N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol
For metal-free carbocatalysts, heteroatom doping and hierarchically porous structure are the significant factors to improve their catalytic performances. Herein, N-, P-co-doped hierarchically porous carbon fiber (NPC–2–800) was prepared by pyrolyzing bamboo pulp in combination with ($ NH_{4} $)2$ HP...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhang, Liyun [verfasserIn] Zhou, Weihai [verfasserIn] Cao, Yongle [verfasserIn] Zhang, Heng [verfasserIn] Zhu, Wancheng [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2024 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s), under exclusive licence to Korean Carbon Society 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Carbon Letters - Springer Nature Singapore, 2019, 34(2024), 8 vom: 12. Juni, Seite 2137-2148 |
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| Übergeordnetes Werk: |
volume:34 ; year:2024 ; number:8 ; day:12 ; month:06 ; pages:2137-2148 |
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| DOI / URN: |
10.1007/s42823-024-00758-6 |
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| Katalog-ID: |
SPR057759634 |
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| 245 | 1 | 0 | |a N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol |
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| 520 | |a For metal-free carbocatalysts, heteroatom doping and hierarchically porous structure are the significant factors to improve their catalytic performances. Herein, N-, P-co-doped hierarchically porous carbon fiber (NPC–2–800) was prepared by pyrolyzing bamboo pulp in combination with ($ NH_{4} $)2$ HPO_{4} $ and activator $ K_{2} $$ CO_{3} $. It was found that ($ NH_{4} $)2$ HPO_{4} $ not only provides N and P atoms, but also significantly affect the morphology and pore structure of the porous carbon. An appropriate dosage of ($ NH_{4} $)2$ HPO_{4} $ facilitates the formation of hierarchically porous carbon fiber in NPC-2–800. Whereas, the carbon fragments with only micropores were obtained in absence of ($ NH_{4} $)2$ HPO_{4} $. The hierarchical porosity and the co-doping of N and P atoms in the NPC-2–800 contribute to its outstanding catalytic performances in the 4-Nitrophenol (4-NP) reduction assisted by $ NaBH_{4} $. The NPC-2–800 exhibits an attractive turnover frequency (TOF) value of 4.29 × $ 10^{–4} $ mmol $ mg^{−1} $ $ min^{−1} $, a low activation energy (Ea) of 24.76 kJ/mol, and an acceptable recyclability for 7 cycles without obvious decrease in activity. Kinetics analyses suggest that the 4-NP reduction proceeds through the Langmuir–Hinshelwood model. In addition, the NPC-2–800 can also efficiently catalyze the 2-NP and 3-NP reduction. Moreover, in the real water body, the NPC-2–800 also showed superior catalytic activity to catalyze 4-NP reduction. This study provides an efficient catalyst for pollutant conversion and elimination as well as guidelines for designing versatile carbon-based catalysts. Graphical abstract | ||
| 650 | 4 | |a Heteroatom doping |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Biomass-derived carbon |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Hierarchically porous carbon |7 (dpeaa)DE-He213 | |
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| 700 | 1 | |a Cao, Yongle |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Heng |e verfasserin |4 aut | |
| 700 | 1 | |a Zhu, Wancheng |e verfasserin |4 aut | |
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10.1007/s42823-024-00758-6 doi (DE-627)SPR057759634 (SPR)s42823-024-00758-6-e DE-627 ger DE-627 rakwb eng Zhang, Liyun verfasserin aut N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Korean Carbon Society 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. For metal-free carbocatalysts, heteroatom doping and hierarchically porous structure are the significant factors to improve their catalytic performances. Herein, N-, P-co-doped hierarchically porous carbon fiber (NPC–2–800) was prepared by pyrolyzing bamboo pulp in combination with ($ NH_{4} $)2$ HPO_{4} $ and activator $ K_{2} $$ CO_{3} $. It was found that ($ NH_{4} $)2$ HPO_{4} $ not only provides N and P atoms, but also significantly affect the morphology and pore structure of the porous carbon. An appropriate dosage of ($ NH_{4} $)2$ HPO_{4} $ facilitates the formation of hierarchically porous carbon fiber in NPC-2–800. Whereas, the