The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System
Abstract The crystal structures of type 1234 and 2234 are not found in compositions $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ and $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ after synthesis under conditions of ambient pressure P = 1 bar and T = 835 °C for τ = 240...
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| Autor*in: |
Starrynets, S. M. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2024 |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Journal of superconductivity and novel magnetism - Springer US, 2006, 37(2024), 5-7 vom: 06. Juni, Seite 1079-1088 |
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| Übergeordnetes Werk: |
volume:37 ; year:2024 ; number:5-7 ; day:06 ; month:06 ; pages:1079-1088 |
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| DOI / URN: |
10.1007/s10948-024-06767-w |
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| Katalog-ID: |
SPR056497407 |
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| 520 | |a Abstract The crystal structures of type 1234 and 2234 are not found in compositions $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ and $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ after synthesis under conditions of ambient pressure P = 1 bar and T = 835 °C for τ = 240 h. This conclusion is obtained as a result of the fact that the series of bismuth superconductors $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $, $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with different boron content x = 0-2 were synthesized followed by slow (rate < 10 °C/sec) cooling or quenching (< 100 °C/sec). Samples of $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with a boron content of x = 0.5 have a significant (> 35%) proportion of the superconducting phase 2223, regardless of the accuracy of observing the temperature modes of synthesis (in temperature ranges < ±10 °C) and cooling after it. A model of the effect of boron on phase equilibrium in Bi-Pb-Sr-Ca-Cu-O system is proposed using the process of boron-bismuth glass formation. Therefore, the boron addition during the synthesis of bismuth superconductors will increase the production process reproducibility of phase 2223. Also, this technology can be used at the synthesis of superconductors from the boron-bismuth not very enriched ores in conditions of limited available resources. | ||
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10.1007/s10948-024-06767-w doi (DE-627)SPR056497407 (SPR)s10948-024-06767-w-e DE-627 ger DE-627 rakwb eng 530 VZ 33.74 bkl Starrynets, S. M. verfasserin aut The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The crystal structures of type 1234 and 2234 are not found in compositions $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ and $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ after synthesis under conditions of ambient pressure P = 1 bar and T = 835 °C for τ = 240 h. This conclusion is obtained as a result of the fact that the series of bismuth superconductors $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $, $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with different boron content x = 0-2 were synthesized followed by slow (rate < 10 °C/sec) cooling or quenching (< 100 °C/sec). Samples of $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with a boron content of x = 0.5 have a significant (> 35%) proportion of the superconducting phase 2223, regardless of the accuracy of observing the temperature modes of synthesis (in temperature ranges < ±10 °C) and cooling after it. A model of the effect of boron on phase equilibrium in Bi-Pb-Sr-Ca-Cu-O system is proposed using the process of boron-bismuth glass formation. Therefore, the boron addition during the synthesis of bismuth superconductors will increase the production process reproducibility of phase 2223. Also, this technology can be used at the synthesis of superconductors from the boron-bismuth not very enriched ores in conditions of limited available resources. Bismuth-boron superconductors (dpeaa)DE-He213 Phase equilibrium (dpeaa)DE-He213 Unit cell (dpeaa)DE-He213 Electric resistivity (dpeaa)DE-He213 Diamagnetic volume fraction (dpeaa)DE-He213 Critical temperature (dpeaa)DE-He213 Model of the phase equilibrium (dpeaa)DE-He213 Enthalten in Journal of superconductivity and novel magnetism Springer US, 2006 37(2024), 5-7 vom: 06. Juni, Seite 1079-1088 Online-Ressource (DE-627)51620386X (DE-600)2246896-1 (DE-576)261570919 1557-1947 nnns volume:37 year:2024 number:5-7 day:06 month:06 pages:1079-1088 https://dx.doi.org/10.1007/s10948-024-06767-w X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.74 Supraleitung VZ AR 37 2024 5-7 06 06 1079-1088 |
