NR/SBR composites reinforced with organically functionalized MWCNTs: simultaneous improvement of tensile strength and elongation and enhanced thermal stability
Butyl acrylate-α-methyl methacrylate-glycidyl methacrylate (BA-MMA-GMA) terpolymer was successfully grafted onto carbon nanotubes (CNTs) via a facile grafting functionalization approach, affording an organically functionalized multiwalled CNTs (O-MWCNTs), which show improved mechanical and thermal p...
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E-Artikel |
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De Gruyter ; 2016 |
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6 |
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Walter de Gruyter Online Zeitschriften |
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Enthalten in: Journal of polymer engineering - Berlin : de Gruyter, 1984, 36(2016), 8 vom: 20. Jan., Seite 813-818 |
| Übergeordnetes Werk: |
volume:36 ; year:2016 ; number:8 ; day:20 ; month:01 ; pages:813-818 ; extent:6 |
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| DOI / URN: |
10.1515/polyeng-2015-0136 |
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NLEJ248140523 |
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| 520 | |a Butyl acrylate-α-methyl methacrylate-glycidyl methacrylate (BA-MMA-GMA) terpolymer was successfully grafted onto carbon nanotubes (CNTs) via a facile grafting functionalization approach, affording an organically functionalized multiwalled CNTs (O-MWCNTs), which show improved mechanical and thermal properties in natural rubber/styrene-butadiene rubber (NR/SBR) composites. Under optimized conditions, the result of elongation at break of NR/SBR composites combined with 1.5 parts per hundred rubber (phr) O-MWCNTs is 450% compared to 376% of pristine NR/SBR composites, which is proportional to tensile strength due to the mixed O-MWCNTs in the rubber matrix. Transmission electron microscopy study shows that O-MWCNTs (1.5 phr) can disperse uniformly in NR/SBR/O-MWCNT composites. A scanning electron microscopy study on the fractured surface morphology of the optimized composites reveals that a BA-MMA-GMA terpolymer can interact with the rubber matrix strongly. The decreased height of the maximum tanδ peak shows that O-MWCNTs can reduce the heat buildup and damping capability of NR/SBR/O-MWCNT composites. The largest enhancement observed in the thermal degradation curves of composites is, for the first time, about 70°C, which can be attributed to enhanced interfacial interaction between MWCNTs and the rubber matrix. | ||
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| 700 | 1 | |a Wang, Huihui |4 oth | |
| 700 | 1 | |a Chen, Jinyang |4 oth | |
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10.1515/polyeng-2015-0136 doi articles2015-2020.pp (DE-627)NLEJ248140523 DE-627 ger DE-627 rakwb NR/SBR composites reinforced with organically functionalized MWCNTs: simultaneous improvement of tensile strength and elongation and enhanced thermal stability De Gruyter 2016 6 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Butyl acrylate-α-methyl methacrylate-glycidyl methacrylate (BA-MMA-GMA) terpolymer was successfully grafted onto carbon nanotubes (CNTs) via a facile grafting functionalization approach, affording an organically functionalized multiwalled CNTs (O-MWCNTs), which show improved mechanical and thermal properties in natural rubber/styrene-butadiene rubber (NR/SBR) composites. Under optimized conditions, the result of elongation at break of NR/SBR composites combined with 1.5 parts per hundred rubber (phr) O-MWCNTs is 450% compared to 376% of pristine NR/SBR composites, which is proportional to tensile strength due to the mixed O-MWCNTs in the rubber matrix. Transmission electron microscopy study shows that O-MWCNTs (1.5 phr) can disperse uniformly in NR/SBR/O-MWCNT composites. A scanning electron microscopy study on the fractured surface morphology of the optimized composites reveals that a BA-MMA-GMA terpolymer can interact with the rubber matrix strongly. The decreased height of the maximum tanδ peak shows that O-MWCNTs can reduce the heat buildup and damping capability of NR/SBR/O-MWCNT composites. The largest enhancement observed in the thermal degradation curves of composites is, for the first time, about 70°C, which can be attributed to enhanced interfacial interaction between MWCNTs and the rubber matrix. Walter de Gruyter Online Zeitschriften carbon nanotubes interfacial interaction rubber matrix Li, Minghua oth Tu, Weixiao oth Chen, Xinfeng oth Wang, Huihui oth Chen, Jinyang oth Enthalten in Journal of polymer engineering Berlin : de Gruyter, 1984 36(2016), 8 vom: 20. Jan., Seite 813-818 (DE-627)NLEJ248236601 (DE-600)2602430-5 2191-0340 nnns volume:36 year:2016 number:8 day:20 month:01 pages:813-818 extent:6 https://doi.org/10.1515/polyeng-2015-0136 Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-DGR GBV_NL_ARTICLE AR 36 2016 8 20 1 813-818 6 |