carbon fragments with only micropores were obtained in absence of ($ NH_{4} $)2$ HPO_{4} $. The hierarchical porosity and the co-doping of N and P atoms in the NPC-2–800 contribute to its outstanding catalytic performances in the 4-Nitrophenol (4-NP) reduction assisted by $ NaBH_{4} $. The NPC-2–800 exhibits an attractive turnover frequency (TOF) value of 4.29 × $ 10^{–4} $ mmol $ mg^{−1} $ $ min^{−1} $, a low activation energy (Ea) of 24.76 kJ/mol, and an acceptable recyclability for 7 cycles without obvious decrease in activity. Kinetics analyses suggest that the 4-NP reduction proceeds through the Langmuir–Hinshelwood model. In addition, the NPC-2–800 can also efficiently catalyze the 2-NP and 3-NP reduction. Moreover, in the real water body, the NPC-2–800 also showed superior catalytic activity to catalyze 4-NP reduction. This study provides an efficient catalyst for pollutant conversion and elimination as well as guidelines for designing versatile carbon-based catalysts. Graphical abstract Heteroatom doping (dpeaa)DE-He213 Biomass-derived carbon (dpeaa)DE-He213 Hierarchically porous carbon (dpeaa)DE-He213 Nitrophenol reduction (dpeaa)DE-He213 Zhou, Weihai verfasserin aut Cao, Yongle verfasserin aut Zhang, Heng verfasserin aut Zhu, Wancheng verfasserin aut Enthalten in Carbon Letters Springer Nature Singapore, 2019 34(2024), 8 vom: 12. Juni, Seite 2137-2148 (DE-627)1066515573 (DE-600)2964055-6 2233-4998 nnns volume:34 year:2024 number:8 day:12 month:06 pages:2137-2148 https://dx.doi.org/10.1007/s42823-024-00758-6 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2024 8 12 06 2137-2148 |
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10.1007/s42823-024-00758-6 doi (DE-627)SPR057759634 (SPR)s42823-024-00758-6-e DE-627 ger DE-627 rakwb eng Zhang, Liyun verfasserin aut N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Korean Carbon Society 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. For metal-free carbocatalysts, heteroatom doping and hierarchically porous structure are the significant factors to improve their catalytic performances. Herein, N-, P-co-doped hierarchically porous carbon fiber (NPC–2–800) was prepared by pyrolyzing bamboo pulp in combination with ($ NH_{4} $)2$ HPO_{4} $ and activator $ K_{2} $$ CO_{3} $. It was found that ($ NH_{4} $)2$ HPO_{4} $ not only provides N and P atoms, but also significantly affect the morphology and pore structure of the porous carbon. An appropriate dosage of ($ NH_{4} $)2$ HPO_{4} $ facilitates the formation of hierarchically porous carbon fiber in NPC-2–800. Whereas, the carbon fragments with only micropores were obtained in absence of ($ NH_{4} $)2$ HPO_{4} $. The hierarchical porosity and the co-doping of N and P atoms in the NPC-2–800 contribute to its outstanding catalytic performances in the 4-Nitrophenol (4-NP) reduction assisted by $ NaBH_{4} $. The NPC-2–800 exhibits an attractive turnover frequency (TOF) value of 4.29 × $ 10^{–4} $ mmol $ mg^{−1} $ $ min^{−1} $, a low activation energy (Ea) of 24.76 kJ/mol, and an acceptable recyclability for 7 cycles without obvious decrease in activity. Kinetics analyses suggest that the 4-NP reduction proceeds through the Langmuir–Hinshelwood model. In addition, the NPC-2–800 can also efficiently catalyze the 2-NP and 3-NP reduction. Moreover, in the real water body, the NPC-2–800 also showed superior catalytic activity to catalyze 4-NP reduction. This study provides an efficient catalyst for pollutant conversion and elimination as well as guidelines for designing versatile carbon-based catalysts. Graphical abstract Heteroatom doping (dpeaa)DE-He213 Biomass-derived carbon (dpeaa)DE-He213 Hierarchically porous carbon (dpeaa)DE-He213 Nitrophenol reduction (dpeaa)DE-He213 Zhou, Weihai verfasserin aut Cao, Yongle verfasserin aut Zhang, Heng verfasserin aut Zhu, Wancheng verfasserin aut Enthalten in Carbon Letters Springer Nature Singapore, 2019 34(2024), 8 vom: 12. Juni, Seite 2137-2148 (DE-627)1066515573 (DE-600)2964055-6 2233-4998 nnns volume:34 year:2024 number:8 day:12 month:06 pages:2137-2148 https://dx.doi.org/10.1007/s42823-024-00758-6 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2024 8 12 06 2137-2148 |
