enhance Cd(II) uptake. The MEPs nanomaterials attached to BSC significantly improved the adsorption capacity, rate, and selection for Cd(II). The adsorption kinetics of Cd(II) by BSCs and BSCs-MEPs was well described by a pseudo-second-order model, with BSCs-MEPs exhibiting a much higher adsorption capacity for Cd(II) (77.00 mg/g) compared to BSCs (55.44 mg/g). The Cd(II) removal by BSCs-MEPs has been accelerated to 2 stages, in which the film diffusion/intraparticle diffusion/chemical reaction participated in the 1st stage. And another stage was dynamic equilibrium process. The adsorption isotherm of BSCs-MEPs demonstrated superior performance for Cd(II) compared to BSCs across a pH range from 2 to 9. Most importantly, even in the presence of high concentration of $ Na^{+} $ or $ Ca^{2+} $ ions, BSCs-MEPs exhibited preferential adsorption for Cd(II), a result not observed with BSCs alone. Analysis of X-ray photoelectron spectroscopy spectra demonstrated that functional groups (-$ NH_{2} $/-COOH/-OH) played an important role in Cd(II) adsorption, while the MEPs attach to BSCs leading to the -$ NH_{3} $+ deprotonation, thus enhanced the BSCs' affinity toward Cd(II). Furthermore, molecular dynamics simulation clearly showed that diffusion coefficients (D) of Cd(II) were much higher than those of $ Ca^{2+} $ in EPS with abundant -$ NH_{2} $, which were responsible for selective adsorption. These findings might provide a valuable approach for treating Cd-contaminated water bodies. Graphical abstract © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Biological soil crusts (BSCs) widely exists in mudflat environment, which is known to be efficient in capturing heavy metals from aqueous solutions; However, their ability to adsorb cadmium (Cd(II)) is limited due to low capacity and selectivity. To address this limitation, manganese ethylenediamine phosphates (MEPs) nanomaterial were incorporated into the BSCs to enhance Cd(II) uptake. The MEPs nanomaterials attached to BSC significantly improved the adsorption capacity, rate, and selection for Cd(II). The adsorption kinetics of Cd(II) by BSCs and BSCs-MEPs was well described by a pseudo-second-order model, with BSCs-MEPs exhibiting a much higher adsorption capacity for Cd(II) (77.00 mg/g) compared to BSCs (55.44 mg/g). The Cd(II) removal by BSCs-MEPs has been accelerated to 2 stages, in which the film diffusion/intraparticle diffusion/chemical reaction participated in the 1st stage. And another stage was dynamic equilibrium process. The adsorption isotherm of BSCs-MEPs demonstrated superior performance for Cd(II) compared to BSCs across a pH range from 2 to 9. Most importantly, even in the presence of high concentration of $ Na^{+} $ or $ Ca^{2+} $ ions, BSCs-MEPs exhibited preferential adsorption for Cd(II), a result not observed with BSCs alone. Analysis of X-ray photoelectron spectroscopy spectra demonstrated that functional groups (-$ NH_{2} $/-COOH/-OH) played an important role in Cd(II) adsorption, while the MEPs attach to BSCs leading to the -$ NH_{3} $+ deprotonation, thus enhanced the BSCs' affinity toward Cd(II). Furthermore, molecular dynamics simulation clearly showed that diffusion coefficients (D) of Cd(II) were much higher than those of $ Ca^{2+} $ in EPS with abundant -$ NH_{2} $, which were responsible for selective adsorption. These findings might provide a valuable approach for treating Cd-contaminated water bodies. Graphical abstract © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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Manganese Ethylenediamine Phosphates Enhanced the Adsorption Capacity and Selectivity of Biological Soil Crusts for Cadmium |
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Liu, Bin Kuang, Xiaolin Song, Huijuan Zeng, Qingru Peng, Liang |
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| score |
7.1694546 |