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10.1515/polyeng-2015-0136 doi articles2015-2020.pp (DE-627)NLEJ248140523 DE-627 ger DE-627 rakwb NR/SBR composites reinforced with organically functionalized MWCNTs: simultaneous improvement of tensile strength and elongation and enhanced thermal stability De Gruyter 2016 6 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Butyl acrylate-α-methyl methacrylate-glycidyl methacrylate (BA-MMA-GMA) terpolymer was successfully grafted onto carbon nanotubes (CNTs) via a facile grafting functionalization approach, affording an organically functionalized multiwalled CNTs (O-MWCNTs), which show improved mechanical and thermal properties in natural rubber/styrene-butadiene rubber (NR/SBR) composites. Under optimized conditions, the result of elongation at break of NR/SBR composites combined with 1.5 parts per hundred rubber (phr) O-MWCNTs is 450% compared to 376% of pristine NR/SBR composites, which is proportional to tensile strength due to the mixed O-MWCNTs in the rubber matrix. Transmission electron microscopy study shows that O-MWCNTs (1.5 phr) can disperse uniformly in NR/SBR/O-MWCNT composites. A scanning electron microscopy study on the fractured surface morphology of the optimized composites reveals that a BA-MMA-GMA terpolymer can interact with the rubber matrix strongly. The decreased height of the maximum tanδ peak shows that O-MWCNTs can reduce the heat buildup and damping capability of NR/SBR/O-MWCNT composites. The largest enhancement observed in the thermal degradation curves of composites is, for the first time, about 70°C, which can be attributed to enhanced interfacial interaction between MWCNTs and the rubber matrix. Walter de Gruyter Online Zeitschriften carbon nanotubes interfacial interaction rubber matrix Li, Minghua oth Tu, Weixiao oth Chen, Xinfeng oth Wang, Huihui oth Chen, Jinyang oth Enthalten in Journal of polymer engineering Berlin : de Gruyter, 1984 36(2016), 8 vom: 20. Jan., Seite 813-818 (DE-627)NLEJ248236601 (DE-600)2602430-5 2191-0340 nnns volume:36 year:2016 number:8 day:20 month:01 pages:813-818 extent:6 https://doi.org/10.1515/polyeng-2015-0136 Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-DGR GBV_NL_ARTICLE AR 36 2016 8 20 1 813-818 6 |
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10.1515/polyeng-2015-0136 doi articles2015-2020.pp (DE-627)NLEJ248140523 DE-627 ger DE-627 rakwb NR/SBR composites reinforced with organically functionalized MWCNTs: simultaneous improvement of tensile strength and elongation and enhanced thermal stability De Gruyter 2016 6 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Butyl acrylate-α-methyl methacrylate-glycidyl methacrylate (BA-MMA-GMA) terpolymer was successfully grafted onto carbon nanotubes (CNTs) via a facile grafting functionalization approach, affording an organically functionalized multiwalled CNTs (O-MWCNTs), which show improved mechanical and thermal properties in natural rubber/styrene-butadiene rubber (NR/SBR) composites. Under optimized conditions, the result of elongation at break of NR/SBR composites combined with 1.5 parts per hundred rubber (phr) O-MWCNTs is 450% compared to 376% of pristine NR/SBR composites, which is proportional to tensile strength due to the mixed O-MWCNTs in the rubber matrix. Transmission electron microscopy study shows that O-MWCNTs (1.5 phr) can disperse uniformly in NR/SBR/O-MWCNT composites. A scanning electron microscopy study on the fractured surface morphology of the optimized composites reveals that a BA-MMA-GMA terpolymer can interact with the rubber matrix strongly. The decreased height of the maximum tanδ peak shows that O-MWCNTs can reduce the heat buildup and damping capability of NR/SBR/O-MWCNT composites. The largest enhancement observed in the thermal degradation curves of composites is, for the first time, about 70°C, which can be attributed to enhanced interfacial interaction between MWCNTs and the rubber matrix. Walter de Gruyter Online Zeitschriften carbon nanotubes interfacial interaction rubber matrix Li, Minghua oth Tu, Weixiao oth Chen, Xinfeng oth Wang, Huihui oth Chen, Jinyang oth Enthalten in Journal of polymer engineering Berlin : de Gruyter, 1984 36(2016), 8 vom: 20. Jan., Seite 813-818 (DE-627)NLEJ248236601 (DE-600)2602430-5 2191-0340 nnns volume:36 year:2016 number:8 day:20 month:01 pages:813-818 extent:6 https://doi.org/10.1515/polyeng-2015-0136 Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-DGR GBV_NL_ARTICLE AR 36 2016 8 20 1 813-818 6 |
