Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates
The photochemistry of an expired Alpha Lipoic Acid-based drug namely MEGO-XL (ML) was investigated. ML showed its application in selective sensing of $ Fe^{3+} $ and $ Pb^{2+} $ avoiding any interference. The lower detection limit values for $ Fe^{3+} $ (1.51 × $ 10^{−4} $ M) and $ Pb^{2+} $ (72.8 µ...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Nadgir, Aishwarya [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
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| Anmerkung: |
© Indian Academy of Sciences 2022 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of chemical sciences - Bangalore : Indian Academy of Science, 1980, 134(2022), 1 vom: 10. Jan. |
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| Übergeordnetes Werk: |
volume:134 ; year:2022 ; number:1 ; day:10 ; month:01 |
| Links: |
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| DOI / URN: |
10.1007/s12039-021-02008-y |
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| Katalog-ID: |
SPR04594556X |
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| 100 | 1 | |a Nadgir, Aishwarya |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates |
| 264 | 1 | |c 2022 | |
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| 520 | |a The photochemistry of an expired Alpha Lipoic Acid-based drug namely MEGO-XL (ML) was investigated. ML showed its application in selective sensing of $ Fe^{3+} $ and $ Pb^{2+} $ avoiding any interference. The lower detection limit values for $ Fe^{3+} $ (1.51 × $ 10^{−4} $ M) and $ Pb^{2+} $ (72.8 µM) suggested the sensitive nature of ML. The stability of the compound was examined under different environmental conditions. Further, the interaction between ML and $ Fe^{3+} $, $ Pb^{2+} $ was studied with the help of Stern–Volmer plots, Benesi–Hildebrand relation. Increased $ K_{SV} $ values with increased temperature suggested that the nature of quenching was purely dynamic in the case of $ Fe^{3+} $ and decreased $ K_{SV} $ values with increased temperature indicated that there might be an occurrence of static quenching in the case of $ Pb^{2+} $. Ethylenediaminetetra acetic acid (EDTA) was used to differentiate the detection of $ Fe^{3+} $ from $ Pb^{2+} $.ML also showed application in sensing $ TiO_{2} $ nanoparticles and in OR logic gate operations. These experimental outcomes hinted that the chosen expired drug ML can be reused for chemosensing and logic gate applications. Graphical abstract The dual-sensing nature [Fe(III) and Pb(II)] of ML is described through Intensity Vs Wavelength graphs. TiO2 sensing nature of ML is also described by KSV graph. The logic gate application of ML is pictorially represented with a truth table and bar graph. | ||
| 650 | 4 | |a Expired drug |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Dual sensing |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Dynamic quenching |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Static quenching |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Logic gate |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Pujar, Malatesh S |4 aut | |
| 700 | 1 | |a Patil, Shivaprasadagouda |4 aut | |
| 700 | 1 | |a Sidarai, Ashok H |4 aut | |
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10.1007/s12039-021-02008-y doi (DE-627)SPR04594556X (SPR)s12039-021-02008-y-e DE-627 ger DE-627 rakwb eng Nadgir, Aishwarya verfasserin aut Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Indian Academy of Sciences 2022 The photochemistry of an expired Alpha Lipoic Acid-based drug namely MEGO-XL (ML) was investigated. ML showed its application in selective sensing of $ Fe^{3+} $ and $ Pb^{2+} $ avoiding any interference. The lower detection limit values for $ Fe^{3+} $ (1.51 × $ 10^{−4} $ M) and $ Pb^{2+} $ (72.8 µM) suggested the sensitive nature of ML. The stability of the compound was examined under different environmental conditions. Further, the interaction between ML and $ Fe^{3+} $, $ Pb^{2+} $ was studied with the help of Stern–Volmer plots, Benesi–Hildebrand relation. Increased $ K_{SV} $ values with increased temperature suggested that the nature of quenching was purely dynamic in the case of $ Fe^{3+} $ and decreased $ K_{SV} $ values with increased temperature indicated that there might be an occurrence of static quenching in the case of $ Pb^{2+} $. Ethylenediaminetetra acetic acid (EDTA) was used to differentiate the detection of $ Fe^{3+} $ from $ Pb^{2+} $.ML also showed