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10.1007/s10948-024-06767-w doi (DE-627)SPR056497407 (SPR)s10948-024-06767-w-e DE-627 ger DE-627 rakwb eng 530 VZ 33.74 bkl Starrynets, S. M. verfasserin aut The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The crystal structures of type 1234 and 2234 are not found in compositions $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ and $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ after synthesis under conditions of ambient pressure P = 1 bar and T = 835 °C for τ = 240 h. This conclusion is obtained as a result of the fact that the series of bismuth superconductors $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $, $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with different boron content x = 0-2 were synthesized followed by slow (rate < 10 °C/sec) cooling or quenching (< 100 °C/sec). Samples of $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with a boron content of x = 0.5 have a significant (> 35%) proportion of the superconducting phase 2223, regardless of the accuracy of observing the temperature modes of synthesis (in temperature ranges < ±10 °C) and cooling after it. A model of the effect of boron on phase equilibrium in Bi-Pb-Sr-Ca-Cu-O system is proposed using the process of boron-bismuth glass formation. Therefore, the boron addition during the synthesis of bismuth superconductors will increase the production process reproducibility of phase 2223. Also, this technology can be used at the synthesis of superconductors from the boron-bismuth not very enriched ores in conditions of limited available resources. Bismuth-boron superconductors (dpeaa)DE-He213 Phase equilibrium (dpeaa)DE-He213 Unit cell (dpeaa)DE-He213 Electric resistivity (dpeaa)DE-He213 Diamagnetic volume fraction (dpeaa)DE-He213 Critical temperature (dpeaa)DE-He213 Model of the phase equilibrium (dpeaa)DE-He213 Enthalten in Journal of superconductivity and novel magnetism Springer US, 2006 37(2024), 5-7 vom: 06. Juni, Seite 1079-1088 Online-Ressource (DE-627)51620386X (DE-600)2246896-1 (DE-576)261570919 1557-1947 nnns volume:37 year:2024 number:5-7 day:06 month:06 pages:1079-1088 https://dx.doi.org/10.1007/s10948-024-06767-w X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.74 Supraleitung VZ AR 37 2024 5-7 06 06 1079-1088 |
| allfields_unstemmed |
10.1007/s10948-024-06767-w doi (DE-627)SPR056497407 (SPR)s10948-024-06767-w-e DE-627 ger DE-627 rakwb eng 530 VZ 33.74 bkl Starrynets, S. M. verfasserin aut The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The crystal structures of type 1234 and 2234 are not found in compositions $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ and $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ after synthesis under conditions of ambient pressure P = 1 bar and T = 835 °C for τ = 240 h. This conclusion is obtained as a result of the fact that the series of bismuth superconductors $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $, $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with different boron content x = 0-2 were synthesized followed by slow (rate < 10 °C/sec) cooling or quenching (< 100 °C/sec). Samples of $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with a boron content of x = 0.5 have a significant (> 35%) proportion of the superconducting phase 2223, regardless of the accuracy of observing the temperature modes of synthesis (in temperature ranges < ±10 °C) and cooling after it. A model of the effect of boron on phase equilibrium in Bi-Pb-Sr-Ca-Cu-O system is proposed using the process of boron-bismuth glass formation. Therefore, the boron addition during the synthesis of bismuth superconductors will increase the production process reproducibility of phase 2223. Also, this technology can be used at the synthesis of superconductors from the boron-bismuth not very enriched ores in conditions of limited available resources. Bismuth-boron superconductors (dpeaa)DE-He213 Phase equilibrium (dpeaa)DE-He213 Unit cell (dpeaa)DE-He213 Electric resistivity (dpeaa)DE-He213 Diamagnetic volume fraction (dpeaa)DE-He213 Critical temperature (dpeaa)DE-He213 Model of the phase equilibrium (dpeaa)DE-He213 Enthalten in Journal of superconductivity and novel magnetism Springer US, 2006 37(2024), 5-7 vom: 06. Juni, Seite 1079-1088 Online-Ressource (DE-627)51620386X (DE-600)2246896-1 (DE-576)261570919 1557-1947 nnns volume:37 year:2024 number:5-7 day:06 month:06 pages:1079-1088 https://dx.doi.org/10.1007/s10948-024-06767-w X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.74 Supraleitung VZ AR 37 2024 5-7 06 06 1079-1088 |
| allfieldsGer |
10.1007/s10948-024-06767-w doi (DE-627)SPR056497407 (SPR)s10948-024-06767-w-e DE-627 ger DE-627 rakwb eng 530 VZ 33.74 bkl Starrynets, S. M. verfasserin aut The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The crystal structures of type 1234 and 2234 are not found in compositions $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ and $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ after synthesis under conditions of ambient pressure P = 1 bar and T = 835 °C for τ = 240 h. This conclusion is obtained as a result of the fact that the series of bismuth superconductors $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $, $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with different boron content x = 0-2 were synthesized followed by slow (rate < 10 °C/sec) cooling or quenching (< 100 °C/sec). Samples of $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with a boron content of x = 0.5 have a significant (> 35%) proportion of the superconducting phase 2223, regardless of the accuracy of observing the temperature modes of synthesis (in temperature ranges < ±10 °C) and cooling after it. A model of the effect of boron on phase equilibrium in Bi-Pb-Sr-Ca-Cu-O system is proposed using the process of boron-bismuth glass formation. Therefore, the boron addition during the synthesis of bismuth superconductors will increase the production process reproducibility of phase 2223. Also, this technology can be used at the synthesis of superconductors from the boron-bismuth not very enriched ores in conditions of limited available resources. Bismuth-boron superconductors (dpeaa)DE-He213 Phase equilibrium (dpeaa)DE-He213 Unit cell (dpeaa)DE-He213 Electric resistivity (dpeaa)DE-He213 Diamagnetic volume fraction (dpeaa)DE-He213 Critical temperature (dpeaa)DE-He213 Model of the phase equilibrium (dpeaa)DE-He213 Enthalten in Journal of superconductivity and novel magnetism Springer US, 2006 37(2024), 5-7 vom: 06. Juni, Seite 1079-1088 Online-Ressource (DE-627)51620386X (DE-600)2246896-1 (DE-576)261570919 1557-1947 nnns volume:37 year:2024 number:5-7 day:06 month:06 pages:1079-1088 https://dx.doi.org/10.1007/s10948-024-06767-w X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.74 Supraleitung VZ AR 37 2024 5-7 06 06 1079-1088 |
