Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein
Spodumene ($ LiAlSi_{2} $$ O_{6} $) has gained attention due to its versatile applications, which include ionizing radiation dosimetry, observed in either monoclinic (α-spodumene) or tetragonal (β-spodumene) symmetries. β-spodumene has been produced by solid-state reactions and conventional sol–gel...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Ferraz, Ricardo Ferrari [verfasserIn] da Conceição Costa Pereira, Maria [verfasserIn] Oliveira, Raquel Aline Pessoa [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2024 |
|---|
| Schlagwörter: |
|---|
| Anmerkung: |
© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
|---|
| Übergeordnetes Werk: |
Enthalten in: Journal of sol gel science and technology - Springer US, 1993, 111(2024), 3 vom: 13. Juli, Seite 718-724 |
|---|---|
| Übergeordnetes Werk: |
volume:111 ; year:2024 ; number:3 ; day:13 ; month:07 ; pages:718-724 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10971-024-06484-9 |
|---|
| Katalog-ID: |
SPR057040966 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | SPR057040966 | ||
| 003 | DE-627 | ||
| 005 | 20240822064715.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 240822s2024 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1007/s10971-024-06484-9 |2 doi | |
| 035 | |a (DE-627)SPR057040966 | ||
| 035 | |a (SPR)s10971-024-06484-9-e | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 600 |a 670 |q VZ |
| 084 | |a 35.18 |2 bkl | ||
| 084 | |a 51.60 |2 bkl | ||
| 100 | 1 | |a Ferraz, Ricardo Ferrari |e verfasserin |0 (orcid)0000-0002-1913-8427 |4 aut | |
| 245 | 1 | 0 | |a Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein |
| 264 | 1 | |c 2024 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. | ||
| 520 | |a Spodumene ($ LiAlSi_{2} $$ O_{6} $) has gained attention due to its versatile applications, which include ionizing radiation dosimetry, observed in either monoclinic (α-spodumene) or tetragonal (β-spodumene) symmetries. β-spodumene has been produced by solid-state reactions and conventional sol–gel methods, which are challenging due to the need for high temperatures and costly reagents, respectively. Alternative routes like the Pechini method and proteic sol–gel methods are promising because they can reduce production costs and environmental pollution. This paper aims to synthesize and characterize β-spodumene using a new sol–gel route assisted by whey protein. In this method, proteins act as chelating agents, aiding in the formation of stable colloidal solutions (sol) containing inorganic precursors. These solutions undergo gelation processes to form a solid connected porous structure (gel), which can then be thermally treated to promote crystallization and obtain the desired material. The process involved subjecting the material to thermal treatments exceeding 800 °C, leading to the crystallization of β-spodumene structure at 1000 °C. Additionally, a thermal treatment at 1100 °C facilitated the elimination of residual sulfur (S) resulting from protein combustion. For sample characterizations, thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) measurements were performed. Preliminary results indicate that β-spodumene was successfully synthesized using the new sol–gel route assisted by whey protein. The potential of whey protein as an eco-friendly chelating agent is highlighted, suggesting possible environmental benefits and paving the way for future advancements in this research area. Graphical Abstract | ||
| 520 | |a Highlights β-spodumene was effectively synthesized by a new sol–gel route assisted by whey protein.Crystalline structure of β-spodumene formed at 1000 °C.Eco-friendly approach using whey protein as a chelating agent in the sol–gel method. | ||
| 650 | 4 | |a Eco-friendly |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Sol–gel |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Spodumene |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Whey protein |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a da Conceição Costa Pereira, Maria |e verfasserin |0 (orcid)0000-0001-5529-2520 |4 aut | |
| 700 | 1 | |a Oliveira, Raquel Aline Pessoa |e verfasserin |0 (orcid)0000-0002-8455-1226 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Journal of sol gel science and technology |d Springer US, 1993 |g 111(2024), 3 vom: 13. Juli, Seite 718-724 |w (DE-627)268757607 |w (DE-600)1472726-2 |x 1573-4846 |7 nnns |
| 773 | 1 | 8 | |g volume:111 |g year:2024 |g number:3 |g day:13 |g month:07 |g pages:718-724 |
| 856 | 4 | 0 | |u https://dx.doi.org/10.1007/s10971-024-06484-9 |m X:SPRINGER |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 912 | |a SYSFLAG_0 | ||
| 912 | |a GBV_SPRINGER | ||
| 912 | |a GBV_ILN_11 | ||
| 912 | |a GBV_ILN_20 | ||
| 912 | |a GBV_ILN_22 | ||
| 912 | |a GBV_ILN_23 | ||
| 912 | |a GBV_ILN_24 | ||
| 912 | |a GBV_ILN_31 | ||
| 912 | |a GBV_ILN_32 | ||
| 912 | |a GBV_ILN_39 | ||
| 912 | |a GBV_ILN_40 | ||
| 912 | |a GBV_ILN_60 | ||
| 912 | |a GBV_ILN_62 | ||
| 912 | |a GBV_ILN_63 | ||
| 912 | |a GBV_ILN_69 | ||
| 912 | |a GBV_ILN_70 | ||
| 912 | |a GBV_ILN_73 | ||
| 912 | |a GBV_ILN_74 | ||
| 912 | |a GBV_ILN_90 | ||
| 912 | |a GBV_ILN_95 | ||
| 912 | |a GBV_ILN_100 | ||
| 912 | |a GBV_ILN_105 | ||
| 912 | |a GBV_ILN_110 | ||
| 912 | |a GBV_ILN_120 | ||
| 912 | |a GBV_ILN_138 | ||
| 912 | |a GBV_ILN_150 | ||
| 912 | |a GBV_ILN_151 | ||
| 912 | |a GBV_ILN_152 | ||
| 912 | |a GBV_ILN_161 | ||
| 912 | |a GBV_ILN_170 | ||
| 912 | |a GBV_ILN_171 | ||
| 912 | |a GBV_ILN_187 | ||
