Bimetallic Single-Atom Catalysts for Water Splitting
Highlights Bimetallic single-atom catalysts (bimSACs) have garnered significant attention for leveraging the synergistic functions of the two metal active centers. This review focuses on the advancements in the field of bimSACs and their pivotal role in hydrogen generation via water splitting. State...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Deshmukh, Megha A. [verfasserIn] Bakandritsos, Aristides [verfasserIn] Zbořil, Radek [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2024 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s) 2024 |
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| Übergeordnetes Werk: |
Enthalten in: Nano-Micro letters - Springer Nature Singapore, 2009, 17(2024), 1 vom: 25. Sept. |
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| Übergeordnetes Werk: |
volume:17 ; year:2024 ; number:1 ; day:25 ; month:09 |
| Links: |
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| DOI / URN: |
10.1007/s40820-024-01505-2 |
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SPR057449368 |
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| 520 | |a Highlights Bimetallic single-atom catalysts (bimSACs) have garnered significant attention for leveraging the synergistic functions of the two metal active centers. This review focuses on the advancements in the field of bimSACs and their pivotal role in hydrogen generation via water splitting. State-of-the-art computational and physicochemical techniques for the analysis of bimSACs and their application in electrocatalytic water splitting are discussed. | ||
| 520 | |a Abstract Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society. The field of catalysis has been revolutionized by single-atom catalysts (SACs), which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports. Recently, bimetallic SACs (bimSACs) have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports. BimSACs offer an avenue for rich metal–metal and metal–support cooperativity, potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges, substrate activation with reversible redox cycles, simultaneous multi-electron transfer, regulation of spin states, tuning of electronic properties, and cyclic transition states with low activation energies. This review aims to encapsulate the growing advancements in bimSACs, with an emphasis on their pivotal role in hydrogen generation via water splitting. We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs, elucidate their electronic properties, and discuss their local coordination environment. Overall, we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction, the two half-reactions of the water electrolysis process. | ||
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10.1007/s40820-024-01505-2 doi (DE-627)SPR057449368 (SPR)s40820-024-01505-2-e DE-627 ger DE-627 rakwb eng 050 VZ Deshmukh, Megha A. verfasserin aut Bimetallic Single-Atom Catalysts for Water Splitting 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2024 Highlights Bimetallic single-atom catalysts (bimSACs) have garnered significant attention for leveraging the synergistic functions of the two metal active centers. This review focuses on the advancements in the field of bimSACs and their pivotal role in hydrogen generation via water splitting. State-of-the-art computational and physicochemical techniques for the analysis of bimSACs and their application in electrocatalytic water splitting are discussed. Abstract Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society. The field of catalysis has been revolutionized by single-atom catalysts (SACs), which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports. Recently, bimetallic SACs (bimSACs) have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports. BimSACs offer an avenue for rich metal–metal and metal–support cooperativity, potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges, substrate activation with reversible redox cycles, simultaneous multi-electron transfer, regulation of spin states, tuning of electronic properties, and cyclic transition states with low activation energies. This review aims to encapsulate the growing advancements in bimSACs, with an emphasis on their pivotal role in hydrogen generation via water splitting. We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs, elucidate their electronic properties, and discuss their local coordination environment. Overall, we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction, the two half-reactions of the water electrolysis process. Single-atom catalysts (dpeaa)DE-He213 Single-atom dimers (dpeaa)DE-He213 Hydrogen evolution (dpeaa)DE-He213 Oxygen evolution (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Bakandritsos, Aristides verfasserin aut Zbořil, Radek verfasserin aut Enthalten in Nano-Micro letters Springer Nature Singapore, 2009 17(2024), 1 vom: 25. Sept. (DE-627)680319581 (DE-600)2642093-4 2150-5551 nnns volume:17 year:2024 number:1 day:25 month:09 https://dx.doi.org/10.1007/s40820-024-01505-2 X:SPRINGER Resolving-System kostenfrei Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 17 2024 1 25 09 |
