Multiple metal sources in polymetallic W-Sn ore deposits revealed by mercury stable isotopes
Abstract Granite-related W-Sn ore systems are commonly associated with coeval Pb-Zn mineralization. It remains unclear whether these metals are derived from the same sources or not. Mercury (Hg) is a common minor component in such systems. Hg isotopes undergo unique mass-independent fractionation (e...
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| Autor*in: |
Tian, Zhendong [verfasserIn] Lehmann, Bernd [verfasserIn] Deng, Changzhou [verfasserIn] Zhang, Xingchun [verfasserIn] Luo, Anbo [verfasserIn] Chen, Yinghua [verfasserIn] Yin, Runsheng [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2024 |
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| Schlagwörter: |
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| Anmerkung: |
© Science China Press 2024 |
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| Übergeordnetes Werk: |
Enthalten in: Science China / Earth sciences - Science China Press, 2010, 67(2024), 11 vom: 08. Okt., Seite 3465-3475 |
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| Übergeordnetes Werk: |
volume:67 ; year:2024 ; number:11 ; day:08 ; month:10 ; pages:3465-3475 |
| Links: |
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| DOI / URN: |
10.1007/s11430-024-1380-4 |
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| Katalog-ID: |
SPR058037233 |
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| 520 | |a Abstract Granite-related W-Sn ore systems are commonly associated with coeval Pb-Zn mineralization. It remains unclear whether these metals are derived from the same sources or not. Mercury (Hg) is a common minor component in such systems. Hg isotopes undergo unique mass-independent fractionation (expressed as $ Δ^{199} $Hg values), which is mainly generated during Hg photochemical reactions on Earth’s surface and not affected by magmatic-hydrothermal processes, offering an excellent opportunity to trace metal sources in hydrothermal systems. We observed near-zero $ Δ^{199} $Hg values in wolframite (−0.10‰ to 0.08‰, n=11), and in skarn- (−0.17‰ to 0.12‰, n=48) and greisen-type (−0.12‰ to 0.10‰, n=11) bulk tin-tungsten ore from eight major ore deposits in South China. These values are identical to those of coeval highly evolved granites (−0.13‰ to 0.12‰, n=49), supporting that Hg in W-Sn ores were sourced from granite. However, sulfides (e.g., pyrite, chalcopyrite, arsenopyrite, galena, and sphalerite) in these deposits exhibit negative to near-zero Δ199Hg values (−0.42‰ to 0.09‰, n=124), which indicates a contribution of Hg and by inference other metals from both Precambrian basement rocks ($ Δ^{199} $Hg<0) and ore-related granites. The study demonstrates that multiple sources of metals were involved in the formation of the polymetallic W-Sn deposits, and further highlights that extraction of metals from basement rocks may be a critical control on the formation of economically important mineralization of base metal sulfides (e.g., Pb, Zn) in granite-related magmatic-hydrothermal systems. | ||
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10.1007/s11430-024-1380-4 doi (DE-627)SPR058037233 (SPR)s11430-024-1380-4-e DE-627 ger DE-627 rakwb eng 550 VZ ASIEN DE-1a fid 6,25 ssgn Tian, Zhendong verfasserin aut Multiple metal sources in polymetallic W-Sn ore deposits revealed by mercury stable isotopes 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press 2024 Abstract Granite-related W-Sn ore systems are commonly associated with coeval Pb-Zn mineralization. It remains unclear whether these metals are derived from the same sources or not. Mercury (Hg) is a common minor component in such systems. Hg isotopes undergo unique mass-independent fractionation (expressed as $ Δ^{199} $Hg values), which is mainly generated during Hg photochemical reactions on Earth’s surface and not affected by magmatic-hydrothermal processes, offering an excellent opportunity to trace metal sources in hydrothermal systems. We observed near-zero $ Δ^{199} $Hg values in wolframite (−0.10‰ to 0.08‰, n=11), and in skarn- (−0.17‰ to 0.12‰, n=48) and greisen-type (−0.12‰ to 0.10‰, n=11) bulk tin-tungsten ore from eight major ore deposits in South China. These values are identical to those of coeval highly evolved