Investigations on Mn shielding the negative effect of Fe in the aluminum alloy anodes used for Al-air batteries
Abstract In this study, Al-Fe and Al-Fe-Mn alloy anodes are prepared and examined. The influence of impurity Fe on the microstructure and properties of Al alloy anodes is investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical testing techniques. The resul...
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Gespeichert in:
| Autor*in: |
Wan, Huan [verfasserIn] Wang, Wei [verfasserIn] Bu, Lu-xia [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2024 |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Journal of solid state electrochemistry - Springer Berlin Heidelberg, 1997, 28(2024), 8 vom: 24. Jan., Seite 2547-2560 |
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| Übergeordnetes Werk: |
volume:28 ; year:2024 ; number:8 ; day:24 ; month:01 ; pages:2547-2560 |
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| DOI / URN: |
10.1007/s10008-024-05801-0 |
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SPR056566557 |
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| 520 | |a Abstract In this study, Al-Fe and Al-Fe-Mn alloy anodes are prepared and examined. The influence of impurity Fe on the microstructure and properties of Al alloy anodes is investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical testing techniques. The results reveal that the presence of impurity Fe in Al alloys significantly shifts the open-circuit potential of the Al anode towards the positive side and reduces its discharge efficiency. However, the adverse impact of impurity Fe is mitigated by alloying with Mn. Specifically, the open-circuit potential of Al-0.20%Fe-0.20%Mn anodes is observed to shift negatively by 70 mV when compared to that of Al-0.20%Fe in a 3 M KOH solution. Furthermore, the anode utilization of Al-0.20%Fe-0.20%Mn anodes, following continuous discharge at 30 mA·$ cm^{−2} $ and 100 mA·$ cm^{−2} $ for 30 min, is found to be 70% and 52% higher, respectively, than that of Al-0.20%Fe anodes. This highlights the effectiveness of Mn modification as a preferable approach to ameliorate the detrimental effects of impurity Fe. | ||
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| 650 | 4 | |a Impurity Fe |7 (dpeaa)DE-He213 | |
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10.1007/s10008-024-05801-0 doi (DE-627)SPR056566557 (SPR)s10008-024-05801-0-e DE-627 ger DE-627 rakwb eng 540 VZ 35.14 bkl 35.90 bkl Wan, Huan verfasserin aut Investigations on Mn shielding the negative effect of Fe in the aluminum alloy anodes used for Al-air batteries 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract In this study, Al-Fe and Al-Fe-Mn alloy anodes are prepared and examined. The influence of impurity Fe on the microstructure and properties of Al alloy anodes is investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical testing techniques. The results reveal that the presence of impurity Fe in Al alloys significantly shifts the open-circuit potential of the Al anode towards the positive side and reduces its discharge efficiency. However, the adverse impact of impurity Fe is mitigated by alloying with Mn. Specifically, the open-circuit potential of Al-0.20%Fe-0.20%Mn anodes is observed to shift negatively by 70 mV when compared to that of Al-0.20%Fe in a 3 M KOH solution. Furthermore, the anode utilization of Al-0.20%Fe-0.20%Mn anodes, following continuous discharge at 30 mA·$ cm^{−2} $ and 100 mA·$ cm^{−2} $ for 30 min, is found to be 70% and 52% higher, respectively, than that of Al-0.20%Fe anodes. This highlights the effectiveness of Mn modification as a preferable approach to ameliorate the detrimental effects of impurity Fe. Al-air battery (dpeaa)DE-He213 Al anode (dpeaa)DE-He213 Utilization (dpeaa)DE-He213 Impurity Fe (dpeaa)DE-He213 Wang, Wei verfasserin (orcid)0000-0001-8086-0390 aut Bu, Lu-xia verfasserin aut Enthalten in Journal of solid state electrochemistry Springer Berlin Heidelberg, 1997 28(2024), 8 vom: 24. Jan., Seite 2547-2560 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:28 year:2024 number:8 day:24 month:01 pages:2547-2560 https://dx.doi.org/10.1007/s10008-024-05801-0 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 VZ 35.90 VZ AR 28 2024 8 24 01 2547-2560 |
| spelling |