| 912 | |a GBV_ILN_213 | ||
| 912 | |a GBV_ILN_224 | ||
| 912 | |a GBV_ILN_230 | ||
| 912 | |a GBV_ILN_250 | ||
| 912 | |a GBV_ILN_281 | ||
| 912 | |a GBV_ILN_285 | ||
| 912 | |a GBV_ILN_293 | ||
| 912 | |a GBV_ILN_370 | ||
| 912 | |a GBV_ILN_602 | ||
| 912 | |a GBV_ILN_636 | ||
| 912 | |a GBV_ILN_702 | ||
| 912 | |a GBV_ILN_2001 | ||
| 912 | |a GBV_ILN_2003 | ||
| 912 | |a GBV_ILN_2004 | ||
| 912 | |a GBV_ILN_2005 | ||
| 912 | |a GBV_ILN_2006 | ||
| 912 | |a GBV_ILN_2007 | ||
| 912 | |a GBV_ILN_2009 | ||
| 912 | |a GBV_ILN_2010 | ||
| 912 | |a GBV_ILN_2011 | ||
| 912 | |a GBV_ILN_2014 | ||
| 912 | |a GBV_ILN_2015 | ||
| 912 | |a GBV_ILN_2020 | ||
| 912 | |a GBV_ILN_2021 | ||
| 912 | |a GBV_ILN_2025 | ||
| 912 | |a GBV_ILN_2026 | ||
| 912 | |a GBV_ILN_2027 | ||
| 912 | |a GBV_ILN_2031 | ||
| 912 | |a GBV_ILN_2034 | ||
| 912 | |a GBV_ILN_2037 | ||
| 912 | |a GBV_ILN_2038 | ||
| 912 | |a GBV_ILN_2039 | ||
| 912 | |a GBV_ILN_2044 | ||
| 912 | |a GBV_ILN_2048 | ||
| 912 | |a GBV_ILN_2049 | ||
| 912 | |a GBV_ILN_2050 | ||
| 912 | |a GBV_ILN_2055 | ||
| 912 | |a GBV_ILN_2056 | ||
| 912 | |a GBV_ILN_2057 | ||
| 912 | |a GBV_ILN_2059 | ||
| 912 | |a GBV_ILN_2061 | ||
| 912 | |a GBV_ILN_2064 | ||
| 912 | |a GBV_ILN_2065 | ||
| 912 | |a GBV_ILN_2068 | ||
| 912 | |a GBV_ILN_2088 | ||
| 912 | |a GBV_ILN_2093 | ||
| 912 | |a GBV_ILN_2106 | ||
| 912 | |a GBV_ILN_2107 | ||
| 912 | |a GBV_ILN_2108 | ||
| 912 | |a GBV_ILN_2110 | ||
| 912 | |a GBV_ILN_2111 | ||
| 912 | |a GBV_ILN_2112 | ||
| 912 | |a GBV_ILN_2113 | ||
| 912 | |a GBV_ILN_2118 | ||
| 912 | |a GBV_ILN_2122 | ||
| 912 | |a GBV_ILN_2129 | ||
| 912 | |a GBV_ILN_2143 | ||
| 912 | |a GBV_ILN_2144 | ||
| 912 | |a GBV_ILN_2147 | ||
| 912 | |a GBV_ILN_2148 | ||
| 912 | |a GBV_ILN_2152 | ||
| 912 | |a GBV_ILN_2153 | ||
| 912 | |a GBV_ILN_2188 | ||
| 912 | |a GBV_ILN_2190 | ||
| 912 | |a GBV_ILN_2232 | ||
| 912 | |a GBV_ILN_2336 | ||
| 912 | |a GBV_ILN_2446 | ||
| 912 | |a GBV_ILN_2470 | ||
| 912 | |a GBV_ILN_2472 | ||
| 912 | |a GBV_ILN_2507 | ||
| 912 | |a GBV_ILN_2522 | ||
| 912 | |a GBV_ILN_2548 | ||
| 912 | |a GBV_ILN_4035 | ||
| 912 | |a GBV_ILN_4037 | ||
| 912 | |a GBV_ILN_4046 | ||
| 912 | |a GBV_ILN_4112 | ||
| 912 | |a GBV_ILN_4125 | ||
| 912 | |a GBV_ILN_4126 | ||
| 912 | |a GBV_ILN_4242 | ||
| 912 | |a GBV_ILN_4246 | ||
| 912 | |a GBV_ILN_4249 | ||
| 912 | |a GBV_ILN_4251 | ||
| 912 | |a GBV_ILN_4305 | ||
| 912 | |a GBV_ILN_4306 | ||
| 912 | |a GBV_ILN_4307 | ||
| 912 | |a GBV_ILN_4313 | ||
| 912 | |a GBV_ILN_4322 | ||
| 912 | |a GBV_ILN_4323 | ||
| 912 | |a GBV_ILN_4324 | ||
| 912 | |a GBV_ILN_4325 | ||
| 912 | |a GBV_ILN_4326 | ||
| 912 | |a GBV_ILN_4328 | ||
| 912 | |a GBV_ILN_4333 | ||
| 912 | |a GBV_ILN_4334 | ||
| 912 | |a GBV_ILN_4335 | ||
| 912 | |a GBV_ILN_4336 | ||
| 912 | |a GBV_ILN_4338 | ||
| 912 | |a GBV_ILN_4393 | ||
| 912 | |a GBV_ILN_4700 | ||
| 936 | b | k | |a 35.18 |q VZ |
| 936 | b | k | |a 51.60 |q VZ |
| 951 | |a AR | ||
| 952 | |d 111 |j 2024 |e 3 |b 13 |c 07 |h 718-724 | ||
| author_variant |
r f f rf rff c c p m d ccpm ccpmd r a p o rap rapo |
|---|---|
| matchkey_str |
article:15734846:2024----::yteiadhrceiainfpdmnbaeslerue |
| hierarchy_sort_str |
2024 |
| bklnumber |
35.18 51.60 |
| publishDate |
2024 |
| allfields |
10.1007/s10971-024-06484-9 doi (DE-627)SPR057040966 (SPR)s10971-024-06484-9-e DE-627 ger DE-627 rakwb eng 600 670 VZ 35.18 bkl 51.60 bkl Ferraz, Ricardo Ferrari verfasserin (orcid)0000-0002-1913-8427 aut Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Spodumene ($ LiAlSi_{2} $$ O_{6} $) has gained attention due to its versatile applications, which include ionizing radiation dosimetry, observed in either monoclinic (α-spodumene) or tetragonal (β-spodumene) symmetries. β-spodumene has been produced by solid-state reactions and conventional sol–gel methods, which are challenging due to the need for high temperatures and costly reagents, respectively. Alternative routes like the Pechini method and proteic sol–gel methods are promising because they can reduce production costs and environmental pollution. This paper aims to synthesize and characterize β-spodumene using a new sol–gel route assisted by whey protein. In this method, proteins act as chelating agents, aiding in the formation of stable colloidal solutions (sol) containing inorganic precursors. These solutions undergo gelation processes to form a solid connected porous structure (gel), which can then be thermally treated to promote crystallization and obtain the desired material. The process involved subjecting the material to thermal treatments exceeding 800 °C, leading to the crystallization of β-spodumene structure at 1000 °C. Additionally, a thermal treatment at 1100 °C facilitated the elimination of residual sulfur (S) resulting from protein combustion. For sample characterizations, thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) measurements were performed. Preliminary results indicate that β-spodumene was successfully synthesized using the new sol–gel route assisted by whey protein. The potential of whey protein as an eco-friendly chelating agent is highlighted, suggesting possible environmental benefits and paving the way for future advancements in this research area. Graphical Abstract Highlights β-spodumene was effectively synthesized by a new sol–gel route assisted by whey protein.Crystalline structure of β-spodumene formed at 1000 °C.Eco-friendly approach using whey protein as a chelating agent in the sol–gel method. Eco-friendly (dpeaa)DE-He213 Sol–gel (dpeaa)DE-He213 Spodumene (dpeaa)DE-He213 Whey protein (dpeaa)DE-He213 da Conceição Costa Pereira, Maria verfasserin (orcid)0000-0001-5529-2520 aut Oliveira, Raquel Aline Pessoa verfasserin (orcid)0000-0002-8455-1226 aut Enthalten in Journal of sol gel science and technology Springer US, 1993 111(2024), 3 vom: 13. Juli, Seite 718-724 (DE-627)268757607 (DE-600)1472726-2 1573-4846 nnns volume:111 year:2024 number:3 day:13 month:07 pages:718-724 https://dx.doi.org/10.1007/s10971-024-06484-9 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 VZ 51.60 VZ AR 111 2024 3 13 07 718-724 |
