Oxygen self-doped physalis peruviana calyx husk-derived porous carbon for supercapacitors

Abstract Physalis peruviana is a widely spread plant, and its calyx husk are rich in cellulose and hemicellulose, making it an ideal precursor for preparing supercapacitor electrode materials. The Physalis peruviana calyx husk is an excellent source of activated carbon and has a honeycomb-like epide...
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Autor*in:	Wang, Yuanyuan [verfasserIn] Dong, Xingshen [verfasserIn] Xia, Yingjing [verfasserIn] Wang, Xueqin [verfasserIn] Liu, Yanxiu [verfasserIn] Qiao, Peng [verfasserIn] Zhang, Geng [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2024

Anmerkung:	© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Übergeordnetes Werk:	Enthalten in: Journal of materials science - Springer US, 1990, 35(2024), 27 vom: Sept.
Übergeordnetes Werk:	volume:35 ; year:2024 ; number:27 ; month:09

Links:	Volltext

DOI / URN:	10.1007/s10854-024-13563-8

Katalog-ID:	SPR057471908

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520			\|a Abstract Physalis peruviana is a widely spread plant, and its calyx husk are rich in cellulose and hemicellulose, making it an ideal precursor for preparing supercapacitor electrode materials. The Physalis peruviana calyx husk is an excellent source of activated carbon and has a honeycomb-like epidermis, veins, and basic tissues. Its unique skeleton additionally assists to provide the material a three-dimensional structure. A series of porous carbon materials were synthesized from the calyx husk of Physalis peruviana via KOH as an activator. The variation of micromorphology, structure, and electrochemical properties of PCC-T materials with activation temperature has been investigated. The PCC-800 material prepared at 800 °C has a surface oxygen content of 11.63%, a rich pore structure (micro-meso-macroporous), and a large specific surface area (2703.75 $ m^{2} $ $ g^{−1} $). In 6 M KOH, PCC-800 has a specific capacitance of 349.7 F $ g^{−1} $ at a current density of 0.5 A $ g^{−1} $ in a three-electrode system, and a capacitance retention of 78.9% even with a 40-fold increase in current density. The assembled symmetric supercapacitor achieved an energy density of 8.95 Wh $ kg^{−1} $ (250 W $ kg^{−1} $) in 6 M KOH and 17.56 Wh $ kg^{−1} $ (187 W $ kg^{−1} $) was obtained in 1 M $ Na_{2} $$ SO_{4} $ electrolyte in a two-electrode system. In addition, the capacitance is reduced by only 1.4% after 6,000 charge–discharge cycles at a current density of 8 A $ g^{−1} $.
700	1		\|a Dong, Xingshen \|e verfasserin \|4 aut
700	1		\|a Xia, Yingjing \|e verfasserin \|4 aut
700	1		\|a Wang, Xueqin \|e verfasserin \|4 aut
700	1		\|a Liu, Yanxiu \|e verfasserin \|4 aut
700	1		\|a Qiao, Peng \|e verfasserin \|4 aut
700	1		\|a Zhang, Geng \|e verfasserin \|4 aut
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912			\|a GBV_ILN_110
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912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
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912			\|a GBV_ILN_187
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912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
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912			\|a GBV_ILN_602
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912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
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912			\|a GBV_ILN_2005
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912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
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912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
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912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
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912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
