Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions
In this research, a novel core-shell nanocatalyst with silica bi-shell around $ Fe_{3} $$ O_{4} $ and nickel active center, i.e. $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to s...
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| Autor*in: |
Saleh, Ebraheem Abdu Musad [verfasserIn] Kassem, Asmaa F. [verfasserIn] Altalbawy, Farag M. A. [verfasserIn] Shoja, Sarah Jawad [verfasserIn] Bokov, Dmitry Olegovich [verfasserIn] Elawady, Ahmed [verfasserIn] Al-Rubaye, Ameer H. [verfasserIn] Saud, Abdulnaser [verfasserIn] Al-Mashhadani, Zuhair I. [verfasserIn] Nejad, Maryam Sadat Ghorayshi [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2024 |
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© The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Silicon - Springer Netherlands, 2009, 16(2024), 9 vom: 02. Apr., Seite 3795-3809 |
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| Übergeordnetes Werk: |
volume:16 ; year:2024 ; number:9 ; day:02 ; month:04 ; pages:3795-3809 |
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| DOI / URN: |
10.1007/s12633-024-02959-0 |
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| Katalog-ID: |
SPR056654227 |
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| 245 | 1 | 0 | |a Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions |
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| 520 | |a In this research, a novel core-shell nanocatalyst with silica bi-shell around $ Fe_{3} $$ O_{4} $ and nickel active center, i.e. $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to synthesize biaryls (18 examples, 15–30 min, 92–98%) and diaryl sulfides (10 examples, 20–140 min, 79–98%) at 80 °C. Excellent performance in speeding up the reaction time, magnetic nature, high porosity, and immobilization of two layers around $ Fe_{3} $$ O_{4} $ are four prominent characteristics of this catalyst. Coating the magnetic core with silica layers led to saving the consumption of the catalyst because this trick leads to the bonding of more organic groups to the substrate, as a result, more nickel enters the mesoporous cavities, and the reaction with a smaller amount of catalyst is finished (in a shorter time). Other advantages of both our production lines are: the ability to recover and reuse the catalyst for up to 8 runs (without a noticeable decrease in its catalytic performance), extensive substrate scope, the employ of commercially accessible materials, simple workup, environmental safety and the heterogeneous nature of the catalyst (by confirming the reusability and hot filtration test results). Graphical Abstract | ||
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| 650 | 4 | |a Core-shell catalyst |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Magnetite nanoparticles |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Biaryls |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Di-aryl sulfides |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Kassem, Asmaa F. |e verfasserin |4 aut | |
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| 700 | 1 | |a Al-Rubaye, Ameer H. |e verfasserin |4 aut | |
| 700 | 1 | |a Saud, Abdulnaser |e verfasserin |4 aut | |
| 700 | 1 | |a Al-Mashhadani, Zuhair I. |e verfasserin |4 aut | |
| 700 | 1 | |a Nejad, Maryam Sadat Ghorayshi |e verfasserin |4 aut | |
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10.1007/s12633-024-02959-0 doi (DE-627)SPR056654227 (SPR)s12633-024-02959-0-e DE-627 ger DE-627 rakwb eng 540 VZ Saleh, Ebraheem Abdu Musad verfasserin (orcid)0000-0003-4683-6770 aut Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this research, a novel core-shell nanocatalyst with silica bi-shell around $ Fe_{3} $$ O_{4} $ and nickel active center, i.e. $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to synthesize biaryls (18 examples, 15–30 min, 92–98%) and diaryl sulfides (10 examples, 20–140 min, 79–98%) at 80 °C. Excellent performance in speeding up the reaction time, magnetic nature, high porosity, and immobilization of two layers around $ Fe_{3} $$ O_{4} $ are four prominent characteristics of this catalyst. Coating the magnetic core with silica layers led to saving the consumption of the catalyst because this trick leads to the bonding of more organic groups to the substrate, as a result, more nickel enters the