Integrated production of biolubricants and biodiesel: process simulation and technical–economic analysis
Abstract The competitiveness of the biodiesel industry and the evolution of its positive socio-environmental externalities may be achieved by adding value to oleochemical by-products to be produced in an integrated way with the production of biodiesel. The development of bio-based lubricants, a subs...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
de Sá Parente, Expedito José [verfasserIn] de Oliveira, Lucas Barbosa [verfasserIn] de Luna, Francisco Murilo Tavares [verfasserIn] Cavalcante, Célio Loureiro [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Biomass Conversion and Biorefinery - Springer Berlin Heidelberg, 2011, 14(2023), 19 vom: 12. Juli, Seite 23709-23732 |
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| Übergeordnetes Werk: |
volume:14 ; year:2023 ; number:19 ; day:12 ; month:07 ; pages:23709-23732 |
| Links: |
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| DOI / URN: |
10.1007/s13399-023-04557-3 |
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SPR05746393X |
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| 520 | |a Abstract The competitiveness of the biodiesel industry and the evolution of its positive socio-environmental externalities may be achieved by adding value to oleochemical by-products to be produced in an integrated way with the production of biodiesel. The development of bio-based lubricants, a substitute for mineral lubricating oils, has emerged as a promising alternative for adding value to vegetable oils, and consequently to biodiesel. This study presents a comprehensive assessment of biolubricant production using biodiesel as a feedstream, employing epoxidation and oxirane ring opening reactions with 2-ethylhexanol (BL1) and water (BL2) as nucleophilic agents. Industrial processes were proposed and simulated for two scenarios, considering all steps for production of BL1 (26.6 cSt at 40 °C and pour point of − 12 °C) and BL2 (99.6 cSt at 40 °C and pour point of − 3 °C). The biolubricant production showed promising profitability, as its minimum selling price (MSP) remained consistently below USD 3000/ton, significantly lower than the average price of mineral lubricants (USD 6000/ton). Both scenarios exhibited minimal variation in the MSP of biolubricants (< 2%). The estimated high internal rates of return (24.5% for scenario 1 and 18.6% for scenario 2) highlight the potential profitability of this technological route, even under very conservative perspectives. A technical–economic analysis of an integrated biodiesel and biolubricant production system demonstrated significant synergies during the installation and operational stages, resulting in 21% Capex savings when retrofitting an existing biodiesel plant for biolubricant co-production. Notably, for various combinations of biolubricant prices above USD 3000/ton, the MSP of biodiesel became lower than the specified price of mineral diesel. These findings indicate the potential of integrating biolubricant and biodiesel production as a strategic approach to enhance the biodiesel competitiveness and maximize its positive externalities on society, economy, and environment. | ||
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10.1007/s13399-023-04557-3 doi (DE-627)SPR05746393X (SPR)s13399-023-04557-3-e DE-627 ger DE-627 rakwb eng 570 VZ de Sá Parente, Expedito José verfasserin (orcid)0000-0002-4047-9314 aut Integrated production of biolubricants and biodiesel: process simulation and technical–economic analysis 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The competitiveness of the biodiesel industry and the evolution of its positive socio-environmental externalities may be achieved by adding value to oleochemical by-products to be produced in an integrated way with the production of biodiesel. The development of bio-based lubricants, a substitute for mineral lubricating oils, has emerged as a promising alternative for adding value to vegetable oils, and consequently to biodiesel. This study presents a comprehensive assessment of biolubricant production using biodiesel as a feedstream, employing epoxidation and oxirane ring opening reactions with 2-ethylhexanol (BL1) and water (BL2) as nucleophilic agents. Industrial processes were proposed and simulated for two scenarios, considering all steps for production of BL1 (26.6 cSt at 40 °C and pour point of − 12 °C) and BL2 (99.6 cSt at 40 °C and pour point of − 3 °C). The biolubricant production showed promising profitability, as its minimum selling price (MSP) remained consistently below USD 3000/ton, significantly lower than the