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author_variant	y w yw x d xd y x yx x w xw y l yl p q pq g z gz
matchkey_str	article:1573482X:2024----::xgnefoepyaiprvaaayhsdrvdoosa
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allfields	10.1007/s10854-024-13563-8 doi (DE-627)SPR057471908 (SPR)s10854-024-13563-8-e DE-627 ger DE-627 rakwb eng 600 670 620 VZ 33.61 bkl 51.10 bkl 51.40 bkl 53.09 bkl Wang, Yuanyuan verfasserin (orcid)0009-0008-2236-0097 aut Oxygen self-doped physalis peruviana calyx husk-derived porous carbon for supercapacitors 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Physalis peruviana is a widely spread plant, and its calyx husk are rich in cellulose and hemicellulose, making it an ideal precursor for preparing supercapacitor electrode materials. The Physalis peruviana calyx husk is an excellent source of activated carbon and has a honeycomb-like epidermis, veins, and basic tissues. Its unique skeleton additionally assists to provide the material a three-dimensional structure. A series of porous carbon materials were synthesized from the calyx husk of Physalis peruviana via KOH as an activator. The variation of micromorphology, structure, and electrochemical properties of PCC-T materials with activation temperature has been investigated. The PCC-800 material prepared at 800 °C has a surface oxygen content of 11.63%, a rich pore structure (micro-meso-macroporous), and a large specific surface area (2703.75 $ m^{2} $ $ g^{−1} $). In 6 M KOH, PCC-800 has a specific capacitance of 349.7 F $ g^{−1} $ at a current density of 0.5 A $ g^{−1} $ in a three-electrode system, and a capacitance retention of 78.9% even with a 40-fold increase in current density. The assembled symmetric supercapacitor achieved an energy density of 8.95 Wh $ kg^{−1} $ (250 W $ kg^{−1} $) in 6 M KOH and 17.56 Wh $ kg^{−1} $ (187 W $ kg^{−1} $) was obtained in 1 M $ Na_{2} $$ SO_{4} $ electrolyte in a two-electrode system. In addition, the capacitance is reduced by only 1.4% after 6,000 charge–discharge cycles at a current density of 8 A $ g^{−1} $. Dong, Xingshen verfasserin aut Xia, Yingjing verfasserin aut Wang, Xueqin verfasserin aut Liu, Yanxiu verfasserin aut Qiao, Peng verfasserin aut Zhang, Geng verfasserin aut Enthalten in Journal of materials science Springer US, 1990 35(2024), 27 vom: Sept. (DE-627)317827154 (DE-600)2016994-2 1573-482X nnns volume:35 year:2024 number:27 month:09 https://dx.doi.org/10.1007/s10854-024-13563-8 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.61 VZ 51.10 VZ 51.40 VZ 53.09 VZ AR 35 2024 27 09
spelling	10.1007/s10854-024-13563-8 doi (DE-627)SPR057471908 (SPR)s10854-024-13563-8-e DE-627 ger DE-627 rakwb eng 600 670 620 VZ 33.61 bkl 51.10 bkl 51.40 bkl 53.09 bkl Wang, Yuanyuan verfasserin (orcid)0009-0008-2236-0097 aut Oxygen self-doped physalis peruviana calyx husk-derived porous carbon for supercapacitors 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Physalis peruviana is a widely spread plant, and its calyx husk are rich in cellulose and hemicellulose, making it an ideal precursor for preparing supercapacitor electrode materials. The Physalis peruviana calyx husk is an excellent source of activated carbon and has a honeycomb-like epidermis, veins, and basic tissues. Its unique skeleton additionally assists to provide the material a three-dimensional structure. A series of porous carbon materials were synthesized from the calyx husk of Physalis peruviana via KOH as an activator. The variation of micromorphology, structure, and electrochemical properties of PCC-T materials with activation temperature has been investigated. The PCC-800 material prepared at 800 °C has a surface oxygen content of 11.63%, a rich pore structure (micro-meso-macroporous), and a large specific surface area (2703.75 $ m^{2} $ $ g^{−1} $). In 6 M KOH, PCC-800 has a specific capacitance of 349.7 F $ g^{−1} $ at a current density of 0.5 A $ g^{−1} $ in a three-electrode system, and a capacitance