Electrocatalytic and morphological effects of antimony adsorbates on deposition of gold
The electrodeposition of Au was studied in the presence of the Sb adsorbates. Large catalytic and morphological effects were found. A deposition of Au is shifted by 250 mV to more positive potentials. The nucleation of Au changes from instantaneous in the absence of Sb, into a progressive one in its...
Ausführliche Beschreibung
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E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1988 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Electrochimica Acta - Amsterdam : Elsevier, 33(1988), 1, Seite 103-108 |
| Übergeordnetes Werk: |
volume:33 ; year:1988 ; number:1 ; pages:103-108 |
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| 520 | |a The electrodeposition of Au was studied in the presence of the Sb adsorbates. Large catalytic and morphological effects were found. A deposition of Au is shifted by 250 mV to more positive potentials. The nucleation of Au changes from instantaneous in the absence of Sb, into a progressive one in its presence. The catalytic effects of Sb have been explained by its influence on adsorption of CN^--containing species, which suppresses the selfinhibition of this reaction. It has been clearly shown that the adatoms of Sb cannot play a role of nucleation sites, which was proposed earlier as a cause of catalytic effects. No evidence of incorporation of Sb into a deposit was found. | ||
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(DE-627)NLEJ173955614 (DE-599)GBVNLZ173955614 DE-627 ger DE-627 rakwb eng Electrocatalytic and morphological effects of antimony adsorbates on deposition of gold 1988 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The electrodeposition of Au was studied in the presence of the Sb adsorbates. Large catalytic and morphological effects were found. A deposition of Au is shifted by 250 mV to more positive potentials. The nucleation of Au changes from instantaneous in the absence of Sb, into a progressive one in its presence. The catalytic effects of Sb have been explained by its influence on adsorption of CN^--containing species, which suppresses the selfinhibition of this reaction. It has been clearly shown that the adatoms of Sb cannot play a role of nucleation sites, which was proposed earlier as a cause of catalytic effects. No evidence of incorporation of Sb into a deposit was found. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Davidovic, D. oth Adzic, R.R. oth in Electrochimica Acta Amsterdam : Elsevier 33(1988), 1, Seite 103-108 (DE-627)NLEJ17393191X (DE-600)1483548-4 0013-4686 nnns volume:33 year:1988 number:1 pages:103-108 http://linkinghub.elsevier.com/retrieve/pii/0013-4686(88)80039-2 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 33 1988 1 103-108 |
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(DE-627)NLEJ173955614 (DE-599)GBVNLZ173955614 DE-627 ger DE-627 rakwb eng Electrocatalytic and morphological effects of antimony adsorbates on deposition of gold 1988 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The electrodeposition of Au was studied in the presence of the Sb adsorbates. Large catalytic and morphological effects were found. A deposition of Au is shifted by 250 mV to more positive potentials. The nucleation of Au changes from instantaneous in the absence of Sb, into a progressive one in its presence. The catalytic effects of Sb have been explained by its influence on adsorption of CN^--containing species, which suppresses the selfinhibition of this reaction. It has been clearly shown that the adatoms of Sb cannot play a role of nucleation sites, which was proposed earlier as a cause of catalytic effects. No evidence of incorporation of Sb into a deposit was found. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Davidovic, D. oth Adzic, R.R. oth in Electrochimica Acta Amsterdam : Elsevier 33(1988), 1, Seite 103-108 (DE-627)NLEJ17393191X (DE-600)1483548-4 0013-4686 nnns volume:33 year:1988 number:1 pages:103-108 http://linkinghub.elsevier.com/retrieve/pii/0013-4686(88)80039-2 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 33 1988 1 103-108 |
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(DE-627)NLEJ173955614 (DE-599)GBVNLZ173955614 DE-627 ger DE-627 rakwb eng Electrocatalytic and morphological effects of antimony adsorbates on deposition of gold 1988 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The electrodeposition of Au was studied in the presence of the Sb adsorbates. Large catalytic and morphological effects were found. A deposition of Au is shifted by 250 mV to more positive potentials. The nucleation of Au changes from instantaneous in the absence of Sb, into a progressive one in its presence. The catalytic effects of Sb have been explained by its influence on adsorption of CN^--containing species, which suppresses the selfinhibition of this reaction. It has been clearly shown that the adatoms of Sb cannot play a role of nucleation sites, which was proposed earlier as a cause of catalytic effects. No evidence of incorporation of Sb into a deposit was found. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Davidovic, D. oth Adzic, R.R. oth in Electrochimica Acta Amsterdam : Elsevier 33(1988), 1, Seite 103-108 (DE-627)NLEJ17393191X (DE-600)1483548-4 0013-4686 nnns volume:33 year:1988 number:1 pages:103-108 http://linkinghub.elsevier.com/retrieve/pii/0013-4686(88)80039-2 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 33 1988 1 103-108 |