10.1007/s10008-024-05801-0 doi (DE-627)SPR056566557 (SPR)s10008-024-05801-0-e DE-627 ger DE-627 rakwb eng 540 VZ 35.14 bkl 35.90 bkl Wan, Huan verfasserin aut Investigations on Mn shielding the negative effect of Fe in the aluminum alloy anodes used for Al-air batteries 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract In this study, Al-Fe and Al-Fe-Mn alloy anodes are prepared and examined. The influence of impurity Fe on the microstructure and properties of Al alloy anodes is investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical testing techniques. The results reveal that the presence of impurity Fe in Al alloys significantly shifts the open-circuit potential of the Al anode towards the positive side and reduces its discharge efficiency. However, the adverse impact of impurity Fe is mitigated by alloying with Mn. Specifically, the open-circuit potential of Al-0.20%Fe-0.20%Mn anodes is observed to shift negatively by 70 mV when compared to that of Al-0.20%Fe in a 3 M KOH solution. Furthermore, the anode utilization of Al-0.20%Fe-0.20%Mn anodes, following continuous discharge at 30 mA·$ cm^{−2} $ and 100 mA·$ cm^{−2} $ for 30 min, is found to be 70% and 52% higher, respectively, than that of Al-0.20%Fe anodes. This highlights the effectiveness of Mn modification as a preferable approach to ameliorate the detrimental effects of impurity Fe. Al-air battery (dpeaa)DE-He213 Al anode (dpeaa)DE-He213 Utilization (dpeaa)DE-He213 Impurity Fe (dpeaa)DE-He213 Wang, Wei verfasserin (orcid)0000-0001-8086-0390 aut Bu, Lu-xia verfasserin aut Enthalten in Journal of solid state electrochemistry Springer Berlin Heidelberg, 1997 28(2024), 8 vom: 24. Jan., Seite 2547-2560 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:28 year:2024 number:8 day:24 month:01 pages:2547-2560 https://dx.doi.org/10.1007/s10008-024-05801-0 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 VZ 35.90 VZ AR 28 2024 8 24 01 2547-2560 |
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10.1007/s10008-024-05801-0 doi (DE-627)SPR056566557 (SPR)s10008-024-05801-0-e DE-627 ger DE-627 rakwb eng 540 VZ 35.14 bkl 35.90 bkl Wan, Huan verfasserin aut Investigations on Mn shielding the negative effect of Fe in the aluminum alloy anodes used for Al-air batteries 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract In this study, Al-Fe and Al-Fe-Mn alloy anodes are prepared and examined. The influence of impurity Fe on the microstructure and properties of Al alloy anodes is investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical testing techniques. The results reveal that the presence of impurity Fe in Al alloys significantly shifts the open-circuit potential of the Al anode towards the positive side and reduces its discharge efficiency. However, the adverse impact of impurity Fe is mitigated by alloying with Mn. Specifically, the open-circuit potential of Al-0.20%Fe-0.20%Mn anodes is observed to shift negatively by 70 mV when compared to that of Al-0.20%Fe in a 3 M KOH solution. Furthermore, the anode utilization of Al-0.20%Fe-0.20%Mn anodes, following continuous discharge at 30 mA·$ cm^{−2} $ and 100 mA·$ cm^{−2} $ for 30 min, is found to be 70% and 52% higher, respectively, than that of Al-0.20%Fe anodes. This highlights the effectiveness of Mn modification as a preferable approach to ameliorate the detrimental effects of impurity Fe. Al-air battery (dpeaa)DE-He213 Al anode (dpeaa)DE-He213 Utilization (dpeaa)DE-He213 Impurity Fe (dpeaa)DE-He213 Wang, Wei verfasserin (orcid)0000-0001-8086-0390 aut Bu, Lu-xia verfasserin aut Enthalten in Journal of solid state electrochemistry Springer Berlin Heidelberg, 1997 28(2024), 8 vom: 24. Jan., Seite 2547-2560 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:28 year:2024 number:8 day:24 month:01 pages:2547-2560 https://dx.doi.org/10.1007/s10008-024-05801-0 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 VZ 35.90 VZ AR 28 2024 8 24 01 2547-2560 |
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10.1007/s10008-024-05801-0 doi (DE-627)SPR056566557 (SPR)s10008-024-05801-0-e DE-627 ger DE-627 rakwb eng 540 VZ 35.14 bkl 35.90 bkl Wan, Huan verfasserin aut Investigations on Mn shielding the negative effect of Fe in the aluminum alloy anodes used for Al-air batteries 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract In this study, Al-Fe and Al-Fe-Mn alloy anodes are prepared and examined. The influence of impurity Fe on the microstructure and properties of Al alloy anodes is investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical testing techniques. The results reveal that the presence of impurity Fe in Al alloys significantly shifts the open-circuit potential of the