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10.1007/s42823-024-00758-6 doi (DE-627)SPR057759634 (SPR)s42823-024-00758-6-e DE-627 ger DE-627 rakwb eng Zhang, Liyun verfasserin aut N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Korean Carbon Society 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. For metal-free carbocatalysts, heteroatom doping and hierarchically porous structure are the significant factors to improve their catalytic performances. Herein, N-, P-co-doped hierarchically porous carbon fiber (NPC–2–800) was prepared by pyrolyzing bamboo pulp in combination with ($ NH_{4} $)2$ HPO_{4} $ and activator $ K_{2} $$ CO_{3} $. It was found that ($ NH_{4} $)2$ HPO_{4} $ not only provides N and P atoms, but also significantly affect the morphology and pore structure of the porous carbon. An appropriate dosage of ($ NH_{4} $)2$ HPO_{4} $ facilitates the formation of hierarchically porous carbon fiber in NPC-2–800. Whereas, the carbon fragments with only micropores were obtained in absence of ($ NH_{4} $)2$ HPO_{4} $. The hierarchical porosity and the co-doping of N and P atoms in the NPC-2–800 contribute to its outstanding catalytic performances in the 4-Nitrophenol (4-NP) reduction assisted by $ NaBH_{4} $. The NPC-2–800 exhibits an attractive turnover frequency (TOF) value of 4.29 × $ 10^{–4} $ mmol $ mg^{−1} $ $ min^{−1} $, a low activation energy (Ea) of 24.76 kJ/mol, and an acceptable recyclability for 7 cycles without obvious decrease in activity. Kinetics analyses suggest that the 4-NP reduction proceeds through the Langmuir–Hinshelwood model. In addition, the NPC-2–800 can also efficiently catalyze the 2-NP and 3-NP reduction. Moreover, in the real water body, the NPC-2–800 also showed superior catalytic activity to catalyze 4-NP reduction. This study provides an efficient catalyst for pollutant conversion and elimination as well as guidelines for designing versatile carbon-based catalysts. Graphical abstract Heteroatom doping (dpeaa)DE-He213 Biomass-derived carbon (dpeaa)DE-He213 Hierarchically porous carbon (dpeaa)DE-He213 Nitrophenol reduction (dpeaa)DE-He213 Zhou, Weihai verfasserin aut Cao, Yongle verfasserin aut Zhang, Heng verfasserin aut Zhu, Wancheng verfasserin aut Enthalten in Carbon Letters Springer Nature Singapore, 2019 34(2024), 8 vom: 12. Juni, Seite 2137-2148 (DE-627)1066515573 (DE-600)2964055-6 2233-4998 nnns volume:34 year:2024 number:8 day:12 month:06 pages:2137-2148 https://dx.doi.org/10.1007/s42823-024-00758-6 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2024 8 12 06 2137-2148 |
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10.1007/s42823-024-00758-6 doi (DE-627)SPR057759634 (SPR)s42823-024-00758-6-e DE-627 ger DE-627 rakwb eng Zhang, Liyun verfasserin aut N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Korean Carbon Society 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. For metal-free carbocatalysts, heteroatom doping and hierarchically porous structure are the significant factors to improve their catalytic performances. Herein, N-, P-co-doped hierarchically porous carbon fiber (NPC–2–800) was prepared by pyrolyzing bamboo pulp in combination with ($ NH_{4} $)2$ HPO_{4} $ and activator $ K_{2} $$ CO_{3} $. It was found that ($ NH_{4} $)2$ HPO_{4} $ not only provides N and P atoms, but also significantly affect the morphology and pore structure of the porous carbon. An appropriate dosage of ($ NH_{4} $)2$ HPO_{4} $ facilitates the formation of hierarchically porous carbon fiber in NPC-2–800. Whereas, the carbon fragments with only micropores were obtained in absence of ($ NH_{4} $)2$ HPO_{4} $. The hierarchical porosity and the co-doping of N and P atoms in the NPC-2–800 contribute to its outstanding catalytic performances in the 4-Nitrophenol (4-NP) reduction assisted by $ NaBH_{4} $. The NPC-2–800 exhibits an attractive turnover frequency (TOF) value of 4.29 × $ 10^{–4} $ mmol $ mg^{−1} $ $ min^{−1} $, a low activation energy (Ea) of 24.76 kJ/mol, and an acceptable recyclability for 7 cycles without obvious decrease in activity. Kinetics analyses suggest that the 4-NP reduction proceeds through the Langmuir–Hinshelwood model. In addition, the NPC-2–800 can also efficiently catalyze the 2-NP and 3-NP reduction. Moreover, in the real water body, the NPC-2–800 also showed superior catalytic activity to catalyze 4-NP reduction. This study provides an efficient catalyst for pollutant conversion and elimination as well as guidelines for designing versatile carbon-based catalysts. Graphical abstract Heteroatom doping (dpeaa)DE-He213 Biomass-derived carbon (dpeaa)DE-He213 Hierarchically porous carbon (dpeaa)DE-He213 Nitrophenol reduction (dpeaa)DE-He213 Zhou, Weihai verfasserin aut Cao, Yongle verfasserin aut Zhang, Heng verfasserin aut Zhu, Wancheng verfasserin aut Enthalten in Carbon Letters Springer Nature Singapore, 2019 34(2024), 8 vom: 12. Juni, Seite 2137-2148 (DE-627)1066515573 (DE-600)2964055-6 2233-4998 nnns volume:34 year:2024 number:8 day:12 month:06 pages:2137-2148 https://dx.doi.org/10.1007/s42823-024-00758-6 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2024 8 12 06 2137-2148 |