granites (−0.13‰ to 0.12‰, n=49), supporting that Hg in W-Sn ores were sourced from granite. However, sulfides (e.g., pyrite, chalcopyrite, arsenopyrite, galena, and sphalerite) in these deposits exhibit negative to near-zero Δ199Hg values (−0.42‰ to 0.09‰, n=124), which indicates a contribution of Hg and by inference other metals from both Precambrian basement rocks ($ Δ^{199} $Hg<0) and ore-related granites. The study demonstrates that multiple sources of metals were involved in the formation of the polymetallic W-Sn deposits, and further highlights that extraction of metals from basement rocks may be a critical control on the formation of economically important mineralization of base metal sulfides (e.g., Pb, Zn) in granite-related magmatic-hydrothermal systems. Tin-tungsten deposit (dpeaa)DE-He213 Mercury isotope (dpeaa)DE-He213 Metal source (dpeaa)DE-He213 Metal zonation (dpeaa)DE-He213 South China (dpeaa)DE-He213 Lehmann, Bernd verfasserin aut Deng, Changzhou verfasserin aut Zhang, Xingchun verfasserin aut Luo, Anbo verfasserin aut Chen, Yinghua verfasserin aut Yin, Runsheng verfasserin aut Enthalten in Science China / Earth sciences Science China Press, 2010 67(2024), 11 vom: 08. Okt., Seite 3465-3475 Online-Ressource (DE-627)623182726 (DE-600)2546528-4 (DE-576)321587324 1869-1897 nnns volume:67 year:2024 number:11 day:08 month:10 pages:3465-3475 https://dx.doi.org/10.1007/s11430-024-1380-4 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER FID-ASIEN SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4029 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4311 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4315 GBV_ILN_4318 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4598 GBV_ILN_4700 AR 67 2024 11 08 10 3465-3475 |
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10.1007/s11430-024-1380-4 doi (DE-627)SPR058037233 (SPR)s11430-024-1380-4-e DE-627 ger DE-627 rakwb eng 550 VZ ASIEN DE-1a fid 6,25 ssgn Tian, Zhendong verfasserin aut Multiple metal sources in polymetallic W-Sn ore deposits revealed by mercury stable isotopes 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press 2024 Abstract Granite-related W-Sn ore systems are commonly associated with coeval Pb-Zn mineralization. It remains unclear whether these metals are derived from the same sources or not. Mercury (Hg) is a common minor component in such systems. Hg isotopes undergo unique mass-independent fractionation (expressed as $ Δ^{199} $Hg values), which is mainly generated during Hg photochemical reactions on Earth’s surface and not affected by magmatic-hydrothermal processes, offering an excellent opportunity to trace metal sources in hydrothermal systems. We observed near-zero $ Δ^{199} $Hg values in wolframite (−0.10‰ to 0.08‰, n=11), and in skarn- (−0.17‰ to 0.12‰, n=48) and greisen-type (−0.12‰ to 0.10‰, n=11) bulk tin-tungsten ore from eight major ore deposits in South China. These values are identical to those of coeval highly evolved granites (−0.13‰ to 0.12‰, n=49), supporting that Hg in W-Sn ores were sourced from granite. However, sulfides (e.g., pyrite, chalcopyrite, arsenopyrite, galena, and sphalerite) in these deposits exhibit negative to near-zero Δ199Hg values (−0.42‰ to 0.09‰, n=124), which indicates a contribution of Hg and by inference other metals from both Precambrian basement rocks ($ Δ^{199} $Hg<0) and ore-related granites. The study demonstrates that multiple sources of metals were involved in the formation of the polymetallic W-Sn deposits, and further highlights that extraction of metals from basement rocks may be a critical control on the formation of economically important mineralization of base metal sulfides (e.g., Pb, Zn) in granite-related magmatic-hydrothermal systems. Tin-tungsten deposit (dpeaa)DE-He213 Mercury isotope (dpeaa)DE-He213 Metal source (dpeaa)DE-He213 Metal zonation (dpeaa)DE-He213 South China (dpeaa)DE-He213 Lehmann, Bernd verfasserin aut Deng, Changzhou verfasserin aut Zhang, Xingchun verfasserin aut Luo, Anbo verfasserin aut Chen, Yinghua verfasserin aut Yin, Runsheng verfasserin aut Enthalten in Science China / Earth sciences Science China Press, 2010 67(2024), 11 vom: 08. Okt., Seite 3465-3475 Online-Ressource (DE-627)623182726 (DE-600)2546528-4 (DE-576)321587324 1869-1897 nnns volume:67 year:2024 number:11 day:08 month:10 pages:3465-3475 https://dx.doi.org/10.1007/s11430-024-1380-4 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER FID-ASIEN SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4029 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4311 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4315 GBV_ILN_4318 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4598 GBV_ILN_4700 AR 67 2024 11 08 10 3465-3475 |