| spelling |
10.1007/s10971-024-06484-9 doi (DE-627)SPR057040966 (SPR)s10971-024-06484-9-e DE-627 ger DE-627 rakwb eng 600 670 VZ 35.18 bkl 51.60 bkl Ferraz, Ricardo Ferrari verfasserin (orcid)0000-0002-1913-8427 aut Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Spodumene ($ LiAlSi_{2} $$ O_{6} $) has gained attention due to its versatile applications, which include ionizing radiation dosimetry, observed in either monoclinic (α-spodumene) or tetragonal (β-spodumene) symmetries. β-spodumene has been produced by solid-state reactions and conventional sol–gel methods, which are challenging due to the need for high temperatures and costly reagents, respectively. Alternative routes like the Pechini method and proteic sol–gel methods are promising because they can reduce production costs and environmental pollution. This paper aims to synthesize and characterize β-spodumene using a new sol–gel route assisted by whey protein. In this method, proteins act as chelating agents, aiding in the formation of stable colloidal solutions (sol) containing inorganic precursors. These solutions undergo gelation processes to form a solid connected porous structure (gel), which can then be thermally treated to promote crystallization and obtain the desired material. The process involved subjecting the material to thermal treatments exceeding 800 °C, leading to the crystallization of β-spodumene structure at 1000 °C. Additionally, a thermal treatment at 1100 °C facilitated the elimination of residual sulfur (S) resulting from protein combustion. For sample characterizations, thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) measurements were performed. Preliminary results indicate that β-spodumene was successfully synthesized using the new sol–gel route assisted by whey protein. The potential of whey protein as an eco-friendly chelating agent is highlighted, suggesting possible environmental benefits and paving the way for future advancements in this research area. Graphical Abstract Highlights β-spodumene was effectively synthesized by a new sol–gel route assisted by whey protein.Crystalline structure of β-spodumene formed at 1000 °C.Eco-friendly approach using whey protein as a chelating agent in the sol–gel method. Eco-friendly (dpeaa)DE-He213 Sol–gel (dpeaa)DE-He213 Spodumene (dpeaa)DE-He213 Whey protein (dpeaa)DE-He213 da Conceição Costa Pereira, Maria verfasserin (orcid)0000-0001-5529-2520 aut Oliveira, Raquel Aline Pessoa verfasserin (orcid)0000-0002-8455-1226 aut Enthalten in Journal of sol gel science and technology Springer US, 1993 111(2024), 3 vom: 13. Juli, Seite 718-724 (DE-627)268757607 (DE-600)1472726-2 1573-4846 nnns volume:111 year:2024 number:3 day:13 month:07 pages:718-724 https://dx.doi.org/10.1007/s10971-024-06484-9 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 VZ 51.60 VZ AR 111 2024 3 13 07 718-724 |
| allfields_unstemmed |
10.1007/s10971-024-06484-9 doi (DE-627)SPR057040966 (SPR)s10971-024-06484-9-e DE-627 ger DE-627 rakwb eng 600 670 VZ 35.18 bkl 51.60 bkl Ferraz, Ricardo Ferrari verfasserin (orcid)0000-0002-1913-8427 aut Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Spodumene ($ LiAlSi_{2} $$ O_{6} $) has gained attention due to its versatile applications, which include ionizing radiation dosimetry, observed in either monoclinic (α-spodumene) or tetragonal (β-spodumene) symmetries. β-spodumene has been produced by solid-state reactions and conventional sol–gel methods, which are challenging due to the need for high temperatures and costly reagents, respectively. Alternative routes like the Pechini method and proteic sol–gel methods are promising because they can reduce production costs and environmental pollution. This paper aims to synthesize and characterize β-spodumene using a new sol–gel route assisted by whey protein. In this method, proteins act as chelating agents, aiding in the formation of stable colloidal solutions (sol) containing inorganic precursors. These solutions undergo gelation processes to form a solid connected porous structure (gel), which can then be thermally treated to promote crystallization and obtain the desired material. The process involved subjecting the material to thermal treatments exceeding 800 °C, leading to the crystallization of β-spodumene structure at 1000 °C. Additionally, a thermal treatment at 1100 °C facilitated the elimination of residual sulfur (S) resulting from protein combustion. For sample characterizations, thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) measurements were performed. Preliminary results indicate that β-spodumene was successfully synthesized using the new sol–gel route assisted by whey protein. The potential of whey protein as an eco-friendly chelating agent is highlighted, suggesting possible environmental benefits and paving the way for future advancements in this research area. Graphical Abstract Highlights β-spodumene was effectively synthesized by a new sol–gel route assisted by whey protein.Crystalline structure of β-spodumene formed at 1000 °C.Eco-friendly approach using whey protein as a chelating agent in the sol–gel method. Eco-friendly (dpeaa)DE-He213 Sol–gel (dpeaa)DE-He213 Spodumene (dpeaa)DE-He213 Whey protein (dpeaa)DE-He213 da Conceição Costa Pereira, Maria verfasserin (orcid)0000-0001-5529-2520 aut Oliveira, Raquel Aline Pessoa verfasserin (orcid)0000-0002-8455-1226 aut Enthalten in Journal of sol gel science and technology Springer US, 1993 111(2024), 3 vom: 13. Juli, Seite 718-724 (DE-627)268757607 (DE-600)1472726-2 1573-4846 nnns volume:111 year:2024 number:3 day:13 month:07 pages:718-724 https://dx.doi.org/10.1007/s10971-024-06484-9 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 VZ 51.60 VZ AR 111 2024 3 13 07 718-724 |