Al anode towards the positive side and reduces its discharge efficiency. However, the adverse impact of impurity Fe is mitigated by alloying with Mn. Specifically, the open-circuit potential of Al-0.20%Fe-0.20%Mn anodes is observed to shift negatively by 70 mV when compared to that of Al-0.20%Fe in a 3 M KOH solution. Furthermore, the anode utilization of Al-0.20%Fe-0.20%Mn anodes, following continuous discharge at 30 mA·$ cm^{−2} $ and 100 mA·$ cm^{−2} $ for 30 min, is found to be 70% and 52% higher, respectively, than that of Al-0.20%Fe anodes. This highlights the effectiveness of Mn modification as a preferable approach to ameliorate the detrimental effects of impurity Fe. Al-air battery (dpeaa)DE-He213 Al anode (dpeaa)DE-He213 Utilization (dpeaa)DE-He213 Impurity Fe (dpeaa)DE-He213 Wang, Wei verfasserin (orcid)0000-0001-8086-0390 aut Bu, Lu-xia verfasserin aut Enthalten in Journal of solid state electrochemistry Springer Berlin Heidelberg, 1997 28(2024), 8 vom: 24. Jan., Seite 2547-2560 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:28 year:2024 number:8 day:24 month:01 pages:2547-2560 https://dx.doi.org/10.1007/s10008-024-05801-0 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 VZ 35.90 VZ AR 28 2024 8 24 01 2547-2560 |
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10.1007/s10008-024-05801-0 doi (DE-627)SPR056566557 (SPR)s10008-024-05801-0-e DE-627 ger DE-627 rakwb eng 540 VZ 35.14 bkl 35.90 bkl Wan, Huan verfasserin aut Investigations on Mn shielding the negative effect of Fe in the aluminum alloy anodes used for Al-air batteries 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract In this study, Al-Fe and Al-Fe-Mn alloy anodes are prepared and examined. The influence of impurity Fe on the microstructure and properties of Al alloy anodes is investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical testing techniques. The results reveal that the presence of impurity Fe in Al alloys significantly shifts the open-circuit potential of the Al anode towards the positive side and reduces its discharge efficiency. However, the adverse impact of impurity Fe is mitigated by alloying with Mn. Specifically, the open-circuit potential of Al-0.20%Fe-0.20%Mn anodes is observed to shift negatively by 70 mV when compared to that of Al-0.20%Fe in a 3 M KOH solution. Furthermore, the anode utilization of Al-0.20%Fe-0.20%Mn anodes, following continuous discharge at 30 mA·$ cm^{−2} $ and 100 mA·$ cm^{−2} $ for 30 min, is found to be 70% and 52% higher, respectively, than that of Al-0.20%Fe anodes. This highlights the effectiveness of Mn modification as a preferable approach to ameliorate the detrimental effects of impurity Fe. Al-air battery (dpeaa)DE-He213 Al anode (dpeaa)DE-He213 Utilization (dpeaa)DE-He213 Impurity Fe (dpeaa)DE-He213 Wang, Wei verfasserin (orcid)0000-0001-8086-0390 aut Bu, Lu-xia verfasserin aut Enthalten in Journal of solid state electrochemistry Springer Berlin Heidelberg, 1997 28(2024), 8 vom: 24. Jan., Seite 2547-2560 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:28 year:2024 number:8 day:24 month:01 pages:2547-2560 https://dx.doi.org/10.1007/s10008-024-05801-0 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 VZ 35.90 VZ AR 28 2024 8 24 01 2547-2560 |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract In this study, Al-Fe and Al-Fe-Mn alloy anodes are prepared and examined. The influence of impurity Fe on the microstructure and properties of Al alloy anodes is investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical testing techniques. The results reveal that the presence of impurity Fe in Al alloys significantly shifts the open-circuit potential of the Al anode towards the positive side and reduces its discharge efficiency. However, the adverse impact of impurity Fe is mitigated by alloying with Mn. Specifically, the open-circuit potential of Al-0.20%Fe-0.20%Mn anodes is observed to shift negatively by 70 mV when compared to that of Al-0.20%Fe in a 3 M KOH solution. Furthermore, the anode utilization of Al-0.20%Fe-0.20%Mn anodes, following continuous discharge at 30 mA·$ cm^{−2} $ and 100 mA·$ cm^{−2} $ for 30 min, is found to be 70% and 52% higher, respectively, than that of Al-0.20%Fe anodes. 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Wan, Huan |
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Wan, Huan ddc 540 bkl 35.14 bkl 35.90 misc Al-air battery misc Al anode misc Utilization misc Impurity Fe Investigations on Mn shielding the negative effect of Fe in the aluminum alloy anodes used for Al-air batteries |