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10.1007/s11430-024-1380-4 doi (DE-627)SPR058037233 (SPR)s11430-024-1380-4-e DE-627 ger DE-627 rakwb eng 550 VZ ASIEN DE-1a fid 6,25 ssgn Tian, Zhendong verfasserin aut Multiple metal sources in polymetallic W-Sn ore deposits revealed by mercury stable isotopes 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press 2024 Abstract Granite-related W-Sn ore systems are commonly associated with coeval Pb-Zn mineralization. It remains unclear whether these metals are derived from the same sources or not. Mercury (Hg) is a common minor component in such systems. Hg isotopes undergo unique mass-independent fractionation (expressed as $ Δ^{199} $Hg values), which is mainly generated during Hg photochemical reactions on Earth’s surface and not affected by magmatic-hydrothermal processes, offering an excellent opportunity to trace metal sources in hydrothermal systems. We observed near-zero $ Δ^{199} $Hg values in wolframite (−0.10‰ to 0.08‰, n=11), and in skarn- (−0.17‰ to 0.12‰, n=48) and greisen-type (−0.12‰ to 0.10‰, n=11) bulk tin-tungsten ore from eight major ore deposits in South China. These values are identical to those of coeval highly evolved granites (−0.13‰ to 0.12‰, n=49), supporting that Hg in W-Sn ores were sourced from granite. However, sulfides (e.g., pyrite, chalcopyrite, arsenopyrite, galena, and sphalerite) in these deposits exhibit negative to near-zero Δ199Hg values (−0.42‰ to 0.09‰, n=124), which indicates a contribution of Hg and by inference other metals from both Precambrian basement rocks ($ Δ^{199} $Hg<0) and ore-related granites. The study demonstrates that multiple sources of metals were involved in the formation of the polymetallic W-Sn deposits, and further highlights that extraction of metals from basement rocks may be a critical control on the formation of economically important mineralization of base metal sulfides (e.g., Pb, Zn) in granite-related magmatic-hydrothermal systems. Tin-tungsten deposit (dpeaa)DE-He213 Mercury isotope (dpeaa)DE-He213 Metal source (dpeaa)DE-He213 Metal zonation (dpeaa)DE-He213 South China (dpeaa)DE-He213 Lehmann, Bernd verfasserin aut Deng, Changzhou verfasserin aut Zhang, Xingchun verfasserin aut Luo, Anbo verfasserin aut Chen, Yinghua verfasserin aut Yin, Runsheng verfasserin aut Enthalten in Science China / Earth sciences Science China Press, 2010 67(2024), 11 vom: 08. Okt., Seite 3465-3475 Online-Ressource (DE-627)623182726 (DE-600)2546528-4 (DE-576)321587324 1869-1897 nnns volume:67 year:2024 number:11 day:08 month:10 pages:3465-3475 https://dx.doi.org/10.1007/s11430-024-1380-4 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER FID-ASIEN SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4029 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4311 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4315 GBV_ILN_4318 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4598 GBV_ILN_4700 AR 67 2024 11 08 10 3465-3475 |
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10.1007/s11430-024-1380-4 doi (DE-627)SPR058037233 (SPR)s11430-024-1380-4-e DE-627 ger DE-627 rakwb eng 550 VZ ASIEN DE-1a fid 6,25 ssgn Tian, Zhendong verfasserin aut Multiple metal sources in polymetallic W-Sn ore deposits revealed by mercury stable isotopes 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press 2024 Abstract Granite-related W-Sn ore systems are commonly associated with coeval Pb-Zn mineralization. It remains unclear whether these metals are derived from the same sources or not. Mercury (Hg) is a common minor component in such systems. Hg isotopes undergo unique mass-independent fractionation (expressed as $ Δ^{199} $Hg values), which is mainly generated during Hg photochemical reactions on Earth’s surface and not affected by magmatic-hydrothermal processes, offering an excellent opportunity