mesoporous cavities, and the reaction with a smaller amount of catalyst is finished (in a shorter time). Other advantages of both our production lines are: the ability to recover and reuse the catalyst for up to 8 runs (without a noticeable decrease in its catalytic performance), extensive substrate scope, the employ of commercially accessible materials, simple workup, environmental safety and the heterogeneous nature of the catalyst (by confirming the reusability and hot filtration test results). Graphical Abstract Silica (dpeaa)DE-He213 Core-shell catalyst (dpeaa)DE-He213 Magnetite nanoparticles (dpeaa)DE-He213 Biaryls (dpeaa)DE-He213 Di-aryl sulfides (dpeaa)DE-He213 Kassem, Asmaa F. verfasserin aut Altalbawy, Farag M. A. verfasserin aut Shoja, Sarah Jawad verfasserin aut Bokov, Dmitry Olegovich verfasserin aut Elawady, Ahmed verfasserin aut Al-Rubaye, Ameer H. verfasserin aut Saud, Abdulnaser verfasserin aut Al-Mashhadani, Zuhair I. verfasserin aut Nejad, Maryam Sadat Ghorayshi verfasserin aut Enthalten in Silicon Springer Netherlands, 2009 16(2024), 9 vom: 02. Apr., Seite 3795-3809 (DE-627)598789545 (DE-600)2491562-2 1876-9918 nnns volume:16 year:2024 number:9 day:02 month:04 pages:3795-3809 https://dx.doi.org/10.1007/s12633-024-02959-0 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2024 9 02 04 3795-3809 |
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10.1007/s12633-024-02959-0 doi (DE-627)SPR056654227 (SPR)s12633-024-02959-0-e DE-627 ger DE-627 rakwb eng 540 VZ Saleh, Ebraheem Abdu Musad verfasserin (orcid)0000-0003-4683-6770 aut Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this research, a novel core-shell nanocatalyst with silica bi-shell around $ Fe_{3} $$ O_{4} $ and nickel active center, i.e. $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to synthesize biaryls (18 examples, 15–30 min, 92–98%) and diaryl sulfides (10 examples, 20–140 min, 79–98%) at 80 °C. Excellent performance in speeding up the reaction time, magnetic nature, high porosity, and immobilization of two layers around $ Fe_{3} $$ O_{4} $ are four prominent characteristics of this catalyst. Coating the magnetic core with silica layers led to saving the consumption of the catalyst because this trick leads to the bonding of more organic groups to the substrate, as a result, more nickel enters the mesoporous cavities, and the reaction with a smaller amount of catalyst is finished (in a shorter time). Other advantages of both our production lines are: the ability to recover and reuse the catalyst for up to 8 runs (without a noticeable decrease in its catalytic performance), extensive substrate scope, the employ of commercially accessible materials, simple workup, environmental safety and the heterogeneous nature of the catalyst (by confirming the reusability and hot filtration test results). Graphical Abstract Silica (dpeaa)DE-He213 Core-shell catalyst (dpeaa)DE-He213 Magnetite nanoparticles (dpeaa)DE-He213 Biaryls (dpeaa)DE-He213 Di-aryl sulfides (dpeaa)DE-He213 Kassem, Asmaa F. verfasserin aut Altalbawy, Farag M. A. verfasserin aut Shoja, Sarah Jawad verfasserin aut Bokov, Dmitry Olegovich verfasserin aut Elawady, Ahmed verfasserin aut Al-Rubaye, Ameer H. verfasserin aut Saud, Abdulnaser verfasserin aut Al-Mashhadani, Zuhair I. verfasserin aut Nejad, Maryam Sadat Ghorayshi verfasserin aut Enthalten in Silicon Springer Netherlands, 2009 16(2024), 9 vom: 02. Apr., Seite 3795-3809 (DE-627)598789545 (DE-600)2491562-2 1876-9918 nnns volume:16 year:2024 number:9 day:02 month:04 pages:3795-3809 https://dx.doi.org/10.1007/s12633-024-02959-0 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2024 9 02 04 3795-3809 |
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10.1007/s12633-024-02959-0 doi (DE-627)SPR056654227 (SPR)s12633-024-02959-0-e DE-627 ger DE-627 rakwb eng 540 VZ Saleh, Ebraheem Abdu Musad verfasserin (orcid)0000-0003-4683-6770 aut Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this research, a novel core-shell nanocatalyst with silica bi-shell around $ Fe_{3} $$ O_{4} $ and nickel active center, i.e. $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to synthesize biaryls (18 examples, 15–30 min, 92–98%) and diaryl sulfides (10 examples, 20–140 min, 79–98%) at 80 °C. Excellent performance in speeding up the reaction time, magnetic nature, high porosity, and immobilization of two layers