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10.1007/s42823-024-00758-6 doi (DE-627)SPR057759634 (SPR)s42823-024-00758-6-e DE-627 ger DE-627 rakwb eng Zhang, Liyun verfasserin aut N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Korean Carbon Society 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. For metal-free carbocatalysts, heteroatom doping and hierarchically porous structure are the significant factors to improve their catalytic performances. Herein, N-, P-co-doped hierarchically porous carbon fiber (NPC–2–800) was prepared by pyrolyzing bamboo pulp in combination with ($ NH_{4} $)2$ HPO_{4} $ and activator $ K_{2} $$ CO_{3} $. It was found that ($ NH_{4} $)2$ HPO_{4} $ not only provides N and P atoms, but also significantly affect the morphology and pore structure of the porous carbon. An appropriate dosage of ($ NH_{4} $)2$ HPO_{4} $ facilitates the formation of hierarchically porous carbon fiber in NPC-2–800. Whereas, the carbon fragments with only micropores were obtained in absence of ($ NH_{4} $)2$ HPO_{4} $. The hierarchical porosity and the co-doping of N and P atoms in the NPC-2–800 contribute to its outstanding catalytic performances in the 4-Nitrophenol (4-NP) reduction assisted by $ NaBH_{4} $. The NPC-2–800 exhibits an attractive turnover frequency (TOF) value of 4.29 × $ 10^{–4} $ mmol $ mg^{−1} $ $ min^{−1} $, a low activation energy (Ea) of 24.76 kJ/mol, and an acceptable recyclability for 7 cycles without obvious decrease in activity. Kinetics analyses suggest that the 4-NP reduction proceeds through the Langmuir–Hinshelwood model. In addition, the NPC-2–800 can also efficiently catalyze the 2-NP and 3-NP reduction. Moreover, in the real water body, the NPC-2–800 also showed superior catalytic activity to catalyze 4-NP reduction. This study provides an efficient catalyst for pollutant conversion and elimination as well as guidelines for designing versatile carbon-based catalysts. Graphical abstract Heteroatom doping (dpeaa)DE-He213 Biomass-derived carbon (dpeaa)DE-He213 Hierarchically porous carbon (dpeaa)DE-He213 Nitrophenol reduction (dpeaa)DE-He213 Zhou, Weihai verfasserin aut Cao, Yongle verfasserin aut Zhang, Heng verfasserin aut Zhu, Wancheng verfasserin aut Enthalten in Carbon Letters Springer Nature Singapore, 2019 34(2024), 8 vom: 12. Juni, Seite 2137-2148 (DE-627)1066515573 (DE-600)2964055-6 2233-4998 nnns volume:34 year:2024 number:8 day:12 month:06 pages:2137-2148 https://dx.doi.org/10.1007/s42823-024-00758-6 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 34 2024 8 12 06 2137-2148 |
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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">For metal-free carbocatalysts, heteroatom doping and hierarchically porous structure are the significant factors to improve their catalytic performances. Herein, N-, P-co-doped hierarchically porous carbon fiber (NPC–2–800) was prepared by pyrolyzing bamboo pulp in combination with ($ NH_{4} $)2$ HPO_{4} $ and activator $ K_{2} $$ CO_{3} $. It was found that ($ NH_{4} $)2$ HPO_{4} $ not only provides N and P atoms, but also significantly affect the morphology and pore structure of the porous carbon. An appropriate dosage of ($ NH_{4} $)2$ HPO_{4} $ facilitates the formation of hierarchically porous carbon fiber in NPC-2–800. Whereas, the carbon fragments with only micropores were obtained in absence of ($ NH_{4} $)2$ HPO_{4} $. The hierarchical porosity and the co-doping of N and P atoms in the NPC-2–800 contribute to its outstanding catalytic performances in the 4-Nitrophenol (4-NP) reduction assisted by $ NaBH_{4} $. The NPC-2–800 exhibits an attractive turnover frequency (TOF) value of 4.29 × $ 10^{–4} $ mmol $ mg^{−1} $ $ min^{−1} $, a low activation energy (Ea) of 24.76 kJ/mol, and an acceptable recyclability for 7 cycles without obvious decrease in activity. Kinetics