| allfieldsGer |
10.1007/s10971-024-06484-9 doi (DE-627)SPR057040966 (SPR)s10971-024-06484-9-e DE-627 ger DE-627 rakwb eng 600 670 VZ 35.18 bkl 51.60 bkl Ferraz, Ricardo Ferrari verfasserin (orcid)0000-0002-1913-8427 aut Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Spodumene ($ LiAlSi_{2} $$ O_{6} $) has gained attention due to its versatile applications, which include ionizing radiation dosimetry, observed in either monoclinic (α-spodumene) or tetragonal (β-spodumene) symmetries. β-spodumene has been produced by solid-state reactions and conventional sol–gel methods, which are challenging due to the need for high temperatures and costly reagents, respectively. Alternative routes like the Pechini method and proteic sol–gel methods are promising because they can reduce production costs and environmental pollution. This paper aims to synthesize and characterize β-spodumene using a new sol–gel route assisted by whey protein. In this method, proteins act as chelating agents, aiding in the formation of stable colloidal solutions (sol) containing inorganic precursors. These solutions undergo gelation processes to form a solid connected porous structure (gel), which can then be thermally treated to promote crystallization and obtain the desired material. The process involved subjecting the material to thermal treatments exceeding 800 °C, leading to the crystallization of β-spodumene structure at 1000 °C. Additionally, a thermal treatment at 1100 °C facilitated the elimination of residual sulfur (S) resulting from protein combustion. For sample characterizations, thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) measurements were performed. Preliminary results indicate that β-spodumene was successfully synthesized using the new sol–gel route assisted by whey protein. The potential of whey protein as an eco-friendly chelating agent is highlighted, suggesting possible environmental benefits and paving the way for future advancements in this research area. Graphical Abstract Highlights β-spodumene was effectively synthesized by a new sol–gel route assisted by whey protein.Crystalline structure of β-spodumene formed at 1000 °C.Eco-friendly approach using whey protein as a chelating agent in the sol–gel method. Eco-friendly (dpeaa)DE-He213 Sol–gel (dpeaa)DE-He213 Spodumene (dpeaa)DE-He213 Whey protein (dpeaa)DE-He213 da Conceição Costa Pereira, Maria verfasserin (orcid)0000-0001-5529-2520 aut Oliveira, Raquel Aline Pessoa verfasserin (orcid)0000-0002-8455-1226 aut Enthalten in Journal of sol gel science and technology Springer US, 1993 111(2024), 3 vom: 13. Juli, Seite 718-724 (DE-627)268757607 (DE-600)1472726-2 1573-4846 nnns volume:111 year:2024 number:3 day:13 month:07 pages:718-724 https://dx.doi.org/10.1007/s10971-024-06484-9 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 VZ 51.60 VZ AR 111 2024 3 13 07 718-724 |
| allfieldsSound |
10.1007/s10971-024-06484-9 doi (DE-627)SPR057040966 (SPR)s10971-024-06484-9-e DE-627 ger DE-627 rakwb eng 600 670 VZ 35.18 bkl 51.60 bkl Ferraz, Ricardo Ferrari verfasserin (orcid)0000-0002-1913-8427 aut Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Spodumene ($ LiAlSi_{2} $$ O_{6} $) has gained attention due to its versatile applications, which include ionizing radiation dosimetry, observed in either monoclinic (α-spodumene) or tetragonal (β-spodumene) symmetries. β-spodumene has been produced by solid-state reactions and conventional sol–gel methods, which are challenging due to the need for high temperatures and costly reagents, respectively. Alternative routes like the Pechini method and proteic sol–gel methods are promising because they can reduce production costs and environmental pollution. This paper aims to synthesize and characterize β-spodumene using a new sol–gel route assisted by whey protein. In this method, proteins act as chelating agents, aiding in the formation of stable colloidal solutions (sol) containing inorganic precursors. These solutions undergo gelation processes to form a solid connected porous structure (gel), which can then be thermally treated to promote crystallization and obtain the desired material. The process involved subjecting the material to thermal treatments exceeding 800 °C, leading to the crystallization of β-spodumene structure at 1000 °C. Additionally, a thermal treatment at 1100 °C facilitated the elimination of residual sulfur (S) resulting from protein combustion. For sample characterizations, thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) measurements were performed. Preliminary results indicate that β-spodumene was successfully synthesized using the new sol–gel route assisted by whey protein. The potential of whey protein as an eco-friendly chelating agent is highlighted, suggesting possible environmental benefits and paving the