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10.1007/s10948-024-06767-w doi (DE-627)SPR056497407 (SPR)s10948-024-06767-w-e DE-627 ger DE-627 rakwb eng 530 VZ 33.74 bkl Starrynets, S. M. verfasserin aut The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The crystal structures of type 1234 and 2234 are not found in compositions $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ and $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ after synthesis under conditions of ambient pressure P = 1 bar and T = 835 °C for τ = 240 h. This conclusion is obtained as a result of the fact that the series of bismuth superconductors $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $, $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with different boron content x = 0-2 were synthesized followed by slow (rate < 10 °C/sec) cooling or quenching (< 100 °C/sec). Samples of $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with a boron content of x = 0.5 have a significant (> 35%) proportion of the superconducting phase 2223, regardless of the accuracy of observing the temperature modes of synthesis (in temperature ranges < ±10 °C) and cooling after it. A model of the effect of boron on phase equilibrium in Bi-Pb-Sr-Ca-Cu-O system is proposed using the process of boron-bismuth glass formation. Therefore, the boron addition during the synthesis of bismuth superconductors will increase the production process reproducibility of phase 2223. Also, this technology can be used at the synthesis of superconductors from the boron-bismuth not very enriched ores in conditions of limited available resources. Bismuth-boron superconductors (dpeaa)DE-He213 Phase equilibrium (dpeaa)DE-He213 Unit cell (dpeaa)DE-He213 Electric resistivity (dpeaa)DE-He213 Diamagnetic volume fraction (dpeaa)DE-He213 Critical temperature (dpeaa)DE-He213 Model of the phase equilibrium (dpeaa)DE-He213 Enthalten in Journal of superconductivity and novel magnetism Springer US, 2006 37(2024), 5-7 vom: 06. Juni, Seite 1079-1088 Online-Ressource (DE-627)51620386X (DE-600)2246896-1 (DE-576)261570919 1557-1947 nnns volume:37 year:2024 number:5-7 day:06 month:06 pages:1079-1088 https://dx.doi.org/10.1007/s10948-024-06767-w X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.74 Supraleitung VZ AR 37 2024 5-7 06 06 1079-1088 |
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Starrynets, S. M. |
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Starrynets, S. M. ddc 530 bkl 33.74 misc Bismuth-boron superconductors misc Phase equilibrium misc Unit cell misc Electric resistivity misc Diamagnetic volume fraction misc Critical temperature misc Model of the phase equilibrium The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System |
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530 VZ 33.74 bkl The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System Bismuth-boron superconductors (dpeaa)DE-He213 Phase equilibrium (dpeaa)DE-He213 Unit cell (dpeaa)DE-He213 Electric resistivity (dpeaa)DE-He213 Diamagnetic volume fraction (dpeaa)DE-He213 Critical temperature (dpeaa)DE-He213 Model of the phase equilibrium (dpeaa)DE-He213 |
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ddc 530 bkl 33.74 misc Bismuth-boron superconductors misc Phase equilibrium misc Unit cell misc Electric resistivity misc Diamagnetic volume fraction misc Critical temperature misc Model of the phase equilibrium |
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ddc 530 bkl 33.74 misc Bismuth-boron superconductors misc Phase equilibrium misc Unit cell misc Electric resistivity misc Diamagnetic volume fraction misc Critical temperature misc Model of the phase equilibrium |
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The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System |
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The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System |
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Starrynets, S. M. |
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the effect of boron on equilibrium of superconducting phases in bi-pb-sr-ca-cu-o system |
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The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System |
| abstract |