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10.1007/s40820-024-01505-2 doi (DE-627)SPR057449368 (SPR)s40820-024-01505-2-e DE-627 ger DE-627 rakwb eng 050 VZ Deshmukh, Megha A. verfasserin aut Bimetallic Single-Atom Catalysts for Water Splitting 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2024 Highlights Bimetallic single-atom catalysts (bimSACs) have garnered significant attention for leveraging the synergistic functions of the two metal active centers. This review focuses on the advancements in the field of bimSACs and their pivotal role in hydrogen generation via water splitting. State-of-the-art computational and physicochemical techniques for the analysis of bimSACs and their application in electrocatalytic water splitting are discussed. Abstract Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society. The field of catalysis has been revolutionized by single-atom catalysts (SACs), which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports. Recently, bimetallic SACs (bimSACs) have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports. BimSACs offer an avenue for rich metal–metal and metal–support cooperativity, potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges, substrate activation with reversible redox cycles, simultaneous multi-electron transfer, regulation of spin states, tuning of electronic properties, and cyclic transition states with low activation energies. This review aims to encapsulate the growing advancements in bimSACs, with an emphasis on their pivotal role in hydrogen generation via water splitting. We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs, elucidate their electronic properties, and discuss their local coordination environment. Overall, we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction, the two half-reactions of the water electrolysis process. Single-atom catalysts (dpeaa)DE-He213 Single-atom dimers (dpeaa)DE-He213 Hydrogen evolution (dpeaa)DE-He213 Oxygen evolution (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Bakandritsos, Aristides verfasserin aut Zbořil, Radek verfasserin aut Enthalten in Nano-Micro letters Springer Nature Singapore, 2009 17(2024), 1 vom: 25. Sept. (DE-627)680319581 (DE-600)2642093-4 2150-5551 nnns volume:17 year:2024 number:1 day:25 month:09 https://dx.doi.org/10.1007/s40820-024-01505-2 X:SPRINGER Resolving-System kostenfrei Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 17 2024 1 25 09 |
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10.1007/s40820-024-01505-2 doi (DE-627)SPR057449368 (SPR)s40820-024-01505-2-e DE-627 ger DE-627 rakwb eng 050 VZ Deshmukh, Megha A. verfasserin aut Bimetallic Single-Atom Catalysts for Water Splitting 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2024 Highlights Bimetallic single-atom catalysts (bimSACs) have garnered significant attention for leveraging the synergistic functions of the two metal active centers. This review focuses on the advancements in the field of bimSACs and their pivotal role in hydrogen generation via water splitting. State-of-the-art computational and physicochemical techniques for the analysis of bimSACs and their application in electrocatalytic water splitting are discussed. Abstract Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society. The field of catalysis has been revolutionized by single-atom catalysts (SACs), which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports. Recently, bimetallic SACs (bimSACs) have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports. BimSACs offer an avenue for rich metal–metal and metal–support cooperativity, potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges, substrate activation with reversible redox cycles, simultaneous multi-electron transfer, regulation of spin states, tuning of electronic properties, and cyclic transition states with low activation energies. This review aims to encapsulate the growing advancements in bimSACs, with an emphasis on their pivotal role in hydrogen generation via water splitting. We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs, elucidate their electronic properties, and discuss their local coordination environment. Overall, we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction, the two half-reactions of the water electrolysis process. Single-atom catalysts (dpeaa)DE-He213 Single-atom dimers (dpeaa)DE-He213 Hydrogen evolution (dpeaa)DE-He213 Oxygen evolution (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Bakandritsos, Aristides verfasserin aut Zbořil, Radek verfasserin aut Enthalten in Nano-Micro letters Springer Nature Singapore, 2009 17(2024), 1 vom: 25. Sept. (DE-627)680319581 (DE-600)2642093-4 2150-5551 nnns volume:17 year:2024 number:1 day:25 month:09 https://dx.doi.org/10.1007/s40820-024-01505-2 X:SPRINGER Resolving-System kostenfrei Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 17 2024 1 25 09 |
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10.1007/s40820-024-01505-2 doi (DE-627)SPR057449368 (SPR)s40820-024-01505-2-e DE-627 ger DE-627 rakwb eng 050 VZ Deshmukh, Megha A. verfasserin aut Bimetallic Single-Atom Catalysts for Water Splitting 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2024 Highlights Bimetallic single-atom catalysts (bimSACs) have garnered significant attention for leveraging the synergistic functions of the two metal active centers. This review focuses on the advancements in the field of bimSACs and their pivotal role in hydrogen generation via water splitting. State-of-the-art computational and physicochemical techniques for the analysis of bimSACs and their application in electrocatalytic water splitting are discussed. Abstract Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society. The field of catalysis has been revolutionized by single-atom catalysts (SACs), which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports. Recently, bimetallic SACs (bimSACs) have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports. BimSACs offer an avenue for rich metal–metal and metal–support cooperativity, potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges, substrate activation