retention of 78.9% even with a 40-fold increase in current density. The assembled symmetric supercapacitor achieved an energy density of 8.95 Wh $ kg^{−1} $ (250 W $ kg^{−1} $) in 6 M KOH and 17.56 Wh $ kg^{−1} $ (187 W $ kg^{−1} $) was obtained in 1 M $ Na_{2} $$ SO_{4} $ electrolyte in a two-electrode system. In addition, the capacitance is reduced by only 1.4% after 6,000 charge–discharge cycles at a current density of 8 A $ g^{−1} $. Dong, Xingshen verfasserin aut Xia, Yingjing verfasserin aut Wang, Xueqin verfasserin aut Liu, Yanxiu verfasserin aut Qiao, Peng verfasserin aut Zhang, Geng verfasserin aut Enthalten in Journal of materials science Springer US, 1990 35(2024), 27 vom: Sept. (DE-627)317827154 (DE-600)2016994-2 1573-482X nnns volume:35 year:2024 number:27 month:09 https://dx.doi.org/10.1007/s10854-024-13563-8 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.61 VZ 51.10 VZ 51.40 VZ 53.09 VZ AR 35 2024 27 09
allfields_unstemmed	10.1007/s10854-024-13563-8 doi (DE-627)SPR057471908 (SPR)s10854-024-13563-8-e DE-627 ger DE-627 rakwb eng 600 670 620 VZ 33.61 bkl 51.10 bkl 51.40 bkl 53.09 bkl Wang, Yuanyuan verfasserin (orcid)0009-0008-2236-0097 aut Oxygen self-doped physalis peruviana calyx husk-derived porous carbon for supercapacitors 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Physalis peruviana is a widely spread plant, and its calyx husk are rich in cellulose and hemicellulose, making it an ideal precursor for preparing supercapacitor electrode materials. The Physalis peruviana calyx husk is an excellent source of activated carbon and has a honeycomb-like epidermis, veins, and basic tissues. Its unique skeleton additionally assists to provide the material a three-dimensional structure. A series of porous carbon materials were synthesized from the calyx husk of Physalis peruviana via KOH as an activator. The variation of micromorphology, structure, and electrochemical properties of PCC-T materials with activation temperature has been investigated. The PCC-800 material prepared at 800 °C has a surface oxygen content of 11.63%, a rich pore structure (micro-meso-macroporous), and a large specific surface area (2703.75 $ m^{2} $ $ g^{−1} $). In 6 M KOH, PCC-800 has a specific capacitance of 349.7 F $ g^{−1} $ at a current density of 0.5 A $ g^{−1} $ in a three-electrode system, and a capacitance retention of 78.9% even with a 40-fold increase in current density. The assembled symmetric supercapacitor achieved an energy density of 8.95 Wh $ kg^{−1} $ (250 W $ kg^{−1} $) in 6 M KOH and 17.56 Wh $ kg^{−1} $ (187 W $ kg^{−1} $) was obtained in 1 M $ Na_{2} $$ SO_{4} $ electrolyte in a two-electrode system. In addition, the capacitance is reduced by only 1.4% after 6,000 charge–discharge cycles at a current density of 8 A $ g^{−1} $. Dong, Xingshen verfasserin aut Xia, Yingjing verfasserin aut Wang, Xueqin verfasserin aut Liu, Yanxiu verfasserin aut Qiao, Peng verfasserin aut Zhang, Geng verfasserin aut Enthalten in Journal of materials science Springer US, 1990 35(2024), 27 vom: Sept. (DE-627)317827154 (DE-600)2016994-2 1573-482X nnns volume:35 year:2024 number:27 month:09 https://dx.doi.org/10.1007/s10854-024-13563-8 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.61 VZ 51.10 VZ 51.40 VZ 53.09 VZ AR 35 2024 27 09
allfieldsGer	10.1007/s10854-024-13563-8 doi (DE-627)SPR057471908 (SPR)s10854-024-13563-8-e DE-627 ger DE-627 rakwb eng 600 670 620 VZ 33.61 bkl 51.10 bkl 51.40 bkl 53.09 bkl Wang, Yuanyuan verfasserin (orcid)0009-0008-2236-0097 aut Oxygen self-doped physalis peruviana calyx husk-derived porous carbon for supercapacitors 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Physalis peruviana is a widely spread plant, and its calyx husk are rich in cellulose and hemicellulose, making it an ideal precursor for preparing supercapacitor electrode materials. The Physalis peruviana calyx husk is an excellent source of activated carbon and has a honeycomb-like