Abstract The crystal structures of type 1234 and 2234 are not found in compositions $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ and $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ after synthesis under conditions of ambient pressure P = 1 bar and T = 835 °C for τ = 240 h. This conclusion is obtained as a result of the fact that the series of bismuth superconductors $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $, $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with different boron content x = 0-2 were synthesized followed by slow (rate < 10 °C/sec) cooling or quenching (< 100 °C/sec). Samples of $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with a boron content of x = 0.5 have a significant (> 35%) proportion of the superconducting phase 2223, regardless of the accuracy of observing the temperature modes of synthesis (in temperature ranges < ±10 °C) and cooling after it. A model of the effect of boron on phase equilibrium in Bi-Pb-Sr-Ca-Cu-O system is proposed using the process of boron-bismuth glass formation. Therefore, the boron addition during the synthesis of bismuth superconductors will increase the production process reproducibility of phase 2223. Also, this technology can be used at the synthesis of superconductors from the boron-bismuth not very enriched ores in conditions of limited available resources. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Abstract The crystal structures of type 1234 and 2234 are not found in compositions $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ and $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ after synthesis under conditions of ambient pressure P = 1 bar and T = 835 °C for τ = 240 h. This conclusion is obtained as a result of the fact that the series of bismuth superconductors $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $, $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with different boron content x = 0-2 were synthesized followed by slow (rate < 10 °C/sec) cooling or quenching (< 100 °C/sec). Samples of $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with a boron content of x = 0.5 have a significant (> 35%) proportion of the superconducting phase 2223, regardless of the accuracy of observing the temperature modes of synthesis (in temperature ranges < ±10 °C) and cooling after it. A model of the effect of boron on phase equilibrium in Bi-Pb-Sr-Ca-Cu-O system is proposed using the process of boron-bismuth glass formation. Therefore, the boron addition during the synthesis of bismuth superconductors will increase the production process reproducibility of phase 2223. Also, this technology can be used at the synthesis of superconductors from the boron-bismuth not very enriched ores in conditions of limited available resources. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Abstract The crystal structures of type 1234 and 2234 are not found in compositions $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ and $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ after synthesis under conditions of ambient pressure P = 1 bar and T = 835 °C for τ = 240 h. This conclusion is obtained as a result of the fact that the series of bismuth superconductors $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $, $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with different boron content x = 0-2 were synthesized followed by slow (rate < 10 °C/sec) cooling or quenching (< 100 °C/sec). Samples of $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with a boron content of x = 0.5 have a significant (> 35%) proportion of the superconducting phase 2223, regardless of the accuracy of observing the temperature modes of synthesis (in temperature ranges < ±10 °C) and cooling after it. A model of the effect of boron on phase equilibrium in Bi-Pb-Sr-Ca-Cu-O system is proposed using the process of boron-bismuth glass formation. Therefore, the boron addition during the synthesis of bismuth superconductors will increase the production process reproducibility of phase 2223. Also, this technology can be used at the synthesis of superconductors from the boron-bismuth not very enriched ores in conditions of limited available resources. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System |
| url |
https://dx.doi.org/10.1007/s10948-024-06767-w |
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| doi_str |
10.1007/s10948-024-06767-w |
| up_date |
2024-07-10T07:10:17.292Z |
| _version_ |
1804175060285521920 |
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M.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2024</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The crystal structures of type 1234 and 2234 are not found in compositions $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ and $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $ after synthesis under conditions of ambient pressure P = 1 bar and T = 835 °C for τ = 240 h. This conclusion is obtained as a result of the fact that the series of bismuth superconductors $ Bi_{1-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{3} $$ Cu_{4} $$ O_{y} $, $ Bi_{2-x} $$ B_{x} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $, $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with different boron content x = 0-2 were synthesized followed by slow (rate < 10 °C/sec) cooling or quenching (< 100 °C/sec). Samples of $ Bi_{1.7-x} $$ B_{x} $$ Pb_{0.3} $$ Sr_{2} $$ Ca_{2} $$ Cu_{3} $$ O_{y} $ with a boron content of x = 0.5 have a significant (> 35%) proportion of the superconducting phase 2223, regardless of the accuracy of observing the temperature modes of synthesis (in temperature ranges < ±10 °C) and cooling after it. A model of the effect of boron on phase equilibrium in Bi-Pb-Sr-Ca-Cu-O system is proposed using the process of boron-bismuth glass formation. Therefore, the boron addition during the synthesis of bismuth superconductors will increase the production process reproducibility of phase 2223. 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