way for future advancements in this research area. Graphical Abstract Highlights β-spodumene was effectively synthesized by a new sol–gel route assisted by whey protein.Crystalline structure of β-spodumene formed at 1000 °C.Eco-friendly approach using whey protein as a chelating agent in the sol–gel method. Eco-friendly (dpeaa)DE-He213 Sol–gel (dpeaa)DE-He213 Spodumene (dpeaa)DE-He213 Whey protein (dpeaa)DE-He213 da Conceição Costa Pereira, Maria verfasserin (orcid)0000-0001-5529-2520 aut Oliveira, Raquel Aline Pessoa verfasserin (orcid)0000-0002-8455-1226 aut Enthalten in Journal of sol gel science and technology Springer US, 1993 111(2024), 3 vom: 13. Juli, Seite 718-724 (DE-627)268757607 (DE-600)1472726-2 1573-4846 nnns volume:111 year:2024 number:3 day:13 month:07 pages:718-724 https://dx.doi.org/10.1007/s10971-024-06484-9 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 VZ 51.60 VZ AR 111 2024 3 13 07 718-724 |
| language |
English |
| source |
Enthalten in Journal of sol gel science and technology 111(2024), 3 vom: 13. Juli, Seite 718-724 volume:111 year:2024 number:3 day:13 month:07 pages:718-724 |
| sourceStr |
Enthalten in Journal of sol gel science and technology 111(2024), 3 vom: 13. Juli, Seite 718-724 volume:111 year:2024 number:3 day:13 month:07 pages:718-724 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
Eco-friendly Sol–gel Spodumene Whey protein |
| dewey-raw |
600 |
| isfreeaccess_bool |
false |
| container_title |
Journal of sol gel science and technology |
| authorswithroles_txt_mv |
Ferraz, Ricardo Ferrari @@aut@@ da Conceição Costa Pereira, Maria @@aut@@ Oliveira, Raquel Aline Pessoa @@aut@@ |
| publishDateDaySort_date |
2024-07-13T00:00:00Z |
| hierarchy_top_id |
268757607 |
| dewey-sort |
3600 |
| id |
SPR057040966 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR057040966</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20240822064715.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">240822s2024 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10971-024-06484-9</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR057040966</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10971-024-06484-9-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">600</subfield><subfield code="a">670</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.18</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.60</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Ferraz, Ricardo Ferrari</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0002-1913-8427</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2024</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Spodumene ($ LiAlSi_{2} $$ O_{6} $) has gained attention due to its versatile applications, which include ionizing radiation dosimetry, observed in either monoclinic (α-spodumene) or tetragonal (β-spodumene) symmetries. β-spodumene has been produced by solid-state reactions and conventional sol–gel methods, which are challenging due to the need for high temperatures and costly reagents, respectively. Alternative routes like the Pechini method and proteic sol–gel methods are promising because they can reduce production costs and environmental pollution. This paper aims to synthesize and characterize β-spodumene using a new sol–gel route assisted by whey protein. In this method, proteins act as chelating agents, aiding in the formation of stable colloidal solutions (sol) containing inorganic precursors. These solutions undergo gelation processes to form a solid connected porous structure (gel), which can then be thermally treated to promote crystallization and obtain the desired material. The process involved subjecting the material to thermal treatments exceeding 800 °C, leading to the crystallization of β-spodumene structure at 1000 °C. Additionally, a thermal treatment at 1100 °C facilitated the elimination of residual sulfur (S) resulting from protein combustion. For sample characterizations, thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) measurements were performed. Preliminary results indicate that β-spodumene was successfully synthesized using the new sol–gel route assisted by whey protein. The potential of whey protein as an eco-friendly chelating agent is highlighted, suggesting possible environmental benefits and paving the way for future advancements in this research area. Graphical Abstract</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Highlights β-spodumene was effectively synthesized by a new sol–gel route assisted by whey protein.Crystalline structure of β-spodumene formed at 1000 °C.Eco-friendly approach using whey protein as a chelating agent in the sol–gel method.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Eco-friendly</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sol–gel</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Spodumene</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Whey protein</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">da Conceição Costa Pereira, Maria</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0001-5529-2520</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Oliveira, Raquel Aline Pessoa</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0002-8455-1226</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of sol gel science and technology</subfield><subfield code="d">Springer US, 1993</subfield><subfield code="g">111(2024), 3 vom: 13. Juli, Seite 718-724</subfield><subfield code="w">(DE-627)268757607</subfield><subfield code="w">(DE-600)1472726-2</subfield><subfield