average price of mineral lubricants (USD 6000/ton). Both scenarios exhibited minimal variation in the MSP of biolubricants (< 2%). The estimated high internal rates of return (24.5% for scenario 1 and 18.6% for scenario 2) highlight the potential profitability of this technological route, even under very conservative perspectives. A technical–economic analysis of an integrated biodiesel and biolubricant production system demonstrated significant synergies during the installation and operational stages, resulting in 21% Capex savings when retrofitting an existing biodiesel plant for biolubricant co-production. Notably, for various combinations of biolubricant prices above USD 3000/ton, the MSP of biodiesel became lower than the specified price of mineral diesel. These findings indicate the potential of integrating biolubricant and biodiesel production as a strategic approach to enhance the biodiesel competitiveness and maximize its positive externalities on society, economy, and environment. Biolubricants (dpeaa)DE-He213 Biodiesel (dpeaa)DE-He213 Epoxidation (dpeaa)DE-He213 Oxirane ring (dpeaa)DE-He213 Industrial process integration (dpeaa)DE-He213 Economic analysis (dpeaa)DE-He213 de Oliveira, Lucas Barbosa verfasserin (orcid)0000-0002-6467-9951 aut de Luna, Francisco Murilo Tavares verfasserin (orcid)0000-0002-9611-2909 aut Cavalcante, Célio Loureiro verfasserin (orcid)0000-0001-9409-3292 aut Enthalten in Biomass Conversion and Biorefinery Springer Berlin Heidelberg, 2011 14(2023), 19 vom: 12. Juli, Seite 23709-23732 (DE-627)645092843 (DE-600)2592298-1 2190-6823 nnns volume:14 year:2023 number:19 day:12 month:07 pages:23709-23732 https://dx.doi.org/10.1007/s13399-023-04557-3 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 14 2023 19 12 07 23709-23732 |
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10.1007/s13399-023-04557-3 doi (DE-627)SPR05746393X (SPR)s13399-023-04557-3-e DE-627 ger DE-627 rakwb eng 570 VZ de Sá Parente, Expedito José verfasserin (orcid)0000-0002-4047-9314 aut Integrated production of biolubricants and biodiesel: process simulation and technical–economic analysis 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The competitiveness of the biodiesel industry and the evolution of its positive socio-environmental externalities may be achieved by adding value to oleochemical by-products to be produced in an integrated way with the production of biodiesel. The development of bio-based lubricants, a substitute for mineral lubricating oils, has emerged as a promising alternative for adding value to vegetable oils, and consequently to biodiesel. This study presents a comprehensive assessment of biolubricant production using biodiesel as a feedstream, employing epoxidation and oxirane ring opening reactions with 2-ethylhexanol (BL1) and water (BL2) as nucleophilic agents. Industrial processes were proposed and simulated for two scenarios, considering all steps for production of BL1 (26.6 cSt at 40 °C and pour point of − 12 °C) and BL2 (99.6 cSt at 40 °C and pour point of − 3 °C). The biolubricant production showed promising profitability, as its minimum selling price (MSP) remained consistently below USD 3000/ton, significantly lower than the average price of mineral lubricants (USD 6000/ton). Both scenarios exhibited minimal variation in the MSP of biolubricants (< 2%). The estimated high internal rates of return (24.5% for scenario 1 and 18.6% for scenario 2) highlight the potential profitability of this technological route, even under very conservative perspectives. A technical–economic analysis of an integrated biodiesel and biolubricant production system demonstrated significant synergies during the installation and operational stages, resulting in 21% Capex savings when retrofitting an existing biodiesel plant for biolubricant co-production. Notably, for various combinations of biolubricant prices above USD 3000/ton, the MSP of biodiesel became lower than the specified price of mineral diesel. These findings indicate the potential of integrating biolubricant and biodiesel production as a strategic approach to enhance the biodiesel competitiveness and maximize its positive externalities on society, economy, and environment. Biolubricants (dpeaa)DE-He213 Biodiesel (dpeaa)DE-He213 Epoxidation (dpeaa)DE-He213 Oxirane ring (dpeaa)DE-He213 Industrial process integration (dpeaa)DE-He213 Economic analysis (dpeaa)DE-He213 de Oliveira, Lucas Barbosa verfasserin (orcid)0000-0002-6467-9951 aut de Luna, Francisco Murilo Tavares verfasserin (orcid)0000-0002-9611-2909 aut Cavalcante, Célio Loureiro verfasserin (orcid)0000-0001-9409-3292 aut Enthalten in Biomass Conversion and Biorefinery Springer Berlin Heidelberg, 2011 14(2023), 19 vom: 12. Juli, Seite 23709-23732 (DE-627)645092843 (DE-600)2592298-1 2190-6823 nnns volume:14 year:2023 number:19 day:12 month:07 pages:23709-23732 https://dx.doi.org/10.1007/s13399-023-04557-3 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 14 2023 19 12 07 23709-23732 |