analyses suggest that the 4-NP reduction proceeds through the Langmuir–Hinshelwood model. In addition, the NPC-2–800 can also efficiently catalyze the 2-NP and 3-NP reduction. Moreover, in the real water body, the NPC-2–800 also showed superior catalytic activity to catalyze 4-NP reduction. This study provides an efficient catalyst for pollutant conversion and elimination as well as guidelines for designing versatile carbon-based catalysts. Graphical abstract</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Heteroatom doping</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Biomass-derived carbon</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hierarchically porous carbon</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nitrophenol reduction</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhou, Weihai</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Cao, Yongle</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Heng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhu, Wancheng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Carbon Letters</subfield><subfield code="d">Springer Nature Singapore, 2019</subfield><subfield code="g">34(2024), 8 vom: 12. 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|
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Zhang, Liyun |
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Zhang, Liyun misc Heteroatom doping misc Biomass-derived carbon misc Hierarchically porous carbon misc Nitrophenol reduction N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol |
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N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol Heteroatom doping (dpeaa)DE-He213 Biomass-derived carbon (dpeaa)DE-He213 Hierarchically porous carbon (dpeaa)DE-He213 Nitrophenol reduction (dpeaa)DE-He213 |
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misc Heteroatom doping misc Biomass-derived carbon misc Hierarchically porous carbon misc Nitrophenol reduction |
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misc Heteroatom doping misc Biomass-derived carbon misc Hierarchically porous carbon misc Nitrophenol reduction |
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N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol |
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N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol |
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Zhang, Liyun Zhou, Weihai Cao, Yongle Zhang, Heng Zhu, Wancheng |
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n-, p-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol |
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N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol |
| abstract |
For metal-free carbocatalysts, heteroatom doping and hierarchically porous structure are the significant factors to improve their catalytic performances. Herein, N-, P-co-doped hierarchically porous carbon fiber (NPC–2–800) was prepared by pyrolyzing bamboo pulp in combination with ($ NH_{4} $)2$ HPO_{4} $ and activator $ K_{2} $$ CO_{3} $. It was found that ($ NH_{4} $)2$ HPO_{4} $ not only provides N and P atoms, but also significantly affect the morphology and pore structure of the porous carbon. An appropriate dosage of ($ NH_{4} $)2$ HPO_{4} $ facilitates the formation of hierarchically porous carbon fiber in NPC-2–800. Whereas, the carbon fragments with only micropores were obtained in absence of ($ NH_{4} $)2$ HPO_{4} $. The hierarchical porosity and the co-doping of N and P atoms in the NPC-2–800 contribute to its outstanding catalytic performances in the 4-Nitrophenol (4-NP) reduction assisted by $ NaBH_{4} $. The NPC-2–800 exhibits an attractive turnover frequency (TOF) value of 4.29 × $ 10^{–4} $ mmol $ mg^{−1} $ $ min^{−1} $, a low activation energy (Ea) of 24.76 kJ/mol, and an acceptable recyclability for 7 cycles without obvious decrease in activity. Kinetics analyses suggest that the 4-NP reduction proceeds through the Langmuir–Hinshelwood model. In addition, the NPC-2–800 can also efficiently catalyze the 2-NP and 3-NP reduction. Moreover, in the real water body, the NPC-2–800 also showed superior catalytic activity to catalyze 4-NP reduction. This study provides an efficient catalyst for pollutant conversion and elimination as well as guidelines for designing versatile carbon-based catalysts. Graphical abstract © The Author(s), under exclusive licence to Korean Carbon Society 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