with reversible redox cycles, simultaneous multi-electron transfer, regulation of spin states, tuning of electronic properties, and cyclic transition states with low activation energies. This review aims to encapsulate the growing advancements in bimSACs, with an emphasis on their pivotal role in hydrogen generation via water splitting. We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs, elucidate their electronic properties, and discuss their local coordination environment. Overall, we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction, the two half-reactions of the water electrolysis process. Single-atom catalysts (dpeaa)DE-He213 Single-atom dimers (dpeaa)DE-He213 Hydrogen evolution (dpeaa)DE-He213 Oxygen evolution (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Bakandritsos, Aristides verfasserin aut Zbořil, Radek verfasserin aut Enthalten in Nano-Micro letters Springer Nature Singapore, 2009 17(2024), 1 vom: 25. Sept. (DE-627)680319581 (DE-600)2642093-4 2150-5551 nnns volume:17 year:2024 number:1 day:25 month:09 https://dx.doi.org/10.1007/s40820-024-01505-2 X:SPRINGER Resolving-System kostenfrei Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 17 2024 1 25 09 |
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10.1007/s40820-024-01505-2 doi (DE-627)SPR057449368 (SPR)s40820-024-01505-2-e DE-627 ger DE-627 rakwb eng 050 VZ Deshmukh, Megha A. verfasserin aut Bimetallic Single-Atom Catalysts for Water Splitting 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2024 Highlights Bimetallic single-atom catalysts (bimSACs) have garnered significant attention for leveraging the synergistic functions of the two metal active centers. This review focuses on the advancements in the field of bimSACs and their pivotal role in hydrogen generation via water splitting. State-of-the-art computational and physicochemical techniques for the analysis of bimSACs and their application in electrocatalytic water splitting are discussed. Abstract Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society. The field of catalysis has been revolutionized by single-atom catalysts (SACs), which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports. Recently, bimetallic SACs (bimSACs) have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports. BimSACs offer an avenue for rich metal–metal and metal–support cooperativity, potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges, substrate activation with reversible redox cycles, simultaneous multi-electron transfer, regulation of spin states, tuning of electronic properties, and cyclic transition states with low activation energies. This review aims to encapsulate the growing advancements in bimSACs, with an emphasis on their pivotal role in hydrogen generation via water splitting. We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs, elucidate their electronic properties, and discuss their local coordination environment. Overall, we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction, the two half-reactions of the water electrolysis process. Single-atom catalysts (dpeaa)DE-He213 Single-atom dimers (dpeaa)DE-He213 Hydrogen evolution (dpeaa)DE-He213 Oxygen evolution (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Bakandritsos, Aristides verfasserin aut Zbořil, Radek verfasserin aut Enthalten in Nano-Micro letters Springer Nature Singapore, 2009 17(2024), 1 vom: 25. Sept. (DE-627)680319581 (DE-600)2642093-4 2150-5551 nnns volume:17 year:2024 number:1 day:25 month:09 https://dx.doi.org/10.1007/s40820-024-01505-2 X:SPRINGER Resolving-System kostenfrei Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 17 2024 1 25 09 |
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Deshmukh, Megha A. |
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Deshmukh, Megha A. ddc 050 misc Single-atom catalysts misc Single-atom dimers misc Hydrogen evolution misc Oxygen evolution misc Water splitting Bimetallic Single-Atom Catalysts for Water Splitting |
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050 VZ Bimetallic Single-Atom Catalysts for Water Splitting Single-atom catalysts (dpeaa)DE-He213 Single-atom dimers (dpeaa)DE-He213 Hydrogen evolution (dpeaa)DE-He213 Oxygen evolution (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 |
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Highlights Bimetallic single-atom catalysts (bimSACs) have garnered significant attention for leveraging the synergistic functions of the two metal active centers. This review focuses on the advancements in the field of bimSACs and their pivotal role in hydrogen generation via water splitting. State-of-the-art computational and physicochemical techniques for the analysis of bimSACs and their application in electrocatalytic water splitting are discussed. Abstract Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society. The field of catalysis has been revolutionized by single-atom catalysts (SACs), which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports. Recently, bimetallic SACs (bimSACs) have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports. BimSACs offer an avenue for rich metal–metal and metal–support cooperativity, potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges, substrate activation with reversible redox cycles, simultaneous multi-electron transfer, regulation of spin states, tuning of electronic properties, and cyclic transition states with low activation energies. This review aims to encapsulate the growing advancements in bimSACs, with an emphasis on their pivotal role in hydrogen generation via water splitting. We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs, elucidate their electronic properties, and discuss their local coordination environment. Overall, we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction, the two half-reactions of the water electrolysis process. © The Author(s) 2024 |