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10.1007/s13399-023-04557-3 doi (DE-627)SPR05746393X (SPR)s13399-023-04557-3-e DE-627 ger DE-627 rakwb eng 570 VZ de Sá Parente, Expedito José verfasserin (orcid)0000-0002-4047-9314 aut Integrated production of biolubricants and biodiesel: process simulation and technical–economic analysis 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The competitiveness of the biodiesel industry and the evolution of its positive socio-environmental externalities may be achieved by adding value to oleochemical by-products to be produced in an integrated way with the production of biodiesel. The development of bio-based lubricants, a substitute for mineral lubricating oils, has emerged as a promising alternative for adding value to vegetable oils, and consequently to biodiesel. This study presents a comprehensive assessment of biolubricant production using biodiesel as a feedstream, employing epoxidation and oxirane ring opening reactions with 2-ethylhexanol (BL1) and water (BL2) as nucleophilic agents. Industrial processes were proposed and simulated for two scenarios, considering all steps for production of BL1 (26.6 cSt at 40 °C and pour point of − 12 °C) and BL2 (99.6 cSt at 40 °C and pour point of − 3 °C). The biolubricant production showed promising profitability, as its minimum selling price (MSP) remained consistently below USD 3000/ton, significantly lower than the average price of mineral lubricants (USD 6000/ton). Both scenarios exhibited minimal variation in the MSP of biolubricants (< 2%). The estimated high internal rates of return (24.5% for scenario 1 and 18.6% for scenario 2) highlight the potential profitability of this technological route, even under very conservative perspectives. A technical–economic analysis of an integrated biodiesel and biolubricant production system demonstrated significant synergies during the installation and operational stages, resulting in 21% Capex savings when retrofitting an existing biodiesel plant for biolubricant co-production. Notably, for various combinations of biolubricant prices above USD 3000/ton, the MSP of biodiesel became lower than the specified price of mineral diesel. These findings indicate the potential of integrating biolubricant and biodiesel production as a strategic approach to enhance the biodiesel competitiveness and maximize its positive externalities on society, economy, and environment. Biolubricants (dpeaa)DE-He213 Biodiesel (dpeaa)DE-He213 Epoxidation (dpeaa)DE-He213 Oxirane ring (dpeaa)DE-He213 Industrial process integration (dpeaa)DE-He213 Economic analysis (dpeaa)DE-He213 de Oliveira, Lucas Barbosa verfasserin (orcid)0000-0002-6467-9951 aut de Luna, Francisco Murilo Tavares verfasserin (orcid)0000-0002-9611-2909 aut Cavalcante, Célio Loureiro verfasserin (orcid)0000-0001-9409-3292 aut Enthalten in Biomass Conversion and Biorefinery Springer Berlin Heidelberg, 2011 14(2023), 19 vom: 12. Juli, Seite 23709-23732 (DE-627)645092843 (DE-600)2592298-1 2190-6823 nnns volume:14 year:2023 number:19 day:12 month:07 pages:23709-23732 https://dx.doi.org/10.1007/s13399-023-04557-3 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 14 2023 19 12 07 23709-23732 |
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10.1007/s13399-023-04557-3 doi (DE-627)SPR05746393X (SPR)s13399-023-04557-3-e DE-627 ger DE-627 rakwb eng 570 VZ de Sá Parente, Expedito José verfasserin (orcid)0000-0002-4047-9314 aut Integrated production of biolubricants and biodiesel: process simulation and technical–economic analysis 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The competitiveness of the biodiesel industry and the evolution of its positive socio-environmental externalities may be achieved by adding value to oleochemical by-products to be produced in an integrated way with the production of biodiesel. The development of bio-based lubricants, a substitute for mineral lubricating oils, has emerged as a promising alternative for adding value to vegetable oils, and consequently to biodiesel. This study presents a comprehensive assessment of biolubricant production using biodiesel as a feedstream, employing epoxidation and oxirane ring opening reactions with 2-ethylhexanol (BL1) and water (BL2) as nucleophilic agents. Industrial processes were proposed and simulated for two scenarios, considering