epidermis, veins, and basic tissues. Its unique skeleton additionally assists to provide the material a three-dimensional structure. A series of porous carbon materials were synthesized from the calyx husk of Physalis peruviana via KOH as an activator. The variation of micromorphology, structure, and electrochemical properties of PCC-T materials with activation temperature has been investigated. The PCC-800 material prepared at 800 °C has a surface oxygen content of 11.63%, a rich pore structure (micro-meso-macroporous), and a large specific surface area (2703.75 $ m^{2} $ $ g^{−1} $). In 6 M KOH, PCC-800 has a specific capacitance of 349.7 F $ g^{−1} $ at a current density of 0.5 A $ g^{−1} $ in a three-electrode system, and a capacitance retention of 78.9% even with a 40-fold increase in current density. The assembled symmetric supercapacitor achieved an energy density of 8.95 Wh $ kg^{−1} $ (250 W $ kg^{−1} $) in 6 M KOH and 17.56 Wh $ kg^{−1} $ (187 W $ kg^{−1} $) was obtained in 1 M $ Na_{2} $$ SO_{4} $ electrolyte in a two-electrode system. In addition, the capacitance is reduced by only 1.4% after 6,000 charge–discharge cycles at a current density of 8 A $ g^{−1} $. Dong, Xingshen verfasserin aut Xia, Yingjing verfasserin aut Wang, Xueqin verfasserin aut Liu, Yanxiu verfasserin aut Qiao, Peng verfasserin aut Zhang, Geng verfasserin aut Enthalten in Journal of materials science Springer US, 1990 35(2024), 27 vom: Sept. (DE-627)317827154 (DE-600)2016994-2 1573-482X nnns volume:35 year:2024 number:27 month:09 https://dx.doi.org/10.1007/s10854-024-13563-8 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.61 VZ 51.10 VZ 51.40 VZ 53.09 VZ AR 35 2024 27 09
allfieldsSound	10.1007/s10854-024-13563-8 doi (DE-627)SPR057471908 (SPR)s10854-024-13563-8-e DE-627 ger DE-627 rakwb eng 600 670 620 VZ 33.61 bkl 51.10 bkl 51.40 bkl 53.09 bkl Wang, Yuanyuan verfasserin (orcid)0009-0008-2236-0097 aut Oxygen self-doped physalis peruviana calyx husk-derived porous carbon for supercapacitors 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Abstract Physalis peruviana is a widely spread plant, and its calyx husk are rich in cellulose and hemicellulose, making it an ideal precursor for preparing supercapacitor electrode materials. The Physalis peruviana calyx husk is an excellent source of activated carbon and has a honeycomb-like epidermis, veins, and basic tissues. Its unique skeleton additionally assists to provide the material a three-dimensional structure. A series of porous carbon materials were synthesized from the calyx husk of Physalis peruviana via KOH as an activator. The variation of micromorphology, structure, and electrochemical properties of PCC-T materials with activation temperature has been investigated. The PCC-800 material prepared at 800 °C has a surface oxygen content of 11.63%, a rich pore structure (micro-meso-macroporous), and a large specific surface area (2703.75 $ m^{2} $ $ g^{−1} $). In 6 M KOH, PCC-800 has a specific capacitance of 349.7 F $ g^{−1} $ at a current density of 0.5 A $ g^{−1} $ in a three-electrode system, and a capacitance retention of 78.9% even with a 40-fold increase in current density. The assembled symmetric supercapacitor achieved an energy density of 8.95 Wh $ kg^{−1} $ (250 W $ kg^{−1} $) in 6 M KOH and 17.56 Wh $ kg^{−1} $ (187 W $ kg^{−1} $) was obtained in 1 M $ Na_{2} $$ SO_{4} $ electrolyte in a two-electrode system. In addition, the capacitance is reduced by only 1.4% after 6,000 charge–discharge cycles at a current density of 8 A $ g^{−1} $. Dong, Xingshen verfasserin aut Xia, Yingjing verfasserin aut Wang, Xueqin verfasserin aut Liu, Yanxiu verfasserin aut Qiao, Peng verfasserin aut Zhang, Geng verfasserin aut Enthalten in Journal of materials science Springer US, 1990 35(2024), 27 vom: Sept. (DE-627)317827154 (DE-600)2016994-2 1573-482X nnns volume:35 year:2024 number:27 month:09 https://dx.doi.org/10.1007/s10854-024-13563-8 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.61 VZ 51.10 VZ 51.40 VZ 53.09 VZ AR 35 2024 27 09