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Highlights Bimetallic single-atom catalysts (bimSACs) have garnered significant attention for leveraging the synergistic functions of the two metal active centers. This review focuses on the advancements in the field of bimSACs and their pivotal role in hydrogen generation via water splitting. State-of-the-art computational and physicochemical techniques for the analysis of bimSACs and their application in electrocatalytic water splitting are discussed. Abstract Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society. The field of catalysis has been revolutionized by single-atom catalysts (SACs), which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports. Recently, bimetallic SACs (bimSACs) have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports. BimSACs offer an avenue for rich metal–metal and metal–support cooperativity, potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges, substrate activation with reversible redox cycles, simultaneous multi-electron transfer, regulation of spin states, tuning of electronic properties, and cyclic transition states with low activation energies. This review aims to encapsulate the growing advancements in bimSACs, with an emphasis on their pivotal role in hydrogen generation via water splitting. We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs, elucidate their electronic properties, and discuss their local coordination environment. Overall, we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction, the two half-reactions of the water electrolysis process. © The Author(s) 2024 |
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Highlights Bimetallic single-atom catalysts (bimSACs) have garnered significant attention for leveraging the synergistic functions of the two metal active centers. This review focuses on the advancements in the field of bimSACs and their pivotal role in hydrogen generation via water splitting. State-of-the-art computational and physicochemical techniques for the analysis of bimSACs and their application in electrocatalytic water splitting are discussed. Abstract Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society. The field of catalysis has been revolutionized by single-atom catalysts (SACs), which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports. Recently, bimetallic SACs (bimSACs) have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports. BimSACs offer an avenue for rich metal–metal and metal–support cooperativity, potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges, substrate activation with reversible redox cycles, simultaneous multi-electron transfer, regulation of spin states, tuning of electronic properties, and cyclic transition states with low activation energies. This review aims to encapsulate the growing advancements in bimSACs, with an emphasis on their pivotal role in hydrogen generation via water splitting. We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs, elucidate their electronic properties, and discuss their local coordination environment. Overall, we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction, the two half-reactions of the water electrolysis process. © The Author(s) 2024 |
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This review focuses on the advancements in the field of bimSACs and their pivotal role in hydrogen generation via water splitting. State-of-the-art computational and physicochemical techniques for the analysis of bimSACs and their application in electrocatalytic water splitting are discussed.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society. The field of catalysis has been revolutionized by single-atom catalysts (SACs), which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports. Recently, bimetallic SACs (bimSACs) have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports. BimSACs offer an avenue for rich metal–metal and metal–support cooperativity, potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges, substrate activation with reversible redox cycles, simultaneous multi-electron transfer, regulation of spin states, tuning of electronic properties, and cyclic transition states with low activation energies. This review aims to encapsulate the growing advancements in bimSACs, with an emphasis on their pivotal role in hydrogen generation via water splitting. We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs, elucidate their electronic properties, and discuss their local coordination environment. Overall, we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction, the two half-reactions of the water electrolysis process.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Single-atom catalysts</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Single-atom dimers</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hydrogen evolution</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oxygen evolution</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Water splitting</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Bakandritsos, Aristides</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zbořil, Radek</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Nano-Micro letters</subfield><subfield code="d">Springer Nature Singapore, 2009</subfield><subfield code="g">17(2024), 1 vom: 25. 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