around $ Fe_{3} $$ O_{4} $ are four prominent characteristics of this catalyst. Coating the magnetic core with silica layers led to saving the consumption of the catalyst because this trick leads to the bonding of more organic groups to the substrate, as a result, more nickel enters the mesoporous cavities, and the reaction with a smaller amount of catalyst is finished (in a shorter time). Other advantages of both our production lines are: the ability to recover and reuse the catalyst for up to 8 runs (without a noticeable decrease in its catalytic performance), extensive substrate scope, the employ of commercially accessible materials, simple workup, environmental safety and the heterogeneous nature of the catalyst (by confirming the reusability and hot filtration test results). Graphical Abstract Silica (dpeaa)DE-He213 Core-shell catalyst (dpeaa)DE-He213 Magnetite nanoparticles (dpeaa)DE-He213 Biaryls (dpeaa)DE-He213 Di-aryl sulfides (dpeaa)DE-He213 Kassem, Asmaa F. verfasserin aut Altalbawy, Farag M. A. verfasserin aut Shoja, Sarah Jawad verfasserin aut Bokov, Dmitry Olegovich verfasserin aut Elawady, Ahmed verfasserin aut Al-Rubaye, Ameer H. verfasserin aut Saud, Abdulnaser verfasserin aut Al-Mashhadani, Zuhair I. verfasserin aut Nejad, Maryam Sadat Ghorayshi verfasserin aut Enthalten in Silicon Springer Netherlands, 2009 16(2024), 9 vom: 02. Apr., Seite 3795-3809 (DE-627)598789545 (DE-600)2491562-2 1876-9918 nnns volume:16 year:2024 number:9 day:02 month:04 pages:3795-3809 https://dx.doi.org/10.1007/s12633-024-02959-0 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2024 9 02 04 3795-3809 |
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10.1007/s12633-024-02959-0 doi (DE-627)SPR056654227 (SPR)s12633-024-02959-0-e DE-627 ger DE-627 rakwb eng 540 VZ Saleh, Ebraheem Abdu Musad verfasserin (orcid)0000-0003-4683-6770 aut Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this research, a novel core-shell nanocatalyst with silica bi-shell around $ Fe_{3} $$ O_{4} $ and nickel active center, i.e. $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to synthesize biaryls (18 examples, 15–30 min, 92–98%) and diaryl sulfides (10 examples, 20–140 min, 79–98%) at 80 °C. Excellent performance in speeding up the reaction time, magnetic nature, high porosity, and immobilization of two layers around $ Fe_{3} $$ O_{4} $ are four prominent characteristics of this catalyst. Coating the magnetic core with silica layers led to saving the consumption of the catalyst because this trick leads to the bonding of more organic groups to the substrate, as a result, more nickel enters the mesoporous cavities, and the reaction with a smaller amount of catalyst is finished (in a shorter time). Other advantages of both our production lines are: the ability to recover and reuse the catalyst for up to 8 runs (without a noticeable decrease in its catalytic performance), extensive substrate scope, the employ of commercially accessible materials, simple workup, environmental safety and the heterogeneous nature of the catalyst (by confirming the reusability and hot filtration test results). Graphical Abstract Silica (dpeaa)DE-He213 Core-shell catalyst (dpeaa)DE-He213 Magnetite nanoparticles (dpeaa)DE-He213 Biaryls (dpeaa)DE-He213 Di-aryl sulfides (dpeaa)DE-He213 Kassem, Asmaa F. verfasserin aut Altalbawy, Farag M. A. verfasserin aut Shoja, Sarah Jawad verfasserin aut Bokov, Dmitry Olegovich verfasserin aut Elawady, Ahmed verfasserin aut Al-Rubaye, Ameer H. verfasserin aut Saud, Abdulnaser verfasserin aut Al-Mashhadani, Zuhair I. verfasserin aut Nejad, Maryam Sadat Ghorayshi verfasserin aut Enthalten in Silicon Springer Netherlands, 2009 16(2024), 9 vom: 02. Apr., Seite 3795-3809 (DE-627)598789545 (DE-600)2491562-2 1876-9918 nnns volume:16 year:2024 number:9 day:02 month:04 pages:3795-3809 https://dx.doi.org/10.1007/s12633-024-02959-0 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2024 9 02 04 3795-3809 |