code="x">1573-4846</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:111</subfield><subfield code="g">year:2024</subfield><subfield code="g">number:3</subfield><subfield code="g">day:13</subfield><subfield code="g">month:07</subfield><subfield code="g">pages:718-724</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s10971-024-06484-9</subfield><subfield code="m">X:SPRINGER</subfield><subfield code="x">Resolving-System</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_0</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_636</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2031</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2039</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2093</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2107</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2144</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2188</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2446</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2472</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2548</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4246</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4328</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.18</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">51.60</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">111</subfield><subfield code="j">2024</subfield><subfield code="e">3</subfield><subfield code="b">13</subfield><subfield code="c">07</subfield><subfield code="h">718-724</subfield></datafield></record></collection>
|
| author |
Ferraz, Ricardo Ferrari |
| spellingShingle |
Ferraz, Ricardo Ferrari ddc 600 bkl 35.18 bkl 51.60 misc Eco-friendly misc Sol–gel misc Spodumene misc Whey protein Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein |
| authorStr |
Ferraz, Ricardo Ferrari |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)268757607 |
| format |
electronic Article |
| dewey-ones |
600 - Technology 670 - Manufacturing |
| delete_txt_mv |
keep |
| author_role |
aut aut aut |
| collection |
springer |
| remote_str |
true |
| illustrated |
Not Illustrated |
| issn |
1573-4846 |
| topic_title |
600 670 VZ 35.18 bkl 51.60 bkl Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein Eco-friendly (dpeaa)DE-He213 Sol–gel (dpeaa)DE-He213 Spodumene (dpeaa)DE-He213 Whey protein (dpeaa)DE-He213 |
| topic |
ddc 600 bkl 35.18 bkl 51.60 misc Eco-friendly misc Sol–gel misc Spodumene misc Whey protein |
| topic_unstemmed |
ddc 600 bkl 35.18 bkl 51.60 misc Eco-friendly misc Sol–gel misc Spodumene misc Whey protein |
| topic_browse |
ddc 600 bkl 35.18 bkl 51.60 misc Eco-friendly misc Sol–gel misc Spodumene misc Whey protein |
| format_facet |
Elektronische Aufsätze Aufsätze Elektronische Ressource |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
cr |
| hierarchy_parent_title |
Journal of sol gel science and technology |
| hierarchy_parent_id |
268757607 |
| dewey-tens |
600 - Technology 670 - Manufacturing |
| hierarchy_top_title |
Journal of sol gel science and technology |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)268757607 (DE-600)1472726-2 |
| title |
Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein |
| ctrlnum |
(DE-627)SPR057040966 (SPR)s10971-024-06484-9-e |
| title_full |
Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein |
| author_sort |
Ferraz, Ricardo Ferrari |
| journal |
Journal of sol gel science and technology |
| journalStr |
Journal of sol gel science and technology |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
600 - Technology |
| recordtype |
marc |
| publishDateSort |
2024 |
| contenttype_str_mv |
txt |
| container_start_page |
718 |
| author_browse |
Ferraz, Ricardo Ferrari da Conceição Costa Pereira, Maria Oliveira, Raquel Aline Pessoa |
| container_volume |
111 |
| class |
600 670 VZ 35.18 bkl 51.60 bkl |
| format_se |
Elektronische Aufsätze |
| author-letter |
Ferraz, Ricardo Ferrari |
| doi_str_mv |
10.1007/s10971-024-06484-9 |
| normlink |
(ORCID)0000-0002-1913-8427 (ORCID)0000-0001-5529-2520 (ORCID)0000-0002-8455-1226 |
| normlink_prefix_str_mv |
(orcid)0000-0002-1913-8427 (orcid)0000-0001-5529-2520 (orcid)0000-0002-8455-1226 |
| dewey-full |
600 670 |
| author2-role |
verfasserin |
| title_sort |
synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein |
| title_auth |
Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein |
| abstract |
Spodumene ($ LiAlSi_{2} $$ O_{6} $) has gained attention due to its versatile applications, which include ionizing radiation dosimetry, observed in either monoclinic (α-spodumene) or tetragonal (β-spodumene) symmetries. β-spodumene has been produced by solid-state reactions and conventional sol–gel methods, which are challenging due to the need for high temperatures and costly reagents, respectively. Alternative routes like the Pechini method and proteic sol–gel methods are promising because they can reduce production costs and environmental pollution. This paper aims to synthesize and characterize β-spodumene using a new sol–gel route assisted by whey protein. In this method, proteins act as chelating agents, aiding in the formation of stable colloidal solutions (sol) containing inorganic precursors. These solutions undergo gelation processes to form a solid connected porous structure (gel), which can then be thermally treated to promote crystallization and obtain the desired material. The process involved subjecting the material to thermal treatments exceeding 800 °C, leading to the crystallization of β-spodumene