to trace metal sources in hydrothermal systems. We observed near-zero $ Δ^{199} $Hg values in wolframite (−0.10‰ to 0.08‰, n=11), and in skarn- (−0.17‰ to 0.12‰, n=48) and greisen-type (−0.12‰ to 0.10‰, n=11) bulk tin-tungsten ore from eight major ore deposits in South China. These values are identical to those of coeval highly evolved granites (−0.13‰ to 0.12‰, n=49), supporting that Hg in W-Sn ores were sourced from granite. However, sulfides (e.g., pyrite, chalcopyrite, arsenopyrite, galena, and sphalerite) in these deposits exhibit negative to near-zero Δ199Hg values (−0.42‰ to 0.09‰, n=124), which indicates a contribution of Hg and by inference other metals from both Precambrian basement rocks ($ Δ^{199} $Hg<0) and ore-related granites. The study demonstrates that multiple sources of metals were involved in the formation of the polymetallic W-Sn deposits, and further highlights that extraction of metals from basement rocks may be a critical control on the formation of economically important mineralization of base metal sulfides (e.g., Pb, Zn) in granite-related magmatic-hydrothermal systems. Tin-tungsten deposit (dpeaa)DE-He213 Mercury isotope (dpeaa)DE-He213 Metal source (dpeaa)DE-He213 Metal zonation (dpeaa)DE-He213 South China (dpeaa)DE-He213 Lehmann, Bernd verfasserin aut Deng, Changzhou verfasserin aut Zhang, Xingchun verfasserin aut Luo, Anbo verfasserin aut Chen, Yinghua verfasserin aut Yin, Runsheng verfasserin aut Enthalten in Science China / Earth sciences Science China Press, 2010 67(2024), 11 vom: 08. Okt., Seite 3465-3475 Online-Ressource (DE-627)623182726 (DE-600)2546528-4 (DE-576)321587324 1869-1897 nnns volume:67 year:2024 number:11 day:08 month:10 pages:3465-3475 https://dx.doi.org/10.1007/s11430-024-1380-4 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER FID-ASIEN SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4029 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4311 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4315 GBV_ILN_4318 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4598 GBV_ILN_4700 AR 67 2024 11 08 10 3465-3475 |
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10.1007/s11430-024-1380-4 doi (DE-627)SPR058037233 (SPR)s11430-024-1380-4-e DE-627 ger DE-627 rakwb eng 550 VZ ASIEN DE-1a fid 6,25 ssgn Tian, Zhendong verfasserin aut Multiple metal sources in polymetallic W-Sn ore deposits revealed by mercury stable isotopes 2024 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press 2024 Abstract Granite-related W-Sn ore systems are commonly associated with coeval Pb-Zn mineralization. It remains unclear whether these metals are derived from the same sources or not. Mercury (Hg) is a common minor component in such systems. Hg isotopes undergo unique mass-independent fractionation (expressed as $ Δ^{199} $Hg values), which is mainly generated during Hg photochemical reactions on Earth’s surface and not affected by magmatic-hydrothermal processes, offering an excellent opportunity to trace metal sources in hydrothermal systems. We observed near-zero $ Δ^{199} $Hg values in wolframite (−0.10‰ to 0.08‰, n=11), and in skarn- (−0.17‰ to 0.12‰, n=48) and greisen-type (−0.12‰ to 0.10‰, n=11) bulk tin-tungsten ore from eight major ore deposits in South China. These values are identical to those of coeval highly evolved granites (−0.13‰ to 0.12‰, n=49), supporting that Hg in W-Sn ores were sourced from granite. However, sulfides (e.g., pyrite, chalcopyrite, arsenopyrite, galena, and sphalerite) in these deposits exhibit negative to near-zero Δ199Hg values (−0.42‰ to 0.09‰, n=124), which indicates a contribution of Hg and by inference other metals from both Precambrian basement rocks ($ Δ^{199} $Hg<0) and ore-related granites. The study demonstrates that multiple sources of metals were involved in the formation of the polymetallic W-Sn deposits, and further highlights that extraction of metals from basement rocks may be a critical control on the formation of economically important mineralization of base metal sulfides (e.g., Pb, Zn) in granite-related magmatic-hydrothermal systems. Tin-tungsten deposit (dpeaa)DE-He213 Mercury isotope (dpeaa)DE-He213 Metal source (dpeaa)DE-He213 Metal zonation (dpeaa)DE-He213 South China (dpeaa)DE-He213 Lehmann, Bernd verfasserin aut Deng, Changzhou