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(DE-627)NLEJ173955614 (DE-599)GBVNLZ173955614 DE-627 ger DE-627 rakwb eng Electrocatalytic and morphological effects of antimony adsorbates on deposition of gold 1988 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The electrodeposition of Au was studied in the presence of the Sb adsorbates. Large catalytic and morphological effects were found. A deposition of Au is shifted by 250 mV to more positive potentials. The nucleation of Au changes from instantaneous in the absence of Sb, into a progressive one in its presence. The catalytic effects of Sb have been explained by its influence on adsorption of CN^--containing species, which suppresses the selfinhibition of this reaction. It has been clearly shown that the adatoms of Sb cannot play a role of nucleation sites, which was proposed earlier as a cause of catalytic effects. No evidence of incorporation of Sb into a deposit was found. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Davidovic, D. oth Adzic, R.R. oth in Electrochimica Acta Amsterdam : Elsevier 33(1988), 1, Seite 103-108 (DE-627)NLEJ17393191X (DE-600)1483548-4 0013-4686 nnns volume:33 year:1988 number:1 pages:103-108 http://linkinghub.elsevier.com/retrieve/pii/0013-4686(88)80039-2 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 33 1988 1 103-108 |
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(DE-627)NLEJ173955614 (DE-599)GBVNLZ173955614 DE-627 ger DE-627 rakwb eng Electrocatalytic and morphological effects of antimony adsorbates on deposition of gold 1988 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The electrodeposition of Au was studied in the presence of the Sb adsorbates. Large catalytic and morphological effects were found. A deposition of Au is shifted by 250 mV to more positive potentials. The nucleation of Au changes from instantaneous in the absence of Sb, into a progressive one in its presence. The catalytic effects of Sb have been explained by its influence on adsorption of CN^--containing species, which suppresses the selfinhibition of this reaction. It has been clearly shown that the adatoms of Sb cannot play a role of nucleation sites, which was proposed earlier as a cause of catalytic effects. No evidence of incorporation of Sb into a deposit was found. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Davidovic, D. oth Adzic, R.R. oth in Electrochimica Acta Amsterdam : Elsevier 33(1988), 1, Seite 103-108 (DE-627)NLEJ17393191X (DE-600)1483548-4 0013-4686 nnns volume:33 year:1988 number:1 pages:103-108 http://linkinghub.elsevier.com/retrieve/pii/0013-4686(88)80039-2 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 33 1988 1 103-108 |
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Electrocatalytic and morphological effects of antimony adsorbates on deposition of gold |
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The electrodeposition of Au was studied in the presence of the Sb adsorbates. Large catalytic and morphological effects were found. A deposition of Au is shifted by 250 mV to more positive potentials. The nucleation of Au changes from instantaneous in the absence of Sb, into a progressive one in its presence. The catalytic effects of Sb have been explained by its influence on adsorption of CN^--containing species, which suppresses the selfinhibition of this reaction. It has been clearly shown that the adatoms of Sb cannot play a role of nucleation sites, which was proposed earlier as a cause of catalytic effects. No evidence of incorporation of Sb into a deposit was found. |
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The electrodeposition of Au was studied in the presence of the Sb adsorbates. Large catalytic and morphological effects were found. A deposition of Au is shifted by 250 mV to more positive potentials. The nucleation of Au changes from instantaneous in the absence of Sb, into a progressive one in its presence. The catalytic effects of Sb have been explained by its influence on adsorption of CN^--containing species, which suppresses the selfinhibition of this reaction. It has been clearly shown that the adatoms of Sb cannot play a role of nucleation sites, which was proposed earlier as a cause of catalytic effects. No evidence of incorporation of Sb into a deposit was found. |
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The electrodeposition of Au was studied in the presence of the Sb adsorbates. Large catalytic and morphological effects were found. A deposition of Au is shifted by 250 mV to more positive potentials. The nucleation of Au changes from instantaneous in the absence of Sb, into a progressive one in its presence. The catalytic effects of Sb have been explained by its influence on adsorption of CN^--containing species, which suppresses the selfinhibition of this reaction. It has been clearly shown that the adatoms of Sb cannot play a role of nucleation sites, which was proposed earlier as a cause of catalytic effects. No evidence of incorporation of Sb into a deposit was found. |
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