language	English
source	Enthalten in Journal of materials science 35(2024), 27 vom: Sept. volume:35 year:2024 number:27 month:09
sourceStr	Enthalten in Journal of materials science 35(2024), 27 vom: Sept. volume:35 year:2024 number:27 month:09
format_phy_str_mv	Article
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dewey-raw	600
isfreeaccess_bool	false
container_title	Journal of materials science
authorswithroles_txt_mv	Wang, Yuanyuan @@aut@@ Dong, Xingshen @@aut@@ Xia, Yingjing @@aut@@ Wang, Xueqin @@aut@@ Liu, Yanxiu @@aut@@ Qiao, Peng @@aut@@ Zhang, Geng @@aut@@
publishDateDaySort_date	2024-09-01T00:00:00Z
hierarchy_top_id	317827154
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Physalis peruviana is a widely spread plant, and its calyx husk are rich in cellulose and hemicellulose, making it an ideal precursor for preparing supercapacitor electrode materials. The Physalis peruviana calyx husk is an excellent source of activated carbon and has a honeycomb-like epidermis, veins, and basic tissues. Its unique skeleton additionally assists to provide the material a three-dimensional structure. A series of porous carbon materials were synthesized from the calyx husk of Physalis peruviana via KOH as an activator. The variation of micromorphology, structure, and electrochemical properties of PCC-T materials with activation temperature has been investigated. The PCC-800 material prepared at 800 °C has a surface oxygen content of 11.63%, a rich pore structure (micro-meso-macroporous), and a large specific surface area (2703.75 $ m^{2} $ $ g^{−1} $). In 6 M KOH, PCC-800 has a specific capacitance of 349.7 F $ g^{−1} $ at a current density of 0.5 A $ g^{−1} $ in a three-electrode system, and a capacitance retention of 78.9% even with a 40-fold increase in current density. The assembled symmetric supercapacitor achieved an energy density of 8.95 Wh $ kg^{−1} $ (250 W $ kg^{−1} $) in 6 M KOH and 17.56 Wh $ kg^{−1} $ (187 W $ kg^{−1} $) was obtained in 1 M $ Na_{2} $$ SO_{4} $ electrolyte in a two-electrode system. 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author	Wang, Yuanyuan
spellingShingle	Wang, Yuanyuan ddc 600 bkl 33.61 bkl 51.10 bkl 51.40 bkl 53.09 Oxygen self-doped physalis peruviana calyx husk-derived porous carbon for supercapacitors
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title_sort	oxygen self-doped physalis peruviana calyx husk-derived porous carbon for supercapacitors
title_auth	Oxygen self-doped physalis peruviana calyx husk-derived porous carbon for supercapacitors
abstract	Abstract Physalis peruviana is a widely spread plant, and its calyx husk are rich in cellulose and hemicellulose, making it an ideal precursor for preparing supercapacitor electrode materials. The Physalis peruviana calyx husk is an excellent source of activated carbon and has a honeycomb-like epidermis, veins, and basic tissues. Its unique skeleton additionally assists to provide the material a three-dimensional structure. A series of porous carbon materials were synthesized from the calyx husk of Physalis peruviana via KOH as an activator. The variation of micromorphology, structure, and electrochemical properties of PCC-T materials with activation temperature has been investigated. The PCC-800 material prepared at 800 °C has a surface oxygen content of 11.63%, a rich pore structure (micro-meso-macroporous), and a large specific surface area (2703.75 $ m^{2} $ $ g^{−1} $). In 6 M KOH, PCC-800 has a specific capacitance of 349.7 F $ g^{−1} $ at a current density of 0.5 A $ g^{−1} $ in a three-electrode system, and a capacitance retention of 78.9% even with a 40-fold increase in current density. The assembled symmetric supercapacitor achieved an energy density of 8.95 Wh $ kg^{−1} $ (250 W $ kg^{−1} $) in 6 M KOH and 17.56 Wh $ kg^{−1} $ (187 W $ kg^{−1} $) was obtained in 1 M $ Na_{2} $$ SO_{4} $ electrolyte in a two-electrode system. In addition, the capacitance is reduced by only 1.4% after 6,000 charge–discharge cycles at a current density of 8 A $ g^{−1} $. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