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10.1515/polyeng-2015-0136 doi articles2015-2020.pp (DE-627)NLEJ248140523 DE-627 ger DE-627 rakwb NR/SBR composites reinforced with organically functionalized MWCNTs: simultaneous improvement of tensile strength and elongation and enhanced thermal stability De Gruyter 2016 6 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Butyl acrylate-α-methyl methacrylate-glycidyl methacrylate (BA-MMA-GMA) terpolymer was successfully grafted onto carbon nanotubes (CNTs) via a facile grafting functionalization approach, affording an organically functionalized multiwalled CNTs (O-MWCNTs), which show improved mechanical and thermal properties in natural rubber/styrene-butadiene rubber (NR/SBR) composites. Under optimized conditions, the result of elongation at break of NR/SBR composites combined with 1.5 parts per hundred rubber (phr) O-MWCNTs is 450% compared to 376% of pristine NR/SBR composites, which is proportional to tensile strength due to the mixed O-MWCNTs in the rubber matrix. Transmission electron microscopy study shows that O-MWCNTs (1.5 phr) can disperse uniformly in NR/SBR/O-MWCNT composites. A scanning electron microscopy study on the fractured surface morphology of the optimized composites reveals that a BA-MMA-GMA terpolymer can interact with the rubber matrix strongly. The decreased height of the maximum tanδ peak shows that O-MWCNTs can reduce the heat buildup and damping capability of NR/SBR/O-MWCNT composites. The largest enhancement observed in the thermal degradation curves of composites is, for the first time, about 70°C, which can be attributed to enhanced interfacial interaction between MWCNTs and the rubber matrix. Walter de Gruyter Online Zeitschriften carbon nanotubes interfacial interaction rubber matrix Li, Minghua oth Tu, Weixiao oth Chen, Xinfeng oth Wang, Huihui oth Chen, Jinyang oth Enthalten in Journal of polymer engineering Berlin : de Gruyter, 1984 36(2016), 8 vom: 20. Jan., Seite 813-818 (DE-627)NLEJ248236601 (DE-600)2602430-5 2191-0340 nnns volume:36 year:2016 number:8 day:20 month:01 pages:813-818 extent:6 https://doi.org/10.1515/polyeng-2015-0136 Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-DGR GBV_NL_ARTICLE AR 36 2016 8 20 1 813-818 6 |
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10.1515/polyeng-2015-0136 doi articles2015-2020.pp (DE-627)NLEJ248140523 DE-627 ger DE-627 rakwb NR/SBR composites reinforced with organically functionalized MWCNTs: simultaneous improvement of tensile strength and elongation and enhanced thermal stability De Gruyter 2016 6 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Butyl acrylate-α-methyl methacrylate-glycidyl methacrylate (BA-MMA-GMA) terpolymer was successfully grafted onto carbon nanotubes (CNTs) via a facile grafting functionalization approach, affording an organically functionalized multiwalled CNTs (O-MWCNTs), which show improved mechanical and thermal properties in natural rubber/styrene-butadiene rubber (NR/SBR) composites. Under optimized conditions, the result of elongation at break of NR/SBR composites combined with 1.5 parts per hundred rubber (phr) O-MWCNTs is 450% compared to 376% of pristine NR/SBR composites, which is proportional to tensile strength due to the mixed O-MWCNTs in the rubber matrix. Transmission electron microscopy study shows that O-MWCNTs (1.5 phr) can disperse uniformly in NR/SBR/O-MWCNT composites. A scanning electron microscopy study on the fractured surface morphology of the optimized composites reveals that a BA-MMA-GMA terpolymer can interact with the rubber matrix strongly. The decreased height of the maximum tanδ peak shows that O-MWCNTs can reduce the heat buildup and damping capability of NR/SBR/O-MWCNT composites. The largest enhancement observed in the thermal degradation curves of composites is, for the first time, about 70°C, which can be attributed to enhanced interfacial interaction between MWCNTs and the rubber matrix. Walter de Gruyter Online Zeitschriften carbon nanotubes interfacial interaction rubber matrix Li, Minghua oth Tu, Weixiao oth Chen, Xinfeng oth Wang, Huihui oth Chen, Jinyang oth Enthalten in Journal of polymer engineering Berlin : de Gruyter, 1984 36(2016), 8 vom: 20. Jan., Seite 813-818 (DE-627)NLEJ248236601 (DE-600)2602430-5 2191-0340 nnns volume:36 year:2016 number:8 day:20 month:01 pages:813-818 extent:6 https://doi.org/10.1515/polyeng-2015-0136 Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-DGR GBV_NL_ARTICLE AR 36 2016 8 20 1 813-818 6 |
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nr/sbr composites reinforced with organically functionalized mwcnts: simultaneous improvement of tensile strength and elongation and enhanced thermal stability |