verfasserin aut Zhang, Xingchun verfasserin aut Luo, Anbo verfasserin aut Chen, Yinghua verfasserin aut Yin, Runsheng verfasserin aut Enthalten in Science China / Earth sciences Science China Press, 2010 67(2024), 11 vom: 08. Okt., Seite 3465-3475 Online-Ressource (DE-627)623182726 (DE-600)2546528-4 (DE-576)321587324 1869-1897 nnns volume:67 year:2024 number:11 day:08 month:10 pages:3465-3475 https://dx.doi.org/10.1007/s11430-024-1380-4 X:SPRINGER Resolving-System lizenzpflichtig Volltext SYSFLAG_0 GBV_SPRINGER FID-ASIEN SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_72 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2574 GBV_ILN_4029 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4155 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4311 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4315 GBV_ILN_4318 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4598 GBV_ILN_4700 AR 67 2024 11 08 10 3465-3475 |
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Enthalten in Science China / Earth sciences 67(2024), 11 vom: 08. Okt., Seite 3465-3475 volume:67 year:2024 number:11 day:08 month:10 pages:3465-3475 |
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Tian, Zhendong @@aut@@ Lehmann, Bernd @@aut@@ Deng, Changzhou @@aut@@ Zhang, Xingchun @@aut@@ Luo, Anbo @@aut@@ Chen, Yinghua @@aut@@ Yin, Runsheng @@aut@@ |
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Tian, Zhendong |
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Tian, Zhendong ddc 550 fid ASIEN ssgn 6,25 misc Tin-tungsten deposit misc Mercury isotope misc Metal source misc Metal zonation misc South China Multiple metal sources in polymetallic W-Sn ore deposits revealed by mercury stable isotopes |
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550 VZ ASIEN DE-1a fid 6,25 ssgn Multiple metal sources in polymetallic W-Sn ore deposits revealed by mercury stable isotopes Tin-tungsten deposit (dpeaa)DE-He213 Mercury isotope (dpeaa)DE-He213 Metal source (dpeaa)DE-He213 Metal zonation (dpeaa)DE-He213 South China (dpeaa)DE-He213 |
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ddc 550 fid ASIEN ssgn 6,25 misc Tin-tungsten deposit misc Mercury isotope misc Metal source misc Metal zonation misc South China |
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ddc 550 fid ASIEN ssgn 6,25 misc Tin-tungsten deposit misc Mercury isotope misc Metal source misc Metal zonation misc South China |
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Multiple metal sources in polymetallic W-Sn ore deposits revealed by mercury stable isotopes |
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Multiple metal sources in polymetallic W-Sn ore deposits revealed by mercury stable isotopes |
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Tian, Zhendong Lehmann, Bernd Deng, Changzhou Zhang, Xingchun Luo, Anbo Chen, Yinghua Yin, Runsheng |
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multiple metal sources in polymetallic w-sn ore deposits revealed by mercury stable isotopes |
| title_auth |
Multiple metal sources in polymetallic W-Sn ore deposits revealed by mercury stable isotopes |
| abstract |
Abstract Granite-related W-Sn ore systems are commonly associated with coeval Pb-Zn mineralization. It remains unclear whether these metals are derived from the same sources or not. Mercury (Hg) is a common minor component in such systems. Hg isotopes undergo unique mass-independent fractionation (expressed as $ Δ^{199} $Hg values), which is mainly generated during Hg photochemical reactions on Earth’s surface and not affected by magmatic-hydrothermal processes, offering an excellent opportunity to trace metal sources in hydrothermal systems. We observed near-zero $ Δ^{199} $Hg values in wolframite (−0.10‰ to 0.08‰, n=11), and in skarn- (−0.17‰ to 0.12‰, n=48) and greisen-type (−0.12‰ to 0.10‰, n=11) bulk tin-tungsten ore from eight major ore deposits in South China. These values are identical to those of coeval highly evolved granites (−0.13‰ to 0.12‰, n=49), supporting that Hg in W-Sn ores were sourced from granite. However, sulfides (e.g., pyrite, chalcopyrite, arsenopyrite, galena, and sphalerite) in these deposits exhibit negative to near-zero Δ199Hg values (−0.42‰ to 0.09‰, n=124), which indicates a contribution of Hg and by inference other metals from both Precambrian basement rocks ($ Δ^{199} $Hg<0) and ore-related granites. The study demonstrates that multiple sources of metals were involved in the formation of the polymetallic W-Sn deposits, and further highlights that extraction of metals from basement rocks may be a critical control on the formation of economically important mineralization of base metal sulfides (e.g., Pb, Zn) in granite-related magmatic-hydrothermal systems. © Science China Press 2024 |