abstractGer	Abstract Physalis peruviana is a widely spread plant, and its calyx husk are rich in cellulose and hemicellulose, making it an ideal precursor for preparing supercapacitor electrode materials. The Physalis peruviana calyx husk is an excellent source of activated carbon and has a honeycomb-like epidermis, veins, and basic tissues. Its unique skeleton additionally assists to provide the material a three-dimensional structure. A series of porous carbon materials were synthesized from the calyx husk of Physalis peruviana via KOH as an activator. The variation of micromorphology, structure, and electrochemical properties of PCC-T materials with activation temperature has been investigated. The PCC-800 material prepared at 800 °C has a surface oxygen content of 11.63%, a rich pore structure (micro-meso-macroporous), and a large specific surface area (2703.75 $ m^{2} $ $ g^{−1} $). In 6 M KOH, PCC-800 has a specific capacitance of 349.7 F $ g^{−1} $ at a current density of 0.5 A $ g^{−1} $ in a three-electrode system, and a capacitance retention of 78.9% even with a 40-fold increase in current density. The assembled symmetric supercapacitor achieved an energy density of 8.95 Wh $ kg^{−1} $ (250 W $ kg^{−1} $) in 6 M KOH and 17.56 Wh $ kg^{−1} $ (187 W $ kg^{−1} $) was obtained in 1 M $ Na_{2} $$ SO_{4} $ electrolyte in a two-electrode system. In addition, the capacitance is reduced by only 1.4% after 6,000 charge–discharge cycles at a current density of 8 A $ g^{−1} $. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
abstract_unstemmed	Abstract Physalis peruviana is a widely spread plant, and its calyx husk are rich in cellulose and hemicellulose, making it an ideal precursor for preparing supercapacitor electrode materials. The Physalis peruviana calyx husk is an excellent source of activated carbon and has a honeycomb-like epidermis, veins, and basic tissues. Its unique skeleton additionally assists to provide the material a three-dimensional structure. A series of porous carbon materials were synthesized from the calyx husk of Physalis peruviana via KOH as an activator. The variation of micromorphology, structure, and electrochemical properties of PCC-T materials with activation temperature has been investigated. The PCC-800 material prepared at 800 °C has a surface oxygen content of 11.63%, a rich pore structure (micro-meso-macroporous), and a large specific surface area (2703.75 $ m^{2} $ $ g^{−1} $). In 6 M KOH, PCC-800 has a specific capacitance of 349.7 F $ g^{−1} $ at a current density of 0.5 A $ g^{−1} $ in a three-electrode system, and a capacitance retention of 78.9% even with a 40-fold increase in current density. The assembled symmetric supercapacitor achieved an energy density of 8.95 Wh $ kg^{−1} $ (250 W $ kg^{−1} $) in 6 M KOH and 17.56 Wh $ kg^{−1} $ (187 W $ kg^{−1} $) was obtained in 1 M $ Na_{2} $$ SO_{4} $ electrolyte in a two-electrode system. In addition, the capacitance is reduced by only 1.4% after 6,000 charge–discharge cycles at a current density of 8 A $ g^{−1} $. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
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container_issue	27
title_short	Oxygen self-doped physalis peruviana calyx husk-derived porous carbon for supercapacitors
url	https://dx.doi.org/10.1007/s10854-024-13563-8
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author2	Dong, Xingshen Xia, Yingjing Wang, Xueqin Liu, Yanxiu Qiao, Peng Zhang, Geng
author2Str	Dong, Xingshen Xia, Yingjing Wang, Xueqin Liu, Yanxiu Qiao, Peng Zhang, Geng
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doi_str	10.1007/s10854-024-13563-8
up_date	2024-10-07T07:44:03.023Z
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