structure at 1000 °C. Additionally, a thermal treatment at 1100 °C facilitated the elimination of residual sulfur (S) resulting from protein combustion. For sample characterizations, thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) measurements were performed. Preliminary results indicate that β-spodumene was successfully synthesized using the new sol–gel route assisted by whey protein. The potential of whey protein as an eco-friendly chelating agent is highlighted, suggesting possible environmental benefits and paving the way for future advancements in this research area. Graphical Abstract Highlights β-spodumene was effectively synthesized by a new sol–gel route assisted by whey protein.Crystalline structure of β-spodumene formed at 1000 °C.Eco-friendly approach using whey protein as a chelating agent in the sol–gel method. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
Spodumene ($ LiAlSi_{2} $$ O_{6} $) has gained attention due to its versatile applications, which include ionizing radiation dosimetry, observed in either monoclinic (α-spodumene) or tetragonal (β-spodumene) symmetries. β-spodumene has been produced by solid-state reactions and conventional sol–gel methods, which are challenging due to the need for high temperatures and costly reagents, respectively. Alternative routes like the Pechini method and proteic sol–gel methods are promising because they can reduce production costs and environmental pollution. This paper aims to synthesize and characterize β-spodumene using a new sol–gel route assisted by whey protein. In this method, proteins act as chelating agents, aiding in the formation of stable colloidal solutions (sol) containing inorganic precursors. These solutions undergo gelation processes to form a solid connected porous structure (gel), which can then be thermally treated to promote crystallization and obtain the desired material. The process involved subjecting the material to thermal treatments exceeding 800 °C, leading to the crystallization of β-spodumene structure at 1000 °C. Additionally, a thermal treatment at 1100 °C facilitated the elimination of residual sulfur (S) resulting from protein combustion. For sample characterizations, thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) measurements were performed. Preliminary results indicate that β-spodumene was successfully synthesized using the new sol–gel route assisted by whey protein. The potential of whey protein as an eco-friendly chelating agent is highlighted, suggesting possible environmental benefits and paving the way for future advancements in this research area. Graphical Abstract Highlights β-spodumene was effectively synthesized by a new sol–gel route assisted by whey protein.Crystalline structure of β-spodumene formed at 1000 °C.Eco-friendly approach using whey protein as a chelating agent in the sol–gel method. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
Spodumene ($ LiAlSi_{2} $$ O_{6} $) has gained attention due to its versatile applications, which include ionizing radiation dosimetry, observed in either monoclinic (α-spodumene) or tetragonal (β-spodumene) symmetries. β-spodumene has been produced by solid-state reactions and conventional sol–gel methods, which are challenging due to the need for high temperatures and costly reagents, respectively. Alternative routes like the Pechini method and proteic sol–gel methods are promising because they can reduce production costs and environmental pollution. This paper aims to synthesize and characterize β-spodumene using a new sol–gel route assisted by whey protein. In this method, proteins act as chelating agents, aiding in the formation of stable colloidal solutions (sol) containing inorganic precursors. These solutions undergo gelation processes to form a solid connected porous structure (gel), which can then be thermally treated to promote crystallization and obtain the desired material. The process involved subjecting the material to thermal treatments exceeding 800 °C, leading to the crystallization of β-spodumene structure at 1000 °C. Additionally, a thermal treatment at 1100 °C facilitated the elimination of residual sulfur (S) resulting from protein combustion. For sample characterizations, thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) measurements were performed. Preliminary results indicate that β-spodumene was successfully synthesized using the new sol–gel route assisted by whey protein. The potential of whey protein as an eco-friendly chelating agent is highlighted, suggesting possible environmental benefits and paving the way for future advancements in this research area. Graphical Abstract Highlights β-spodumene was effectively synthesized by a new sol–gel route assisted by whey protein.Crystalline structure of β-spodumene formed at 1000 °C.Eco-friendly approach using whey protein as a chelating agent in the sol–gel method. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| collection_details |
SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 |
| container_issue |
3 |
| title_short |
Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein |
| url |
https://dx.doi.org/10.1007/s10971-024-06484-9 |
| remote_bool |
true |
| author2 |
da Conceição Costa Pereira, Maria Oliveira, Raquel Aline Pessoa |
| author2Str |
da Conceição Costa Pereira, Maria Oliveira, Raquel Aline Pessoa |
| ppnlink |
268757607 |
| mediatype_str_mv |
c |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1007/s10971-024-06484-9 |
| up_date |
2024-08-22T04:49:35.185Z |
| _version_ |