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NR/SBR composites reinforced with organically functionalized MWCNTs: simultaneous improvement of tensile strength and elongation and enhanced thermal stability |
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Butyl acrylate-α-methyl methacrylate-glycidyl methacrylate (BA-MMA-GMA) terpolymer was successfully grafted onto carbon nanotubes (CNTs) via a facile grafting functionalization approach, affording an organically functionalized multiwalled CNTs (O-MWCNTs), which show improved mechanical and thermal properties in natural rubber/styrene-butadiene rubber (NR/SBR) composites. Under optimized conditions, the result of elongation at break of NR/SBR composites combined with 1.5 parts per hundred rubber (phr) O-MWCNTs is 450% compared to 376% of pristine NR/SBR composites, which is proportional to tensile strength due to the mixed O-MWCNTs in the rubber matrix. Transmission electron microscopy study shows that O-MWCNTs (1.5 phr) can disperse uniformly in NR/SBR/O-MWCNT composites. A scanning electron microscopy study on the fractured surface morphology of the optimized composites reveals that a BA-MMA-GMA terpolymer can interact with the rubber matrix strongly. The decreased height of the maximum tanδ peak shows that O-MWCNTs can reduce the heat buildup and damping capability of NR/SBR/O-MWCNT composites. The largest enhancement observed in the thermal degradation curves of composites is, for the first time, about 70°C, which can be attributed to enhanced interfacial interaction between MWCNTs and the rubber matrix. |
| abstractGer |
Butyl acrylate-α-methyl methacrylate-glycidyl methacrylate (BA-MMA-GMA) terpolymer was successfully grafted onto carbon nanotubes (CNTs) via a facile grafting functionalization approach, affording an organically functionalized multiwalled CNTs (O-MWCNTs), which show improved mechanical and thermal properties in natural rubber/styrene-butadiene rubber (NR/SBR) composites. Under optimized conditions, the result of elongation at break of NR/SBR composites combined with 1.5 parts per hundred rubber (phr) O-MWCNTs is 450% compared to 376% of pristine NR/SBR composites, which is proportional to tensile strength due to the mixed O-MWCNTs in the rubber matrix. Transmission electron microscopy study shows that O-MWCNTs (1.5 phr) can disperse uniformly in NR/SBR/O-MWCNT composites. A scanning electron microscopy study on the fractured surface morphology of the optimized composites reveals that a BA-MMA-GMA terpolymer can interact with the rubber matrix strongly. The decreased height of the maximum tanδ peak shows that O-MWCNTs can reduce the heat buildup and damping capability of NR/SBR/O-MWCNT composites. The largest enhancement observed in the thermal degradation curves of composites is, for the first time, about 70°C, which can be attributed to enhanced interfacial interaction between MWCNTs and the rubber matrix. |
| abstract_unstemmed |
Butyl acrylate-α-methyl methacrylate-glycidyl methacrylate (BA-MMA-GMA) terpolymer was successfully grafted onto carbon nanotubes (CNTs) via a facile grafting functionalization approach, affording an organically functionalized multiwalled CNTs (O-MWCNTs), which show improved mechanical and thermal properties in natural rubber/styrene-butadiene rubber (NR/SBR) composites. Under optimized conditions, the result of elongation at break of NR/SBR composites combined with 1.5 parts per hundred rubber (phr) O-MWCNTs is 450% compared to 376% of pristine NR/SBR composites, which is proportional to tensile strength due to the mixed O-MWCNTs in the rubber matrix. Transmission electron microscopy study shows that O-MWCNTs (1.5 phr) can disperse uniformly in NR/SBR/O-MWCNT composites. A scanning electron microscopy study on the fractured surface morphology of the optimized composites reveals that a BA-MMA-GMA terpolymer can interact with the rubber matrix strongly. The decreased height of the maximum tanδ peak shows that O-MWCNTs can reduce the heat buildup and damping capability of NR/SBR/O-MWCNT composites. The largest enhancement observed in the thermal degradation curves of composites is, for the first time, about 70°C, which can be attributed to enhanced interfacial interaction between MWCNTs and the rubber matrix. |
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NR/SBR composites reinforced with organically functionalized MWCNTs: simultaneous improvement of tensile strength and elongation and enhanced thermal stability |
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Li, Minghua Tu, Weixiao Chen, Xinfeng Wang, Huihui Chen, Jinyang |
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