For metal-free carbocatalysts, heteroatom doping and hierarchically porous structure are the significant factors to improve their catalytic performances. Herein, N-, P-co-doped hierarchically porous carbon fiber (NPC–2–800) was prepared by pyrolyzing bamboo pulp in combination with ($ NH_{4} $)2$ HPO_{4} $ and activator $ K_{2} $$ CO_{3} $. It was found that ($ NH_{4} $)2$ HPO_{4} $ not only provides N and P atoms, but also significantly affect the morphology and pore structure of the porous carbon. An appropriate dosage of ($ NH_{4} $)2$ HPO_{4} $ facilitates the formation of hierarchically porous carbon fiber in NPC-2–800. Whereas, the carbon fragments with only micropores were obtained in absence of ($ NH_{4} $)2$ HPO_{4} $. The hierarchical porosity and the co-doping of N and P atoms in the NPC-2–800 contribute to its outstanding catalytic performances in the 4-Nitrophenol (4-NP) reduction assisted by $ NaBH_{4} $. The NPC-2–800 exhibits an attractive turnover frequency (TOF) value of 4.29 × $ 10^{–4} $ mmol $ mg^{−1} $ $ min^{−1} $, a low activation energy (Ea) of 24.76 kJ/mol, and an acceptable recyclability for 7 cycles without obvious decrease in activity. Kinetics analyses suggest that the 4-NP reduction proceeds through the Langmuir–Hinshelwood model. In addition, the NPC-2–800 can also efficiently catalyze the 2-NP and 3-NP reduction. Moreover, in the real water body, the NPC-2–800 also showed superior catalytic activity to catalyze 4-NP reduction. This study provides an efficient catalyst for pollutant conversion and elimination as well as guidelines for designing versatile carbon-based catalysts. Graphical abstract © The Author(s), under exclusive licence to Korean Carbon Society 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
For metal-free carbocatalysts, heteroatom doping and hierarchically porous structure are the significant factors to improve their catalytic performances. Herein, N-, P-co-doped hierarchically porous carbon fiber (NPC–2–800) was prepared by pyrolyzing bamboo pulp in combination with ($ NH_{4} $)2$ HPO_{4} $ and activator $ K_{2} $$ CO_{3} $. It was found that ($ NH_{4} $)2$ HPO_{4} $ not only provides N and P atoms, but also significantly affect the morphology and pore structure of the porous carbon. An appropriate dosage of ($ NH_{4} $)2$ HPO_{4} $ facilitates the formation of hierarchically porous carbon fiber in NPC-2–800. Whereas, the carbon fragments with only micropores were obtained in absence of ($ NH_{4} $)2$ HPO_{4} $. The hierarchical porosity and the co-doping of N and P atoms in the NPC-2–800 contribute to its outstanding catalytic performances in the 4-Nitrophenol (4-NP) reduction assisted by $ NaBH_{4} $. The NPC-2–800 exhibits an attractive turnover frequency (TOF) value of 4.29 × $ 10^{–4} $ mmol $ mg^{−1} $ $ min^{−1} $, a low activation energy (Ea) of 24.76 kJ/mol, and an acceptable recyclability for 7 cycles without obvious decrease in activity. Kinetics analyses suggest that the 4-NP reduction proceeds through the Langmuir–Hinshelwood model. In addition, the NPC-2–800 can also efficiently catalyze the 2-NP and 3-NP reduction. Moreover, in the real water body, the NPC-2–800 also showed superior catalytic activity to catalyze 4-NP reduction. This study provides an efficient catalyst for pollutant conversion and elimination as well as guidelines for designing versatile carbon-based catalysts. Graphical abstract © The Author(s), under exclusive licence to Korean Carbon Society 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| container_issue |
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| title_short |
N-, P-co-doped hierarchically porous carbon fiber derived from bamboo pulp as efficient carbocatalyst for reduction of 4-nitrophenol |
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https://dx.doi.org/10.1007/s42823-024-00758-6 |
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Zhou, Weihai Cao, Yongle Zhang, Heng Zhu, Wancheng |
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Zhou, Weihai Cao, Yongle Zhang, Heng Zhu, Wancheng |
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10.1007/s42823-024-00758-6 |
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2024-10-12T04:47:51.760Z |
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| score |
7.400218 |