application in sensing $ TiO_{2} $ nanoparticles and in OR logic gate operations. These experimental outcomes hinted that the chosen expired drug ML can be reused for chemosensing and logic gate applications. Graphical abstract The dual-sensing nature [Fe(III) and Pb(II)] of ML is described through Intensity Vs Wavelength graphs. TiO2 sensing nature of ML is also described by KSV graph. The logic gate application of ML is pictorially represented with a truth table and bar graph. Expired drug (dpeaa)DE-He213 Dual sensing (dpeaa)DE-He213 Dynamic quenching (dpeaa)DE-He213 Static quenching (dpeaa)DE-He213 Logic gate (dpeaa)DE-He213 Pujar, Malatesh S aut Patil, Shivaprasadagouda aut Sidarai, Ashok H aut Enthalten in Journal of chemical sciences Bangalore : Indian Academy of Science, 1980 134(2022), 1 vom: 10. Jan. (DE-627)338479384 (DE-600)2064209-X 0973-7103 nnns volume:134 year:2022 number:1 day:10 month:01 https://dx.doi.org/10.1007/s12039-021-02008-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 134 2022 1 10 01 |
| spelling |
10.1007/s12039-021-02008-y doi (DE-627)SPR04594556X (SPR)s12039-021-02008-y-e DE-627 ger DE-627 rakwb eng Nadgir, Aishwarya verfasserin aut Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Indian Academy of Sciences 2022 The photochemistry of an expired Alpha Lipoic Acid-based drug namely MEGO-XL (ML) was investigated. ML showed its application in selective sensing of $ Fe^{3+} $ and $ Pb^{2+} $ avoiding any interference. The lower detection limit values for $ Fe^{3+} $ (1.51 × $ 10^{−4} $ M) and $ Pb^{2+} $ (72.8 µM) suggested the sensitive nature of ML. The stability of the compound was examined under different environmental conditions. Further, the interaction between ML and $ Fe^{3+} $, $ Pb^{2+} $ was studied with the help of Stern–Volmer plots, Benesi–Hildebrand relation. Increased $ K_{SV} $ values with increased temperature suggested that the nature of quenching was purely dynamic in the case of $ Fe^{3+} $ and decreased $ K_{SV} $ values with increased temperature indicated that there might be an occurrence of static quenching in the case of $ Pb^{2+} $. Ethylenediaminetetra acetic acid (EDTA) was used to differentiate the detection of $ Fe^{3+} $ from $ Pb^{2+} $.ML also showed application in sensing $ TiO_{2} $ nanoparticles and in OR logic gate operations. These experimental outcomes hinted that the chosen expired drug ML can be reused for chemosensing and logic gate applications. Graphical abstract The dual-sensing nature [Fe(III) and Pb(II)] of ML is described through Intensity Vs Wavelength graphs. TiO2 sensing nature of ML is also described by KSV graph. The logic gate application of ML is pictorially represented with a truth table and bar graph. Expired drug (dpeaa)DE-He213 Dual sensing (dpeaa)DE-He213 Dynamic quenching (dpeaa)DE-He213 Static quenching (dpeaa)DE-He213 Logic gate (dpeaa)DE-He213 Pujar, Malatesh S aut Patil, Shivaprasadagouda aut Sidarai, Ashok H aut Enthalten in Journal of chemical sciences Bangalore : Indian Academy of Science, 1980 134(2022), 1 vom: 10. Jan. (DE-627)338479384 (DE-600)2064209-X 0973-7103 nnns volume:134 year:2022 number:1 day:10 month:01 https://dx.doi.org/10.1007/s12039-021-02008-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 134 2022 1 10 01 |
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10.1007/s12039-021-02008-y doi (DE-627)SPR04594556X (SPR)s12039-021-02008-y-e DE-627 ger DE-627 rakwb eng Nadgir, Aishwarya verfasserin aut Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Indian Academy of Sciences 2022 The photochemistry of an expired Alpha Lipoic Acid-based drug namely MEGO-XL (ML) was investigated. ML showed its application in selective sensing of $ Fe^{3+} $ and $ Pb^{2+} $ avoiding any interference. The lower detection limit values for $ Fe^{3+} $ (1.51 × $ 10^{−4} $ M) and $ Pb^{2+} $ (72.8 µM) suggested the sensitive nature of ML. The stability of the compound was examined under different environmental conditions. Further, the interaction between ML and $ Fe^{3+} $, $ Pb^{2+} $ was studied with the help of Stern–Volmer plots, Benesi–Hildebrand relation. Increased $ K_{SV} $ values with increased temperature suggested that the nature of quenching was purely dynamic in the case of $ Fe^{3+} $ and decreased $ K_{SV} $ values with increased temperature indicated that there might be an occurrence of static quenching in the case of $ Pb^{2+} $. Ethylenediaminetetra acetic acid (EDTA) was used to differentiate the detection of $ Fe^{3+} $ from $ Pb^{2+} $.ML also showed application in sensing $ TiO_{2} $ nanoparticles and in OR logic gate operations. These experimental outcomes hinted that the chosen expired drug ML can be reused for chemosensing and logic gate applications. Graphical abstract The dual-sensing nature [Fe(III) and Pb(II)] of ML is described through Intensity Vs Wavelength graphs. TiO2 sensing nature of ML is also described by KSV graph. The logic gate application of ML is pictorially represented with a truth table and bar graph. Expired drug (dpeaa)DE-He213 Dual sensing (dpeaa)DE-He213 Dynamic quenching (dpeaa)DE-He213 Static quenching (dpeaa)DE-He213 Logic gate (dpeaa)DE-He213 Pujar, Malatesh S aut Patil, Shivaprasadagouda aut Sidarai, Ashok H aut Enthalten in Journal of chemical sciences Bangalore : Indian Academy of Science, 1980 134(2022), 1 vom: 10. Jan. (DE-627)338479384 (DE-600)2064209-X 0973-7103 nnns volume:134 year:2022 number:1 day:10 month:01 https://dx.doi.org/10.1007/s12039-021-02008-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 134 2022 1 10 01 |
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10.1007/s12039-021-02008-y doi (DE-627)SPR04594556X (SPR)s12039-021-02008-y-e DE-627 ger DE-627 rakwb eng Nadgir, Aishwarya verfasserin aut Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Indian Academy of Sciences 2022 The photochemistry of an expired Alpha Lipoic Acid-based drug namely MEGO-XL (ML) was investigated. ML showed its application in selective sensing of $ Fe^{3+} $ and $ Pb^{2+} $ avoiding any interference. The lower detection limit values for $ Fe^{3+} $ (1.51 × $ 10^{−4} $ M) and $ Pb^{2+} $ (72.8 µM) suggested the sensitive nature of ML. The stability of the compound was examined under different environmental conditions. Further, the interaction between ML and $ Fe^{3+} $, $ Pb^{2+} $ was studied with the help of Stern–Volmer plots, Benesi–Hildebrand relation. Increased $ K_{SV} $ values with increased temperature suggested that the nature of quenching was purely dynamic in the case of $ Fe^{3+} $ and decreased $ K_{SV} $ values with increased temperature indicated that there might be an occurrence of static quenching in the case of $ Pb^{2+} $. Ethylenediaminetetra acetic acid (EDTA) was used to differentiate the detection of $ Fe^{3+} $ from $ Pb^{2+} $.ML also showed application in sensing $ TiO_{2} $ nanoparticles and in OR logic gate operations. These experimental outcomes hinted that the chosen expired drug ML can be reused for chemosensing and logic gate applications. Graphical abstract The dual-sensing nature [Fe(III) and Pb(II)] of ML is described through Intensity Vs Wavelength graphs. TiO2 sensing nature of ML is also described by KSV graph. The logic gate application of ML is pictorially represented with a truth table and bar graph. Expired drug (dpeaa)DE-He213 Dual sensing (dpeaa)DE-He213 Dynamic quenching (dpeaa)DE-He213 Static quenching (dpeaa)DE-He213 Logic gate (dpeaa)DE-He213 Pujar, Malatesh S aut Patil, Shivaprasadagouda aut Sidarai, Ashok H aut Enthalten in Journal of chemical sciences Bangalore : Indian Academy of Science, 1980 134(2022), 1 vom: 10. Jan. (DE-627)338479384 (DE-600)2064209-X 0973-7103 nnns volume:134 year:2022 number:1 day:10 month:01 https://dx.doi.org/10.1007/s12039-021-02008-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 134 2022 1 10 01 |
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10.1007/s12039-021-02008-y doi (DE-627)SPR04594556X (SPR)s12039-021-02008-y-e DE-627 ger DE-627 rakwb eng Nadgir, Aishwarya verfasserin aut Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Indian Academy of Sciences 2022 The photochemistry of an expired Alpha Lipoic Acid-based drug namely MEGO-XL (ML) was investigated. ML showed its application in selective sensing of $ Fe^{3+} $ and $ Pb^{2+} $ avoiding any interference. The lower detection limit values for $ Fe^{3+} $ (1.51 × $ 10^{−4} $ M) and $ Pb^{2+} $ (72.8 µM) suggested the sensitive nature of ML. The stability of the compound was examined under different environmental conditions. Further, the interaction between ML and $ Fe^{3+} $, $ Pb^{2+} $ was studied with the help of Stern–Volmer plots, Benesi–Hildebrand relation. Increased $ K_{SV} $ values with increased temperature suggested that the nature of quenching was purely dynamic in the case of $ Fe^{3+} $ and decreased $ K_{SV} $ values with increased temperature indicated that there might be an occurrence of static quenching in the case of $ Pb^{2+} $. Ethylenediaminetetra