| abstractGer |
Abstract Granite-related W-Sn ore systems are commonly associated with coeval Pb-Zn mineralization. It remains unclear whether these metals are derived from the same sources or not. Mercury (Hg) is a common minor component in such systems. Hg isotopes undergo unique mass-independent fractionation (expressed as $ Δ^{199} $Hg values), which is mainly generated during Hg photochemical reactions on Earth’s surface and not affected by magmatic-hydrothermal processes, offering an excellent opportunity to trace metal sources in hydrothermal systems. We observed near-zero $ Δ^{199} $Hg values in wolframite (−0.10‰ to 0.08‰, n=11), and in skarn- (−0.17‰ to 0.12‰, n=48) and greisen-type (−0.12‰ to 0.10‰, n=11) bulk tin-tungsten ore from eight major ore deposits in South China. These values are identical to those of coeval highly evolved granites (−0.13‰ to 0.12‰, n=49), supporting that Hg in W-Sn ores were sourced from granite. However, sulfides (e.g., pyrite, chalcopyrite, arsenopyrite, galena, and sphalerite) in these deposits exhibit negative to near-zero Δ199Hg values (−0.42‰ to 0.09‰, n=124), which indicates a contribution of Hg and by inference other metals from both Precambrian basement rocks ($ Δ^{199} $Hg<0) and ore-related granites. The study demonstrates that multiple sources of metals were involved in the formation of the polymetallic W-Sn deposits, and further highlights that extraction of metals from basement rocks may be a critical control on the formation of economically important mineralization of base metal sulfides (e.g., Pb, Zn) in granite-related magmatic-hydrothermal systems. © Science China Press 2024 |
| abstract_unstemmed |
Abstract Granite-related W-Sn ore systems are commonly associated with coeval Pb-Zn mineralization. It remains unclear whether these metals are derived from the same sources or not. Mercury (Hg) is a common minor component in such systems. Hg isotopes undergo unique mass-independent fractionation (expressed as $ Δ^{199} $Hg values), which is mainly generated during Hg photochemical reactions on Earth’s surface and not affected by magmatic-hydrothermal processes, offering an excellent opportunity to trace metal sources in hydrothermal systems. We observed near-zero $ Δ^{199} $Hg values in wolframite (−0.10‰ to 0.08‰, n=11), and in skarn- (−0.17‰ to 0.12‰, n=48) and greisen-type (−0.12‰ to 0.10‰, n=11) bulk tin-tungsten ore from eight major ore deposits in South China. These values are identical to those of coeval highly evolved granites (−0.13‰ to 0.12‰, n=49), supporting that Hg in W-Sn ores were sourced from granite. However, sulfides (e.g., pyrite, chalcopyrite, arsenopyrite, galena, and sphalerite) in these deposits exhibit negative to near-zero Δ199Hg values (−0.42‰ to 0.09‰, n=124), which indicates a contribution of Hg and by inference other metals from both Precambrian basement rocks ($ Δ^{199} $Hg<0) and ore-related granites. The study demonstrates that multiple sources of metals were involved in the formation of the polymetallic W-Sn deposits, and further highlights that extraction of metals from basement rocks may be a critical control on the formation of economically important mineralization of base metal sulfides (e.g., Pb, Zn) in granite-related magmatic-hydrothermal systems. © Science China Press 2024 |
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Multiple metal sources in polymetallic W-Sn ore deposits revealed by mercury stable isotopes |
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https://dx.doi.org/10.1007/s11430-024-1380-4 |
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Lehmann, Bernd Deng, Changzhou Zhang, Xingchun Luo, Anbo Chen, Yinghua Yin, Runsheng |
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2024-10-25T04:56:21.662Z |
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