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540 VZ 35.14 bkl 35.90 bkl Investigations on Mn shielding the negative effect of Fe in the aluminum alloy anodes used for Al-air batteries Al-air battery (dpeaa)DE-He213 Al anode (dpeaa)DE-He213 Utilization (dpeaa)DE-He213 Impurity Fe (dpeaa)DE-He213 |
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investigations on mn shielding the negative effect of fe in the aluminum alloy anodes used for al-air batteries |
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Investigations on Mn shielding the negative effect of Fe in the aluminum alloy anodes used for Al-air batteries |
| abstract |
Abstract In this study, Al-Fe and Al-Fe-Mn alloy anodes are prepared and examined. The influence of impurity Fe on the microstructure and properties of Al alloy anodes is investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical testing techniques. The results reveal that the presence of impurity Fe in Al alloys significantly shifts the open-circuit potential of the Al anode towards the positive side and reduces its discharge efficiency. However, the adverse impact of impurity Fe is mitigated by alloying with Mn. Specifically, the open-circuit potential of Al-0.20%Fe-0.20%Mn anodes is observed to shift negatively by 70 mV when compared to that of Al-0.20%Fe in a 3 M KOH solution. Furthermore, the anode utilization of Al-0.20%Fe-0.20%Mn anodes, following continuous discharge at 30 mA·$ cm^{−2} $ and 100 mA·$ cm^{−2} $ for 30 min, is found to be 70% and 52% higher, respectively, than that of Al-0.20%Fe anodes. This highlights the effectiveness of Mn modification as a preferable approach to ameliorate the detrimental effects of impurity Fe. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Abstract In this study, Al-Fe and Al-Fe-Mn alloy anodes are prepared and examined. The influence of impurity Fe on the microstructure and properties of Al alloy anodes is investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical testing techniques. The results reveal that the presence of impurity Fe in Al alloys significantly shifts the open-circuit potential of the Al anode towards the positive side and reduces its discharge efficiency. However, the adverse impact of impurity Fe is mitigated by alloying with Mn. Specifically, the open-circuit potential of Al-0.20%Fe-0.20%Mn anodes is observed to shift negatively by 70 mV when compared to that of Al-0.20%Fe in a 3 M KOH solution. Furthermore, the anode utilization of Al-0.20%Fe-0.20%Mn anodes, following continuous discharge at 30 mA·$ cm^{−2} $ and 100 mA·$ cm^{−2} $ for 30 min, is found to be 70% and 52% higher, respectively, than that of Al-0.20%Fe anodes. This highlights the effectiveness of Mn modification as a preferable approach to ameliorate the detrimental effects of impurity Fe. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Abstract In this study, Al-Fe and Al-Fe-Mn alloy anodes are prepared and examined. The influence of impurity Fe on the microstructure and properties of Al alloy anodes is investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical testing techniques. The results reveal that the presence of impurity Fe in Al alloys significantly shifts the open-circuit potential of the Al anode towards the positive side and reduces its discharge efficiency. However, the adverse impact of impurity Fe is mitigated by alloying with Mn. Specifically, the open-circuit potential of Al-0.20%Fe-0.20%Mn anodes is observed to shift negatively by 70 mV when compared to that of Al-0.20%Fe in a 3 M KOH solution. Furthermore, the anode utilization of Al-0.20%Fe-0.20%Mn anodes, following continuous discharge at 30 mA·$ cm^{−2} $ and 100 mA·$ cm^{−2} $ for 30 min, is found to be 70% and 52% higher, respectively, than that of Al-0.20%Fe anodes. This highlights the effectiveness of Mn modification as a preferable approach to ameliorate the detrimental effects of impurity Fe. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| title_short |
Investigations on Mn shielding the negative effect of Fe in the aluminum alloy anodes used for Al-air batteries |
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https://dx.doi.org/10.1007/s10008-024-05801-0 |
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Wang, Wei Bu, Lu-xia |
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10.1007/s10008-024-05801-0 |
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| score |
7.4028378 |