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10.1007/s12633-024-02959-0 doi (DE-627)SPR056654227 (SPR)s12633-024-02959-0-e DE-627 ger DE-627 rakwb eng 540 VZ Saleh, Ebraheem Abdu Musad verfasserin (orcid)0000-0003-4683-6770 aut Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. In this research, a novel core-shell nanocatalyst with silica bi-shell around $ Fe_{3} $$ O_{4} $ and nickel active center, i.e. $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to synthesize biaryls (18 examples, 15–30 min, 92–98%) and diaryl sulfides (10 examples, 20–140 min, 79–98%) at 80 °C. Excellent performance in speeding up the reaction time, magnetic nature, high porosity, and immobilization of two layers around $ Fe_{3} $$ O_{4} $ are four prominent characteristics of this catalyst. Coating the magnetic core with silica layers led to saving the consumption of the catalyst because this trick leads to the bonding of more organic groups to the substrate, as a result, more nickel enters the mesoporous cavities, and the reaction with a smaller amount of catalyst is finished (in a shorter time). Other advantages of both our production lines are: the ability to recover and reuse the catalyst for up to 8 runs (without a noticeable decrease in its catalytic performance), extensive substrate scope, the employ of commercially accessible materials, simple workup, environmental safety and the heterogeneous nature of the catalyst (by confirming the reusability and hot filtration test results). Graphical Abstract Silica (dpeaa)DE-He213 Core-shell catalyst (dpeaa)DE-He213 Magnetite nanoparticles (dpeaa)DE-He213 Biaryls (dpeaa)DE-He213 Di-aryl sulfides (dpeaa)DE-He213 Kassem, Asmaa F. verfasserin aut Altalbawy, Farag M. A. verfasserin aut Shoja, Sarah Jawad verfasserin aut Bokov, Dmitry Olegovich verfasserin aut Elawady, Ahmed verfasserin aut Al-Rubaye, Ameer H. verfasserin aut Saud, Abdulnaser verfasserin aut Al-Mashhadani, Zuhair I. verfasserin aut Nejad, Maryam Sadat Ghorayshi verfasserin aut Enthalten in Silicon Springer Netherlands, 2009 16(2024), 9 vom: 02. Apr., Seite 3795-3809 (DE-627)598789545 (DE-600)2491562-2 1876-9918 nnns volume:16 year:2024 number:9 day:02 month:04 pages:3795-3809 https://dx.doi.org/10.1007/s12633-024-02959-0 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2024 9 02 04 3795-3809 |
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Saleh, Ebraheem Abdu Musad @@aut@@ Kassem, Asmaa F. @@aut@@ Altalbawy, Farag M. A. @@aut@@ Shoja, Sarah Jawad @@aut@@ Bokov, Dmitry Olegovich @@aut@@ Elawady, Ahmed @@aut@@ Al-Rubaye, Ameer H. @@aut@@ Saud, Abdulnaser @@aut@@ Al-Mashhadani, Zuhair I. @@aut@@ Nejad, Maryam Sadat Ghorayshi @@aut@@ |
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Saleh, Ebraheem Abdu Musad |
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Saleh, Ebraheem Abdu Musad ddc 540 misc Silica misc Core-shell catalyst misc Magnetite nanoparticles misc Biaryls misc Di-aryl sulfides Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions |
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540 VZ Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions Silica (dpeaa)DE-He213 Core-shell catalyst (dpeaa)DE-He213 Magnetite nanoparticles (dpeaa)DE-He213 Biaryls (dpeaa)DE-He213 Di-aryl sulfides (dpeaa)DE-He213 |
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ddc 540 misc Silica misc Core-shell catalyst misc Magnetite nanoparticles misc Biaryls misc Di-aryl sulfides |
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ddc 540 misc Silica misc Core-shell catalyst misc Magnetite nanoparticles misc Biaryls misc Di-aryl sulfides |
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Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions |
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Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions |
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Saleh, Ebraheem Abdu Musad Kassem, Asmaa F. Altalbawy, Farag M. A. Shoja, Sarah Jawad Bokov, Dmitry Olegovich Elawady, Ahmed Al-Rubaye, Ameer H. Saud, Abdulnaser Al-Mashhadani, Zuhair I. Nejad, Maryam Sadat Ghorayshi |
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effective role of two layers of silica in the performance of $ fe_{3} $$ o_{4} $$ xsio_{2} $@$ ysio_{2} $@bispyp-ni core-shell catalyst for c-c and c-s coupling reactions |
| title_auth |
Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions |
| abstract |