acetic acid (EDTA) was used to differentiate the detection of $ Fe^{3+} $ from $ Pb^{2+} $.ML also showed application in sensing $ TiO_{2} $ nanoparticles and in OR logic gate operations. These experimental outcomes hinted that the chosen expired drug ML can be reused for chemosensing and logic gate applications. Graphical abstract The dual-sensing nature [Fe(III) and Pb(II)] of ML is described through Intensity Vs Wavelength graphs. TiO2 sensing nature of ML is also described by KSV graph. The logic gate application of ML is pictorially represented with a truth table and bar graph. Expired drug (dpeaa)DE-He213 Dual sensing (dpeaa)DE-He213 Dynamic quenching (dpeaa)DE-He213 Static quenching (dpeaa)DE-He213 Logic gate (dpeaa)DE-He213 Pujar, Malatesh S aut Patil, Shivaprasadagouda aut Sidarai, Ashok H aut Enthalten in Journal of chemical sciences Bangalore : Indian Academy of Science, 1980 134(2022), 1 vom: 10. Jan. (DE-627)338479384 (DE-600)2064209-X 0973-7103 nnns volume:134 year:2022 number:1 day:10 month:01 https://dx.doi.org/10.1007/s12039-021-02008-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 134 2022 1 10 01 |
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Nadgir, Aishwarya @@aut@@ Pujar, Malatesh S @@aut@@ Patil, Shivaprasadagouda @@aut@@ Sidarai, Ashok H @@aut@@ |
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ML showed its application in selective sensing of $ Fe^{3+} $ and $ Pb^{2+} $ avoiding any interference. The lower detection limit values for $ Fe^{3+} $ (1.51 × $ 10^{−4} $ M) and $ Pb^{2+} $ (72.8 µM) suggested the sensitive nature of ML. The stability of the compound was examined under different environmental conditions. Further, the interaction between ML and $ Fe^{3+} $, $ Pb^{2+} $ was studied with the help of Stern–Volmer plots, Benesi–Hildebrand relation. Increased $ K_{SV} $ values with increased temperature suggested that the nature of quenching was purely dynamic in the case of $ Fe^{3+} $ and decreased $ K_{SV} $ values with increased temperature indicated that there might be an occurrence of static quenching in the case of $ Pb^{2+} $. Ethylenediaminetetra acetic acid (EDTA) was used to differentiate the detection of $ Fe^{3+} $ from $ Pb^{2+} $.ML also showed application in sensing $ TiO_{2} $ nanoparticles and in OR logic gate operations. These experimental outcomes hinted that the chosen expired drug ML can be reused for chemosensing and logic gate applications. Graphical abstract The dual-sensing nature [Fe(III) and Pb(II)] of ML is described through Intensity Vs Wavelength graphs. TiO2 sensing nature of ML is also described by KSV graph. 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Nadgir, Aishwarya |
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Nadgir, Aishwarya misc Expired drug misc Dual sensing misc Dynamic quenching misc Static quenching misc Logic gate Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates |
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Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates Expired drug (dpeaa)DE-He213 Dual sensing (dpeaa)DE-He213 Dynamic quenching (dpeaa)DE-He213 Static quenching (dpeaa)DE-He213 Logic gate (dpeaa)DE-He213 |
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Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates |
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Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates |
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Nadgir, Aishwarya Pujar, Malatesh S Patil, Shivaprasadagouda Sidarai, Ashok H |
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photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of fe(iii) and pb(ii) and logic gates |
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Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates |
| abstract |