1808061877648883712 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">SPR057040966</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20240822064715.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">240822s2024 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10971-024-06484-9</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR057040966</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10971-024-06484-9-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">600</subfield><subfield code="a">670</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.18</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.60</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Ferraz, Ricardo Ferrari</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0002-1913-8427</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis and characterization of β-spodumene by a new sol–gel route assisted by whey protein</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2024</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Spodumene ($ LiAlSi_{2} $$ O_{6} $) has gained attention due to its versatile applications, which include ionizing radiation dosimetry, observed in either monoclinic (α-spodumene) or tetragonal (β-spodumene) symmetries. β-spodumene has been produced by solid-state reactions and conventional sol–gel methods, which are challenging due to the need for high temperatures and costly reagents, respectively. Alternative routes like the Pechini method and proteic sol–gel methods are promising because they can reduce production costs and environmental pollution. This paper aims to synthesize and characterize β-spodumene using a new sol–gel route assisted by whey protein. In this method, proteins act as chelating agents, aiding in the formation of stable colloidal solutions (sol) containing inorganic precursors. These solutions undergo gelation processes to form a solid connected porous structure (gel), which can then be thermally treated to promote crystallization and obtain the desired material. The process involved subjecting the material to thermal treatments exceeding 800 °C, leading to the crystallization of β-spodumene structure at 1000 °C. Additionally, a thermal treatment at 1100 °C facilitated the elimination of residual sulfur (S) resulting from protein combustion. For sample characterizations, thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) measurements were performed. Preliminary results indicate that β-spodumene was successfully synthesized using the new sol–gel route assisted by whey protein. The potential of whey protein as an eco-friendly chelating agent is highlighted, suggesting possible environmental benefits and paving the way for future advancements in this research area. Graphical Abstract</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Highlights β-spodumene was effectively synthesized by a new sol–gel route assisted by whey protein.Crystalline structure of β-spodumene formed at 1000 °C.Eco-friendly approach using whey protein as a chelating agent in the sol–gel method.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Eco-friendly</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sol–gel</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Spodumene</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Whey protein</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">da Conceição Costa Pereira, Maria</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0001-5529-2520</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Oliveira, Raquel Aline Pessoa</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0002-8455-1226</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of sol gel science and technology</subfield><subfield code="d">Springer US, 1993</subfield><subfield code="g">111(2024), 3 vom: 13. Juli, Seite 718-724</subfield><subfield code="w">(DE-627)268757607</subfield><subfield code="w">(DE-600)1472726-2</subfield><subfield code="x">1573-4846</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:111</subfield><subfield code="g">year:2024</subfield><subfield code="g">number:3</subfield><subfield code="g">day:13</subfield><subfield code="g">month:07</subfield><subfield code="g">pages:718-724</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s10971-024-06484-9</subfield><subfield code="m">X:SPRINGER</subfield><subfield code="x">Resolving-System</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_0</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_636</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2031</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2039</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2093</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2107</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2144</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2188</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2446</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2472</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2548</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4246</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4328</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.18</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">51.60</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">111</subfield><subfield code="j">2024</subfield><subfield code="e">3</subfield><subfield code="b">13</subfield><subfield code="c">07</subfield><subfield code="h">718-724</subfield></datafield></record></collection>
|
| score |
7.4017525 |