all steps for production of BL1 (26.6 cSt at 40 °C and pour point of − 12 °C) and BL2 (99.6 cSt at 40 °C and pour point of − 3 °C). The biolubricant production showed promising profitability, as its minimum selling price (MSP) remained consistently below USD 3000/ton, significantly lower than the average price of mineral lubricants (USD 6000/ton). Both scenarios exhibited minimal variation in the MSP of biolubricants (< 2%). The estimated high internal rates of return (24.5% for scenario 1 and 18.6% for scenario 2) highlight the potential profitability of this technological route, even under very conservative perspectives. A technical–economic analysis of an integrated biodiesel and biolubricant production system demonstrated significant synergies during the installation and operational stages, resulting in 21% Capex savings when retrofitting an existing biodiesel plant for biolubricant co-production. Notably, for various combinations of biolubricant prices above USD 3000/ton, the MSP of biodiesel became lower than the specified price of mineral diesel. These findings indicate the potential of integrating biolubricant and biodiesel production as a strategic approach to enhance the biodiesel competitiveness and maximize its positive externalities on society, economy, and environment. Biolubricants (dpeaa)DE-He213 Biodiesel (dpeaa)DE-He213 Epoxidation (dpeaa)DE-He213 Oxirane ring (dpeaa)DE-He213 Industrial process integration (dpeaa)DE-He213 Economic analysis (dpeaa)DE-He213 de Oliveira, Lucas Barbosa verfasserin (orcid)0000-0002-6467-9951 aut de Luna, Francisco Murilo Tavares verfasserin (orcid)0000-0002-9611-2909 aut Cavalcante, Célio Loureiro verfasserin (orcid)0000-0001-9409-3292 aut Enthalten in Biomass Conversion and Biorefinery Springer Berlin Heidelberg, 2011 14(2023), 19 vom: 12. Juli, Seite 23709-23732 (DE-627)645092843 (DE-600)2592298-1 2190-6823 nnns volume:14 year:2023 number:19 day:12 month:07 pages:23709-23732 https://dx.doi.org/10.1007/s13399-023-04557-3 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 14 2023 19 12 07 23709-23732 |
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10.1007/s13399-023-04557-3 doi (DE-627)SPR05746393X (SPR)s13399-023-04557-3-e DE-627 ger DE-627 rakwb eng 570 VZ de Sá Parente, Expedito José verfasserin (orcid)0000-0002-4047-9314 aut Integrated production of biolubricants and biodiesel: process simulation and technical–economic analysis 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract The competitiveness of the biodiesel industry and the evolution of its positive socio-environmental externalities may be achieved by adding value to oleochemical by-products to be produced in an integrated way with the production of biodiesel. The development of bio-based lubricants, a substitute for mineral lubricating oils, has emerged as a promising alternative for adding value to vegetable oils, and consequently to biodiesel. This study presents a comprehensive assessment of biolubricant production using biodiesel as a feedstream, employing epoxidation and oxirane ring opening reactions with 2-ethylhexanol (BL1) and water (BL2) as nucleophilic agents. Industrial processes were proposed and simulated for two scenarios, considering all steps for production of BL1 (26.6 cSt at 40 °C and pour point of − 12 °C) and BL2 (99.6 cSt at 40 °C and pour point of − 3 °C). The biolubricant production showed promising profitability, as its minimum selling price (MSP) remained consistently below USD 3000/ton, significantly lower than the average price of mineral lubricants (USD 6000/ton). Both scenarios exhibited minimal variation in the MSP of biolubricants (< 2%). The estimated high internal rates of return (24.5% for scenario 1 and 18.6% for scenario 2) highlight the potential profitability of this technological route, even under very conservative perspectives. A technical–economic analysis of an integrated biodiesel and biolubricant production system demonstrated significant synergies during the installation and operational stages, resulting in 21% Capex savings when retrofitting an existing biodiesel plant for biolubricant co-production. Notably, for various combinations of biolubricant prices above USD 3000/ton, the MSP of biodiesel became lower than the specified price of mineral diesel. These findings indicate the potential of integrating biolubricant and biodiesel production as a strategic approach to enhance the biodiesel competitiveness and maximize its positive externalities on society, economy, and environment. Biolubricants (dpeaa)DE-He213 Biodiesel (dpeaa)DE-He213 Epoxidation (dpeaa)DE-He213 Oxirane ring (dpeaa)DE-He213 Industrial process integration (dpeaa)DE-He213 Economic analysis (dpeaa)DE-He213 de Oliveira, Lucas Barbosa verfasserin (orcid)0000-0002-6467-9951 aut de Luna, Francisco Murilo Tavares verfasserin (orcid)0000-0002-9611-2909 aut Cavalcante, Célio Loureiro verfasserin (orcid)0000-0001-9409-3292 aut Enthalten in Biomass Conversion and Biorefinery Springer Berlin Heidelberg, 2011 14(2023), 19 vom: 12. Juli, Seite 23709-23732 (DE-627)645092843 (DE-600)2592298-1 2190-6823 nnns volume:14 year:2023 number:19 day:12 month:07 pages:23709-23732 https://dx.doi.org/10.1007/s13399-023-04557-3 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 14 2023 19 12 07 23709-23732 |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The competitiveness of the biodiesel industry and the evolution of its positive socio-environmental externalities may be achieved by adding value to oleochemical by-products to be produced in an integrated way with the production of biodiesel. The development of bio-based lubricants, a substitute for mineral lubricating oils, has emerged as a promising alternative for adding value to vegetable oils, and consequently to biodiesel. This study presents a comprehensive assessment of biolubricant production using biodiesel as a feedstream, employing epoxidation and oxirane ring opening reactions with 2-ethylhexanol (BL1) and water (BL2) as nucleophilic agents. Industrial processes were proposed and simulated for two scenarios, considering all steps for production of BL1 (26.6 cSt at 40 °C and pour point of − 12 °C) and BL2 (99.6 cSt at 40 °C and pour point of − 3 °C). The biolubricant production showed promising profitability, as its minimum selling price (MSP) remained consistently below USD 3000/ton, significantly lower than the average price of mineral lubricants (USD 6000/ton). Both scenarios exhibited minimal variation in the MSP of biolubricants (< 2%). The estimated high internal rates of return (24.5% for scenario 1 and 18.6% for scenario 2) highlight the potential profitability of this technological route, even under very conservative perspectives. A technical–economic analysis of an integrated biodiesel and biolubricant production system demonstrated significant synergies during the installation and operational stages, resulting in 21% Capex savings when retrofitting an existing biodiesel plant for biolubricant co-production. Notably, for various combinations of biolubricant prices above USD 3000/ton, the MSP of biodiesel became lower than the specified price of mineral diesel. 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integrated production of biolubricants and biodiesel: process simulation and technical–economic analysis |
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Integrated production of biolubricants and biodiesel: process simulation and technical–economic analysis |
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Abstract The competitiveness of the biodiesel industry and the evolution of its positive socio-environmental externalities may be achieved by adding value to oleochemical by-products to be produced in an integrated way with the production of biodiesel. The development of bio-based lubricants, a substitute for mineral lubricating oils, has emerged as a promising alternative for adding value to vegetable oils, and consequently to biodiesel. This study presents a comprehensive assessment of biolubricant production using biodiesel as a feedstream, employing epoxidation and oxirane ring opening reactions with 2-ethylhexanol (BL1) and water (BL2) as nucleophilic agents. Industrial processes were proposed and simulated for two scenarios, considering all steps for production of BL1 (26.6 cSt at 40 °C and pour point of − 12 °C) and BL2 (99.6 cSt at 40 °C and pour point of − 3 °C). The biolubricant production showed promising profitability, as its minimum selling price (MSP) remained consistently below USD 3000/ton, significantly lower than the average price of mineral lubricants (USD 6000/ton). Both scenarios exhibited minimal variation in the MSP of biolubricants (< 2%). The estimated high internal rates of return (24.5% for scenario 1 and 18.6% for scenario 2) highlight the potential profitability of this technological route, even under very conservative perspectives. A technical–economic analysis of an integrated biodiesel and biolubricant production system demonstrated significant synergies during the installation and operational stages, resulting in 21% Capex savings when retrofitting an existing biodiesel plant for biolubricant co-production. Notably, for various combinations of biolubricant prices above USD 3000/ton, the MSP of biodiesel became lower than the specified price of mineral diesel. These findings indicate the potential of integrating biolubricant and biodiesel production as a strategic approach to enhance the biodiesel competitiveness and maximize its positive externalities on society, economy, and environment. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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Abstract The competitiveness of the biodiesel industry and the evolution of its positive socio-environmental externalities may be achieved by adding value to oleochemical by-products to be produced in an integrated way with the production of biodiesel. The development of bio-based lubricants, a substitute for mineral lubricating oils, has emerged as a promising alternative for adding value to vegetable oils, and consequently to biodiesel. This study presents a comprehensive assessment of biolubricant production using biodiesel as a feedstream, employing epoxidation and oxirane ring opening reactions with 2-ethylhexanol (BL1) and water (BL2) as nucleophilic agents. Industrial processes were proposed and simulated for two scenarios, considering all steps for production of BL1 (26.6 cSt at 40 °C and pour point of − 12 °C) and BL2 (99.6 cSt at 40 °C and pour point of − 3 °C). The biolubricant production showed promising profitability, as its minimum selling price (MSP) remained consistently below USD 3000/ton, significantly lower than the average price of mineral lubricants (USD 6000/ton). Both scenarios exhibited minimal variation in the MSP of biolubricants (< 2%). The estimated high internal rates of return (24.5% for scenario 1 and 18.6% for scenario 2) highlight the potential profitability of this technological route, even under very conservative perspectives. A technical–economic analysis of an integrated biodiesel and biolubricant production system demonstrated significant synergies during the installation and operational stages, resulting in 21% Capex savings when retrofitting an existing biodiesel plant for biolubricant co-production. Notably, for various combinations of biolubricant prices above USD 3000/ton, the MSP of biodiesel became lower than the specified price of mineral diesel. These findings indicate the potential of integrating biolubricant and biodiesel production as a strategic approach to enhance the biodiesel competitiveness and maximize its positive externalities on society, economy, and environment. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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Abstract The competitiveness of the biodiesel industry and the evolution of its positive socio-environmental externalities may be achieved by adding value to oleochemical by-products to be produced in an integrated way with the production of biodiesel. The development of bio-based lubricants, a substitute for mineral lubricating oils, has emerged as a promising alternative for adding value to vegetable oils, and consequently to biodiesel. This study presents a comprehensive assessment of biolubricant production using biodiesel as a feedstream, employing epoxidation and oxirane ring opening reactions with 2-ethylhexanol (BL1) and water (BL2) as nucleophilic agents. Industrial processes were proposed and simulated for two scenarios, considering all steps for production of BL1 (26.6 cSt at 40 °C and pour point of − 12 °C) and BL2 (99.6 cSt at 40 °C and pour point of − 3 °C). The biolubricant production showed promising profitability, as its minimum selling price (MSP) remained consistently below USD 3000/ton, significantly lower than the average price of mineral lubricants (USD 6000/ton). Both scenarios exhibited minimal variation in the MSP of biolubricants (< 2%). The estimated high internal rates of return (24.5% for scenario 1 and 18.6% for scenario 2) highlight the potential profitability of this technological route, even under very conservative perspectives. A technical–economic analysis of an integrated biodiesel and biolubricant production system demonstrated significant synergies during the installation and operational stages, resulting in 21% Capex savings when retrofitting an existing biodiesel plant for biolubricant co-production. Notably, for various combinations of biolubricant prices above USD 3000/ton, the MSP of biodiesel became lower than the specified price of mineral diesel. These findings indicate the potential of integrating biolubricant and biodiesel production as a strategic approach to enhance the biodiesel competitiveness and maximize its positive externalities on society, economy, and environment. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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7.3982124 |