In this research, a novel core-shell nanocatalyst with silica bi-shell around $ Fe_{3} $$ O_{4} $ and nickel active center, i.e. $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to synthesize biaryls (18 examples, 15–30 min, 92–98%) and diaryl sulfides (10 examples, 20–140 min, 79–98%) at 80 °C. Excellent performance in speeding up the reaction time, magnetic nature, high porosity, and immobilization of two layers around $ Fe_{3} $$ O_{4} $ are four prominent characteristics of this catalyst. Coating the magnetic core with silica layers led to saving the consumption of the catalyst because this trick leads to the bonding of more organic groups to the substrate, as a result, more nickel enters the mesoporous cavities, and the reaction with a smaller amount of catalyst is finished (in a shorter time). Other advantages of both our production lines are: the ability to recover and reuse the catalyst for up to 8 runs (without a noticeable decrease in its catalytic performance), extensive substrate scope, the employ of commercially accessible materials, simple workup, environmental safety and the heterogeneous nature of the catalyst (by confirming the reusability and hot filtration test results). Graphical Abstract © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
In this research, a novel core-shell nanocatalyst with silica bi-shell around $ Fe_{3} $$ O_{4} $ and nickel active center, i.e. $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to synthesize biaryls (18 examples, 15–30 min, 92–98%) and diaryl sulfides (10 examples, 20–140 min, 79–98%) at 80 °C. Excellent performance in speeding up the reaction time, magnetic nature, high porosity, and immobilization of two layers around $ Fe_{3} $$ O_{4} $ are four prominent characteristics of this catalyst. Coating the magnetic core with silica layers led to saving the consumption of the catalyst because this trick leads to the bonding of more organic groups to the substrate, as a result, more nickel enters the mesoporous cavities, and the reaction with a smaller amount of catalyst is finished (in a shorter time). Other advantages of both our production lines are: the ability to recover and reuse the catalyst for up to 8 runs (without a noticeable decrease in its catalytic performance), extensive substrate scope, the employ of commercially accessible materials, simple workup, environmental safety and the heterogeneous nature of the catalyst (by confirming the reusability and hot filtration test results). Graphical Abstract © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
In this research, a novel core-shell nanocatalyst with silica bi-shell around $ Fe_{3} $$ O_{4} $ and nickel active center, i.e. $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to synthesize biaryls (18 examples, 15–30 min, 92–98%) and diaryl sulfides (10 examples, 20–140 min, 79–98%) at 80 °C. Excellent performance in speeding up the reaction time, magnetic nature, high porosity, and immobilization of two layers around $ Fe_{3} $$ O_{4} $ are four prominent characteristics of this catalyst. Coating the magnetic core with silica layers led to saving the consumption of the catalyst because this trick leads to the bonding of more organic groups to the substrate, as a result, more nickel enters the mesoporous cavities, and the reaction with a smaller amount of catalyst is finished (in a shorter time). Other advantages of both our production lines are: the ability to recover and reuse the catalyst for up to 8 runs (without a noticeable decrease in its catalytic performance), extensive substrate scope, the employ of commercially accessible materials, simple workup, environmental safety and the heterogeneous nature of the catalyst (by confirming the reusability and hot filtration test results). Graphical Abstract © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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Effective Role of Two Layers of Silica in the Performance of $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions |
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Kassem, Asmaa F. Altalbawy, Farag M. A. Shoja, Sarah Jawad Bokov, Dmitry Olegovich Elawady, Ahmed Al-Rubaye, Ameer H. Saud, Abdulnaser Al-Mashhadani, Zuhair I. Nejad, Maryam Sadat Ghorayshi |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">In this research, a novel core-shell nanocatalyst with silica bi-shell around $ Fe_{3} $$ O_{4} $ and nickel active center, i.e. $ Fe_{3} $$ O_{4} $$ xSiO_{2} $@$ ySiO_{2} $@BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to synthesize biaryls (18 examples, 15–30 min, 92–98%) and diaryl sulfides (10 examples, 20–140 min, 79–98%) at 80 °C. 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