The photochemistry of an expired Alpha Lipoic Acid-based drug namely MEGO-XL (ML) was investigated. ML showed its application in selective sensing of $ Fe^{3+} $ and $ Pb^{2+} $ avoiding any interference. The lower detection limit values for $ Fe^{3+} $ (1.51 × $ 10^{−4} $ M) and $ Pb^{2+} $ (72.8 µM) suggested the sensitive nature of ML. The stability of the compound was examined under different environmental conditions. Further, the interaction between ML and $ Fe^{3+} $, $ Pb^{2+} $ was studied with the help of Stern–Volmer plots, Benesi–Hildebrand relation. Increased $ K_{SV} $ values with increased temperature suggested that the nature of quenching was purely dynamic in the case of $ Fe^{3+} $ and decreased $ K_{SV} $ values with increased temperature indicated that there might be an occurrence of static quenching in the case of $ Pb^{2+} $. Ethylenediaminetetra acetic acid (EDTA) was used to differentiate the detection of $ Fe^{3+} $ from $ Pb^{2+} $.ML also showed application in sensing $ TiO_{2} $ nanoparticles and in OR logic gate operations. These experimental outcomes hinted that the chosen expired drug ML can be reused for chemosensing and logic gate applications. Graphical abstract The dual-sensing nature [Fe(III) and Pb(II)] of ML is described through Intensity Vs Wavelength graphs. TiO2 sensing nature of ML is also described by KSV graph. The logic gate application of ML is pictorially represented with a truth table and bar graph. © Indian Academy of Sciences 2022 |
| abstractGer |
The photochemistry of an expired Alpha Lipoic Acid-based drug namely MEGO-XL (ML) was investigated. ML showed its application in selective sensing of $ Fe^{3+} $ and $ Pb^{2+} $ avoiding any interference. The lower detection limit values for $ Fe^{3+} $ (1.51 × $ 10^{−4} $ M) and $ Pb^{2+} $ (72.8 µM) suggested the sensitive nature of ML. The stability of the compound was examined under different environmental conditions. Further, the interaction between ML and $ Fe^{3+} $, $ Pb^{2+} $ was studied with the help of Stern–Volmer plots, Benesi–Hildebrand relation. Increased $ K_{SV} $ values with increased temperature suggested that the nature of quenching was purely dynamic in the case of $ Fe^{3+} $ and decreased $ K_{SV} $ values with increased temperature indicated that there might be an occurrence of static quenching in the case of $ Pb^{2+} $. Ethylenediaminetetra acetic acid (EDTA) was used to differentiate the detection of $ Fe^{3+} $ from $ Pb^{2+} $.ML also showed application in sensing $ TiO_{2} $ nanoparticles and in OR logic gate operations. These experimental outcomes hinted that the chosen expired drug ML can be reused for chemosensing and logic gate applications. Graphical abstract The dual-sensing nature [Fe(III) and Pb(II)] of ML is described through Intensity Vs Wavelength graphs. TiO2 sensing nature of ML is also described by KSV graph. The logic gate application of ML is pictorially represented with a truth table and bar graph. © Indian Academy of Sciences 2022 |
| abstract_unstemmed |
The photochemistry of an expired Alpha Lipoic Acid-based drug namely MEGO-XL (ML) was investigated. ML showed its application in selective sensing of $ Fe^{3+} $ and $ Pb^{2+} $ avoiding any interference. The lower detection limit values for $ Fe^{3+} $ (1.51 × $ 10^{−4} $ M) and $ Pb^{2+} $ (72.8 µM) suggested the sensitive nature of ML. The stability of the compound was examined under different environmental conditions. Further, the interaction between ML and $ Fe^{3+} $, $ Pb^{2+} $ was studied with the help of Stern–Volmer plots, Benesi–Hildebrand relation. Increased $ K_{SV} $ values with increased temperature suggested that the nature of quenching was purely dynamic in the case of $ Fe^{3+} $ and decreased $ K_{SV} $ values with increased temperature indicated that there might be an occurrence of static quenching in the case of $ Pb^{2+} $. Ethylenediaminetetra acetic acid (EDTA) was used to differentiate the detection of $ Fe^{3+} $ from $ Pb^{2+} $.ML also showed application in sensing $ TiO_{2} $ nanoparticles and in OR logic gate operations. These experimental outcomes hinted that the chosen expired drug ML can be reused for chemosensing and logic gate applications. Graphical abstract The dual-sensing nature [Fe(III) and Pb(II)] of ML is described through Intensity Vs Wavelength graphs. TiO2 sensing nature of ML is also described by KSV graph. The logic gate application of ML is pictorially represented with a truth table and bar graph. © Indian Academy of Sciences 2022 |
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Photochemistry of an alpha lipoic acid-based drug and its application in dual sensing of Fe(III) and Pb(II) and logic gates |
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https://dx.doi.org/10.1007/s12039-021-02008-y |
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Pujar, Malatesh S Patil, Shivaprasadagouda Sidarai, Ashok H |
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10.1007/s12039-021-02008-y |
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2024-07-03T19:19:41.300Z |
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|
| score |
7.4000816 |